Laser component
10367324 ยท 2019-07-30
Assignee
Inventors
Cpc classification
B29C66/73772
PERFORMING OPERATIONS; TRANSPORTING
B29C66/00145
PERFORMING OPERATIONS; TRANSPORTING
H01S3/108
ELECTRICITY
H01S5/0216
ELECTRICITY
H01S3/0405
ELECTRICITY
B29C66/028
PERFORMING OPERATIONS; TRANSPORTING
International classification
H01S5/02
ELECTRICITY
B29C65/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A laser component is provided, including a laser medium and a transparent heat transmitting member, at least one of which is oxide. Bonding surfaces of the laser medium and the transparent heat transmitting member are exposed to oxygen plasma, and thereafter the bonding surfaces are brought into contact without heating. The laser medium and the transparent heat transmitting member are bonded at atomic levels, their thermal resistance is low, and no large residual stress is generated due to the bonding taking place under normal temperature. The process of oxygen plasma exposure ensures transparency of their bonding interface. The laser medium and the transparent heat transmitting member are stably bond via an amorphous layer.
Claims
1. A method of manufacturing a laser component having a laser medium and a transparent heat transmitting member, wherein at least one of the laser medium and the transparent heat transmitting member is oxide, the method comprising: surface-active bonding a bonding surface of the laser medium and a bonding surface of the transparent heat transmitting member by radiating an inert gas atomic beam to both the bonding surface of the laser medium and the bonding surface of the transparent heat transmitting member in vacuum, and after the radiating bringing the bonding surface of the laser medium and the bonding surface of the transparent heat transmitting member into contact, wherein: the laser medium and the transparent heat transmitting member are bonded via an amorphous layer, the amorphous layer is composed of a material derived from the laser medium and the transparent heat transmitting member, and is transparent to an excitation beam, any colored layer causing an energy loss of 1% or more is not observed in the laser component, and the laser component outputs a laser beam having a power greater than 10 MW (megawatts).
2. The method according to claim 1, wherein the bonding surfaces are brought into contact without heating.
3. A laser component comprising a laser medium and a transparent heat transmitting member, wherein at least one of the laser medium and the transparent heat transmitting member is oxide, the laser medium and the transparent heat transmitting member are bonded via an amorphous layer formed by surface-active bonding a bonding surface of the laser medium and a bonding surface of the transparent heat transmitting member by radiating an inert gas atomic beam to both the bonding surface of the laser medium and the bonding surface of the transparent heat transmitting member in vacuum, and after the radiating bringing the bonding surface of the laser medium and the bonding surface of the transparent heat transmitting member into contact, the amorphous layer is composed of a material derived from the laser medium and the transparent heat transmitting member, and is transparent to an excitation beam, any colored layer causing an energy loss of 1% or more is not observed in the laser component, and the laser component outputs a laser beam having a power greater than 10 MW (megawatts).
4. The laser component according to claim 3, wherein the laser medium is an optical gain material.
5. The laser component according to claim 3, wherein the laser medium is a nonlinear optical material.
6. The laser component according to claim 3, further comprising: a dielectric multilayer film provided between the laser medium and the transparent heat transmitting member.
7. The laser component according to claim 3, further comprising: an intermediate layer provided between the laser medium and the transparent heat transmitting member, wherein a difference in a refractive index of the laser medium and a refractive index of the intermediate layer is less than 9%, a difference in the refractive index of the intermediate layer and a refractive index of the transparent heat transmitting member is less than 9%, and a difference in the refractive index of the laser medium and the refractive index of the transparent heat transmitting member is equal to or more than 9%.
8. The laser component according to claim 3, wherein a plurality of laser mediums and a plurality of transparent heat transmitting members are provided, and the plurality of laser mediums and the plurality of transparent heat transmitting members are arranged serially in an order by which the laser mediums and the transparent heat transmitting members appear alternately.
9. The laser component according to claim 8, wherein a thickness of each laser medium in a laminate direction is equal to or less than one-fifth () of a diameter of the laser medium.
10. The laser component according to claim 8, wherein the laser mediums comprise different types of laser mediums, and the laser mediums of different types are arranged serially.
11. The laser component according to claim 10, wherein the laser mediums comprise a group of laser mediums having a same luminescent center element and different base materials, and the group of laser mediums is arranged serially.
12. The laser component according to claim 10, wherein the laser mediums comprise a group of laser mediums having a same base material and different luminescent center elements, and the group of laser mediums is arranged serially.
13. The laser component according to claim 10, wherein the laser mediums comprise a group of laser mediums having different luminescent center elements and different base materials, and the group of laser mediums is arranged serially.
14. The laser component according to claim 8, wherein the laser mediums have different dopant concentrations, the dopant concentration of the laser medium arranged in a vicinity of an end face to be exposed to the excitation beam is lower than the dopant concentration of the laser medium arranged far away from the end face.
15. The laser component according to claim 8, wherein each of the laser mediums is a nonlinear optical material, the laser mediums comprise a group of laser mediums having different thicknesses, and the group of laser mediums is arranged serially.
16. The laser component according to claim 8, wherein the transparent heat transmitting members are arranged at respective ends of a serial arrangement.
17. The laser component according to claim 16, wherein each of the transparent heat transmitting members arranged at ends of the serial arrangement is made of a single crystal, and the laser mediums are made of ceramic.
18. The laser component according to claim 17, wherein end faces of the transparent heat transmitting members arranged at ends of the serial arrangement are coated.
19. The laser component according to claim 3, wherein the laser medium is made of ceramic, and the transparent heat transmitting member is made of a single crystal.
20. The laser component according to claim 19, wherein the transparent heat transmitting members are arranged at both end faces of the laser medium.
21. The laser component according to claim 20, wherein end faces of the transparent heat transmitting members arranged at the end faces of the laser medium are coated.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION
(16)
(17) Oxygen plasma radiation is for cleaning the bonding surfaces, and it aims to achieve a same effect as inert gas atomic beam radiation to be described later. Due to this, in a conventional surface-active bonding, both the oxygen plasma radiation and the inert gas atomic beam radiation were not carried out in combination. Further, in a surface activating process, oxygen must be removed from an outermost surface layer of a bonding face which is stabilized by bonding with the oxygen. It is a natural assumption that the oxygen will not be removed by the use of the oxygen plasma, therefore, a concept of oxygen plasma exposure was never considered. According to the studies herein, it has been found that transparency deterioration at the interface can be prevented and a variety of surface-active-bondable materials can be increased by adding the oxygen plasma radiation before the conventional surface-active bonding. Further, in the case of heterogeneously bonding the laser medium and the transparent heat transmitting member, they bond firmly via the amorphous layer.
(18) Note that a reference sign 40 in
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(21) The intermediate layer 24 may be formed after having exposed the laser medium 10 and the transparent heat transmitting member 20 to the oxygen plasma and further exposed them to inert gas atomic beam. The surface-active bonding thereof can be performed in an order of the radiation to the inert gas ion, the formation of the intermediate layer 24, and bringing the laser medium 10 and the transparent heat transmitting member 20 into contact and applying pressure thereto.
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(26) If the intermediate layers 14, 24 do not serve the role of the homogeneous films, a homogeneous film may be formed on one of or both of the intermediate layers 14, 24. Further, in addition to the intermediate layers 14, 24, one of or both of the dielectric multilayer films 12, 22 may be formed.
(27) The technique disclosed herein can be applied to laser components having a combination of YAG and sapphire, or a combination of YVO.sub.4, an intermediate layer, and diamond, or the like.
(28) Embodiments
(29) (First Embodiment)
(30)
(31) In this embodiment, the dielectric multilayer film 22 is formed on a surface of a sapphire substrate that is to be the transparent heat transmitting member 20, and a YAG thin film that is to be the homogeneous film 26 is formed on a surface of the dielectric multilayer film 22. These films are both formed by sputtering. These samples are exposed to oxygen plasma 30 (
(32) (Second Embodiment)
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(34) (Third Embodiment)
(35) As shown in
(36) (Fourth Embodiment)
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(38) (Fifth Embodiment)
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(40) (Sixth Embodiment)
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(42) (Seventh Embodiment)
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(44) The intermediate layer 14 and the intermediate layer 24 may also serve as homogeneous films. Alternatively, the intermediate layers 14 and 24 may configure two-layers structure of the intermediate layer that alleviate the difference in the refractive indexes by two different levels. In this case, an amorphous layer that is not shown is formed between the intermediate layer 14 and the intermediate layer 24, and thus the bonding therebetween is established stably.
(45) Various types of known laser mediums may be used. For instance, oxide with rare earth dopant, oxide with transitional metal dopant and oxide that works as a color center and the like may be used as an optical gain material. Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb may be exemplified as the rare earth dopant to be a luminescent center. Ti, V, Cr, Mn, Fe, Co, Ni, and Cu may be exemplified as the transitional metal dopant to be the luminescent center. Garnet-based materials such as YAG, YSAG, YGAG, YSGG, GGG, GSGG, and LuAG, fluoridated materials such as YLF, LiSAF, LiCAF, MgF.sub.2, and CaF.sub.2, vanadate-based materials such as YVO.sub.4, GdVO.sub.4, and LuVO.sub.4, apatite-based materials such as FAP, sFAP, VAP, and sVAP, alumina-based materials such as Al.sub.2O.sub.3 and BeAl.sub.2O.sub.3, dioxide or trioxide-based materials such as Y.sub.2O.sub.3, Sc.sub.2O.sub.3, and Lu.sub.2O.sub.3, and tungstate-based materials such as KGW, KYW may be exemplified as types of a base material. The base material may be mono crystals a single crystal, an amorphous or a ceramic material. Further, it may be various types of non-crystalline glass. LN, LT, KTP, KTA, RTP, RTA, LBO, CLBO, CBO, BBO, BiBO, KBBF, BABF, crystallized quartz, COB, YCOB, GdCOB, GdYCOB, YAB, KDP, KD*P, and ZGP may be exemplified as a nonlinear optical material.
(46) Sapphire, diamond, and dopant-free YAG may be exemplified as the transparent heat transmitting member. Sic may also be used as the transparent heat transmitting member, however, the transparency thereof is insufficient as of this day so its use is limited, such as to arrange it outside a resonator. PbCl.sub.2, Ta.sub.2O.sub.5, TiO.sub.2, HfO.sub.2, ZnS, ZnSe, NdO.sub.2, and ZrO.sub.2 may be exemplified as the intermediate layer for diamond. Al.sub.2O.sub.3, Y.sub.2O.sub.3, La.sub.2O.sub.3, MgO, PbF.sub.2, Sc.sub.2O.sub.3, and YAG may be exemplified as the intermediate layer for sapphire.
(47) Next, laser devices that use laser components will be described.
(48) (Laser Device of First Embodiment)
(49)
(50) the left end surface of the transparent heat transmitting member 20A is nonreflective to an excitation beam wavelength but highly reflective to a laser beam wavelength;
(51) the right end surface of the transparent heat transmitting member 20A is nonreflective to the excitation beam wavelength and also nonreflective to the laser beam wavelength;
(52) the left end surface of the transparent heat transmitting member 20B is nonreflective to the excitation beam wavelength and also nonreflective to the laser beam wavelength; and
(53) the right end surface of the transparent heat transmitting member 20B is highly reflective to the excitation beam wavelength and partially reflective to the laser beam wavelength.
(54) In this embodiment, a resonator system is enclosed between the left end surface of the transparent heat transmitting member 20A and the right end surface of the transparent heat transmitting member 20B, and the transparent heat transmitting member 20A and the transparent heat transmitting member 20B are arranged within a resonator in this system.
(55) When the laser medium 10 is made of ceramic, and the transparent heat transmitting members 20A, 20B are made of a single crystal or amorphous, damage resistivity of the microchip laser resonator is improved.
(56) For example, YAG, YVO.sub.4, or (s-)FAP with luminescent center element additives may be used as the laser medium 10, additive-free YAG, sapphire, or diamond may be used as the transparent heat transmitting members 20A, 20B. If differences in refractive indexes between the laser medium 10 and the transparent heat transmitting members 20A, 20B are less than 9%, the intermediate layer is not necessary. For example, if the laser medium 10 is YAG or (s-)FAP with the luminescent center element additives, and the transparent heat transmitting members 20A, 20B are additive-free YAG or sapphire, intermediate layer(s) are not necessary.
(57) If a laser medium is YVO.sub.4 with the luminescent center substance additives, and transparent heat transmitting members are sapphire, a difference in refractive indexes becomes 19%, in which case the use of the intermediate layer(s) is preferable. It is preferable to use one or more types of sulfa, SiO.sub.2, and HfO having refractive indexes being median values of the refractive indexes of the aforementioned members as the intermediate layer(s).
(58) If the laser medium is YVO.sub.4 with the luminescent center substance additives, and the transparent heat transmitting members are diamond, it is preferable to use one or more types of TiO.sub.2, ZnS, and Ta.sub.2O.sub.3 having the refractive indexes being median values of the refractive indexes of the aforementioned members as the intermediate layer(s).
(59) The dielectric multilayer film may be formed between the transparent heat transmitting member 20A and the laser medium 10 and between the transparent heat transmitting member 20B and the laser medium 10. In this case, a homogeneous film having same material with a counterpart bonding surface may be formed on an outermost surface of the dielectric multilayer film to perform the homogeneous surface-active bonding, or the homogeneous film may not be formed to perform the heterogeneous surface-active bonding. In the latter case, an amorphous layer is formed at the bonding interfaces and thereby facilitates the bonding.
(60) When the excitation beam is radiated to the left end surface of the transparent heat transmitting member 20A, this microchip laser resonator outputs the laser beam from the right end surface of the transparent heat transmitting member 20B. Notably, the transparent heat transmitting member 20B on a side that outputs the laser beam may be omitted in some cases.
(61) (Laser Device of Second Embodiment)
(62) As shown in
(63) (Laser Device of Third Embodiment)
(64) As shown in
(65) It is preferable to enlarge a diameter of the transparent heat transmitting members 20A, 20B, 20C to be larger than the diameter of the laser medium 10A and the Q switch 10B. In this case, a relationship is established, in which these serially-bonded laser components are housed in a cylinder having high thermal transmissivity, and outer circumferential surfaces of the transparent heat transmitting members 20A, 20B, 20C contact an inner circumferential surface of the cylinder. Heat from the laser medium 10A is transmitted to the cylinder through the transparent heat transmitting members 20A, 20C. Heat from the Q switch 10B is transmitted to the cylinder through the transparent heat transmitting members 20C, 20B. When the cylinder is cooled, the laser medium 10A and the Q switch 10B are also cooled.
(66) (Laser Device of Fourth Embodiment)
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(68) A thickness of each laser medium 10 is preferably equal to or thinner than one-fifth () of the diameter of the laser medium. When they are thinned to this extent, temperature distribution along an optical path in the laser medium becomes uniformized, and beam quality is significantly improved.
(69) Laser mediums of different types may be arranged serially. For example, when plural types of optical gain materials which added a common luminescence center substance in different types of base materials are arranged serially, a resonating wavelength of the laser resonator can be configured as a broad band as described in SATO et. al. Plural types of optical gain materials with different luminescent center substances may be arranged serially. For example, Tm:YAG, transparent heat transmitting member, Ho:YAG, and transparent heat transmitting member may configure a unit, and the plural units may repeatedly be arranged in serial. Due to this, a phenomenon in which light emission from Tm excites Ho can be achieved.
(70) (Laser Device of Fifth Embodiment)
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(72) (Laser Device of Sixth Embodiment)
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(74) (Laser Device of Seventh Embodiment)
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(76) (Laser Device of Eighth Embodiment)
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(78) 1) all the interfaces are nonreflective to both the excitation beam and laser beam wavelengths. If YAG is used as the optical gain mediums 10 and sapphire is used as the transparent heat transmitting members 20, they may be bonded by heterogeneous surface-active bonding. When YAG and sapphire are surface-active bonded, reflectance at their bond interface becomes 0.1% or less, and there will be no need to provide a nonreflective coating by the dielectric multilayer film or the intermediate layer. Further, YAG and sapphire both contain Al.sub.2O.sub.3, which further omits the need of the homogeneous film;
(79) 2) one of left and right interfaces of the transparent heat transmitting member 20 that is on the rightmost side is highly reflective to the excitation beam but nonreflective to the laser beam wavelength, and all remaining interfaces are nonreflective to both the excitation beam and the laser beam wavelength; and
(80) 3) in the above 1) and 2), one of left and right interfaces of the transparent heat transmitting member 20 that is on the leftmost side is nonreflective to the excitation beam but highly reflective to the laser beam wavelength.
(81) In this device, the left end surface is radiated with the excitation beam, and the input laser beam is inputted from the right end surface. By so doing, a laser beam is outputted from the right end surface. The output laser beam has higher or amplified intensity than that of the input laser beam.
(82) In this embodiment, dopant concentration of the luminescent center element in the optical gain mediums 10 on the left side, where the strong excitation beam radiation is carried out, is set low, and dopant concentration of the luminescent center element in the optical gain mediums 10 on the right side, where the excitation beam attenuates, is set high. Due to this, the excitation beam is not absorbed drastically in localized areas, and an adjustment can be made to uniformize absorption over an entire excitation area. Temperatures inside the laser device can be uniformized, and local overheating can be prevented. Alternatively, portions in vicinities of the respective ends and a center portion of a serial connection may be distinguished, and dopant concentration of the luminescent center element in the portions in vicinities of the respective ends may be set low, and dopant concentration of the luminescent center element in the center portion may be set high. This arrangement is useful when excitation beams radiate both end faces of the serial connection.
(83) Microchip laser, fiber laser, rod laser, and disk laser may be exemplified as source light for the amplifier.
(84) In a device that arranges a plurality of homogeneous laser mediums serially and use them for amplification, amplification rate can be increased. As an alternative thereof, a laser amplifier with different types of laser mediums serially arranged therein is also useful. If a wavelength range of input laser beam is broad, the use of the plural types of laser mediums enables amplification of the entire wavelength range of the input laser beam. In all of the above cases, overheating of the laser mediums can be prevented due to each laser medium being cooled from its both side surfaces.
(85) (Laser Device of Ninth Embodiment)
(86) As shown in
(87) A wavelength converter may be realized using the structure of
(88) Further, the bonding may be performed so that directions of nonlinear polarization is inverted according to a coherence length of a targeted wavelength, or so that quasi-phase matching is realized, in which temporal halts are repeated. In the quasi-phase matching, a chirp structure for expanding the range or controlling a phase relationship may be build therein.
(89) As a resonator profile, a parallel-plate resonator is suitable for high power output than a stable resonator.
(90) The technique that carries out the oxygen plasma exposure prior to the surface-active bonding is especially effective for bonding the laser medium and the transparent heat transmitting member, however, it is not limited to this. For example, it is also effective in cases of bonding a laser medium constituted of oxide to a nontransparent heat transmitting member (metal heat sink such as Cu or CuW). In this case, the dielectric multilayer film is formed on the surface of the laser medium to adjust it to exhibit a property of total reflection. An alumina film, or a metal film such as Au, AuSn is formed on an outermost surface of the dielectric multilayer film. These laser medium and metal heat sink are exposed to the oxygen plasma, and thereafter surface-active bonded. Due to this, thermal resistance between the laser medium and the metal heat sink is maintained low, and bonding reliability is improved.
(91) Further, the pre-processing of exposing to the oxygen plasma may be replaced with another cleaning process, which is a cleaning process with less damage.
(92) The technique disclosed herein is especially effective in cases where at least one of the laser medium and the transparent heat transmitting member is oxide, however, it is not limited thereto, and it is effective also for cases where at least one of the laser medium and the transparent heat transmitting member contains light element. Especially, in cases where the light element included within first to third periods of the periodic table is contained, the transparency and stability of the bonding surface can be improved by subjecting the containing member to the oxygen plasma exposure for pre-washing.
(93) Specific examples of the present invention have been described in detail, however, these are mere exemplary indications and thus do not limit the scope of the claims. For example, the laser mediums and the transparent heat transmitting members appear alternately in the embodiments, however, there are cases where the laser mediums appear consecutively at parts in the serial arrangement. In such a case, the consecutive laser mediums can collectively be regarded as one laser medium. Thus, this is also complying with the rule that the laser mediums and the transparent heat transmitting members appear alternately.
(94) The art described in the claims includes modifications and variations of the specific examples presented above. Technical features described in the description and the drawings may technically be useful alone or in various combinations, and are not limited to the combinations as originally claimed. Further, the art described in the description and the drawings may concurrently achieve a plurality of aims, and technical significance thereof resides in achieving any one of such aims.