Advanced CPV solar cell assembly process
10361326 · 2019-07-23
Assignee
Inventors
- Cécile Aulnette (Lumbin, FR)
- Rainer Krause (Mainz-Kostheim, DE)
- Frank DIMROTH (Freiburg, DE)
- Eric Guiot (Goncelin, FR)
- Eric Mazaleyrat (Crolles, FR)
- Charlotte Drazek (Grenoble, FR)
Cpc classification
H01L31/052
ELECTRICITY
H01L27/1421
ELECTRICITY
Y02E10/547
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L31/0443
ELECTRICITY
Y02E10/544
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
H01L31/0443
ELECTRICITY
H01L31/052
ELECTRICITY
H01L31/054
ELECTRICITY
H01L31/0693
ELECTRICITY
H01L31/028
ELECTRICITY
Abstract
This disclosure relates to a solar cell assembly structure for supporting a concentrator photovoltaic cell comprising a semiconducting structure and a diode, wherein the semiconducting structure comprises a first semiconducting region at least a part of which for placing the concentrator photovoltaic cell structure, and a second semiconducting region for realizing the diode within or on the second semiconducting region and wherein the part of the first semiconducting region for placing the concentrator photovoltaic cell structure and the second semiconducting region are not vertically overlapping.
Claims
1. A solar cell assembly structure, comprising: a concentrator photovoltaic cell structure; a diode; and a semiconductor structure, comprising: a first conductive region, the concentrator photovoltaic cell structure disposed on at least a part of the first conductive region, the first conductive region being doped n-type or p-type with a dopant concentration greater than 1E18 cm.sup.3; and a second conductive region doped with the same type of dopant as the first conductive region and with a lower concentration as the first conductive region, the diode disposed within or on the second conductive region; and an electrically conductive substrate electrically connecting the first conducting region and the second conducting region and providing a back contact between the diode and the photovoltaic cell; and wherein the first and second conductive regions do not vertically overlap with one another and are arranged in the same horizontal plane.
2. The solar cell assembly structure according to claim 1, further comprising an electrical contact pad in electrical contact with each of the diode and the concentrator photovoltaic cell structure.
3. The solar cell assembly structure according to claim 2, wherein the first and second conductive regions comprise a semiconductor material.
4. The solar cell assembly structure according to claim 3, wherein the electrically conductive substrate comprises a metal.
5. The solar cell assembly structure according to claim 1, wherein the diode comprises a first doped region and a second doped region, and wherein the first and second doped regions have different polarity.
6. The solar cell assembly structure according to claim 5, wherein the polarity of the diode is p-type on n-type, with a positive pole contacting a front contact and a negative pole contacting the first conductive region.
7. The solar cell assembly structure according to claim 6, wherein the first conducting region of the semiconductor structure has the same type of doping as the second doped region of the diode.
8. The solar cell assembly structure according to claim 7, wherein the first and/or second doped regions are realized via diffusion doping and/or epitaxial growth.
9. A solar cell assembly comprising a plurality of solar cell assembly structures according to claim 7 mounted on a heat sink.
10. The solar cell assembly according to claim 9, wherein the concentrator photovoltaic cell structure and the diode of each solar cell assembly structure of the plurality are bonded on the first and second conductive regions, respectively, using molecular or direct bonding.
11. The solar cell assembly according to claim 10, wherein the diode is connected in an antiparallel manner to the concentrator photovoltaic cell structure.
12. The solar cell assembly according to claim 11, wherein the concentrator photovoltaic cell structure is a multi-junction cell made of a III-V compound semiconductor, the III-V compound semiconductor selected from the group consisting of InGaAs, InGaAsP, GaAs, and InGaP.
13. The solar cell assembly according to claim 12, wherein the concentrator photovoltaic cell structure has a thickness lower than 10 m.
14. The solar cell assembly according to claim 13, wherein the concentrator photovoltaic cell structure comprises a bottom layer made of p-doped material and the first conductive region is p-doped, and molecular bonding is realized between the p-doped bottom layer and the first conductive region, and is a p-p bonding, type.
15. The solar cell assembly according to claim 13, wherein the concentrator photovoltaic cell structure comprises a top layer made of n-doped material and a bottom layer made of p-doped material and further comprises a p-n tunnel diode realized on the bottom layer, the first conductive region is n-doped, and molecular bonding is realized between a free n-doped face of the tunnel diode and the first conductive region, and is an n-n bonding type.
16. The solar cell assembly according to claim 13, with an area ratio between the solar cell assembly, structure and the concentrator photovoltaic cell structure in the range from 1.2 to 1 up to 10 to 1.
17. The solar cell assembly according to claim 13, wherein the solar cell assembly structures of the plurality are mounted on the heat sink via an adhesive.
18. A plurality of solar cell assembly structures according to claim 8, wherein the plurality of solar cell assembly structures is realized on a wafer with a diameter of 2 inches, 4 inches, 6 inches, 8 inches, 11 inches, or 400 cm and made of silicon or silicon on molybdenum.
19. The solar cell assembly structure according to claim 2, wherein the first and second conductive regions comprise Si.
20. The solar cell assembly structure according to claim 2, wherein the first and second conductive regions comprise Ge.
21. The solar cell assembly structure according to claim 2, wherein the first and second conductive regions comprise SiGe.
22. The solar cell assembly structure according to claim 3, wherein the electrically conductive substrate comprises molybdenum.
23. The solar cell assembly structure according to claim 3, wherein the electrically conductive substrate comprises tungsten.
24. The solar cell assembly according to claim 9, wherein the concentrator photovoltaic cell structure and the diode are bonded on the first and second conductive regions, respectively, using thermal compression bonding.
25. The solar cell assembly according to claim 9, wherein the concentrator photovoltaic cell structure and the diode are bonded on the first and second conductive regions, respectively, using metallic bonding.
26. The solar cell assembly according to claim 16, with an area ratio between the solar cell assembly structure and the concentrator photovoltaic cell structure in the range from 2 to 1 up to 4 to 1.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The disclosure will be described in more detail, by way of example, hereinafter using advantageous embodiments and with reference to the drawings. The described embodiments are only possible configurations in which the individual features may, however, as described above, be implemented independently of each other or may be omitted. Equal elements illustrated in the drawings are provided with equal reference signs. Parts of the description relating to equal elements illustrated in the different drawings may be left out. In the drawings:
(2)
(3)
(4)
(5)
(6)
DETAILED DESCRIPTION
(7) This disclosure will now be described with reference to specific embodiments. It will be apparent to the skilled person that features and alternatives from any of the embodiments can be combined, independently of each other, with features and alternatives of any other embodiment.
(8) In particular,
(9) More specifically, in
(10) Electrical contact pad 6110 is realized on semiconductor structure 1800 rather than heat sink 6100. For instance, the contact pad 6110 could be placed on the back side of the semiconductor structure, however, it is more preferential to realize all the contacts, in particular, contact pad 6110, on the front side, allowing easier connection to other solar cell assemblies. The contact could be realized, similarly to contacts 6210, 6410, by metal deposition, patterning, printing, etc. The diode 6220 acts as a protection against reverse currents that could occasionally flow through the photovoltaic cell 6420 and damage the latter, and both the diode 6220 and the photovoltaic cell 6420 are said to have opposite polarity or also commonly known to be connected in an antiparallel manner.
(11) Semiconductor structure 1800 or solar cell assembly structure 111 can have a lateral dimension in the range from 2 mm by 2 mm, up to 50 mm by 50 mm. The vertical dimension of the semiconductor structure 1800 or solar cell assembly structure 111 can be in the range 0.05 mm to 2 mm. Semiconductor structure 1800 can be realized in any of silicon, SiGe, Ge, or any semiconductor-on-metal or metal compounds substrate, in particular, silicon-on-molybdenum or tungsten, and any combinations thereof, as also described, for instance, with respect to
(12) The advantage of such structure consists in the fact that the layers 6240, 6250 as well as 6440, 6450 shown in
(13) The semiconductor structure 1800 or solar cell assembly structure 111 may be mounted on the heat sink 6100 via an adhesive 1810 if the heat transfer through the semiconductor structure 1800 alone is not sufficient. However, contrary to the case of
(14) Although the embodiment of
(15) Still alternatively, or in addition, the diode could be realized within semiconductor structure 1800, as will be described with reference to
(16) It is clear to those skilled in the art that any change of polarity of the photovoltaic cell structure 6420 or the diode 6220 from n-type over p-type to p-type over n-type is possible as long as the opposite polarity of the solar cell and bypass diode are maintained. Tunnel diodes below the photovoltaic cell structure 3420 or below the diode 2220 can be used to make an ohmic contact between an n-type and p-type semiconductor layer.
(17) The semiconductor structure 1800 shown in
(18) In particular,
(19) In particular, in
(20) Semiconductor structure 2800 or solar cell assembly structure 222 can have a lateral dimension in the range from 2 mm by 2 mm, up to 50 mm by 50 mm. The vertical dimension of the semiconductor structure 2800 or solar cell assembly structure 222 can be in the range from 0.05 mm to 2 mm. Semiconductor structure 2800 can be realized in any of silicon, SiGe, Ge, or any semiconductor-on-metal or metal compounds substrate, in particular, silicon-on-molybdenum or tungsten, and any combinations thereof, as also described, for instance, with respect to
(21) More specifically, in
(22) Here, as well as in the rest of the description, the term diode is to be interpreted generally. Accordingly, the diode 2220 can be realized by providing a doping of the region identified by reference numeral 2220, which is opposite to the doping of the rest of semiconductor structure 2800. For instance, the semiconductor structure 2800 could be doped with an n-type doping, while the diode 2220, which may require two polarities, could be doped with a p-type doping or vice-versa. Alternatively, the diode could be realized by providing both a p-type and an n-type doping, thereby realizing a p-n junction diode, in the region identified by reference numeral 2220. Still alternatively or in addition, the diode could be realized by a metal-semiconductor contact, for instance, by placing metal on the region identified by reference numeral 2220. In the following, for ease of description, all these and equivalent diode technology alternatives will be referred to as diode 2220. For instance, in
(23) In
(24) In
(25)
(26) In the three realizations of
(27) It is clear to those skilled in the art that any change of polarity inside the photovoltaic cell 3420 or the diode 2220 from n/p to p/n is possible as long as the opposite polarity of the solar cell and bypass diode are maintained. A tunnel diode below the photovoltaic cell 3420 can be used to make an ohmic contact between an n-type and p-type semiconductor layer.
(28) All of the above-mentioned realizations can, as will be clear to those skilled in the art, be combined in several manners.
(29) In general, the diode 2220 could be realized by doping the semiconductor structure 2800 with P, Sb, As (for instance, for the n-type in Si) or B, Ga, In (for instance, for the p-type in Si) with a concentration in the range of 5E15 to 5E20 cm.sup.3. The realization of diode 2220 within semiconductor structure 2800 could be realized by semiconductor technology processing, by processing the semiconductor structure 2800 alone, before joining it to the other elements of solar cell assembly 2000.
(30) Thus, instead of realizing the diode 6220 independently and then assembling it on heat sink, as in
(31) Additionally, as can be seen in
(32) Furthermore, the placement of the diode 2220 on the side of photovoltaic cell 3420 provides the further advantages that the diode is not in the thermal dissipation path of the photovoltaic cell 3420.
(33) 100641 The semiconductor structures 1800 and 2800 can advantageously be used as a carrier for a photovoltaic cell 6420 and 3420, which may otherwise not be stable alone for a subsequent pick-and-place process due to small thickness. In particular, the photovoltaic cell 6420 or 3420 can be placed, with the already mentioned pick-and-place method, or wafer bonded. The area ratio between the photovoltaic cell 6420 or 3420 and the semiconductor structures 1800 and 2800 can be in the range from 1.2 to 1, to 10 to 1, especially 2 to 1 to 4 to 1. This results in a semiconductor structure bigger than the photovoltaic cells 6420 and 3420, which gives place for the realization of the diode 6220 or 2220 and the electrical contact pad 6110, and facilitates the subsequent manufacturing steps, such as, for instance, a better handling is achieved for the pick-and-place process. For instance, gluing of the bigger semiconductor structures 1800 and 2800 on the heat sink 6100 is easier than gluing of the smaller photovoltaic cell 6420 or 3420, reducing the risk of damaging sensitive elements, such as, for instance, the cell.
(34)
(35) In particular,
(36) More specifically, doped region 5820, which includes the above-defined second semiconducting region, and which can have a lower doping than doped region 5830, which includes the above-defined first semiconducting region, are electrically connected via the electrically conductive substrate 5810. As a result of such arrangement, it is possible to achieve a low reverse current for the diode 2220, while still having a low resistance path through the doped region 5830. The low reverse current is advantageous since, as the diode 2220 is reverse-biased during normal operation of the photovoltaic cell, it reduces losses by reducing the current flowing through the diode.
(37) In some embodiments, the doping of doped region 5820 can be in the range from 5E15 to 5E17 cm.sup.3, while the doping of doped region 5830 can be in the range from 1E18 to 5E20 cm.sup.3. The materials used for doping of doped regions 5820 and/or 5830 can be B, Ga, P, Sb, As, In in case of Si or SiGe.
(38) Although doped region 5830 is illustrated as extending to the bottom and to the borders of semiconductor structure 5800, this disclosure is not limited thereto. Alternatively, doped region 5830 could be shaped so as to provide a doped layer of a thickness in the range of 300 nm to 2 mm surrounding the photovoltaic cell 6420. Similarly, the doped region 5820 can also be locally restricted around diode 2220.
(39) Although the alternative embodiment of
(40) All of the contacts mentioned in the above-described embodiments can be composed of materials like Au, Ag, Ti, Pd, Pt, Zn, Ge, Ni, etc., or, more generally, can be plated to achieve better conductivity.
(41) Any of the doped regions mentioned in the above-described embodiments can be realized via diffusion doping and/or epitaxial growth.
(42) Moreover, it will be clear to those skilled in the art that the n-p polarities described above can be reciprocally inverted, while still obtaining the same advantageous effects as far as facing of regions with the same doping polarity is concerned.
(43) It will be further clear to those skilled in the art that the different embodiments are examples only of the disclosure and that features from the embodiments can be combined in several advantageous ways, in accordance with the embodiments.