Method for fixing and treating a flexible plate on a drum and flexible plate
11535028 · 2022-12-27
Assignee
Inventors
Cpc classification
B41C1/05
PERFORMING OPERATIONS; TRANSPORTING
B41C1/1083
PERFORMING OPERATIONS; TRANSPORTING
B41F27/005
PERFORMING OPERATIONS; TRANSPORTING
B41N1/12
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A method for fixing and treating a flexible plate on a drum includes: providing a flexible plate comprising a support layer made of a first material and at least one additional layer made of a second material which is different from the first material, wherein one or more thin film side wings are connected to one or more sides of the flexible plate. The one or more thin film side wings have a thickness which is at least 5 times smaller than the thickness of the flexible plate. The method further includes positioning the flexible plate on the drum such that the lower face of each thin film side wing of the flexible plate covers at least one vacuum suction opening, and performing a treatment on at least one layer of the flexible plate while rotating the drum.
Claims
1. A method for fixing and treating a flexible plate on a drum with a plurality of vacuum suction openings, said method comprising the steps: providing a flexible plate comprising a support layer made of a first material and at least one additional layer made of a second material which is different from said first material, wherein one or more thin film side wings are connected to one or more sides of the flexible plate, said one or more thin film side wings having a thickness which is at least 5 times smaller than the thickness of the flexible plate, said one or more thin film side wings having a lower face which is substantially free from adhesive; positioning the flexible plate on the drum such that the lower face of each thin film side wing of the flexible plate covers at least one vacuum suction opening of the plurality of vacuum suction openings; and rotating the drum while applying vacuum through the plurality of vacuum suction openings, and performing a treatment on at least one layer of said at least one additional layer of the flexible plate while rotating the drum.
2. The method of claim 1, wherein the one or more thin film side wings comprise two longitudinal thin film side wings at opposite longitudinal sides of the flexible plate, and wherein the flexible plate is positioned on the drum with the two longitudinal thin film side wings oriented in a circumferential direction of the drum.
3. The method of claim 2, wherein the plurality of vacuum suction openings form a pattern extending in a circumferential direction and in an axial direction of the drum, wherein, seen in the axial direction the vacuum suction openings are arranged at a predetermined maximum distance of each other, and wherein a width (w) of each longitudinal thin film side wing of the flexible plate is larger than said predetermined maximum distance, such that at least one vacuum suction opening is covered by each longitudinal thin film side wing; wherein the width of the longitudinal thin film side wings, seen in a direction perpendicular on the opposite longitudinal sides, is larger than 0.5.
4. The method of claim 1, wherein the one or more thin film side wings comprise a leading and/or trailing thin film side wing attached to a leading and/or trailing edge of the flexible plate; and wherein the flexible plate is positioned on the drum with the leading and/or trailing thin film side wing oriented parallel to an axial direction of the drum such that, when positioned on the drum, the leading and/or trailing thin film side wing cover a portion between the leading edge and the trailing edge of the flexible plate.
5. The method of claim 1, wherein the performing of a treatment comprises removing material from at least one layer of the at least one additional layer.
6. The method of claim 1, wherein the one or more thin film side wings are fixed to the support layer.
7. The method of claim 1, wherein the one or more thin film side wings and the support layer are formed as one integral film.
8. The method of claim 1, wherein the flexible plate is substantially rectangular.
9. The method of claim 1, wherein the one or more thin film side wings each extend over at least 50% of the length of the respective side.
10. The method of claim 1, wherein the at least one additional layer comprises a photosensitive layer.
11. The method of claim 1, wherein the radius of the drum is larger than 15 cm.
12. The method of claim 1, wherein the drum is rotated with a speed between 10 and 5000 rpm.
13. The method of claim 1, wherein the flexible plate is a relief precursor; wherein the relief precursor is any one of the following: a direct engravable plate, such as a plate with an ablatable mask layer; a solvent or water developable plate; a thermally developable plate; a plate with a photosensitive layer, a plate with a photosensitive layer and an ablatable mask layer; a micro reactor; and a Fresnel lens.
14. The method of claim 1, wherein the one or more thin film side wings are provided as any one of the following: natural or artificial polymer films, coated paper, and a combination thereof.
15. The method of claim 1, wherein the one or more thin film side wings have a thickness which is smaller than 0.5 mm.
16. A treated flexible plate obtained according to the method of claim 1.
17. The method of claim 1, wherein said one or more thin film side wings has a thickness which is at least 10 times smaller than the thickness of the flexible plate.
18. A flexible plate suitable to be fixed on a drum, said flexible plate comprising: a support layer made of a first material and at least one additional layer made of a second material which is different from said first material, said additional layer configured to be treated while fixed on the drum, wherein one or more thin film side wings are connected to one or more sides of the flexible plate, wherein said one or more thin film side wings has a thickness which is at least 5 times smaller than the thickness of the flexible plate; and wherein said one or more thin film side wings has a lower face which is substantially free from adhesive.
19. The flexible plate according to claim 18, wherein the one or more thin film side wings are fixed to the support layer.
20. The flexible plate according to claim 18, wherein the one or more thin film side wings and the support layer are formed as one integral film.
21. The flexible plate according to claim 18, wherein the flexible plate has a thickness between 1 and 10 mm.
22. The flexible plate according to claim 18, wherein the flexible plate has a leading edge and a trailing edge and two opposite longitudinal sides extending between the leading and the trailing edge; wherein the one or more thin film side wings comprise: two longitudinal thin film side wings connected to the opposite longitudinal sides of the flexible plate; and/or a leading and/or trailing thin film side wing connected to the leading and/or trailing edge of the flexible plate, wherein the width of the two longitudinal thin film side wings, seen in a direction perpendicular on the opposite longitudinal sides of the flexible plate, is in the range of 0.5 mm to 100 mm.
23. The flexible plate according to claim 18, wherein the at least one additional layer comprises a photosensitive layer and a mask layer.
24. The flexible plate according to claim 18, wherein the thickness of the one or more thin film side wings is smaller than 0.5 mm.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The accompanying drawings are used to illustrate presently preferred non-limiting exemplary embodiments of devices of the present invention. The above and other advantages of the features and objects of the invention will become more apparent and the invention will be better understood from the following detailed description when read in conjunction with the accompanying drawings, in which:
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DESCRIPTION OF EMBODIMENTS
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(7) The flexible plate 100 of
(8) The flexible plate 100 is preferably a relief precursor with an additional layer 110 intended to contain a relief structure after treatment on the drum 200. For example, the additional layer 110 may be any one of the following: a direct engravable layer (e.g. by laser), a solvent or water developable layer, a thermally developable layer, a photosensitive layer, a combination of a photosensitive layer and a mask layer. Optionally there may be provided one or more further additional layers 160 on top of additional layer 110, see
(9) In a preferred embodiment the flexible plate 100 is a relief printing plate precursor, preferably with a support layer 170 made of a polyester of polymer material, and with an additional layer 110 made of a directly engravable material such as a resin material. The optional layer 160 may then be a laser ablative layer. In an exemplary embodiment the printing precursor may contain at least a dimensionally stable support layer 170, a relief layer 110 and an imagable mask layer 160.
(10) Optionally, further layers may be present. There may be a cover layer at the top of all other layers which is removed before the imagable mask layer 160 is imaged. There may be an anti-halation layer between the support layer 170 and the relief layer 110 or it may be located at the side of the support layer 170 which is opposite of the relief layer 110. There may be one or more barrier layers between the relief layer 110 and the imagable mask layer 160 which prevent diffusion of oxygen. Between the different layers described above one or more adhesion layers may be located which ensure proper adhesion of the different layers. One or more layers may be removable by treatment with a liquid. The liquids used may be the same or different for different layers. Preferably the liquids used are different.
(11) In a preferred embodiment the flexible plate is a relief precursor with a photosensitive layer and a mask layer. The mask layer may be ablated or changed in transparency during the treatment and forms a mask with transparent and non-transparent areas. Underneath of transparent areas of the mask the photosensitive layer undergoes a change in solubility and/or fluidity upon irradiation. The change is used to generate the relief by removing parts of the photosensitive layer in one or more subsequent steps. The change in solubility and/or fluidity may be achieved by photo-induced polymerization and/or crosslinking, rendering the irradiated areas less soluble and less meltable. In other cases the electromagnetic radiation may cause breaking of bonds or cleavage of protective groups rendering the irradiated areas more soluble and/or meltable. Preferably a process using photo-induced crosslinking and/or polymerization is used.
(12) In an embodiment the flexible plate comprises a photosensitive layer comprising at least a photo-initiator or a photo-initiator system, a binder and a reactive compound or monomer. A photo-initiator is a compound which upon irradiation with electromagnetic radiation may form a reactive species which can start a polymerization reaction, a crosslinking reaction, a chain or bond scission reaction which leads to a change of the solubility and/or meltability of the composition. Photo-initiators are known which cleave and generate radicals, acids or bases. Such initiators are known to the person skilled in the art and described e.g. in: Bruce M. Monroe et al., Chemical Review, 93, 435 (1993), R. S. Davidson, Journal of Photochemistry and Biology A: Chemistry, 73, 81 (1993), J. P. Faussier, Photoinitiated Polymerization Theory and Applications: Rapra Review. Vol. 9, Report, RapraTechnology (1998), M. Tsunooka et al., 25 Prog. Polym. Sci., 21, 1 (1996), F. D. Saeva, Topics in Current Chemistry, 1 56, 59 (1990), G. G. Maslak, Topics in Current Chemistry, 168, 1 (1993), H. B. Shuster et al., JAGS, 112, 6329 (1990) and I. D. F. Eaton et al., JAGS, 102, 3298 (1980), P. Fouassier and J. F. Rabek, Radiation Curing in Polymer Science and Technology, pages 77 to 117 (1993) or K. K. Dietliker, Photoinitiators for free Radical and Cationic Polymerisation, Chemistry & Technology of UV & EB Formulation for Coatings, Inks and Paints, Volume, 3, Sita Technology LID, London 1991; or R. S. Davidson, Exploring the Science, technology and Applications of U.V. and E.B. Curing, Sita Technology LTD, London 1999. Further initiators are described in JP45-37377, JP44-86516, U.S. Pat. Nos. 3,567,453, 4,343,891, EP109772, EP109773, JP63138345, JP63142345, JP63142346, JP63143537, JP4642363, JP59152396, JP611151197, JP6341484, JP2249 and JP24705, JP626223, JP6314340, JP1559174831, JP1304453 and JP1152109.
(13) Binders are linear, branched or dendritic polymers which may be homopolymers or copolymers. Copolymers can be random, alternating or block copolymers. As binder, those polymers which are either soluble, dispersible or emulsifiable in either aqueous solutions, organic solvents or combinations of both are used. Suitable polymeric binders are those conventionally used for the production of letterpress printing plates, such as completely or partially hydrolyzed polyvinyl esters, for example partially hydrolyzed polyvinyl acetates, polyvinyl alcohol derivatives, e. g. partially hydrolyzed vinyl acetate/alkylene oxide graft copolymers, or polyvinyl alcohols subsequently acrylated by a polymer-analogous reaction, as described, for example, in EP-A-0079514, EP-A-0224164 or EP-A-0059988, and mixtures thereof. Also suitable as polymeric binders are polyurethanes or polyamides which are soluble in water or water/alcohol mixtures, as described, for example, in EP-A-00856472 or DE-A-1522444. For flexographic printing precursors elastomeric binders are used. The thermoplastic-elastomeric block copolymers comprise at least one block which consists essentially of alkenylaromatics, and at least one block which consists essentially of 1,3-dienes. The alkenylaromatics may be, for example, styrene, α-methylstyrene, or vinyltoluene. Styrene is preferable. The 1,3-diener are preferably butadiene and/or isoprene. These block copolymers may be linear, branched, or radial block copolymers. Generally speaking, they are triblock copolymers of the A-B-A type, but they may also be diblock polymers of the A-B type, or may be polymers having a plurality of alternating elastomeric and thermoplastic blocks. A-B-A-B-A, for example. Mixtures of two or more different block copolymers may also be used. Commercial triblock copolymers frequently include certain fractions of diblock copolymers. The diene units may be 1,2- or 1,4-linked. Also possible for use, furthermore, are thermoplastic elastomeric block copolymers with styrene and blocks and a random styrene-butadiene middle block. Use may also be made, of course, of mixtures of two or more thermoplastic-elastomeric binders, provided that the properties of the relief-forming layer are not negatively impacted as a result. As well as the stated thermoplastic-elastomeric block copolymers, the photopolymerizable layer may also comprise further elastomeric binders other than the block copolymers. With additional binders of this kind, also called secondary binders, the properties of the photopolymerizable layer can be modified. Examples of a secondary binder are vinyltoluene-a-methylstyrene copolymers. These polymer hinders account for in general from 20 to 98%, preferably from 50 to 90% by weight of the total amount of the layer.
(14) Reactive compounds or monomers which are suitable for the preparation of the mixtures are those which are polymerizable and are compatible with the binders. Useful monomers of this type generally have a boiling point above 100° C. They usually have a molecular weight of less than 3000, preferably less than 2000. The ethylenically unsaturated monomers used ought to be compatible with the hinders, and they have at least one polymerizable, ethylenically unsaturated group. As monomers it is possible in particular to use esters or amides of acrylic acid or methacrylic acid with mono- or polyfunctional alcohols, amines, aminoalcohols or hydroxyethers and hydroxyesters, esters of fumaric acid or maleic, acid, and allyl compounds. Esters of acrylic acid or methacrylic acid are preferred. Preference is given to 1,4-butanediol diacrylate, 1,6-hexanediol diacrylate, 1,6-hexanediol dimethacrylate, 1,9-nonanediol diacrylate, or trimethylolpropane tri(meth)acrylate. Mixtures of different monomers can of course be used. The total amount of all the monomers used in the relief-forming layer together is generally 1 to 20 wt %, preferably 5 to 20 wt %, based in each case on the sum of all the constituents of the relief-forming layer. The amount of monomers having two ethylenically unsaturated groups is preferably 5 to 20 wt %, based on the sum of all constituents of the relief-forming layer, more preferably 8 to 18 wt %.
(15) The photosensitive layer may comprise further components. The further components are selected from the group consisting of a further polymer, a filler, a plasticizer, an anti-blocking agent, a monomer, an additive (e.g. a stabilizer, a dye), a stabilizer, a crosslinker, a binder, a colour forming compound, a dye, a pigment, an antioxidant and combinations thereof.
(16) In a further embodiment the flexible plate comprises a photosensitive layer as described above and a mask layer, the mask layer comprising at least a compound capable of absorbing electromagnetic radiation and a component capable of being removed by ablation (also known as digital plate precursor). Preferably the mask layer is an integral layer of the relief precursor and is in direct contact with the photosensitive layer or with a functional layer disposed between photosensitive layer and mask layer. This functional layer is preferably a barrier layer and blocks oxygen. The mask layer may be imagable by ablation and removable by solvents or by thermal development. The mask layer is heated and removed by irradiation with high energy electromagnetic radiation, whereby an image-wise structured mask is formed, which is used to transfer the structure onto the relief precursor. In order to do so the mask layer may be non-transparent in the UV region and absorb radiation in the VIS-IR region of the electromagnetic spectrum. The VIS-IR radiation may then be used to heat and ablate the layer. The optical density of the mask layer in the UV region between 330 and 420 nm is in the range of 1 to 5, preferably in the range of 1.5 to 4 and more preferably in the range of 2 to 4. Optical density is determined using a -rite 361TX Densitometer with the setting “Density” with UV-Filter. The optical density of the mask layer in the VIS-IR-region between 340 and 660 nm is in the range of 1 to 5, preferably in the range of 1.5 to 4 and more preferably in the range of 2 to 4. Optical density is determined using a -rite 361TX Densitometer with the setting “Density”.
(17) The layer thickness of the ablatable mask layer may be in the range of 0.1 to 5 μm, preferably 0.3 to 4 μm, more preferably 1 to 3 mm. The laser sensitivity of the mask layer (measured as energy needed to ablate 1 cm.sup.2) may be in the range of 0.1 to 10 mJ/cm.sup.2, preferably in the range of 0.3 to 5 mJ/cm.sup.2, most preferably in the range of 0.5 to 5 mJ/cm.sup.2.
(18) A first and a second longitudinal thin film side wing 120, 130 are connected to a first and a second opposite longitudinal side 112, 113 of the flexible plate 100, respectively. The two longitudinal thin film side wings 120, 130 protrude outwardly from the opposite longitudinal sides 112, 113 of the flexible plate 100. The thin film side wines 120, 130 have a thickness t which is at least 5 times, more preferably at least 10 times, even more preferably at least 50 times smaller than the thickness T of the flexible plate 100. The thickness T of the flexible plate 100 is the total thickness, i.e. including the thickness of the support layer 170 and any one or more additional layers 110, 160.
(19) According to an exemplary embodiment of the method, the flexible plate 100 is positioned on the drum 200 with the two longitudinal thin film side wings oriented in a circumferential direction of the drum 200, and such that each thin film longitudinal side wing 120, 130 of the flexible plate 100 covers at least one vacuum suction opening 250 of the plurality of vacuum suction openings 250, see
(20) After the positioning of the flexible plate 100 on the drum 200, a vacuum is applied through the plurality of vacuum suction openings 250 and the drum is rotated 200 whilst performing a treatment on at least one layer of the at least one additional layer 110, 160 of the flexible plate 100. The performing of a treatment may comprise removing material from at least one layer of the at least one additional layer 110, 160, e.g. by a laser, in order to obtain a relief structure in the at least one layer. In other embodiments the optional layer 160 may be a mask layer, and the treatment may comprise irradiating the additional layer 110, e.g. a photosensitive layer, through the mask layer 160. More generally the performing of a treatment may comprise any type of treatment, e.g. one of the following: exposure to electromagnetic waves; engraving; exposure to material jets, such as particle jets, fluid jets, gas jets; exposure to a plasma; exposure to a continuous web such as for thermal development; or combinations thereof.
(21) Preferably the thin film side wings 120, 130 are fixed to the support layer 170, and more preferably the thin film side wings 120, 130 are integrated with the support layer 170 (i.e. the support layer 170 and the side wings 120, 130 are provided as an integral layer), as in the embodiment of the
(22) The plurality of vacuum suction openings 250 form a pattern extending in a circumferential direction and in an axial direction of the drum 200, wherein, seen in the axial direction, the vacuum suction openings 250 are arranged at a predetermined maximum distance d of each other, see
(23) Preferably, the flexible plate 100 is substantially rectangular and the thin film side wings 120, 130 extend over at least 50% of the length of the opposite sides, preferably over at least 75%, more preferably over substantially the entire length of the opposite sides, as illustrated in the embodiment of
(24) Preferably, the radius of the drum 200 is larger than 15 cm. The length L of the flexible plate 100 may be e.g. between 10 cm and 100 cm, depending on the size of the drum 200. The width W may also vary depending on the length of the drum 200. It is noted that multiple flexible plates may be arranged next to each other on the drum 200.
(25) Preferably, the drum 200 is rotated with a speed which is between 10 and 5000 rpm, more preferable between 250 rpm and 1000 rpm.
(26) By providing the flexible plate 100 with thin film side wings 120, 130 on opposite sides, the flexible plate 100 will be fixed well, without having to tape the flexible plate 100 on the drum. Indeed, the thin film side wings 120, 130 extend over at least one vacuum suction opening 250 so that the opposite sides 112, 113 of the flexible plate 100 are maintained fixed against the drum 200, also when the drum rotates at a high speeds. Any risk that the opposite sides 112, 113 are detached is significantly reduced. The illustrated method results in a faster process which avoids a taping step. Further, since no taping step is needed, the method may be more easily automated by implementing e.g. an automated loading of the flexible plate 100 on the drum 200.
(27) The thin film side wings 120, 130 and/or the support layer 170 may be provided as any one of the following: natural or artificial polymer films, coated paper, a combination thereof. The thin film side wings 120, 130 and/or the support layer 170 may comprise any one of the following materials: polymer or polymer derivatives, such as polyalkene; (polyethylene, polyisoprene, polyhutadiene), polyamines, polyethers, polyols, polyesters (PET), polyamides, polyimides, polysaccharides; starch; cellulose. Preferably, the thin film side wings 120, 130 and/or the support layer 170 have a thickness t which is smaller than 500 micron, e.g. between 100 micron and 400 micron. The flexible plate 100 may have a thickness between 1 mm and 10 mm, preferably between 2 mm and 8 mm, even more preferably between 2 mm and 7 mm.
(28) Exemplary embodiments of the invention also relate to a treated flexible plate 100, e.g. an engraved printing plate, obtained according to the method of any one of the above described embodiments.
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(35) Other features of the flexible plate 100 that have been described above for
(36) Whilst the principles of the invention have been set out above in connection with specific embodiments, it is to be understood that this description is merely made by way of example and not as a limitation of the scope of protection which is determined by the appended claims.