Method for manufacturing nylon 66 hollow fiber
10344401 ยท 2019-07-09
Assignee
Inventors
- Yen-Hsiao Chen (Yunlin County, TW)
- Chung-Chen Wu (Yunlin County, TW)
- Chi-Lu Huang (Yunlin County, TW)
- Chuan-Shing Lin (Yunlin County, TW)
Cpc classification
D01D5/088
TEXTILES; PAPER
D03D15/283
TEXTILES; PAPER
D01D5/24
TEXTILES; PAPER
B29L2031/731
PERFORMING OPERATIONS; TRANSPORTING
B29B2013/005
PERFORMING OPERATIONS; TRANSPORTING
B29K2077/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
D01D5/096
TEXTILES; PAPER
D01D1/10
TEXTILES; PAPER
D03D15/00
TEXTILES; PAPER
D02J1/22
TEXTILES; PAPER
D01D5/24
TEXTILES; PAPER
Abstract
A method for manufacturing a nylon 66 hollow fiber includes steps as follows. A plurality of nylon 66 particles are provided. A melting step is provided, wherein the nylon 66 particles are melted so as to form a spun liquid. A fiber spitting step is provided, wherein the spun liquid goes through a hollow spinneret plate so as to form hollow nascent fibers. An evacuating step is provided, wherein the hollow nascent fibers are preliminarily solidified so as to form hollow half-solidified fibers. A cooling step is provided, wherein the hollow half-solidified fibers are cooled and solidified so as to form solidified fibers. A collecting and oiling step is provided. A drawing step is provided. A winding step is provided so as to obtain the nylon 66 hollow fiber.
Claims
1. A method for manufacturing a nylon 66 hollow fiber, comprising: providing a plurality of nylon 66 particles; providing a melting step, wherein the nylon 66 particles are melted so as to form a spun liquid; providing a fiber spitting step, wherein the spun liquid goes through a hollow spinneret plate so as to form a plurality of hollow nascent fibers; providing an evacuating step, wherein a thermal energy of the hollow nascent fibers is taken away by evacuating, and the hollow nascent fibers are preliminarily solidified so as to form a plurality of hollow half-solidified fibers; providing a cooling step, wherein a cooling wind with a temperature ranging from 16 C. to 22 C. is provided for cooling and solidifying the hollow half-solidified fibers so as to form a plurality of solidified fibers; providing a collecting and oiling step, wherein the solidified fibers are collected and oiled so as to form a bundled fiber; providing a drawing step, wherein the bundled fiber is drawn so as to form a stretched fiber, and the drawing step comprises a plurality of drawing sub-steps and an oiling sub-step, the oiling sub-step is conducted between two of the drawing sub-steps, and the bundled fiber is oiled by an oiling roller assembly; and providing a winding step, wherein the stretched fiber is wound around a cylindrical element so as to obtain the nylon 66 hollow fiber.
2. The method for manufacturing the nylon 66 hollow fiber of claim 1, wherein the drawing step comprises a first drawing sub-step, a second drawing sub-step, a third drawing sub-step, a fourth drawing sub-step, a fifth drawing sub-step and a sixth drawing sub-step, and the oiling sub-step is conducted between the first drawing sub-step and the second drawing sub-step.
3. The method for manufacturing the nylon 66 hollow fiber of claim 1, further comprising: providing a viscosity adjusting step, wherein a relative viscosity in sulfuric acid of the nylon 66 particles is adjusted to a range of 3.2 to 3.4.
4. The method for manufacturing the nylon 66 hollow fiber of claim 1, further comprising: providing a moisture adjusting step, wherein a moisture content of the nylon 66 particles is adjusted to a range of 500 ppm to 2000 ppm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The disclosure can be more fully understood by reading the following detailed description of the embodiment, with reference made to the accompanying drawings as follows:
(2)
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DETAILED DESCRIPTION
Method For Manufacturing A Nylon 66 Hollow Fiber
(8)
(9) In Step 110, a plurality of nylon 66 particles are provided. A weight-average molecular weight of the nylon 66 particles can be 30000 to 50000. A polydispersity index (PDI) of the nylon 66 particles can be 1.5 to 2.5. A relative viscosity in sulfuric acid of the nylon 66 particles can be in a range of 3.2 to 3.4. When the relative viscosity in sulfuric acid of the nylon 66 particles is smaller than 3.2, the strength of the nylon 66 hollow fiber may be excessively low. When the relative viscosity in sulfuric acid of the nylon 66 particles is greater than 3.4, the residence time of a spun liquid of nylon 66 in the manifold may be excessively long, and is unfavorable for spinning. A moisture content of the nylon 66 particles can be in a range of 500 ppm to 2000 ppm. Therefore, the moisture content of the nylon 66 particles is proper, better spinning properties can be obtained, and the probability of fiber break and degradation of the nylon 66 particles can be reduced.
(10) In Step 120, a melting step is provided, wherein the nylon 66 particles are melted so as to form the spun liquid. The melting step can be conducted in an extruder at a temperature ranging from 290 C. to 295 C. When the temperature is lower than 290 C., the current of the extruder increases, which is unfavorable for melting the nylon 66 particles. When the temperature is higher than 295 C., the nylon 66 particles tend to decomposed and cannot be spun.
(11) In Step 130, a fiber spitting step is provided, wherein the spun liquid goes through a hollow spinneret plate so as to form a plurality of hollow nascent fibers.
(12) In Step 140, an evacuating step is provided, wherein a thermal energy of the hollow nascent fibers is taken away by evacuating, and the hollow nascent fibers are preliminarily solidified so as to form a plurality of hollow half-solidified fibers. Therefore, an excessive swell of the hollow nascent fibers can be prevented. Accordingly, an excessively small inner diameter of the nylon 66 hollow fiber can be avoided. Furthermore, a rapid cooling of the hollow nascent fibers which may reduce a strength of the nylon 66 hollow fiber can be avoided.
(13) In Step 150, a cooling step is provided, wherein a cooling wind with a temperature ranging from 16 C. to 22 C. is provided for cooling and solidifying the hollow half-solidified fibers so as to form a plurality of solidified fibers. Therefore, the temperature of the cooling wind is proper. When the temperature is less than 16 C., the cooling is too fast, and the uniaxial alignment of the molecules is affected. When the temperature is greater than 22 C., the cooling is insufficient, which is unfavorable for the drawing step that follows. The wind speed of the cooling wind can be in the range of 0.55 m/s to 0.75 m/s.
(14) In Step 160, a collecting and oiling step is provided, wherein the solidified fibers are collected and oiled so as to form a bundled fiber. The technique of oiling the solidified fibers is conventional, and will not be described herein.
(15) In Step 170, a drawing step is provided, wherein the bundled fiber is drawn so as to form a stretched fiber.
(16)
(17) In Step 171, a first drawing sub-step is provided, wherein the bundled fiber is drawn with a rotational speed of 580 m/min to 780 m/min at room temperature. In Step 172, a second drawing sub-step is provided, wherein the bundled fiber is drawn with a rotational speed of 615 m/min to 815 m/min at a temperature ranging from 55 C. to 65 C. In Step 173, a third drawing sub-step is provided, wherein the bundled fiber is drawn with a rotational speed of 1700 m/min to 2300 m/min at a temperature ranging from 130 C. to 150 C. In Step 174, a fourth drawing sub-step is provided, wherein the bundled fiber is drawn with a rotational speed of 2600 m/min to 3200 m/min at a temperature ranging from 200 C. to 220 C. In Step 175, a fifth drawing sub-step is provided, wherein the bundled fiber is drawn with a rotational speed of 2950 m/min to 3350 m/min at a temperature ranging from 210 C. to 230 C. In Step 176, a sixth drawing sub-step is provided, wherein the bundled fiber is drawn with a rotational speed of 2780 m/min to 3180 m/min at a temperature ranging from 170 C. to 190 C. The strength of the final product, i.e., the nylon 66 hollow fiber, can be improved by the multistage draw of Step 171 to Step 176. Moreover, the bundled fiber can be heat set by Step 170. Accordingly, the internal stress of the bundled fiber can be reduced, and the hollow ratio of the final product, i.e., the nylon 66 hollow fiber, can be maintained.
(18)
(19) Please back to
(20)
(21) In Step 100, a viscosity adjusting step is provided, wherein a relative viscosity in sulfuric acid of the nylon 66 particles is adjusted to a range of 3.2 to 3.4. When the relative viscosity in sulfuric acid of the nylon 66 particles, such as the commercially available nylon 66 particles, is out the forging range, Step 100 can be conducted prior to Step 110, so that the yield and physical property of the nylon 66 hollow fiber can be enhanced.
(22) In Step 105, a moisture adjusting step is provided, wherein a moisture content of the nylon 66 particles is adjusted to a range of 500 ppm to 2000 ppm. When the moisture content of the nylon 66 particles, such as the commercially available nylon 66 particles, is out the forging range, Step 105 can be conducted prior to Step 110, so that the yield and physical property of the nylon 66 hollow fiber can be enhanced.
(23) The detail of Step 110 to Step 180 have been described above, and will not be repeated herein.
Equipment For Manufacturing the Nylon 66 Hollow Fiber
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(25) When manufacture the nylon 66 hollow fiber, the nylon 66 particles are put into the feeding tank 511 and then into the extruder 510. The nylon 66 particles are melted in the extruder 510 so as to form the spun liquid. A temperature of the extruder 510 can be ranging from 290 C. to 295 C. Afterward, the screw (not shown) within the extruder 510 is driven by the servo motor 512 so as to extrude the spun liquid from the extruder 510 into the manifold 520. The temperature of the manifold 520 is controlled in the range of 290 C. to 295 C., so that the solidification of the spun liquid can be prevented before the spun liquid enters into the spinning beam 530. Then the spun liquid flows from the manifold 520 into the spinning beam 530 and goes through the hollow spinneret plate 531 so as to form a plurality of hollow nascent fibers. Meanwhile, the evacuating room 540 is evacuated by the evacuating device 541, so that a thermal energy of the hollow nascent fibers is taken away by the evacuating device 541, and the hollow nascent fibers are preliminarily solidified so as to form a plurality of hollow half-solidified fibers. The evacuating rate of the evacuating device 541 can be 5 m/s to 12 m/s. Afterward, the hollow half-solidified fibers are cooled and solidified by the cooling wind provided by the cooling device 551 so as to form a plurality of solidified fibers, and the solidified fibers are collected and oiled by the collecting and oiling device 560 so as to form a bundled fiber. The bundled fiber is drawn by the first godet roller assembly 571, the second godet roller assembly 573, the third godet roller assembly 574, the fourth godet roller assembly 575, the fifth godet roller assembly 576, and the sixth godet roller assembly 577 of the drawing device 570, and oiled by the oiling roller assembly 572 of the drawing device 570, so that a stretched fiber is formed. The rotational speed of the first godet roller assembly 571 can be 580 m/min to 780 m/min. The rotational speed of the second godet roller assembly 573 can be 615 m/min to 815 m/min, and the temperature of the second godet roller assembly 573 can be 55 C. to 65 C. The rotational speed of the third godet roller assembly 574 can be 1700 m/min to 2300 m/min, and the temperature of the third godet roller assembly 574 can be 130 C. to 150 C. The rotational speed of the fourth godet roller assembly 575 can be 2600 m/min to 3200 m/min, and the temperature of the fourth godet roller assembly 575 can be 200 C. to 220 C. The rotational speed of the fifth godet roller assembly 576 can be 2950 m/min to 3350 m/min, and the temperature of the fifth godet roller assembly 576 can be 210 C. to 230 C. The rotational speed of the sixth godet roller assembly 577 can be 2780 m/min to 3180 m/min, and the temperature of the sixth godet roller assembly 577 can be ranging from 170 C. to 190 C. Finally, the stretched fiber is wound around the cylindrical element 581 so as to obtain the nylon 66 hollow fiber. The rotational speed of the winding device 580 can be 2800 m/min to 3200 m/min.
Nylon 66 Hollow Fiber
(26) A nylon 66 hollow fiber according to the present disclosure can be manufactured by the aforementioned method and equipment. A hollow ratio of the nylon 66 hollow fiber according to the present disclosure can be 8% to 12%. A hollow ratio of a conventional nylon 66 hollow fiber is about 1% to 3%. By using the method and equipment according to the present disclosure, the hollow ratio of the nylon 66 hollow fiber can be increased significantly. Furthermore, a strength of the nylon 66 hollow fiber according to the present disclosure can be 7.0 g/d to 9.0 g/d, and an elongation of the nylon 66 hollow fiber according to the present disclosure can be 20% to 26%, which shows that the nylon 66 hollow fiber according to the present disclosure can maintain the physical properties, such as strength and elongation while having a high hollow ratio.
Examples and Comparative Examples
Example 1
(27) the commercially available nylon 66 particles are dealt with a viscosity adjusting step. Specifically, the nylon 66 particles are put into a drying container, wherein nitrogen gas with a temperature of 175 C. is introduced into the drying container at a speed of 800 Nm.sup.3/hr. The dew point in the drying container is 20 C. A solid state polymerization of the nylon 66 particles is conducted. The time of the solid state polymerization is 24 hours, so that a relative viscosity in sulfuric acid of the nylon 66 particles is in a range of 3.2 to 3.4. Then a moisture adjusting step is provided. The nylon 66 particles dealt with the viscosity adjusting step (i.e., the solid state polymerization) are dried at 90 C. to 100 C. under nitrogen atmosphere till the moisture content of the nylon 66 particles is in the range of 500 ppm to 2000 ppm. The nylon 66 particles dealt with the viscosity adjusting step and the moisture adjusting step are used to produce the nylon 66 hollow fiber by the equipment in
Comparative Example 1
(28) the hollow spinneret plate 531 in Example 1 is replaced by a circular spinneret plate (both the shape and the number of the spinnerets of the circular spinneret plate are different from that of the hollow spinneret plate 531). When the spun liquid goes through the circular spinneret plate, a plurality of solid nascent fibers with circular cross section can be formed, and the final product of Comparative Example 1 is a nylon 66 solid fiber with circular cross section. Furthermore, the evacuating step and the oiling sub-step are omitted in Comparative Example 1. That is, the evacuating room 540 is not evacuated by the evacuating device 541, and the bundled fiber is not oiled by the oiling roller assembly 572. The other steps and conditions of Comparative Example 1 are the same as that of Example 1, and are listed in Table 1, whereby a 235/68 nylon 66 solid fiber is obtained.
Comparative Example 2
(29) Comparing to Example 1, the evacuating step and the oiling sub-step are omitted in Comparative Example 1. That is, the evacuating room 540 is not evacuated by the evacuating device 541, and the bundled fiber is not oiled by the oiling roller assembly 572. The other steps and conditions of Comparative Example 2 are the same as that of Example 1, and are listed in Table 1, whereby a 235/72 nylon 66 hollow fiber is obtained.
(30) TABLE-US-00001 TABLE 1 Example Comparative Comparative 1 Example 1 Example 2 Specification 235/72 235/68 235/72 cross section hollow circular hollow evacuated by the evacuating Yes No No device 541 wind speed/temperature 0.55/18 0.55/18 0.55/18 of the cooling wind [(m/s)/ C.] oiled by the oiling device 560 Yes Yes Yes rotational speed of the 680 680 680 first godet roller assembly 571 (m/min) oiled by the oiling roller Yes No No assembly 572. rotational speed/temperature 715/60 715/60 715/60 of the second godet roller assembly 573 [(m/min)/ C.] rotational speed/temperature 2000/140 2000/140 2000/140 of the third godet roller assembly 574 [(m/min)/ C.] rotational speed/temperature 2900/210 2900/210 2900/210 of the fourth godet roller assembly 575 [(m/min)/ C.)] rotational speed/temperature 3150/220 3150/220 3150/220 of the fifth godet roller assembly 576 [(m/min)/ C.)] rotational speed/temperature 2980/180 2980/180 2980/180 of the sixth godet roller assembly 577 [(m/min)/ C.)] rotational speed of the 3000 3000 3000 winding device 580 (m/min)
(31) The actual denier, strength, elongation and hollow ratio of the nylon 66 hollow fiber of Example 1 and Comparative Example 2 and the nylon 66 solid fiber of Comparative Example 1 are measured, wherein the measurement of the actual denier is according to ASTM D1907-2010, the measurement of the strength is according to ASTM 2256, the measurement of the elongation is according to ASTM 2256, and the measurement of the hollow ratio is as follows. First, the scanning electron microscope (SEM) photographs of the nylon 66 hollow fiber of Example 1 and comparative Example 2 are captured. Second, the inner diameter and the outer diameter of the nylon 66 hollow fiber of Example 1 and comparative Example 2 shown in the SEM photographs are measured. The hollow ratio is calculated from the following formula: the hollow ratio (%)=(inner diameter/outer diameter)*100%. The measuring result of the actual denier, the strength, the elongation and the hollow ratio of the nylon 66 hollow fiber of Example 1 and Comparative Example 2 and the nylon 66 solid fiber of Comparative Example 1 are listed in Table 2.
(32) TABLE-US-00002 TABLE 2 Comparative Comparative Example 1 Example 1 Example 2 actual denier (Denier) 210 235 210 strength (g/d) 8.4 8.3 8.25 elongation (%) 24.5 25.5 25 hollow ratio (%) 8-12 N/A 1-3
(33) As shown in Table 2, the hollow ratio of Example 1 is much greater than that of Comparative Example 2. It is apparent that the method and equipment for manufacturing the nylon 66 hollow fiber according to the present disclosure can effectively enhance the hollow ratio of the nylon 66 hollow fiber. Furthermore, the strength of Example 1 is better than that of Comparative Example 1, and the elongation of Example 1 is comparable to that of Comparative Example 1, which shows the nylon 66 hollow fiber according to the present disclosure can have a higher hollow ratio while maintaining the physical properties, such as strength and elongation, which are comparable to that of a nylon 66 solid fiber.
Example 2
(34) the nylon 66 hollow fiber of Example 1 is further processed so as to form a 450/144 air-textured yarn (ATY), and the air-textured yarn is woven so as to form a woven fabric, the warp densityweft density of the woven fabric is 4935. The unit of the warp density and the unit of the weft density are (number of the ATY)/inch.
Comparative Example 3
(35) the nylon 66 solid fiber of Comparative Example 1 is further processed so as to form a 500/136 air-textured yarn, and the air-textured yarn is woven so as to form a woven fabric, the warp densityweft density of the woven fabric is 4935. The unit of the warp density and the unit of the weft density are (number of the ATY)/inch.
(36) The taber abrasion, tearing strength and tensile strength of the woven fabric of Example 2 and Comparative Example 3 are measured, wherein the measurement of the taber abrasion is according to ASTMD-3884 (2000 cycle), the measurement of the tearing strength is according to ISO 13937-2, the measurement of the tensile strength is according to ISO 13934-1, and the measuring results are listed in Table 3.
(37) TABLE-US-00003 TABLE 3 Example Comparative 2 Example 3 taber Weight of a yard of the woven 6.7515 6.7707 abrasion fabric before abrasion (GSM) Weight of a yard of the woven 6.5638 6.5611 fabric after abrasion (GSM) Weight loss (%) 2.78 3.1 tearing strength (N) 111.08 101.0 tensile strength (N) 1289 1335
(38) The woven fabric of Example 2 is woven by ATY made of the nylon 66 hollow fiber, and the woven fabric of Comparative Example 3 is woven by ATY made of the nylon 66 solid fiber. The Denier of the ATY of Example 2 is smaller than that of Comparative Example 3. However, as shown in Table 3, the taber abrasion and the tearing strength of the woven fabric of Example 2 are better than that of Comparative Example 3, and the tensile strength of the woven fabric of Example 2 is only slightly inferior to that of Comparative Example 3. It is apparent that the woven fabric made of the nylon 66 hollow fiber according to the present disclosure can satisfy lightweight requirement while maintaining the tearing strength and the tensile strength and having an excellent taber abrasion.
(39) It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the present disclosure without departing from the scope or spirit of the disclosure. In view of the foregoing, it is intended that the present disclosure cover modifications and variations of this disclosure provided they fall within the scope of the following claims.