FULL-COLOR MONOLITHIC MICRO-LED PIXELS
20190229149 ยท 2019-07-25
Inventors
Cpc classification
H01L33/62
ELECTRICITY
H01L33/30
ELECTRICITY
H01L33/06
ELECTRICITY
H01L33/44
ELECTRICITY
H01L2933/0066
ELECTRICITY
International classification
H01L27/15
ELECTRICITY
H01L33/62
ELECTRICITY
H01L33/00
ELECTRICITY
H01L33/06
ELECTRICITY
H01L33/30
ELECTRICITY
H01L33/44
ELECTRICITY
Abstract
Monolithic pixels are implemented by laterally disposed green, blue and red micro-LED sub-pixels separated by dielectric sidewalls. The green and blue sub-pixels are formed with nitride-based material layers while the red sub-pixel is formed with non-nitride-based material layers that yield an optically-efficient red sub-pixel that is intensity-balanced with the green and blue sub-pixels.
Claims
1. A multi-color monolithic pixel comprising: a first sub-pixel having a light-emitting diode (LED) material stack that (i) includes at least one nitride material layer and (ii) has a light emitting surface; a second sub-pixel having a LED material stack that (i) includes at least one non-nitride material layer not included in the LED material stack of the first sub-pixel and (ii) has a light emitting surface that is substantially coplanar with the light emitting surface of the LED material stack of the first sub-pixel; and a shared dielectric sidewall disposed between the LED material stacks of the first and second sub-pixels.
2. The multi-color monolithic pixel of claim 1 wherein the at least one non-nitride material layer comprises gallium phosphide.
3. The multi-color monolithic pixel of claim 1 wherein the at least one non-nitride material layer comprises aluminum gallium arsenide.
4. The multi-color monolithic pixel of claim 1 wherein the LED material stack of the second sub-pixel lacks contains no nitride material layers.
5. The multi-color monolithic pixel of claim 1 wherein the LED material stack of the first sub-pixel comprises an active layer that emits visible light predominantly in the blue spectrum, and LED material stack of the second sub-pixel comprises an active layer that emits visible light predominantly in the red spectrum.
6. The multi-color monolithic pixel of claim 5 further comprising a third sub-pixel having an LED material stack that (i) lacks the non-nitride material layer included in the LED material stack of the second pixel and (ii) includes at least one nitride layer and an active layer that emits visible light predominantly in the green spectrum.
7. The multi-color monolithic pixel of claim 1 wherein the LED material stacks of each of the first and second sub-pixels has a light emitting surface having a dimension less than 100 microns.
8. The multi-color monolithic pixel of claim 1 wherein the LED material stack of the first sub-pixel comprises an active layer disposed between gallium nitride anode and cathode layers, and wherein the LED material stack of the second sub-pixel comprises an active layer disposed between non-nitride anode and cathode layers.
9. The multi-color monolithic pixel of claim 8 wherein the non-nitride anode and cathode layers of the LED material stack of the second sub-pixel comprise at least one of gallium phosphide or aluminum gallium arsenide.
10. The multi-color monolithic pixel of claim 1 wherein the LED material stacks of the first and second sub-pixels are mounted side by side on a display backplane.
11. A method of fabricating a multi-color monolithic pixel, the method comprising: epitaxially growing on a shared silicon substrate, as a first sub-pixel of the multi-color monolithic pixel, a first light-emitting diode (LED) material stack having at least one nitride material layer; and epitaxially growing on the shared silicon substrate, as a second sub-pixel of the multi-color monolithic pixel, a second LED material stack having at least one non-nitride material layer not included in the LED material stack of the first sub-pixel.
12. The method of claim 11 wherein epitaxially growing the first and second LED material stacks on the shared silicon substrate comprises epitaxially growing the first and second LED material stacks on a (111) silicon substrate.
13. The method of claim 11 wherein epitaxially growing the first and second LED material stacks on the shared silicon substrate comprises epitaxially growing the first and second LED material stacks on a silicon wafer.
14. The method of claim 11 wherein epitaxially growing the first LED material stack on the shared silicon substrate comprises forming a nitride-based buffer layer over the silicon substrate and epitaxially growing the first LED material stack on the nitride-based buffer layer, and wherein epitaxially growing the second LED material stack on the shared silicon substrate comprises forming a non-nitride-based buffer layer over the silicon substrate and epitaxially growing the second LED material stack on the nitride-based buffer layer.
15. The method of claim 11 wherein the at least one non-nitride material layer comprises at least one of gallium phosphide or aluminum gallium arsenide, and wherein the second LED material stack contains no nitride material layers.
16. The method of claim 11 wherein epitaxially growing the first LED material stack comprises epitaxially growing a nitride-based active layer that emits visible light predominantly in the blue spectrum, and wherein epitaxially growing the second LED material stack comprises epitaxially growing a non-nitride-based active layer that emits visible light predominantly in the red spectrum, the method further comprising epitaxially growing on the shared silicon substrate, as a third sub-pixel of the multi-color monolithic pixel, a third LED material stack having a nitride-based active layer that emits visible light predominantly in the green spectrum.
17. The method of claim 11 wherein epitaxially growing the first and second LED material stacks on the shared silicon substrate comprises epitaxially growing first and second LED material stacks having respective light emitting surfaces each with a dimension less than 100 microns.
18. The method of claim 11 further comprising forming a dielectric sidewall between and in contact with the first and second LED material stacks.
19. The method of claim 11 wherein epitaxially growing the first and second LED material stacks on the shared silicon substrate comprises epitaxially growing first and second LED material stacks having substantially coplanar light emitting surfaces.
20. A method of forming a light-emitting display, the method comprising epitaxially growing on a shared silicon substrate a first light-emitting diode (LED) material stack having at least one nitride material layer; and epitaxially growing on the shared silicon substrate a second LED material stack having at least one non-nitride material layer not included in the LED material stack of the first sub-pixel; and simultaneously bonding the first and second LED material stacks to a backplane of the light-emitting display to form first and second light-emitting elements thereof.
Description
DRAWING
[0004] The various embodiments disclosed herein are illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawings and in which like reference numerals refer to similar elements and in which:
[0005]
[0006]
[0007]
DETAILED DESCRIPTION
[0008] Monolithic pixels having laterally arranged micro-LED sub-pixels formed from heterogeneous red and blue/green material stacks are disclosed herein in various embodiments together with processes for their wafer-integrated fabrication and post-production application. In a number of embodiments, the monolithic pixels are each constituted by red, green and blue sub-pixels formed alternately with nitride-based material layers (blue and green sub-pixels) and non-nitride-based material layers (red sub-pixel)an approach that yields, with high process repeatability and control, an optically-efficient red sub-pixel that is intensity-balanced with counterpart green and blue sub-pixels all on the same wafer.
[0009]
[0010] Still referring to
[0011] A light-reflection and seed layer (collectively 147) is disposed on the bottom of each micro-LED material stack (micro-LEDs are inverted in the cross-sectional view with the bottom p-type layer shown on top), and cathode/anode contacts 151, 153 are formed respectively over the seed/reflection layer and a conductive via 155 (extending to the anode layer and electrically isolated from the cathode layer and MQW by via-isolation oxide 157). By this arrangement, a forward bias potential applied between the cathode and anode contacts for a given sub-pixel will produce electroluminescence (electron-hole recombination) within the corresponding multi-quantum-well and thus light emission. The bottom reflective layer and silicon oxide or silicon nitride sidewalls 158 (e.g., SiO.sub.2 or SiN.sub.X) redirect light toward the pixel surface (the carrier-side surface of the anode material layers) for enhanced surface light emission. Contact bumps or balls 161 enable one-step (i.e., solder reflow step) electrical contact and physical joining of the micro-pixels to a rigid or flexible display backplane.
[0012]
[0013] Referring first to
[0014] Still referring to
[0015] Proceeding from the structure at 195, buffer layers optimized for nitride epitaxy are deposited or grown over the wafer, followed by wafer-wide epitaxial growth of n-type gallium nitride (n-GaN) to yield the arrangement shown at 197. A silicon nitride mask is deposited selectively deposited or grown at the green sub-pixel site as shown at 199 (e.g., through wafer-wide SiN.sub.X deposition/growth, followed by masking at green sub-pixel site and etching away of unmasked silicon nitride from red and blue sub-pixel sites), followed by wafer-wide formation of blue-optimized multi-quantum-wells (MQW-B) and then wafer-wide formation of p-type gallium nitride (p-GaN) to yield the structure shown at 201. At this point, the blue sub-pixel material stack is complete, with the n-GaN and p-GaN layers forming the micro-LED anode and cathode, respectively, and the blue-optimized multi-quantum-well (MQW-B) forming the active layer of the LED.
[0016] At 203 (still
[0017] Still referring to
[0018] To finalize the hetero micro-pixel structure, a fourth passivation layer is formed wafer-wide as shown at 219, and then selectively masked at the red-pixel site as shown at 221. Thereafter, a multi-step process is carried out to etch the unmasked material stacks in the green and blue sub-pixel sites down to the second passivation and third layers, respectively. In one embodiment, for example, layers above the p-GaN layer of blue sub-pixel site and above the n-GaP layer of the green sub-pixel site are dry etched, followed by removal of the last layers of MQW-G and buffer-R above the second and third passivation layers in the blue and green sites, respectively, through chemical etch (e.g., H.sub.3PO.sub.4) that does not attack the passivation layers above the blue and green sub-pixel cathode layers. After etching down to the second and third passivation layers above the blue and green sub-pixel sites, the mask layer is stripped from the red sub-pixel site, followed by wafer-wide removal of the final passivation layersthat is, removing the second passivation layer from above the blue sub-pixels, removing the third passivation layer from above the green sub-pixels and removing the fourth passivation layer from above the red sub-pixels. The resulting wafer structure is shown at 223monolithic, laterally disposed micro-LED sub-pixels having phosphide-based (or non-nitride) red and nitride-based blue/green material stacks.
[0019] Reflecting on the LED material stacks within the finalized epitaxial structure, AlN and AlGaN buffer layers may be used for the blue and green sub-pixels, while non-nitride buffer layers (e.g., GaAs) are used for the red sub-pixel. In a number of process embodiments, two-step and modulation growth methods are employed to control the nucleation process of GaAs on the (111) silicon substrate within the red sub-pixel sitesan approach that grows substantially planar, low-defect two dimensional buffer layers instead of the high-defect three dimensional (i.e., textured-surface rather than planar) buffer layers that typically result from conventional GaAs on silicon epitaxy. The improved red-site buffer layer (i.e., improved planarity with reduced defect count) in turn enables successful epitaxial growth of high-quality red micro-LED structures.
[0020] As with the cathode and anode layers, nitride-based materials are used to grow the multi-quantum wells for the green and blue sub-pixels (e.g., InGaN for well layers and GaN for barrier layers), while non-nitride materials are used to grow the multi-quantum-well for the red sub-pixel (e.g., (AlIn).sub.XGa.sub.1-xP for well layers and (AlIn).sub.yGa.sub.1-yP for barrier layers, where x is generally less than y).
[0021] The micro-pixel fabrication process shown in
[0022] At 263, a second passivation layer is grown or deposited over the wafer, followed by patterned masking (e.g., photoresist) of the blue and red sub-pixel sites to enable selective material layer removal at the green sub-pixel site as shown at 265that is etching down to the nitride-based anode layer that is to be shared (at least temporarily) by the blue and green sub-pixels. At 267, a green-optimized multi-quantum-well layer is grown wafer-wide followed by wafer-wide growth of a nitride-based layer to form the green sub-pixel multi-quantum-well and cathode layers. The blue and green sub-pixel layer stacks are complete at this point, though it remains to electrically isolate either the blue/green cathode layers (the separately grown p-GaN layers in the embodiment shown), the shared anode layer or both so that the blue and green sub-pixels may be separately powered and controlled.
[0023] Still referring to
[0024] To finalize the micro-pixel structure, a fourth passivation layer is formed over the wafer, followed by selective masking over the red sub-pixel site as shown at 275. At this point the second, third and fourth passivation layers form a composite layer above the cathode layers of the blue, green and red sub-pixels, respectively. Accordingly, the unmasked material layers above the composite passivation layer (i.e., above the second passivation layer in the blue sub-pixel site and above the third passivation layer in the green sub-pixel site) are etched away, followed by removal of the masking material from the red sub-pixel site, resulting in the structure shown at 277. The composite passivation layer above the sub-pixel cathode layers is removed, followed by isolation sidewall formation (i.e., trench etching and oxide back-fill) to yield the wafer structure shown at 279monolithic, laterally disposed micro-LED sub-pixels having phosphide-based (or non-nitride) red and nitride-based blue/green material stacks.
[0025] The following additional considerations and options may bear on the choice of materials and process steps described in reference to
[0041]
[0042] As the conductive material layer will maintain wafer structural integrity at this point, the silicon substrate may be etched away (to yield the structure at 311) followed by removal of the heterogenous buffer layers as shown at 313. At 315, Micro-balls or bumps or other electrical contact structures (314) are deposited on the conductive-material surface above strategic contact points for the anode and cathode layers of the blue, green and red sub-pixels. The light-emission surfaces of the sub-pixels (i.e., exposed surfaces of the heterogenous anode layers) are textured at 317 to improve light emission efficiency, followed by adherence of the light-emission surface to a carrier structure (as shown at 319), such as a dicing tape or the like (e.g., blue tape or UV tape). At 321, the conductive material layer is patterned and etched to form electrically-distinct positive and negative contacts to the cathode and anode material layers of respective sub-pixels. At 323, streetlines between neighboring micro-pixels are etched away to singulate the micro-pixels, relying on individual pixel adherence to the carrier structure to maintain wafer-level micro-pixel alignment. At this point, the micro-pixels are ready for pre-transfer testing/repair (330) and then transfer to a display backplane. Carrier structure expansion operations may be carried out as necessary to establish a micro-pixel pitch according to the contact-pitch within the destined backplane.
[0043] In one embodiment, as part of pre-transfer testing/repair operation 330, wafer-level probing (e.g., effecting photo-luminescence by laser scanning, or by electrical probing/powering of individual micro-LEDs within the micro-pixel array) is carried out at 331 to identify and log the location/coordinates of defective micro-pixels, remove the defective micro-pixels (333) and replace the defective micro-pixels with known good micro-pixels (335). The replacement micro-pixels may be obtained from previous process runs (i.e., other micro-pixel wafers) or from peripheral or spare regions of the wafer under test/repair. In either case, after replacement of the defective micro-pixels, the wafer is ready for micro-pixel transfer. Accordingly, the wafer (or selected portions thereof) is aligned contact-to contact with a display backplane as shown at 341, followed by pressure and/or heat bonding of the adjoining contacts (343) and removal of the carrier to complete the transfer as shown at 345.
[0044] In the foregoing description and in the accompanying drawings, specific terminology and drawing symbols have been set forth to provide a thorough understanding of the disclosed embodiments. In some instances, the terminology and symbols may imply specific details that are not required to practice those embodiments. For example, any of the specific dimensions, quantities, material types, fabrication steps and the like can be different from or re-ordered relative to those described above. The term coupled is used herein to express a direct connection as well as a connection through one or more intervening circuits or structures. The terms exemplary and embodiment are used to express an example, not a preference or requirement. Also, the terms may and can are used interchangeably to denote optional (permissible) subject matter. The absence of either term should not be construed as meaning that a given feature or technique is required.
[0045] Various modifications and changes can be made to the embodiments presented herein without departing from the broader spirit and scope of the disclosure. For example, features or aspects of any of the embodiments can be applied in combination with any other of the embodiments or in place of counterpart features or aspects thereof. Accordingly, the specification and drawings are to be regarded in an illustrative rather than a restrictive sense.