690 MPA-GRADE MEDIUM MANGANESE STEEL MEDIUM THICK STEEL WITH HIGH STRENGTH AND LOW YIELD RATIO AND MANUFACTURING METHOD THEREFOR

Abstract

The present disclosure discloses a 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness and a manufacture method thereof, which relates to the technical field of steel smelting. The 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness is composed of the following chemical composition in mass percentage: C: 0.05%-0.10%, Mn: 4.1%-4.7%, Si: 0.15%-0.4%, P≤0.010%, S≤0.003%, Ti: 0.01%-0.05%, Ni+Cr+Mo≤0.6%, and the balance of Fe and unavoidable impurities. The steel plate manufactured meets the safety performance and construction cost requirements of the construction machinery on the ultra-high-strength steel in complex environments.

Claims

1. A 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness, wherein, the 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness is composed of the following chemical composition in mass percentage: C: 0.05%-0.10%, Mn: 4.1%-4.7%, Si: 0.15%-0.4%, P≤0.010%, S≤0.003%, Ti: 0.01%-0.05%, Ni+Cr+Mo≤0.6%, and the balance of Fe and unavoidable impurities.

2. The 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness according to claim 1, wherein, a thickness of a steel plate is less than 80 mm, and a yield ratio of the steel plate is less than 0.86.

3. The 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness according to claim 1, wherein, the 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness is composed of the following chemical composition in mass percentage: C: 0.09%-0.10%, Mn: 4.65%-4.7%, Si: 0.18%-0.22%, P≤0.010%, S≤0.003%, Ti: 0.022%-0.028%, Ni+Cr+Mo≤0.6%, and the balance of Fe and unavoidable impurities.

4. The 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness according to claim 1, wherein, the 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness is composed of the following chemical composition in mass percentage: C: 0.05%-0.06%, Mn: 4.23%-4.47%, Si: 0.20%-0.26%, P≤0.010%, S≤0.003%, Ti: 0.018%-0.026%, Ni+Cr+Mo≤0.6%, and the balance of Fe and unavoidable impurities.

5. The 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness according to claim 1, wherein, the 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness is composed of the following chemical composition in mass percentage: C: 0.05%-0.07%, Mn: 4.1%-4.28%, Si: 0.15%-0.21%, P≤0.010%, S≤0.003%, Ti: 0.033%-0.045%, Ni+Cr+Mo≤0.6%, and the balance of Fe and unavoidable impurities.

6. A method for manufacturing the 690 MPa high-strength medium-manganese steel with low yield ratio and medium thickness of claim 2, wherein, comprising: molten iron desulfurization treatment and converter smelting: reducing contents of P and S to be ≤0.010% and 0.003% in a molten steel, respectively; ladle furnace (LF) refining: alloying C, Mn, Si, Ti, Ni, Cr, and Mo in a required mass fraction; slab casting: a casting speed for a continuous casting slab being ≤1.0 m/min, and cleaning up surface defects; slab heating control: a temperature being 1060-1140° C., and a soaking time being 40-90 min; slab rolling control: performing a two-stage rolling process, wherein, an initial rolling temperature and a final rolling temperature in a first stage are ≤1020° C. and ≥920° C., respectively; and the initial rolling temperature and the final rolling temperature in a second stage are ≤890° C. ° C. and ≥800° C., respectively; post-rolling cooling control: a cooling rate being ≥5° C./s, and a self-tempering temperature of a surface of the steel plate after cooling being ≤350° C.; and post-rolling heat treatment: putting the steel plate into a heat treatment furnace for tempering within 48 hours after rolling; wherein, a tempering temperature is 600-650° C., and the soaking time is 40-70 min; the steel plate is air-cooled to room temperature after tempering.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0029] FIG. 1 is a metallographic structure diagram of a steel plate after performing heat treatment in Example 1 of the present disclosure.

DETAILED DESCRIPTION OF THE EMBODIMENTS

Example 1

[0030] This example provides the 690 MPa high-strength medium-manganese steel with low yield ratio and the thickness of 70 mm, including the following chemical composition in mass percentage: C: 0.09%, Mn: 4.65%, Si: 0.22%, P: 0.008%, S: 0.001%, Ti: 0.028%, Ni+Cr+Mo: 0.58%, and the balance of Fe and unavoidable impurities.

[0031] The method for manufacturing the steel plate is as follows:

[0032] Converter smelting is carried out after the molten iron desulfurization treatment is performed, so that the contents of S and P in the molten steel are reduced. C, Mn, Si, Ti, Ni, Cr, and Mo in the required mass fraction are alloyed after the ladle furnace (LF) refining is completed. The continuous casting method is adopted with the casting speed of the continuous casting slab being 0.5 m/min, and the surface defects are cleaned up, to obtain the slab with the thickness of 320 mm. The obtained slab is heated to 1130° C. with the soaking time of 70 min. The heated slab is performed with the two-stage rolling process. The initial rolling temperature and the final rolling temperature in the first stage are 1010° C. and 965° C., respectively. The initial rolling temperature and the final rolling temperature in the second stage are 885° C. and 832° C., respectively. The rolled steel plate is water-cooled with the cooling rate of 6.1° C./s, and the self-tempering temperature of the surface of the steel plate after cooling is lower than 200° C. Tempering as the heat treatment is carried out immediately after rolling, with the tempering temperature of 640° C. and the soaking time of 82 min. The steel plate is air-cooled to room temperature after tempering.

Example 2

[0033] This example provides the 690 MPa high-strength medium-manganese steel with low yield ratio and the thickness of 50 mm, including the following chemical composition in mass percentage: C: 0.06%, Mn: 4.47%, Si: 0.26%, P: 0.009%, S: 0.001%, Ti: 0.026%, Ni+Cr+Mo: 0.46%, and the balance of Fe and unavoidable impurities.

[0034] The method for manufacturing the steel plate is as follows:

[0035] Converter smelting is carried out after the molten iron desulfurization treatment is performed, so that the contents of S and P in the molten steel are reduced. C, Mn, Si, Ti, Ni, Cr, and Mo in the required mass fraction are alloyed after the LF refining is completed. The continuous casting method is adopted with the casting speed of the continuous casting slab being 0.6 m/min, and the surface defects are cleaned up, to obtain the slab with the thickness of 320 mm. The obtained slab is heated to 1130° C. with the soaking time of 70 min. The heated slab is performed with the two-stage rolling process. The initial rolling temperature and the final rolling temperature in the first stage are 1005° C. and 945° C., respectively. The initial rolling temperature and the final rolling temperature in the second stage are 865° C. and 823° C., respectively. The rolled steel plate is water-cooled with the cooling rate of 7.3° C./s, and the self-tempering temperature of the surface of the steel plate after cooling is lower than 200° C. Tempering as the heat treatment is carried out immediately after rolling, with the tempering temperature of 630° C. and the soaking time of 71 min. The steel plate is air-cooled to room temperature after tempering.

Example 3

[0036] This example provides the 690 MPa high-strength medium-manganese steel with low yield ratio and with the thickness of 30 mm, including the following chemical composition in mass percentage: C: 0.05%, Mn: 4.28%, Si: 0.21%, P: 0.008%, S: 0.001%, Ti: 0.033%, Ni+Cr+Mo: 0.39%, and the balance of Fe and unavoidable impurities.

[0037] The method for manufacturing the steel plate is as follows:

[0038] Converter smelting is carried out after the molten iron desulfurization treatment is performed, so that the contents of S and P in the molten steel are reduced. C, Mn, Si, Ti, Ni, Cr, and Mo in the required mass fraction are alloyed after the LF refining is completed. The continuous casting method is adopted with the casting speed of the continuous casting slab being 0.6 m/min, and the surface defects are cleaned up, to obtain the slab with the thickness of 260 mm. The obtained slab is heated to 1110° C. with the soaking time of 59 min. The heated slab is performed with the two-stage rolling process. The initial rolling temperature and the final rolling temperature in the first stage are 1005° C. and 935° C., respectively. The initial rolling temperature and the final rolling temperature in the second stage are 870° C. and 812° C., respectively. The rolled steel plate is water-cooled with the cooling rate of 12.1° C./s, and the self-tempering temperature of the surface of the steel plate after cooling is lower than 200° C. Tempering as the heat treatment is carried out immediately after rolling, with the tempering temperature of 610° C. and the soaking time of 55 min. The steel plate is air-cooled to room temperature after tempering.

[0039] The comprehensive mechanical properties of the steel plates manufactured in Examples 1-3 are shown in Table 1.

TABLE-US-00001 TABLE 1 Comprehensive mechanical properties of the steel plates manufactured in Examples 1-3 Properties result Yield Tensile Charpy impact Thickness/ Sampling strength/ strength/ Yield Elongation/ Bend test energy/J Examples mm site MPa MPa ratio % d = 3a −40° C. −60° C. Example 1 70 ¼t 681 806 0.845 23 intact 248 185 265 195 227 177 ½t 660 785 0.841 24 intact 198 148 202 169 185 152 Example 2 50 ¼t 723 846 0.855 21 intact 295 196 288 172 282 189 ½t 703 829 0.848 23 intact 201 165 195 155 210 171 Example 3 30 ¼t 742 865 0.857 20 intact 276 199 281 187 266 192 ½t 722 843 0.856 22 intact 286 221 267 211 277 231

TABLE-US-00002 TABLE 2 Comprehensive mechanical properties of Q690M steel with 690MPa level in GB/T 1591-2018 standard Yield Nominal strength Tensile Elongation thickness/ (no less strength/ no less Bend mm than)/MPa MPa than/% Minimum Charpy impact energy/J test ≤16 690 770-940 14    0° C.: transverse 55, longitudinal 34 D = 2a >16-40 680 −20° C.: transverse 47, longitudinal 27 D = 3a >40-63 670 750-920 −40° C.: transverse 31, longitudinal 20 >63-80 650 730-900

[0040] Table 2 shows the comprehensive mechanical properties requirements of the Q690M steel with 690 MPa level in the GB/T 1591-2018 standard. It can be seen from FIG. 1 that the present disclosure uses manganese as the main alloying element to replace the precious Ni—Mo alloy. The hardenability of the steel plate is improved through the Mn element, so that the steel plate forms martensite in a wide range of cooling rate, and then forms part of reversed austenite in the two-phase region annealing process. The tempered martensite increases the strength of the steel plate, and the reversed austenite improves the toughness and plasticity of the steel plate. Thus, the steel plate manufactured has high strength, low yield ratio, and excellent mechanical properties of the steel core, which meets the safety performance and construction cost requirements of the construction machinery on the ultra-high-strength steel in the complex environments.

[0041] In addition to the above-mentioned examples, the present disclosure may also have other examples. All technical solutions formed by equivalent replacements or transformations shall fall within the protection scope of the present disclosure.