MIXING ELEMENTS WITH A REDUCED STRUCTURAL DEPTH FOR STATIC MIXERS
20190232239 · 2019-08-01
Inventors
Cpc classification
B01F25/431974
PERFORMING OPERATIONS; TRANSPORTING
B01F2215/0431
PERFORMING OPERATIONS; TRANSPORTING
B01F2215/0427
PERFORMING OPERATIONS; TRANSPORTING
B01F25/43161
PERFORMING OPERATIONS; TRANSPORTING
B01F2215/0422
PERFORMING OPERATIONS; TRANSPORTING
B01F2101/2805
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The invention relates to mixing elements with a reduced structural depth for static mixers, to static mixers comprising at least two mixing elements with a reduced structural depth, and to a method for mixing fluids using a mixing element with a reduced structural depth or a static mixer comprising at least two mixing elements with a reduced structural depth. In the mixing elements, the thickness of the transverse strut at its thickest point is maximally 0.9 to 1.1 times the thickness of the webs multiplied by the cosine of half the opening angle O divided by the sine of the whole opening angle O.
Claims
1. A mixing element which has at least one transverse strut from which there originate, at right angles to the longest extent of the transverse strut, at least three webs, at least one web of these at least three webs lying in alternation relative to at least two webs with respect to the longest extent of the transverse strut, and the webs lying on opposite sides of the transverse strut enclosing an opening angle O of 60 to 120, wherein the thickness of the transverse strut (dQ) at its thickest point is not more than 0.9 to 1.1 times the thickness of the webs (dS) multiplied by the cosine of half the opening angle O divided by the sine of the full opening angle O.
2. The mixing element as claimed in claim 1, wherein the webs lying on opposite sides of the transverse strut enclose an opening angle O of 75 to 105.
3. The mixing element as claimed in claim 1, wherein the thickness of the transverse strut (dQ) at its thickest point is 0.95 to 1.05 times the thickness of the webs (dS) multiplied by the cosine of half the opening angle O divided by the sine of the full opening angle O, i.e. dQ=(1+/0.05)*dS*cos (0.5*O)/sin O.
4. The mixing element as claimed in claim 1, wherein the width of the opening between two adjacent webs which lie on the same side of the transverse strut from which they depart is greater, in the main flow direction, than the width of a web.
5. The mixing element as claimed in claim 1, wherein the mixing element comprises a sleeve.
6. A static mixer comprising at least two mixing elements as claimed in claim 1.
7. The static mixer as claimed in claim 6, wherein the at least two mixing elements are directly adjacent.
8. The static mixer as claimed in claim 6 wherein the static mixer is constructed exclusively of the at least two mixing elements.
9. The static mixer as claimed in claim 6, wherein at least one mixing element comprises a sleeve.
10. A method for mixing fluids, comprising mixing utilizing a mixing element as claimed in claim 1.
11. A method for mixing fluids, comprising mixing utilizing a static mixer as claimed in claim 6.
12. A method for producing polymers or polymer mixtures, comprising mixing utilizing a mixing element as claimed in claim 1.
13. A method for producing polymers or polymer mixtures, comprising mixing utilizing a static mixer claimed in claim 6.
14. The mixing element as claimed in claim 1, wherein the webs lying on opposite sides of the transverse strut enclose an opening angle O of 85 to 95.
15. The mixing element as claimed in claim 1, wherein the webs lying on opposite sides of the transverse strut enclose an opening angle O of 90.
16. The mixing element as claimed in claim 1, wherein the thickness of the transverse strut (dQ) at its thickest point is 0.98 to 1.02 times the thickness of the webs (dS) multiplied by the cosine of half the opening angle O divided by the sine of the full opening angle O, i.e. dQ=(1+/0.02)*dS*cos (0.5*O)/sin O.
17. The mixing element as claimed in claim 1, wherein the thickness of the transverse strut (dQ) at its thickest point is equal to the thickness of the webs (dS) multiplied by the cosine of half the opening angle O divided by the sine of the full opening angle O, i.e. dQ=dS*cos (0.5*O)/sin O.
18. The static mixer as claimed in claim 6, wherein all the mixing elements comprise a sleeve.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0029] The invention is elucidated below by drawings, without being thereby limited to the embodiments shown in the drawings.
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DETAILED DESCRIPTION
[0041] Preferably the thickness of the transverse strut (dQ) at its thickest point is 0.95 to 1.05 times the thickness of the webs (dS) multiplied by the cosine of half the opening angle O divided by the sine of the full opening angle O, i.e. dQ=(1+/0.05)*dS*cos (0.5*O)/sin O, very preferably 0.98 to 1.02 times the thickness of the webs (dS) multiplied by the cosine of half the opening angle O divided by the sine of the full opening angle O, i.e. dQ=(1+/0.02)*dS*cos (0.5*O)/sin O, and in particular the thickness of the transverse strut dQ=dS*cos (0.5*O)/sin O.
[0042] With further preference the thickness dQ of the transverse strut is the same over a continuous distance, including the middle of the transverse strut length, of 90%, preferably more than 95%, more preferably more than 98%, very preferably more than 99% of the transverse strut length, with a deviation of not more than 5%, preferably not more than 2%, more preferably not more than 1%.
[0043] With further preference at least the side of a transverse strut (transverse strut side) facing the webs has the form of a rectangle, this rectangle lying at right angles to the main flow direction of the fluids.
[0044] With further preference the thickness of the webs (dS) is 0.01 to 0.07, preferably 0.015 to 0.06, and very preferably 0.02 to 0.05 times the diameter of the mixing element at right angles to the main flow direction.
[0045] The mixing element of the invention may have a sleeve. Where the mixing element of the invention has a sleeve, the outer faces of the transverse struts and the end faces of the sleeve lie in one plane.
[0046] Surprisingly it has been found that not only does such a mixing element bring about a better mixing outcome than mixing elements from the prior art, but also that the pressure loss during mixing is lower, without the residence time being increased or the diameter or the free volume of the mixing element or static mixer being increased. It is therefore possible to operate with a reduced entry pressure upstream of the mixing element.
[0047] By means of the reduced pressure loss, firstly, there is a saving on the energy needed to generate the pressure, and secondly the reduced pressure loss leads to a lower temperature increase during the mixing process. This in turn reduces temperature-related damage affecting the fluid to be mixed or fluids to be mixed with one another. With a higher pressure loss, moreover, greater expenditure on apparatus is required, in the form, for example, of more powerful pumps and thicker walls.
[0048] It has surprisingly been found as well, moreover, that for the same or better mixing outcome, the pressure loss through the mixing element of the invention can be diminished additionally if in the main flow direction, the width of the opening between two adjacent webs which lie on the same side of the transverse strut from which they depart is greater than the width of a web. This web width of these two webs in this case is substantially the same.
[0049] An additional advantage of the mixing element of the invention is that it has a lower structural depth than a comparable mixing element from the prior art. A mixing element of the invention, accordingly, has a structural depth reduced by twice the thickness of the transverse strut. For an opening angle O of 90 and a customary ratio of static mixer diameter to web thickness of 20:1, this may easily achieve a structural depth which is approximately 20% lower. The space saving resulting from this is desirable technically, particularly since in general there is not only one mixing element of the invention but rather numerous mixing elements of the invention installed in a pipe through which the fluids for mixing are flowing. In analogy to the prior-art static mixers already described earlier on above, these mixing elements then form a static mixer of the invention.
[0050] This achieves the additional object of providing a mixing element which, for the same or better mixing outcome and simultaneous reduction in pressure loss, has a lower structural depth than comparable mixing elements from the prior art.
[0051] An effect of the lower structural depth on the part of the mixing element of the invention is a lower residence time of the fluid to be mixed or fluids to be mixed with one another in the mixing element. This in turn reduces the thermal loads and consequently temperature-related damage affecting the fluid to be mixed or fluids to be mixed with one another.
[0052] Additionally it has surprisingly been found that if at least two of the mixing elements of the invention are arranged bordering on the one another directly so that their transverse strut sides facing one another lie flush one after another and are in contact over their full area, with one of the two mixing elements being rotated by 180 relative to the other mixing element about its axis perpendicular to the main flow direction and lying parallel to the transverse struts, but the two mixing elements lying one after another and of the same kind have no rotation relative to one another in the plane lying normal to the main flow direction, relative to the other mixing element, the mechanical strength of the static mixer of the invention constructed from the at least two mixing elements of the invention, by comparison with a static mixer constructed from the same number of conventional mixing elements in the same arrangement as the mixing elements of the invention, is not lowered but is in fact increased in the flow direction, while in the other directions it remains at least the same.
[0053] With an arrangement in accordance with the invention of this kind, the interfaces of the imaginary prolongations of the outer contours of the webs in the region of the cross section of a transverse strut, the section being taken at right angles to the transverse strut length and at right angles to the transverse strut width, in other words parallel to the transverse strut thickness (dQ), form a rhombus. For an opening angle O of 90, this rhombus is a square.
[0054] The effect of this arrangement in accordance with the invention is that flows of force are uniform. In particular, the flows of force through the webs without deflection are transmitted directly from one mixing element of the invention to the subsequent mixing element of the invention, thus preventing torques at the transition between web and transverse strut, and also preventing the associated additional shearing stresses. Consequently, as already maintained earlier on above, the strength is increased. Other advantages of the mixing element of the invention and of the static mixer of the invention are the saving on material for production of the mixer, and the fact that increased throughput can be tolerated.
[0055] When using the mixing elements of the invention, therefore, there is no risk of a mixing element of the invention or of a static mixer constructed from at least two mixing elements of the invention becoming compressed under the load of the fluid in motion. On the contrary: the mixing element of the invention is suitable for greater loading than a corresponding prior-art mixing element, and a static mixer composed of at least two mixing elements of the invention is suitable for greater loading than a corresponding prior-art static mixer.
[0056] The advantages of the mixing element of the inventionviz. the improved mixing outcome, the lower pressure loss, and the greater mechanical strengthare manifested particularly if at least two of the mixing elements of the invention are present in a static mixer. In particular, the advantages of the mixing element of the invention are manifested if the at least two mixing elements of the invention are directly adjacent and if one mixing element of the invention is rotated by 180 to the respectively adjacent mixing element about its axis perpendicular to the main flow direction and lying parallel to the transverse struts, so that the transverse strut sides of the mixing elements that face away from the webs of the respective mixing element lie directly on one another and contact one another over their full area. The advantages of the mixing element of the invention are manifested very particularly if at least two of the mixing elements of the invention form a static mixer, in other words if the static mixer is constructed exclusively of the mixing elements of the invention.
[0057] Another subject of the present invention, therefore, is a static mixer comprising at least two mixing elements of the invention. A subject of the present invention more particularly is also a static mixer constructed exclusively of the mixing elements of the invention.
[0058] Here, one or more, or all, of the mixing elements of the invention may or may not have a sleeve. The static mixer of the invention as well may or may not have a sleeve.
[0059] A sleeve of this kind may on the outside have marking grooves or marking pins which hinder or prevent incorrect installation or assembly of the mixing element or static mixer into a tube through which there flow the fluids to be mixed.
[0060] A further subject of the present invention is also a method for mixing fluids using a mixing element of the invention. A further subject of the present invention more particularly is also a method for mixing using a static mixer of the invention.
[0061] Fluids which can be mixed advantageously using a mixing element of the invention or a static mixer of the invention are the aforesaid polymer melts or other fluids having a viscosity of 0.1 to 10 000 Pas. Hence a mixing element of the invention or a static mixer of the invention may also be used, for example, to mix one polymer melt with another, additized polymer melt, or to mix a polymer melt with a solvent. This operation takes place, for example, during the production of polymers or mixtures of polymers. Accordingly, the mixing element of the invention and the static mixer of the invention also serve for the production of polymers and mixtures of polymers and polymer solutions. The components to be mixed may form a homogeneous mixture (no phase boundary observable between the components) or a disperse mixture (phase boundary observable between the components). If a component is dispersed, this disperse phase may be solid, liquid or gaseous. The components to be mixed may have the same viscosity or a viscosity different from one to another. The viscosity ratios may be up to 1:10 000. The proportionsin weight fractions for solids and liquids and in volume fractions for gasesare from 0.1:99.9% to 50:50%, preferably 3:97% to 15:85%. The polymer melt or polymer melts preferably comprise a melt of a thermoplastic polymer or melts of two or more thermoplastic polymers. A thermoplastic polymer is also referred to for short below as thermoplastic.
[0062] Processed with particular preference using a mixing element of the invention or using a static mixer of the invention are thermoplastic polymers from the series encompassing polycarbonate, polyamide, polyesters, especially polybutylene terephthalate or polyethylene terephthalate, polyethers, thermoplastic polyurethane, polyacetal, fluoropolymer, especially polyvinylidene fluoride, polyethersulfones, polyolefin, especially polyethylene or polypropylene, polyimide, polyacrylate, especially poly(methyl) methacrylate, polyphenylene oxide, polyphenylene sulfide, polyetherketone, polyaryletherketone, styrene polymers, especially polystyrene, styrene copolymers, especially styrene-acrylonitrile copolymer, acrylonitrile-butadiene-styrene block copolymer or polyvinyl chloride. Likewise processed preferably with a mixing element of the invention or with a static mixer of the invention are blends, so called, of the polymers listed, as understood by the skilled person to refer to a combination of two or more polymers. Particularly preferred are polycarbonate and blends containing polycarbonate, the polycarbonate having been obtained very preferably by the interfacial process or by the melt transesterification process.
[0063] It is known, further, that with a mixing element of the invention or with a static mixer of the invention it is possible to process further fluids such as, for example, oils, epoxy resins, polyurethanes, foodstuffs, paints and varnishes, creams, pastes, metal melts, salt melts or glass melts.
[0064] Polymer solutions which as products can be processed with a mixing element of the invention or with a static mixer of the invention are, for example, rubbers or thermoplastics with their monomers and/or solvents. Processed preferably with a mixing element of the invention or with a static mixer of the invention are solutions of polymers selected from the series encompassing styrene-acrylonitrile copolymer with styrene, acrylonitrile and/or ethylbenzene, acrylonitrile-butadiene-styrene block copolymers with styrene, acrylonitrile, butadiene and/or ethylbenzene, polycarbonate with chlorobenzene and/or methylene chloride, polyamide with caprolactam or water, polyoxymethylene with formaldehyde, poly(methyl) methacrylate with methyl methacrylate, and polyethylene with hexane or cyclohexane. A mixing element of the invention or a static mixer of the invention is used with particular preference for processing polymer solutions comprising polycarbonate in chlorobenzene and/or methylene chloride.
[0065] Polycarbonates for the purposes of the present invention are not only homopolycarbonates but also copolycarbonates and/or polyester carbonates; the polycarbonates, in a known way, may be linear or branched. Also referred to in accordance with the invention are mixtures of polycarbonates.
[0066] The polycarbonates can be produced in a known way from diphenols, carbonic acid derivatives, optionally chain terminators, and branching agents. Details of the production of polycarbonates have been well-known to the skilled person for at least about 40 years. Reference may be made here, by way of example, to Schnell, Chemistry and Physics of Polycarbonates, Polymer Reviews, Volume 9, Interscience Publishers, New York, London, Sydney 1964, to D. Freitag, U. Grigo, P. R. Miller, H. Nouvertn, BAYER AG, Polycarbonates in Encyclopedia of Polymer Science and Engineering, Volume 11, Second Edition, 1988, pages 648-718, and finally, to U. Grigo, K. Kirchner, and P. R. Mller, Polycarbonate in Becker/Braun, Kunststoff-Handbuch, Volume 31, Polycarbonates, Polyacetals, Polyesters, Cellulose esters, Carl Hanser Verlag Munich, Vienna 1992, pages 117-299.
[0067] Aromatic polycarbonates are produced, for example, by reaction of diphenols with carbonic halides, preferably phosgene, and/or with aromatic dicarboxylic dihalides, preferably benzene dicarboxylic dihalides, by the interfacial process, optionally with use of chain terminators and optionally with use of branching agents having a functionality of three or more than three. Also possible is production via a melt polymerization process, by reaction of diphenols with, for example, diphenyl carbonate. Examples of diphenols suitable for production of the polycarbonates are hydroquinone, resorcinol, dihydroxybiphenyls, bis(hydroxyphenyl)alkanes, bis(hydroxyphenyl)cycloalkanes, bis(hydroxyphenyl) sulfides, bis(hydroxyphenyl) ethers, bis(hydroxyphenyl) ketones, bis(hydroxyphenyl) sulfones, bis(hydroxyphenyl) sulfoxides, --bis(hydroxyphenyl)diisopropylbenzenes, phthalimidines derived from isatin or phenolphthalein derivatives, and also to the related ring-alkylated, ring-arylated, and ring-halogenated compounds.
[0068] Preferred diphenols are 4,4-dihydroxybiphenyl, 2,2-bis(4-hydroxyphenyl)propane (bisphenol A), 2,4-bis(4-hydroxyphenyl)-2-methylbutane, 1,1-bis(4-hydroxyphenyl)-p-diisopropylbenzene, 2,2-bis(3-methyl-4-hydroxyphenyl)propane, dimethyl bisphenol A, bis(3,5-dimethyl-4-hydroxyphenyl)methane, 2,2-bis(3,5-dimethyl-4-hydroxyphenyl)propane, bis(3,5-dimethyl-4-hydroxyphenyl) sulfone, 2,4-bis(3,5-dimethyl-4-hydroxyphenyl)-2-methylbutane, 1,1-bis(3,5-dimethyl-4-hydroxyphenyl)-p-diisopropylbenzene, and 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane.
[0069] Particularly preferred diphenols are 2,2-bis(4-hydroxyphenyl)propane (bisphenol A), 2,2-bis(3,5-dimethyl-4-hydroxyphenyl)propane, 1,1-bis(4-hydroxyphenyl)cyclohexane, 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane, and dimethyl bisphenol A.
[0070] These and other suitable diphenols are described for example in U.S. Pat. Nos. 3,028,635, 2,999,825, 3,148,172, 2,991,273, 3,271,367, 4,982,014, and 2,999,846, in DE-A 1 570 703, DE-A 2 063 050, DE-A 2 036 052, DE-A 2 211 956, and DE-A 3 832 396, in FR-A 1 561 518, in the monograph by H. Schnell in Chemistry and Physics of Polycarbonates, Interscience Publishers, New York 1964 and also in JP-A 62039/1986, JP-A 62040/1986, and JP-A 105550/1986.
[0071] In the case of the homopolycarbonates, only one diphenol is used; in the case of the copolycarbonates, two or more diphenols are used.
[0072] Suitable carbonic acid derivatives are, for example, phosgene or diphenyl carbonate.
[0073] Suitable chain terminators which can be used in producing the polycarbonates are monophenols. Examples of suitable monophenols are phenol itself, alkylphenols such cresols, p-tert-butylphenol, cumylphenol, and mixtures thereof.
[0074] Preferred chain terminators are the phenols which are singly or multiply substituted by C.sub.1 to C.sub.30 alkyl radicals, linear or branched, preferably unsubstituted, or substituted by tert-butyl. Particularly preferred chain terminators are phenol, cumylphenol and/or p-tert-butylphenol. The amount of chain terminator to be used is preferably 0.1 to 5 mol %, based on moles of diphenols employed in each case. The chain terminators may be added before, during or after the reaction with a carbonic acid derivative.
[0075] Suitable branching agents are the compounds with a functionality of three or more than three that are known in polycarbonate chemistry, especially those having three or more than three phenolic OH groups.
[0076] Examples of suitable branching agents are 1,3,5-tri(4-hydroxyphenyl)benzene, 1,1,1-tri(4-hydroxyphenyl)ethane, tri(4-hydroxyphenyl)phenylmethane, 2,4-bis(4-hydroxyphenylisopropyl)-phenol, 2,6-bis(2-hydroxy-5-methyl-benzyl)-4-methylphenol, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)propane, tetra(4-hydroxyphenyl)methane, tetra(4-(4-hydroxyphenylisopropyl)-phenoxy)methane, and 1,4-bis((4,4-dihydroxytriphenyl)methyl)benzene and 3,3-bis(3-methyl-4-hydroxyphenyl)-2-oxo-2,3-dihydroindole.
[0077] The amount of any branching agents to be used is preferably 0.05 mol % to 3 mol %, based on moles of diphenols used in each case. The branching agents may either be included in the initial charge with the diphenols and the chain terminators in the aqueous-alkaline phase, or added in solution in an organic solvent before the phosgenation. In the case of the transesterification process, the branching agents are used together with the diphenols.
[0078] Particularly preferred polycarbonates are the homopolycarbonate based on bisphenol A, the homopolycarbonate based on 1,3-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane, and the copolycarbonates based on the two monomers bisphenol A and 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane.
[0079] Additionally it is possible optionally, based on the weight of the thermoplastic, for there to be up to 50.0 wt %, preferably 0.2 to 40 wt %, more preferably 0.10 to 30.0 wt %, of other customary additives present.
[0080] This group encompasses flame retardants, antidrip agents, heat stabilizers, mold release agents, antioxidants, UV absorbers, IR absorbers, antistats, optical brighteners, light-scattering agents, colorants such as pigments, including inorganic pigments, carbon black and/or dyes, and inorganic fillers in amounts customary for polycarbonate. These additives may be added individually or else in a mixture.
[0081] Such additives as are customarily added in the case of polycarbonates are described for example in EP-A 0 839 623, WO-A 96/15102, EP-A 0 500 496 or Plastics Additives Handbook, Hans Zweifel, 5th Edition 2000, Hanser Verlag, Munich.
[0082] In the production of a polycarbonate, the mixing elements or static mixers of the invention are used preferably after the last devolatilization stage of the polycarbonate. In the case of production of polycarbonate by the interfacial process, this stage is generally after a tube or strand devolatilizer, and in the case of production of polycarbonate by the melt polymerization process, after a high-viscosity reactor. Upstream in flow direction of a mixing element or static mixer of the invention, a main flow of unadditized polycarbonate is fed with a secondary flow of additized polycarbonate. The mixing ratio here is in a range from 99:1 to 80:20, preferably 98:2 to 85:15, more preferably from 95:5 to 90:10, in each case by weight fraction.
[0083] If a mixing element of the invention or a static mixer of the invention is used in the production of polycarbonate, it has the effectthrough the lower temperature increase caused by the lower pressure loss, and by the lower residence time caused by the lower structural depthof reducing temperature damage to the polycarbonate. This in turn yields a polycarbonate whose yellowing is lower and transparency higher than that of a polycarbonate produced under otherwise identical conditions but without the use of a mixing element of the invention or a static mixer of the invention.
[0084] Another subject of the present invention, therefore, is a method for producing polycarbonate using a mixing element of the invention. Also a subject of the present invention, therefore, is a method for producing polycarbonate using a static mixer of the invention.
[0085] The invention is elucidated below by drawings, without being thereby limited to the embodiments shown in the drawings.
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3.1 first mixing element
3.2 second mixing element, rotated by 180 relative to the first mixing element about its axis perpendicular to the main flow direction and lying parallel to the transverse struts
3.3 third mixing element, oriented like first mixing element
3.4 fourth mixing element, oriented like second mixing element
3.5 fifth mixing element, oriented like first mixing element 3.1, but rotated, viewed in flow direction, by 90 in circumferential direction counterclockwise
3.6 sixth mixing element, rotated by 180 relative to the fifth mixing element about its axis perpendicular to the main flow direction and lying parallel to the transverse struts
3.7 seventh mixing element, oriented like fifth mixing element
3.8 eighth mixing element, oriented like sixth mixing element
3.9 ninth mixing element, oriented like first mixing element
3.10 tenth mixing element, oriented like second mixing element
3.11 eleventh mixing element, oriented like first mixing element
3.12 twelfth mixing element, oriented like second mixing element
3.13 thirteenth mixing element, oriented like fifth mixing element
3.14 fourteenth mixing element, oriented like sixth mixing element
3.15 fifteenth mixing element, oriented like seventh mixing element
3.16 sixteenth mixing element, oriented like eighth mixing element
3.17 main flow direction
3.18 tube in which the mixing elements are installed
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