Pyrolysis reactor system for the conversion and analysis of organic solid waste

Abstract

The pyrolysis reactor system for the conversion and analysis of organic solid waste is a dual gas-liquid separation system, allowing for the conversion of organic solid waste, as well as analysis of the conversion products. A pyrolysis reactor is provided for converting the organic solid waste into a solid product and a gas-liquid product mixture through pyrolysis. A source of carrier gas is in fluid communication with the pyrolysis reactor for degrading the organic solid waste. A first gas-liquid separator is in fluid communication with the pyrolysis reactor and receives the gas-liquid product mixture therefrom, separating a portion of gas therefrom. A second gas-liquid separator is in fluid communication with the first gas-liquid separator and receives the gas-liquid product mixture therefrom and separates the remainder of the gas therefrom. The remainder of the gas and the separated liquid are each collected separately from one another, in addition to the char.

Claims

1. A pyrolysis reactor system for the conversion and analysis of organic solid waste, comprising: a pyrolysis fixed bed cylindrical reactor for converting organic solid waste into a solid product and a gas-liquid product mixture through pyrolysis, the reactor includes a three-zone furnace wherein each zone provides a temperature of up to 850 C., wherein the reactor includes a collection unit in direct communication therewith to collect the solid product; a source of carrier gas in contact with the pyrolysis reactor for achieving pyrolytic conditions therein; a first gas-liquid separator in fluid communication with the pyrolysis reactor and a chiller, the first gas-liquid separator receiving the gas-liquid product mixture directly from the pyrolysis reactor, separating a portion of gas therefrom, and outputting the portion of gas from the first gas-liquid separator for analysis thereof; a condenser receiving the gas-liquid product mixture directly from the first gas-liquid separator; a second gas-liquid separator in direct fluid communication with the condenser, the second gas-liquid separator receiving the gas-liquid product mixture therefrom and separating the remainder of the gas therefrom, whereby the remainder of the gas and the separated liquid are each collected separately from one another for analysis thereof; and a multi-port valve for separating the separated liquid into fractional components for automatic sampling of the liquid.

2. The pyrolysis reactor system as recited in claim 1, wherein said pyrolysis reactor further comprises an outlet hopper for receiving the solid product.

3. The pyrolysis reactor system as recited in claim 1, further comprising a mass flow controller in communication with said pyrolysis reactor and said source of carrier gas for selectively controlling rate of flow of the organic solid waste into said pyrolysis reactor.

4. The pyrolysis reactor system as recited in claim 1, wherein the carrier gas comprises nitrogen.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The sole drawing FIGURE is a schematic diagram of a pyrolysis reactor system for the conversion and analysis of organic solid waste according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

(2) The pyrolysis reactor system for the conversion and analysis of organic solid waste 10 is a dual gas-liquid separation system, allowing for the conversion of organic solid waste, such as plastics, biomass, municipal solid waste, etc. as well as analysis of the conversion products. As shown in the sole drawing FIGURE, a pyrolysis reactor 40 is provided for converting the organic solid waste (OSW) into a solid product and a gas-liquid product mixture through pyrolysis. It should be understood that any suitable type of pyrolysis reactor may be utilized, such as the conventional cylindrical, packed bed reactor 40 shown in the sole drawing FIGURE, which is coupled with a conventional three-zone furnace, heated by three separate temperature elements (TEs) 44, 48, 52, which are each respectively under the control of conventional temperature indicators/controllers (TICs) 46, 50, 54. The use of the conventional three-zone furnace allows for experimentation under varying temperatures and at varying points. TICs 46, 50, 54 may be thermocouples or the like. Each of the three zones may be selectively heated up to 850 C. Preferably, the pyrolysis reactor system for the conversion and analysis of organic solid waste 10 is scalable and allows for the treatment of different quantities of feedstock, preferably ranging from batches of 100 g to 600 g. The pyrolysis reactor system for the conversion and analysis of organic solid waste 10 can further preferably also handle a packing material, such as, for example, alumina packing.

(3) As in a conventional pyrolysis reaction system, a source of carrier gas 12, such as nitrogen or any other suitable non-combustible gas, is in fluid communication with the pyrolysis reactor 40 for delivering the organic solid waste (OSW) into the pyrolysis reactor 40. As in a conventional pyrolysis reaction system, the organic solid waste may be fed into the carrier stream (and, ultimately, the reactor 40) by any suitable type of feed hopper or the like. As shown in the sole drawing FIGURE, additional components may be utilized in the feed, such as a filter 14 allowing for separation out of material by size or type, as well as a pressure monitor, such as a pressure transducer (PT) or transmitter 16, allowing for active monitoring of the nitrogen pressure. A mass flow controller 24 may be further provided, allowing for the selective control over the flow rate of the organic solid waste (carried by the nitrogen gas). In the sole drawing FIGURE, the mass flow controller 24 is shown in communication with conventional needle valves 18, 20, 22 for controlling, at these points, the flow toward reactor 40. In this way, the mass flow can be controlled between 0 to 500 mL/min.

(4) Additionally, a check valve 26 or the like may be provided to prevent backflow from the reactor 40. As the organic solid waste is fed into feed bed 42 of the reactor 40, pre-heating thereof may be controlled by a further temperature element 28 and monitored by a corresponding temperature indicator (TI) 28. Pressure at the feed point may also be monitored by a pressure gauge (PG) 32, a pressure transducer or transmitter 34, or the like. Additionally safety measures, such as pressure safety or pressure relief valve 36 and/or a rupture disc 38, may also be provided in the feed line.

(5) Following pyrolysis of the organic solid waste, the solid product (i.e., char and ash) is collected in a hopper 56 and may be dispensed by an isolation valve 58 or the like. A first gas-liquid separator 70 is in fluid communication with the pyrolysis reactor 40 for receiving the gas-liquid product mixture therefrom and separating a portion of gas therefrom. The portion of gas is output from the first gas-liquid separator 70 for analysis thereof by a gas chromatograph (GC) 68 or the like. As shown, flow of the portion of gas delivered to GC 68 may be controlled by needle valves 60, 62 or the like. Further, the temperature of the gas portion may be controlled by temperature element 66 and monitored by temperature indicator 64. It should be understood that any suitable type of gas-liquid separation may be used, such as cooled gas-liquid separation. In this example, a chiller 72 is in fluid communication with the first gas-liquid separator 70. The chiller 72 further acts to provide the gas sample to the gas chromatograph 68 at an acceptable temperature for analysis. In the sole drawing FIGURE, the first gas-liquid separator 70 is shown as a conventional cooled jacket type gas-liquid separator. In this example, service fluid is circulated through the jacket, in a conventional manner, with the service fluid being temperature controlled by the chiller 72, which may operate in a range of 40 C. to 180 C. This further serves as a primary temperature guard, thus reducing the load on the condenser 74 and second gas-liquid separator 82 (as will be described in greater detail below).

(6) The gas-liquid mixture flows to a second gas-liquid separator 82, through the condenser 74 for full separation of the remainder of the gas from the liquid. It should be understood that any suitable type of condenser may be utilized. The condenser 74 is provided with sufficient heat transfer area to condense the product vapor delivered by the reactor 40 and the first gas-liquid separator 70. As with the first gas-liquid separator 70, the service fluid may be circulated into the condenser 74 in the range of 40 C. to 180 C. As shown, the gas is collected in a gas collector 86, and the flow thereto may be controlled and regulated by a back pressure regulator 84 or the like, which operates in conjunction with a pressure controller (PC) 100. Preferably, the second gas-liquid separator 82 is similar to the first gas-liquid separator 70, i.e., it may also be a conventional cooled jacket type gas-liquid separator. Here, the temperature of the circulating service fluid is selected based on the process requirements.

(7) The separated liquid is also delivered to a sample collection vessel 90, and samples may be dispensed through a needle valve 92 or the like. As shown, liquid flow may be under the control of a liquid control valve 80, which may be directly monitored and controlled by a liquid controller (LC) 102 (monitoring and controlling temperature, pressure, flow rate, etc.). The liquid controller 102 preferably includes level monitoring, allowing the valve 80 to act as a level control valve, enabling liquid sampling at a desired rate and preventing flooding of the delivery tube.

(8) As shown, a multi-port valve 98 may be provided for fractional separation of liquid components under nitrogen flow through a valve 96 for additional analysis of component fractions in a fraction collector 94. For example, a six-port valve may be used for automatic sampling of the liquid. When fractionation is desired, a sample collection vessel 90 is used to collect any excess product. As shown, any gases that may have been captured can exit the vessel 90, passing through a check valve 88 for collection in gas collector 86 for sampling thereof.

(9) It should be understood that the pyrolysis reactor system for the conversion and analysis of organic solid waste 10 may be used with a wide variety of organic solid and/or polymeric waste products. Thus, the end products will vary significantly. For example, the gases collected in gas collector 86 may be light hydrocarbon gases, and the liquids collected in vessel 90 and/or fraction collector 94 may be in the form of heavy waxes and oils. As an example, if the organic solid waste is a polyolefin, one may expect the resultant pyrolysis products to include ethane, ethane, propene and propane. If end of life tires (ELTs) are to be used and treated, one may epect styrene, butadiene and polyaromatics. Additionally, as noted above, although the pyrolysis reactor 40 may be any suitable type of pyrolysis reactor, such as, for example, a conventional fixed bed, batch reactor, the furnace associated therewith is preferably a conventional three-zone furnace. For purposes of study and analysis, one of the three zones of the pyrolysis reactor is selected for performance of the pyrolysis, and each of the three zones preferably operates at a unique temperature up to 850 C.

(10) It is to be understood that the present invention is not limited to the embodiments described above, but encompasses any and all embodiments within the scope of the following claims.