Stretch-sleeve film

Abstract

The present invention concerns a film (1), which contains at least one inner layer (3, 4, 5) and two outer layers (2, 6) enclosing at least one inner layer (3, 4, 5) where the, at least one, inner layer (3, 4, 5) contains a polymer A in a quantity from 70 to 100 wt. %, preferably 80 to 99 wt. % and especially preferably from 90 to 99 wt. %, relative to the total weight of the inner layer (3, 4, 5), which is characterized by special interesting properties, where the outer layers (2, 6) contain a mixture of polymer A and a polymer B, where polymer B is selected from the group consisting of low-density polyethylenes, said film (1) having a thickness from 30 to 70 m, preferably 35 to 60 m and especially 40 to 55 and an elastic restoring capacity of more than 95% at an elongation of 55%. The present invention also concerns a process for the production of a film, the use of the wealth. As a stretch-sleeve up film and articles provided with the oil of the invention, such as packaging. The present disclosure is directed to a stretch-sleeve film and articles including the stretch-sleeve film. The stretch-sleeve film includes at least three layers including two skin layers and a core layer. The core layer includes at least 75 wt % of an ethylene/a-olefin copolymer (A) characterized by (i) a density from 0.890 g/cc to 0.920 g/cc; (ii) a Mw/Mn from 2.0 to 4.0; (iii) a ZSVR less than 6.0; and (iv) a CDC from 85 to 150. At least one skin layer includes a polymeric material selected from the ethylene/a-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof. The stretch-sleeve film has an elastic recovery at 55% stretch of at least 95%.

Claims

1. A stretch-sleeve film comprising: a. at least three layers comprising two skin layers and a core layer; b. the core layer comprising at least 75 wt % of an ethylene/1-octene copolymer (A) characterized by i. a density from 0.890 g/cc to 0.910 g/cc; ii. a Mw/Mn from 2.0 to 4.0; iii. a ZSVR less than 6.0; iv. a CDC from 85 to 150; v. a vinyl unsaturation of less than 0.15 vinyls per 1000 carbon atoms; and c. at least one of the skin layers comprises a polymeric material selected from the group consisting of the ethylene/1-octene copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

2. The stretch-sleeve film of claim 1 wherein the core layer comprises from 75 wt % to 100 wt % of the ethylene/1-octene copolymer (A) and from 25 wt % to 0 wt % of a polymeric material selected from the group consisting of a low density polyethylene, a medium density polyethylene, and combinations thereof.

3. The stretch-sleeve film of claim 1 wherein the core layer comprises from 75 wt % to 99 wt % of the ethylene/1-octene copolymer (A) and from 25 wt % to 1 wt % of a low density polyethylene.

4. The stretch-sleeve film of claim 1 wherein each skin layer is composed of the same polymeric material, the polymeric material selected from the group consisting of the ethylene/1-octene copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

5. The stretch-sleeve film of claim 1 wherein the stretch-sleeve film is a coextruded blown film.

6. The stretch-sleeve film of claim 1 comprising at least one inner layer located between the core layer and a skin layer, the inner layer comprising a polymeric material selected from the group consisting of the ethylene/1-octene copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

7. The stretch-sleeve film of claim 1 wherein the stretch-sleeve film comprises at least two inner layers, wherein each inner layer is located between the core layer and one of the skin layers.

8. The stretch-sleeve film of claim 1 having a thickness from 25 microns to 75 microns.

9. The stretch-sleeve film of claim 1 having an elastic recovery at 55% stretch of at least 95%.

10. The stretch-sleeve film of claim 1 having a tensile strength greater than 30 MPa.

11. The stretch-sleeve film of claim 1 having a modulus of elasticity of at least 95 MPa.

12. An article comprising: a container; and the stretch-sleeve film of claim 1, the stretch-sleeve film surrounding an outer surface of the container.

13. The article of claim 12 wherein the film is compressively engaged to the outer surface with a holding force expressed as tensile strength from 4 MPa to 10 MPa.

14. The article of claim 12 wherein the stretch-sleeve film comprises at least one of printing and a colorant.

Description

(1) The present invention is explained in more detail below with reference to the preferred examples of embodiments and the drawings. They show:

(2) FIG. 1 is a schematic structure of one variant of the film, according to the invention

(3) FIG. 2 is a representation of a bottle provided with the film of the invention

(4) FIG. 3 is an improved representation of the grooves on the bottle, according to FIG. 2.

(5) FIG. 4 is an NMR spectrograph showing the resins analyzed for the determination of unsaturation.

ADDITIONAL BACKGROUND AND SUMMARY

(6) Stretch-sleeves provide a cost effective method for decorating complex shaped containers. They also enable the wall thickness of plastic containers to be reduced, eliminate the need for colored containers, and provide new types of promotional opportunities. Stretch-sleeves are able to achieve these benefits through the sleeve conforming tightly to the container shape. These many benefits have made stretch-sleeves one of the fastest growing label technologies in recent years.

(7) Conventional stretch-sleeves, however, lack the stretchability to conform to highly contoured bottles and containers. A need therefore exists for stretch-sleeve films with improved properties, such as improved stretchability and elasticity, to meet the demand of containers with ever-greater degrees of contour.

(8) The present disclosure is directed to a stretch-sleeve film. In an embodiment, the stretch-sleeve film includes at least three layers including two skin layers and a core layer. The core layer includes at least 75 wt % of an ethylene/-olefin copolymer (A) characterized by (i) a density from 0.890 g/cc to 0.920 g/cc; (ii) a Mw/Mn from 2.0 to 4.0; (iii) a ZSVR less than 6.0; and (iv) a CDC from 85 to 150.

(9) At least one skin layer includes a polymeric material selected from the ethylene/-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(10) In an embodiment, the stretch-sleeve film has an elastic recovery at 55% stretch of at least 95%.

(11) The present disclosure is directed to an article. In an embodiment, the article includes a container and a stretch-sleeve film surrounding an outer surface of the container. The stretch-sleeve film includes at least three layers including two skin layers and a core layer. The core layer includes at least 75 wt % of an ethylene/-olefin copolymer (A) characterized by (i) a density from 0.890 g/cc to 0.920 g/cc; (ii) a Mw/Mn from 2.0 to 4.0; (iii) a ZSVR less than 6.0; and (iv) a CDC from 85 to 150

(12) At least one skin layer includes a polymeric material selected from the ethylene/-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(13) In an embodiment, the stretch-sleeve film has an elastic recovery at 55% stretch of at least 95%.

(14) The present disclosure is directed to a stretch-sleeve film. In an embodiment, the stretch-sleeve film includes at least three layers including two skin layers and a core layer. The core layer includes at least 75 wt % of an ethylene/-olefin copolymer (A) characterized by (i) a density from 0.890 g/cc to 0.920 g/cc; (ii) a Mw/Mn from 2.0 to 4.0; (iii) a ZSVR less than 6.0; and (iv) a CDC from 85 to 150.

(15) At least one skin layer includes a polymeric material selected from the ethylene/-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(16) 1. Stretch-Sleeve Film

(17) The present disclosure provides a stretch-sleeve film. A stretch-sleeve film, as used herein, is a tubular (or closed loop) single-piece film having an elastic recovery sufficient to compressively hold the stretch-sleeve in a set position on the outer surface of an object. The natural memory (elastic recovery) of the film material is sufficient to hold the stretch-sleeve in place by way of compressive friction-fit. A stretch-sleeve does not require an adhesive to stay in place on the outer surface of the object, such as a container, for example.

(18) A stretch-sleeve is different than, and is distinct from, a shrink sleeve or a shrink wrap because a stretch-sleeve does not require exposure to heat (such as by way of a heat tunnel, for example) to trigger elastic recovery, or shrink.

(19) A stretch-sleeve film is tubular in configuration and when applied, the stretch-sleeve film extends around the entire perimeter (or circumference) of an object (such as a container) to completely surround at least one cross-sectional (plane) perimeter of the target object.

(20) Stretch-sleeve films are typically applied to objects (such as containers) with stretch-sleeve labeling machinery. When in place, the stretch-sleeve compresses (i.e., contracts) radially inward around the object, contacting the outer surface of the object. The stretch-sleeve applies a radially inward compressive force onto the outer surface of the object sufficient to adhere the stretch-sleeve to the object.

(21) The stretch-sleeve film is also able to expand or contract with the object. Stretch-sleeve films find advantageous application as labels for containers (polymeric, glass, metal), squeeze bottles, carbonated beverage containers, hot-fill container, and cold-fill containers which typically exhibit container expansion and contraction.

(22) 2. Ethylene/-olefin Copolymer (A)

(23) The present stretch-sleeve film includes at least three layers including two skin layers and a core layer. The core layer includes at least 75 wt % of an ethylene/-olefin copolymer (A). The ethylene/-olefin copolymer (A) is an ethylene-based polymer. The term ethylene-based polymer is a polymer that contains more than 50 mole percent polymerized ethylene monomer (based on the total amount of polymerizable monomers) and contains at least one comonomer.

(24) The ethylene/-olefin copolymer (A) includes (a) less than 100 percent, for example, at least 70 percent, or at least 80 percent, or at least 90 percent, by weight of the units derived from ethylene; and (b) less than 30 percent, for example, less than 25 percent, or less than 20 percent, or less than 10 percent, by weight of units derived from one or more -olefin comonomers. The term ethylene/-olefin copolymer refers to a polymer that contains more than 50 mole percent polymerized ethylene monomer (based on the total amount of polymerizable monomers) and, optionally, may contain at least one comonomer.

(25) The -olefin comonomers typically have no more than 20 carbon atoms. For example, the -olefin comonomers may preferably have 3 to 10 carbon atoms, and more preferably 3 to 8 carbon atoms. Exemplary -olefin comonomers include, but are not limited to, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, and 4-methyl-1-pentene. The one or more -olefin comonomers may be, for example, selected from the group consisting of propylene, 1-butene, 1-hexene, and 1-octene; or in the alternative, from the group consisting of 1-hexene and 1-octene.

(26) The ethylene/-olefin copolymer (A) is characterized by having a Comonomer Distribution Constant (CDC) in the range of from greater than from 45 to 400, for example from 75 to 300, or from 75 to 200, or from 85 to 150, or from 85 to 130.

(27) The ethylene/-olefin copolymer (A) is characterized by having a zero shear viscosity ratio (ZSVR) in the range of from 2 to 20, for example, from 2 to 10, or from 2 to 6, or from 2.5 to 4.

(28) The ethylene/-olefin copolymer (A) has a density in the range of 0.890 to 0.930 g/cc. For example, the density can be from a lower limit of 0.890, or 0.895, or 0.900, 0.901, 0.902, 0.903, or 0.904 g/cc to an upper limit of 0.910, or 0.920, or 0.925, or 0.930 g/cc.

(29) The ethylene/-olefin copolymer (A) has a molecular weight distribution (M.sub.w/M.sub.n) in the range of from 1.8 to 3.5. For example, the molecular weight distribution (M.sub.w/M.sub.n) can be from a lower limit of 1.8, 2, 2.1, or 2.2 to an upper limit of 2.5, 2.6, 2.7, 2.9, 3.2, or 3.5. The ethylene/-olefin copolymer (A) has a melt index (I.sub.2) in the range of 0.1 to 5 g/10 minutes. For example, the melt index (I.sub.2) can be from a lower limit of 0.1, 0.2, 0.5, or 0.8 g/10 minutes to an upper limit of 1.2, 1.5, 1.8, 2.0, 2.2, 2.5, 3.0, 4.0, 4.5 or 5.0 g/10 minutes.

(30) The ethylene/-olefin copolymer (A) has a molecular weight (M.sub.w) in the range of 50,000 to 250,000 Daltons. For example, the molecular weight (M.sub.w) can be from a lower limit of 50,000, 60,000, 70,000 Daltons to an upper limit of 150,000, 180,000, 200,000 or 250,000 Daltons.

(31) The ethylene/-olefin copolymer (A) has a molecular weight distribution (M.sub.z/M.sub.w) in the range of less than 4, for example, less than 3, or from 2 to 2.8.

(32) The ethylene/-olefin copolymer (A) has a vinyl unsaturation of less than 0.15 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition.

(33) The ethylene/-olefin copolymer (A) has a long chain branching frequency in the range of from 0.02 to 3 long chain branches (LCB) per 1000 carbons (1000 C).

(34) In one embodiment, the ethylene/-olefin copolymer (A) comprises less than or equal to 100 parts, for example, less than 10 parts, less than 8 parts, less than 5 parts, less than 4 parts, less than 1 parts, less than 0.5 parts, or less than 0.1 parts, by weight of metal complex residues remaining from a catalyst system comprising a metal complex of a polyvalent aryloxyether per one million parts of the ethylene-based polymer composition. The metal complex residues remaining from the catalyst system comprising a metal complex of a polyvalent aryloxyether in the ethylene-based polymer composition may be measured by x-ray fluorescence (XRF), which is calibrated to reference standards. The polymer resin granules can be compression molded at elevated temperature into plaques having a thickness of about of an inch for the x-ray measurement in a preferred method. At very low concentrations of metal complex, such as below 0.1 ppm, ICP-AES would be a suitable method to determine metal complex residues present in the ethylene-based polymer composition.

(35) The ethylene/-olefin copolymer (A) may further comprise additional components such as one or more other polymers and/or one or more additives. Such additives include, but are not limited to, antistatic agents, color enhancers, dyes, lubricants, fillers such as TiO.sub.2 or CaCO.sub.3, opacifiers, nucleators, processing aids, pigments, primary antioxidants, secondary antioxidants, processing aids, UV stabilizers, anti-blocks, slip agents, tackifiers, fire retardants, anti-microbial agents, odor reducer agents, anti-fungal agents, and combinations thereof. The ethylene/-olefin copolymer (A) may contain from about 0.1 to about 10 percent by the combined weight of such additives, based on the weight of the ethylene/-olefin copolymer including such additives.

(36) In one embodiment, ethylene/-olefin copolymer (A) has a comonomer distribution profile comprising a monomodal distribution or a bimodal distribution in the temperature range of from 35 C. to 120 C., excluding purge.

(37) Any conventional ethylene (co)polymerization reaction processes may be employed to produce the ethylene-based polymer composition. Such conventional ethylene (co)polymerization reaction processes include, but are not limited to, gas phase polymerization process, slurry phase polymerization process, solution phase polymerization process, and combinations thereof using one or more conventional reactors, e.g. fluidized bed gas phase reactors, loop reactors, stirred tank reactors, batch reactors in parallel, series, and/or any combinations thereof.

(38) In an embodiment, the ethylene/-olefin copolymer (A) is prepared via a process comprising the steps of: (a) polymerizing ethylene and optionally one or more -olefins in the presence of a first catalyst to form a semi-crystalline ethylene-based polymer in a first reactor or a first part of a multi-part reactor; and (b) reacting freshly supplied ethylene and optionally one or more -olefins in the presence of a second catalyst comprising an organometallic catalyst thereby forming an ethylene/-olefin interpolymer composition in at least one other reactor or a later part of a multi-part reactor, wherein at least one of the catalyst systems in step (a) or (b) comprises a metal complex of a polyvalent aryloxyether corresponding to the formula:

(39) ##STR00001##

(40) wherein M.sup.3 is Ti, Hf or Zr, preferably Zr;

(41) Ar.sup.4 is independently in each occurrence a substituted C.sub.9-20 aryl group, wherein the substituents, independently in each occurrence, are selected from the group consisting of alkyl; cycloalkyl; and aryl groups; and halo-, trihydrocarbylsilyl- and halohydrocarbyl-substituted derivatives thereof, with the proviso that at least one substituent lacks co-planarity with the aryl group to which it is attached;

(42) T.sup.4 is independently in each occurrence a C.sub.2-20 alkylene, cycloalkylene or cycloalkenylene group, or an inertly substituted derivative thereof;

(43) R.sup.21 is independently in each occurrence hydrogen, halo, hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di(hydrocarbyl)amino group of up to 50 atoms not counting hydrogen;

(44) R.sup.3 is independently in each occurrence hydrogen, halo, hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino of up to 50 atoms not counting hydrogen, or two R.sup.3 groups on the same arylene ring together or an R.sup.3 and an R.sup.21 group on the same or different arylene ring together form a divalent ligand group attached to the arylene group in two positions or join two different arylene rings together; and

(45) R.sup.D is independently in each occurrence halo or a hydrocarbyl or trihydrocarbylsilyl group of up to 20 atoms not counting hydrogen, or 2 R.sup.D groups together are a hydrocarbylene, hydrocarbadiyl, diene, or poly(hydrocarbyl)silylene group.

(46) In an embodiment, the ethylene/-olefin copolymer (A) is produced by way of a polyvalent aryloxyether (hereafter polyvalent aryloxyether-catalyzed HDPE) that is [2,2-[1,3-propanediylbis(oxy-O)]bis[3,5,5-tris(1,1-dimethylethyl)-5-methyl[1,1:3,1-terphenyl]-2-olato-O]]dimethyl-, (OC-6-33)-Zirconium, represented by the structure (I) below.

(47) ##STR00002##

(48) The ethylene/-olefin copolymer (A) may be produced via a solution polymerization according to the following exemplary process.

(49) All raw materials (ethylene, 1-octene) and the process solvent (a narrow boiling range high-purity isoparaffinic solvent commercially available under the tradename Isopar E from ExxonMobil Corporation) are purified with molecular sieves before introduction into the reaction environment. Hydrogen is supplied in pressurized cylinders as a high purity grade and is not further purified. The reactor monomer feed (ethylene) stream is pressurized via mechanical compressor to a pressure that is above the reaction pressure, approximate to 750 psig. The solvent and comonomer (1-octene) feed is pressurized via mechanical positive displacement pump to a pressure that is above the reaction pressure, approximately 750 psig. The individual catalyst components are manually batch diluted to specified component concentrations with purified solvent (Isopar E) and pressurized to a pressure that is above the reaction pressure, approximately 750 psig. All reaction feed flows are measured with mass flow meters, independently controlled with computer automated valve control systems.

(50) The continuous solution polymerization reactor system may consist of two liquid full, non-adiabatic, isothermal, circulating, and independently controlled loops operating in a series configuration. Each reactor has independent control of all fresh solvent, monomer, comonomer, hydrogen, and catalyst component feeds. The combined solvent, monomer, comonomer and hydrogen feed to each reactor is independently temperature controlled to anywhere between 5 C. to 50 C. and typically 40 C. by passing the feed stream through a heat exchanger. The fresh comonomer feed to the polymerization reactors can be manually aligned to add comonomer to one of three choices: the first reactor, the second reactor, or the common solvent and then split between both reactors proportionate to the solvent feed split. The total fresh feed to each polymerization reactor is injected into the reactor at two locations per reactor roughly with equal reactor volumes between each injection location. The fresh feed is controlled typically with each injector receiving half of the total fresh feed mass flow. The catalyst components are injected into the polymerization reactor through specially designed injection stingers and are each separately injected into the same relative location in the reactor with no contact time prior to the reactor. The primary catalyst component feed is computer controlled to maintain the reactor monomer concentration at a specified target. The two cocatalyst components are fed based on calculated specified molar ratios to the primary catalyst component. Immediately following each fresh injection location (either feed or catalyst), the feed streams are mixed with the circulating polymerization reactor contents with static mixing elements. The contents of each reactor are continuously circulated through heat exchangers responsible for removing much of the heat of reaction and with the temperature of the coolant side responsible for maintaining isothermal reaction environment at the specified temperature. Circulation around each reactor loop is provided by a screw pump. The effluent from the first polymerization reactor (containing solvent, monomer, comonomer, hydrogen, catalyst components, and molten polymer) exits the first reactor loop and passes through a control valve (responsible for maintaining the pressure of the first reactor at a specified target) and is injected into the second polymerization reactor of similar design. As the stream exits the reactor, it is contacted with a deactivating agent, e.g. water, to stop the reaction. In addition, various additives such as antioxidants, can be added at this point. The stream then goes through another set of static mixing elements to evenly disperse the catalyst deactivating agent and additives.

(51) Following additive addition, the effluent (containing solvent, monomer, comonomer, hydrogen, catalyst components, and molten polymer) passes through a heat exchanger to raise the stream temperature in preparation for separation of the polymer from the other lower boiling reaction components. The stream then enters a two stage separation and devolatilization system where the polymer is removed from the solvent, hydrogen, and unreacted monomer and comonomer. The recycled stream is purified before entering the reactor again. The separated and devolatized polymer melt is pumped through a die specially designed for underwater pelletization, cut into uniform solid pellets, dried, and transferred into a hopper.

(52) In an embodiment, the ethylene/-olefin copolymer (A) has one, some or all of the following properties: (i) a density from 0.890 g/cc to 0.920 g/cc; (ii) a Mw/Mn from 2.0 to 4.0; (iii) a ZSVR less than 6.0; and (iv) a CDC from 85 to 150.

(53) In an embodiment, the ethylene/-olefin copolymer (A) is an ethylene/octene copolymer and has one, some or all of the following properties: (i) a density from 0.900 g/cc to 0.91 g/cc; (ii) a Mw/Mn from 2.0 to 3.0; (iii) a ZSVR from 2.0 to 4.0; (iv) a CDC from 100 to 130; (v) an I.sub.2 from 0.5 g/10 min to 1.5 g/10 min; (vi) an I.sub.10/I.sub.2 from 7.5 to 8.5; (vii) a vinyl unsaturation of less than 0.15 vinyls per 1000 carbon atoms; (viii) a Tm from 97 C. to 103 C.; and (ix) a heat of melting from 100 J/g to 110 J/g.

(54) The present ethylene/-olefin copolymer (A) may comprise two or more embodiments disclosed herein.

(55) 3. Skin Layers

(56) The present stretch-sleeve film includes two skin layers. A skin layer, as used herein, is the outermost layer of the film. The skin layers may be the same or may be different.

(57) The skin layers are composed of a polymeric material selected from the ethylene/-olefin copolymer (A) (described above), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(58) In an embodiment, the skin layers are composed of a polymeric material selected from the ethylene/-olefin copolymer (A) (described above), a low density polyethylene, a medium density polyethylene a polyolefin plastomer, an ethylene vinyl acetate copolymer (EVA) with less the 5 wt % vinyl acetate (VA), and combinations thereof.

(59) A low density ethylene-based polymer (or LDPE) is an ethylene homopolymer having a density from 0.915 g/cc to 0.930 g/cc and is produced by way high pressure free radical polymerization, in a tubular, or autoclave process or hybrids thereof. The LDPE excludes linear low density polyethylene, excludes high density polyethylene (i.e., ethylene-based polymer with density greater than 0.94 g/cc) and excludes the ethylene/-olefin copolymer (A).

(60) The LDPE has an M.sub.w/M.sub.n greater than 5.0, or greater than 6.0. In an embodiment, the LDPE has an M.sub.w/M.sub.n with a lower limit from 6.0, or 7.0, or 8.0 to an upper limit from 10.0, or 11.0, or 12.0, or 13.0, or 14.0, or 15.0.

(61) The LDPE has an I.sub.2 from 0.1 g/10 min to 30 g/10 min, or 0.2 g/10 min to 15 g/10 min, or from 0.5 g/10 min to 5.0 g/10 min. In an embodiment, the LDPE has an I.sub.2 from 1.0 g/10 min to 5.0 g/10 min.

(62) In an embodiment, the LDPE has a density from 0.915 g/cc to 0.925 g/cc and a melt index from 0.5 g/10 min to 5.0 g/10 min.

(63) In an embodiment, the LDPE is produced in a high-pressure tubular reactor (HP-LDPE). The HP-LDPE has a density from 0.915 g/cc, or 0.920 g/cc to 0.93 g/cc. The HP-LDPE has an I.sub.2 from 0.5 g/10 min, or 1.0 g/10 min, or 2.0 g/10 min, to 3.0 g/10 min, or 4.0 g/10 min, or 5.0 g/10 min.

(64) In an embodiment, the LDPE is a HP-LDPE (tubular) with one, some, or all of the following properties: a density from 0.915 g/cc to 0.930 g/cc; a M.sub.w/M.sub.n from 5.0 to 7.0; and an I.sub.2 from 0.5 g/10 min to 5.0 g/10 min.

(65) A medium density polyethylene, (or MDPE), as used herein, is an ethylene-based polymer having a density range from 0.926 g/cc to less than 0.940 g/cc. MDPE can be produced by chromium/silica catalysts, Ziegler-Natta catalysts, constrained geometry catalysts or metallocene catalysts. The MDPE excludes LDPE, excludes HDPE, and excludes the ethylene/-olefin copolymer (A).

(66) The MDPE includes (a) less than or equal to 100 percent, for example, at least 70 percent, or at least 80 percent, or at least 90 percent, by weight of the units derived from ethylene; and (b) less than 30 percent, for example, less than 25 percent, or less than 20 percent, or less than 10 percent, by weight of units derived from one or more -olefin comonomers.

(67) The -olefin comonomers typically have no more than 20 carbon atoms. For example, the -olefin comonomers may have 3 to 10 carbon atoms, or 3 to 8 carbon atoms. Exemplary -olefin comonomers include, but are not limited to, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, and 4-methyl-1-pentene. In an embodiment, the one or more -olefin comonomers may, for example, be selected from propylene, 1-butene, 1-hexene, and 1-octene, and combinations thereof. In a further embodiment, the one or more -olefin comonomers are selected from 1-hexene, 1-octene, and combinations thereof.

(68) The MDPE has a weight average molecular weight (M.sub.w) in the range from 15,000 to 150,000 Daltons. For example, the molecular weight (M.sub.w) can be from a lower limit of 15,000, 20,000, or 30,000 Daltons to an upper limit of 100,000, 120,000, or 150,000 Daltons.

(69) The MDPE has a melt index (MI or I.sub.2) in the range from 0.5 g/10 minutes (min) to 5.0 g/10 minutes. For example, the melt index (I.sub.2) can be from a lower limit of 0.5, or 1.0, or 1.5 2.0, or 2.5 or g/10 minutes to an upper limit of 3.5 or 4.0, or 4.5, or 5.0 g/10 minutes.

(70) Each of the ethylene/-olefin copolymer (A), the MDPE and the LDPE may further include additional optional components such as one or more additives. Such additives include, but are not limited to, antistatic agents, color enhancers, dyes, lubricants, fillers, pigments, primary antioxidants, secondary antioxidants, processing aids, UV stabilizers, anti-blocks, slip agents, tackifiers, fire retardants, anti-microbial agents, odor reducer agents, anti-fungal agents, and combinations thereof.

(71) In an embodiment, the core layer of the stretch-sleeve film includes from 75 wt % to 100 wt % of the ethylene/-olefin copolymer (A) and from 25 wt % to greater than 0 wt %, or 0 wt % of a polymeric material selected from a low density polyethylene, a medium density polyethylene, and combinations thereof. Weight percent is based on total weight of the core layer.

(72) In an embodiment, the core layer includes from 75 wt % to 99 wt % of the ethylene/-olefin copolymer (A) and from 25 wt % to 1 wt % of a LDPE.

(73) In an embodiment, the core layer includes 100 wt % of the ethylene/-olefin copolymer (A). Weight percent is based on total weight of the core layer.

(74) In an embodiment, each skin layer is composed of the same polymeric material(s). The polymeric material for the skin layers is selected from the ethylene/-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(75) In an embodiment, the stretch-sleeve film is a three layer film and consists of the two skin layers and the core layer (skin/core/skin).

(76) In an embodiment, the stretch-sleeve film includes at least one inner layer. The inner layer is located between the core layer and a skin layer. The inner layer is composed of one or more polymeric materials selected from the ethylene/-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(77) In an embodiment, the stretch-sleeve film includes at two inner layers. Each inner layer is located between the core layer and a skin layer. The inner layers can be the same or can be different. Each inner layer is composed of one or more polymeric materials selected from the ethylene/-olefin copolymer (A), a low density polyethylene, a medium density polyethylene, and combinations thereof.

(78) In an embodiment, the stretch-sleeve film is a three layer film with the following structure: A/B/C. In a further embodiment, the skin layers (A and C) are composed of the same material.

(79) In an embodiment, the stretch-sleeve film is a five layer film with the following structure: A/B/C/D/E. In a further embodiment, the skin layers (A and E) are composed of the same material. In a further embodiment, the inner layers (B/C/D) are composed of the same material.

(80) In an embodiment, the stretch-sleeve film is a seven layer film with the following structure: A/B/C/D/E/F/G. In a further embodiment, the skin layers (A and G) are composed of the same material. In a further embodiment, the inner layers (B/C/D/E/F) are composed of the same material.

(81) In an embodiment, each skin layer has a thickness that is from 5% to 15% of the overall thickness of the stretch-sleeve film.

(82) In an embodiment, the stretch-sleeve film has a thickness from 25 microns, or 30 microns, or 40 microns to 60 microns, or 70 microns, or 75 microns.

(83) In an embodiment, the stretch-sleeve film has a thickness of 50 microns.

(84) In an embodiment, stretch-sleeve film is a coextruded blown film.

(85) The present stretch-sleeve film may be produced using any blown film extrusion or co-extrusion processes. Blown film extrusion processes are essentially the same as regular extrusion processes up until the die. The die in a blown film extrusion process is generally an upright cylinder with a circular opening similar to a pipe die. The diameter can be a few centimeters to more than three meters across. The molten plastic is pulled upwards from the die by a pair of nip rolls above the die (from 4 meters to 20 meters or more above the die depending on the amount of cooling required). Changing the speed of these nip rollers will change the gauge (wall thickness) of the film. Around the die sits an air-ring. The air-ring cools the film as it travels upwards. In the center of the die is an air outlet from which compressed air can be forced into the center of the extruded circular profile, creating a bubble. This expands the extruded circular cross section by some ratio (a multiple of the die diameter). This ratio, called the blow-up ratio or BUR can be just a few percent to more than 200 percent of the original diameter. The nip rolls flatten the bubble into a double layer of film whose width (called the layflat) is equal to the circumference of the bubble. This film can then be spooled or printed on, cut into shapes, and heat sealed into bags or other items.

(86) In some instances a blown film line capable of producing a greater than desired number of layers may be used. For example, a five layer line may be used to produce a 3 layered stretch-sleeve film. In such cases, one or more of the stretch-sleeve film layers comprises two or more sub-layers, each sub-layer having an identical composition.

(87) The present stretch-sleeve film has an elastic recovery at 55% stretch of at least 95%. A further embodiment, the stretch-sleeve film has an elastic recovery at 60% stretch of at least 95%. Bounded by no particular theory, Applicant discovered that the presence of at least 75 wt % of the ethylene/-olefin copolymer (A) in the core layer improves elastic recovery. The present stretch-sleeve film also exhibits suitable film stiffness for effective sleeving operations, suitable sleeve sealing strength, and suitable optical properties for printability.

(88) In an embodiment, the stretch-sleeve film has a tensile strength from 25 MPa to 40 MPa. In a further embodiment, the stretch-sleeve film has a tensile strength greater than 30 MPa, or greater than 30 MPa to 40 MPa.

(89) In an embodiment, the stretch-sleeve film has a modulus of elasticity from 75 MPa to 200 MPa. In a further embodiment, the stretch-sleeve film has a modulus of elasticity of at least 95 MPa to 150 MPa.

(90) 4. Article

(91) The present disclosure provides an article. In an embodiment, the article includes a container and the present stretch-sleeve film surrounds an outer circumference of the container. The stretch-sleeve film may be any stretch-sleeve film as previously discussed herein.

(92) The container may be made of metal, wood, glass, or a polymeric material (such as HDPE or PET). In an embodiment, the container is a bottle. Nonlimiting examples of suitable bottles include squeeze bottle, carbonated beverage bottle, hot-fill bottle, and cold-fill bottle.

(93) In an embodiment, the stretch-sleeve film is compressively engaged to the outer container surface with a holding force expressed as tensile strength from 4 MPa to 10 MPa at elongation from 5% to 60%.

(94) In an embodiment, the stretch-sleeve film includes printing (such as branding, for example).

(95) In an embodiment, the stretch-sleeve film includes a colorant.

(96) In an embodiment, the stretch-sleeve film includes a point of weakness to facilitate removal of the stretch-sleeve film from the container.

(97) In an embodiment, the stretch-sleeve film is a high-contour stretch-sleeve film. A high-contour stretch-sleeve film, as used herein, is a stretch-sleeve film wherein the stretched diameter (sleeve is stretched radially outward, or stretched diameter) of the stretch-sleeve film is at least 50% greater than the unstretched sleeve (sleeve is unstretched radially, or unstretched diameter). In a further embodiment, the high-contour stretch-sleeve film has a stretched diameter at least 50%, or 55%, or 60%, or 65% greater than the unstretched diameter.

(98) The present stretch-sleeve film molds into the contours of a shaped container, a shaped bottle or jar without the need for heat or glue application. The present stretch-sleeve film, and the present high-contour stretch-sleeve film in particular, is suitable to mold to the contours of a high-contour container. A high-contour container, as used herein, is a container or bottle, where the difference in largest to smallest diameter along the height of the container or bottle covered by a sleeve exceeds 50%. In an embodiment, a high-contour container includes radial ribs separated by 0.5 millimeter (mm), or 1 mm, or 2 mm, or 3 mm, or 4 mm, or 5 mm to 6, mm, or 7 mm, or 8 mm, or 9 mm, or 10 mm.

(99) Non-limiting examples of suitable articles include food products (dairy containers, juice containers, energy drink bottles, carbonated beverage bottles, non-carbonated beverage bottles, alcohol beverage bottles) and condiment containers.

(100) Definitions

(101) The terms comprising, including, having and their derivatives do not exclude the presence of any additional component or procedure. The term, consisting essentially of excludes any other component or procedure, except those essential to operability. The term consisting of excludes any component or procedure not specifically stated.

(102) The term polymer is a macromolecular compound prepared by polymerizing monomers of the same or different type. Polymer includes homopolymers, copolymers, terpolymers, interpolymers, and so on. The term interpolymer means a polymer prepared by the polymerization of at least two types of monomers or comonomers. It includes, but is not limited to, copolymers (which usually refers to polymers prepared from two different types of monomers or comonomers, terpolymers (which usually refers to polymers prepared from three different types of monomers or comonomers), tetrapolymers (which usually refers to polymers prepared from four different types of monomers or comonomers), and the like.

(103) Test Methods

(104) Density

(105) Samples that are measured for density are prepared according to ASTM D-1928. Measurements are made within one hour of sample pressing using ASTM D-792, Method B.

(106) Elastic recovery and modulus of elasticity are measured in accordance with ASTM D5459-95 (Reapproved 2012); Standard Test Method for Machine Direction Elastic Recovery and Permanent Deformation and Stress Retention of Stretch Wrap Film; modified for stretch labels as follow:

(107) Specimen width: 15 mm

(108) Gap distance: 150 mm

(109) Test speed to desired elongation: 500 mm/minute (min)

(110) Holding time at elongation: 3 seconds

(111) Return speed: 500 mm/min

(112) Holding time @ 0% elongation: 6 seconds

(113) Speed to get minimum force of 0.1N/15 mm: 100 mm/min

(114) Tensile strength is measured in accordance with ISO 527-3: 1995; PlasticsDetermination of tensile properties with the following conditions used:

(115) Specimen: Type 2

(116) Test speed: 5 mm/min

(117) Grips: Convex

(118) Grip distance: 100 mm

(119) Holding force (expressed as tensile strength) is determined in accordance with ISO 527-3:1995; PlasticsDetermination of tensile properties with the following conditions:

(120) Specimen: Type 1

(121) Test speed: 5 mm/min

(122) Grips: Convex

(123) Grip distance: 100 mm

(124) Melt Index

(125) Melt index (MI), or I.sub.2, is measured in accordance with ASTM-D 1238, Condition 190 C./2.16 kg, and is reported in grams eluted per 10 minutes. I.sub.10 is measured in accordance with ASTM-D 1238, Condition 190 C./10 kg, and is reported in grams eluted per 10 minutes.

(126) Gel Permeation Chromatography (GPC)

(127) The Gel Permeation Chromatography (GPC) system consists of a Waters (Milford, Mass.) 150 C. high temperature chromatograph (other suitable high temperatures GPC instruments include Polymer Laboratories (Shropshire, UK) Model 210 and Model 220) equipped with an on-board differential refractometer (RI) (other suitable concentration detectors can include an IR4 infra-red detector from Polymer ChAR (Valencia, Spain)). Data collection is performed using Viscotek TriSEC software, Version 3, and a 4-channel Viscotek Data Manager DM400. The system is also equipped with an on-line solvent degassing device from Polymer Laboratories (Shropshire, United Kingdom).

(128) Suitable high temperature GPC columns can be used such as four 30 cm long Shodex HT803 13 micron columns or four 30 cm Polymer Labs columns of 20-micron mixed-pore-size packing (MixA LS, Polymer Labs). The sample carousel compartment is operated at 140 C. and the column compartment is operated at 150 C. The samples are prepared at a concentration of 0.1 grams of polymer in 50 milliliters of solvent. The chromatographic solvent and the sample preparation solvent contain 200 ppm of trichlorobenzene (TCB). Both solvents are sparged with nitrogen. The polyethylene samples are gently stirred at 160 C. for four hours. The injection volume is 200 microliters. The flow rate through the GPC is set at 1 ml/minute.

(129) The GPC column set is calibrated by running 21 narrow molecular weight distribution polystyrene standards. The molecular weight (MW) of the standards ranges from 580 to 8,400,000, and the standards are contained in 6 cocktail mixtures. Each standard mixture has at least a decade of separation between individual molecular weights. The standard mixtures are purchased from Polymer Laboratories. The polystyrene standards are prepared at 0.025 g in 50 mL of solvent for molecular weights equal to or greater than 1,000,000 and 0.05 g in 50 mL of solvent for molecular weights less than 1,000,000. The polystyrene standards are dissolved at 80 C. with gentle agitation for 30 minutes. The narrow standards mixtures are run first and in order of decreasing highest molecular weight component to minimize degradation. The polystyrene standard peak molecular weights are converted to polyethylene molecular weight using the following Equation (as described in Williams and Ward, J. Polym. Sci., Polym. Letters, 6, 621 (1968)):
M.sub.polyethylene=A(M.sub.polystyrene).sup.B,

(130) where M is the molecular weight of polyethylene or polystyrene (as marked), and B is equal to 1.0. It is known to those of ordinary skill in the art that A may be in a range of about 0.38 to about 0.44 and is determined at the time of calibration using a broad polyethylene standard. Use of this polyethylene calibration method to obtain molecular weight values, such as the molecular weight distribution (MWD or M.sub.w/M.sub.n), and related statistics (generally refers to conventional GPC or cc-GPC results), is defined here as the modified method of Williams and Ward.

(131) The moments of the molecular weight distribution, M.sub.n (number-average molecular weight), M.sub.w (weight-average molecular weight) and M.sub.z (z-average molecular weight) are computed from the data as follows, where W.sub.i is weight fraction of species with molecular weight M.sub.i:

(132) $M_n=\frac{\underset{i}{.Math.}{W}_i}{\underset{i}{.Math.}\left(W_i/M_i\right)}{M}_w=\frac{\underset{i}{.Math.}{W}_i.Math.M_i}{\underset{i}{.Math.}{W}_i}$$M_z=\frac{\underset{i}{.Math.}{W}_i.Math.M_i^2}{\underset{i}{.Math.}{W}_i.Math.M_i}$

(133) Differential Scanning Calorimetry

(134) Measurements are performed with a TA instruments Q1000 DSC, equipped with an RCS (refrigerated cooling system) and an autosampler. Each sample is first melt pressed into a thin film at 175 C.; the melted sample is then air-cooled to room temperature. A 3-10 mg, 6 mm diameter specimen is extracted from the cooled polymer, weighed, placed in a light aluminum pan (ca 50 mg), and crimped shut. The thermal behavior of the sample is determined by ramping the sample temperature up and down to create a heat flow versus temperature profile. During testing, a nitrogen purge gas flow of 50 ml/min is used. First, the sample is rapidly heated to 180 C. and held isothermal for 3 min in order to remove its thermal history. Next, the sample is cooled to 40 C. at 10 C./min cooling rate and held isothermal at 40 C. for 3 min. The sample is then heated to 150 C. (2nd heating scan) at a 10 C./min heating rate. The cooling and heating (2nd scan) curves are recorded. The cooling curve is analyzed by setting baseline endpoints from the beginning of the crystallization to 20 C. The heating curve is analyzed by setting baseline endpoints from 20 C. to the end of the melt. The values determined are peak melting temperature (Tm), peak crystallization temperature (Tc), heat of fusion (Hf) (in J/g) and heat of crystallization (Hc) (in J/g).

(135) Crystallization Elution Fractionation (CEF) Method: Comonomer distribution analysis is performed with Crystallization Elution Fractionation (CEF) (PolymerChar in Spain) (B Monrabal et al, Macromol Symp. 257, 71-79 (2007)). Ortho-dichlorobenzene (ODCB) with 600 ppm antioxidant butylatedhydroxytoluene (BHT) is used as solvent. Sample preparation is done with autosampler at 160 C. for 2 hours under shaking at 4 mg/ml (unless otherwise specified). The injection volume is 300 l. The temperature profile of CEF is: crystallization at 3 C./min from 110 C. to 30 C., the thermal equilibrium at 30 C. for 5 minutes, elution at 3 C./min from 30 C. to 140 C. The flow rate during crystallization is at 0.052 ml/min. The flow rate during elution is at 0.50 ml/min. The data is collected at one data point/second. CEF column is packed by the Dow Chemical Company with glass beads at 125 m6% (MO-SCI Specialty Products) with inch stainless tubing. Glass beads are acid washed by MO-SCI Specialty with the request from the Dow Chemical Company. Column volume is 2.06 ml. Column temperature calibration is performed by using a mixture of NIST Standard Reference Material Linear polyethylene 1475a (1.0 mg/ml) and Eicosane (2 mg/ml) in ODCB. Temperature is calibrated by adjusting elution heating rate so that NIST linear polyethylene 1475a has a peak temperature at 101.0 C., and Eicosane has a peak temperature of 30.0 C. The CEF column resolution is calculated with a mixture of NIST linear polyethylene 1475a (1.0 mg/ml) and hexacontane (Fluka, purum, 97.0%, 1 mg/ml). A baseline separation of hexacontane and NIST polyethylene 1475a is achieved. The area of hexacontane (from 35.0 to 67.0 C.) to the area of NIST 1475a from 67.0 to 110.0 C. is 50 to 50, the amount of soluble fraction below 35.0 C. is <1.8 wt %. The CEF column resolution is defined in the following equation:

(136) $\mathrm{Resolution}=\frac{\begin{array}{c}\mathrm{Peak}\mathrm{temperature}\mathrm{of}\mathrm{NIST}1475a-\\ \mathrm{Peak}\mathrm{Temperature}\mathrm{of}\mathrm{Hexacontane}\end{array}}{\begin{array}{c}\mathrm{Half}\text{-}\mathrm{height}\mathrm{Width}\mathrm{of}\mathrm{NIST}1475a+\\ \mathrm{Half}\text{-}\mathrm{height}\mathrm{Width}\mathrm{of}\mathrm{Hexacontane}\end{array}}$
where the column resolution is 6.0.

(137) Comonomer Distribution Constant (CDC) Method: Comonomer distribution constant (CDC) is calculated from comonomer distribution profile by CEF. CDC is defined as Comonomer Distribution Index divided by Comonomer Distribution Shape Factor multiplying by 100 as shown in the following equation:

(138) $\mathrm{CDC}=\frac{\mathrm{Comonomer}\mathrm{Distrubution}\mathrm{Index}}{\mathrm{Comonomer}\mathrm{Distribution}\mathrm{Shape}\mathrm{Factor}}=\frac{\mathrm{Comonomer}\mathrm{Distribution}\mathrm{Index}}{\mathrm{Half}\mathrm{Width}/\mathrm{Stdev}}*100$

(139) Comonomer distribution index stands for the total weight fraction of polymer chains with the comonomer content ranging from 0.5 of median comonomer content (C.sub.median) and 1.5 of C.sub.median from 35.0 to 119.0 C. Comonomer Distribution Shape Factor is defined as a ratio of the half width of comonomer distribution profile divided by the standard deviation of comonomer distribution profile from the peak temperature (T.sub.p).

(140) CDC is calculated from comonomer distribution profile by CEF, and CDC is defined as Comonomer Distribution Index divided by Comonomer Distribution Shape Factor multiplying by 100 as shown in the following Equation:

(141) $\mathrm{CDC}=\frac{\mathrm{Comonomer}\mathrm{Distrubution}\mathrm{Index}}{\mathrm{Comonomer}\mathrm{Distribution}\mathrm{Shape}\mathrm{Factor}}=\frac{\mathrm{Comonomer}\mathrm{Distribution}\mathrm{Index}}{\mathrm{Half}\mathrm{Width}/\mathrm{Stdev}}*100$

(142) wherein Comonomer distribution index stands for the total weight fraction of polymer chains with the comonomer content ranging from 0.5 of median comonomer content (C.sub.median) and 1.5 of C.sub.median from 35.0 to 119.0 C., and wherein Comonomer Distribution Shape Factor is defined as a ratio of the half width of comonomer distribution profile divided by the standard deviation of comonomer distribution profile from the peak temperature (T.sub.p).

(143) CDC is calculated according to the following steps: (A) Obtain a weight fraction at each temperature (T) (wT(T)) from 35.0 C. to 119.0 C. with a temperature step increase of 0.200 C. from CEF according to the following Equation: (B) Calculate the median temperature (T.sub.median) at cumulative weight fraction of 0.500,

(144) $\underset{35}{\overset{119.0}{}}{w}_T\left(T\right)dT=1$
according to the following Equation: (C) Calculate the corresponding median comonomer content in mole % (C.sub.median) at

(145) $\underset{35}{\overset{T_{\mathrm{median}}}{}}{w}_T\left(T\right)dT=0.5$
the median temperature (T.sub.median) by using comonomer content calibration curve according to
the following Equation:

(146) $\ln \left(1-\mathrm{comonomerc}\mathrm{ontent}\right)=-\frac{207.26}{273.12+T}+0.5533$$R^2=0.997$ (D) Construct a comonomer content calibration curve by using a series of reference materials with known amount of comonomer content, i.e., eleven reference materials with narrow comonomer distribution (mono-modal comonomer distribution in CEF from 35.0 to 119.0 C.) with weight average M.sub.w of 35,000 to 115,000 (measured via conventional GPC) at a comonomer content ranging from 0.0 mole % to 7.0 mole % are analyzed with CEF at the same experimental conditions specified in CEF experimental sections; (E) Calculate comonomer content calibration by using the peak temperature (T.sub.p) of each reference material and its comonomer content; The calibration is calculated from each reference material according to the following Equation:

(147) $\ln \left(1-\mathrm{comonomercontent}\right)=-\frac{207.26}{273.12+T}+0.5533$$R^2=0.997$
wherein: R.sup.2 is the correlation constant; (F) Calculate Comonomer Distribution Index from the total weight fraction with a comonomer content ranging from 0.5*C.sub.median to 1.5*C.sub.median, and if T.sub.median is higher than 98.0 C., Comonomer Distribution Index is defined as 0.95; (G) Obtain Maximum peak height from CEF comonomer distribution profile by searching each data point for the highest peak from 35.0 C. to 119.0 C. (if the two peaks are identical, then the lower temperature peak is selected); half width is defined as the temperature difference between the front temperature and the rear temperature at the half of the maximum peak height, the front temperature at the half of the maximum peak is searched forward from 35.0 C., while the rear temperature at the half of the maximum peak is searched backward from I 19.0 C., in the case of a well defined bimodal distribution where the difference in the peak temperatures is equal to or greater than the I.1 times of the sum of half width of each peak, the half width of the inventive ethylene-based polymer composition is calculated as the arithmetic average of the half width of each peak; (H) Calculate the standard deviation of temperature (Stdev) according the following Equation:

(148) $\mathrm{Stdev}=\sqrt{\underset{35.0}{\overset{119.0}{.Math.}}{\left(T-T_p\right)}^2*w_T\left(T\right)}$

(149) Creep Zero Shear Viscosity Measurement Method

(150) Zero-shear viscosities are obtained via creep tests that are conducted on an AR-G2 stress controlled rheometer (TA Instruments; New Castle, Del.) using 25-mm-diameter parallel plates at 190 C. The rheometer oven is set to test temperature for at least 30 minutes prior to zeroing fixtures. At the testing temperature a compression molded sample disk is inserted between the plates and allowed to come to equilibrium for 5 minutes. The upper plate is then lowered down to 50 m above the desired testing gap (1.5 mm). Any superfluous material is trimmed off and the upper plate is lowered to the desired gap. Measurements are done under nitrogen purging at a flow rate of 5 L/min. Default creep time is set for 2 hours.

(151) A constant low shear stress of 20 Pa is applied for all of the samples to ensure that the steady state shear rate is low enough to be in the Newtonian region. The resulting steady state shear rates are in the range of 10.sup.3 to 10.sup.4 s.sup.1 for the samples in this study. Steady state is determined by taking a linear regression for all the data in the last 10% time window of the plot of log (J(t)) vs. log(t), where J(t) is creep compliance and t is creep time. If the slope of the linear regression is greater than 0.97, steady state is considered to be reached, then the creep test is stopped. In all cases in this study the slope meets the criterion within 2 hours. The steady state shear rate is determined from the slope of the linear regression of all of the data points in the last 10% time window of the plot of vs. t, where is strain. The zero-shear viscosity is determined from the ratio of the applied stress to the steady state shear rate.

(152) In order to determine if the sample is degraded during the creep test, a small amplitude oscillatory shear test is conducted before and after the creep test on the same specimen from 0.1 to 100 rad/s. The complex viscosity values of the two tests are compared. If the difference of the viscosity values at 0.1 rad/s is greater than 5%, the sample is considered to have degraded during the creep test, and the result is discarded.

(153) Zero-Shear Viscosity Ratio (ZSVR) is defined as the ratio of the zero-shear viscosity (ZSV) of the branched polyethylene material to the ZSV of the linear polyethylene material at the equivalent weight average molecular weight (Mw-gpc) according to the following Equation:

(154) 0$\mathrm{ZSVR}=\frac{{}_{0B}}{{}_{0L}}=\frac{{}_{0B}}{2.29{10}^{-15}{M}_{w-\mathrm{gpc}}^{3.65}}$

(155) The ZSV value is obtained from creep test at 190 C. via the method described above. The Mw-gpc value is determined by the conventional GPC method. The correlation between ZSV of linear polyethylene and its Mw-gpc is established based on a series of linear polyethylene reference materials. A description for the ZSV-Mw relationship can be found in the ANTEC proceeding: Karjala, Teresa P.; Sammler, Robert L.; Mangnus, Marc A.; Hazlitt, Lonnie G.; Johnson, Mark S.; Hagen, Charles M., Jr.; Huang, Joe W. L.; Reichek, Kenneth N. Detection of low levels of long-chain branching in polyolefins. Annual Technical ConferenceSociety of Plastics Engineers (2008), 66th 887-891.

(156) .sup.1H NMR Method

(157) 3.26 g of stock solution is added to 0.133 g of polyolefin sample in 10 mm NMR tube. The stock solution is a mixture of tetrachloroethane-d.sub.2 (TCE) and perchloroethylene (50:50, w:w) with 0.001M Cr.sup.3+. The solution in the tube is purged with N.sub.2 for 5 minutes to reduce the amount of oxygen. The capped sample tube is left at room temperature overnight to swell the polymer sample. The sample is dissolved at 110 C. with shaking. The samples are free of the additives that may contribute to unsaturation, e.g. slip agents such as erucamide.

(158) The .sup.1H NMR is run with a 10 mm cryoprobe at 120 C. on Bruker AVANCE 400 MHz spectrometer.

(159) Two experiments are run to get the unsaturation: the control and the double presaturation experiments. For the control experiment, the data is processed with exponential window function with LB=1 Hz, baseline is corrected from 7 to 2 ppm. The signal from residual .sup.1H of TCE is set to 100, the integral I.sub.total from 0.5 to 3 ppm is used as the signal from whole polymer in the control experiment. The number of CH.sub.2 group, NCH.sub.2, in the polymer is calculated as following:
NcH.sub.2=I.sub.total/2

(160) For the double presaturation experiment, the data is processed with exponential window function with LB=1 Hz, baseline is corrected from 6.6 to 4.5 ppm. The signal from residual .sup.1H of TCE is set to 100, the corresponding integrals for unsaturations (I.sub.vinylene, I.sub.trisubstituted, I.sub.vinyl and I.sub.vinylidene) are integrated based on the region shown in FIG. 4.

(161) The number of unsaturation unit for vinylene, trisubstituted, vinyl and vinylidene are calculated:
N.sub.vinylene=I.sub.vinylene/2
N.sub.trisubstituted=I.sub.trisubstitute
N.sub.vinyl=I.sub.vinyl/2
N.sub.vinylidene=I.sub.vinylidene/2

(162) The unsaturation unit/1,000,000 carbons is calculated as following:
N.sub.vinylene/1,000,000C=(N.sub.vinylene/NCH.sub.2)*1,000,000
N.sub.trisubstituted/1,000,000C=(N.sub.trisubstituted/NCH.sub.2)*1,000,000
N.sub.vinyl/1,000,000C=(N.sub.vinyl/NCH.sub.2)*1,000,000
N.sub.vinylidene/1,000,000C=(N.sub.vinylidene/NCH.sub.2)*1,000,000

(163) The requirement for unsaturation NMR analysis includes: level of quantitation is 0.470.02/1,000,000 carbons for Vd2 with 200 scans (less than 1 hour data acquisition including time to run the control experiment) with 3.9 wt % of sample (for Vd2 structure, see Macromolecules, vol. 38, 6988, 2005), 10 mm high temperature cryoprobe. The level of quantitation is defined as signal to noise ratio of 10.

(164) The chemical shift reference is set at 6.0 ppm for the .sup.1H signal from residual proton from TCT-d2. The control is run with ZG pulse, TD 32768, NS 4, DS 12, SWH 10,000 Hz, AQ 1.64 s, D1 14 s. The double presaturation experiment is run with a modified pulse sequence, O1P 1.354 ppm, O2P 0.960 ppm, PL9 57 db, PL21 70 db, TD 32768, NS 200, DS 4, SWH 10,000 Hz, AQ 1.64 s, D1 1 s, D13 13 s. The modified pulse sequences for unsaturation with Bruker AVANCE 400 MHz spectrometer are shown below:

(165) TABLE-US-00001 ;lc1prf2_zz prosol relations=<lcnmr> #include <Avance.incl> d12=20u d11=4u 1 ze d12 pl21:f2 2 30m d13 d12 pl9:f1 d1 cw:f1 ph29 cw:f2 ph29 d11 do:f1 do:f2 d12 pl1:f1 p1 ph1 go=2 ph31 30m mc #0 to 2 F0(zd) exit ph1=0 2 2 0 1 3 3 1 ph29=0 ph31=0 2 2 0 1 3 3 1

(166) Preparation of Blends by Twin Screw Extruder Compounding

(167) Blends are prepared with a 30 mm co-rotating, intermeshing Coperion Werner-Pfleiderer ZSK-30 (ZSK-30) twin screw extruder. The ZSK-30 has ten barrel sections with an overall length of 960 mm and a 32 length to diameter ratio (L/D). The temperature in the feed zone is 80 C. Zones 1 to 4 are set at 160, 180, 185 and 190 C., respectively. The die temperature is 230 C. The screw speed is set at 325 rpm resulting in an output rate of approximately 18.14 kg/hr (40 lb/hr).

EXAMPLE 1

(168) A film is prepared with the structure shown in FIG. 1. The film 1 consists of a total of 5 layers. 3 inner layers, 3, 4 and 5 are arranged between the outer layers 2 and 6. The layers display the following structure:

(169) TABLE-US-00002 Layer Thickness No. Composition Wt. % (m) 2 Polymer A (Elite At 6101) 63.5 15 Polymer B (Riblene FF 34) 20.0 Colorant (white) 14.0 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 3 Polymer A (Elite At 6101) 98.0 7 Lubricant 2.0 4 Polymer A (Elite At 6101) 86.0 6 Lubricant 2.0 Colorant (white) 12.0 5 Polymer A (Elite At 6101) 98.0 7 Lubricant 2.0 6 Polymer A (Elite At 6101) 63.5 15 Polymer B (Riblene FF 34) 20.0 Dyestuff (white, NG 8600 H1) 14.0 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5

(170) The layers were fabricated by using the conventional blow-extrusion process into a 5-layered film.

(171) The film thus produced was applied to a bottle (7) using a stretch-sleeve machine. In FIG. 2. The bottle (7) with the film of the invention provided on its outer surface is shown. The bottle has a contour with the segments of different diameter (8, 9, 10). As FIG. 2 shows, the film of the invention according to example 1 clings optimally to the outer surface of the bottle (7).

(172) FIG. 3 shows an enlarged representation of the segment (9) of the bottle (7) in FIG. 2. One recognizes that the inventive film in this segment also with a complicated contour fits optimally on the outer surface of the bottle (7).

EXAMPLE 2

(173) A film is prepared with the structure shown in FIG. 1 as is described in example 1. The film 1 consists of a total of 5 layers. Inner layers, 3, 4 and 5 are arranged between the outer layers 2 and 6. The layers display the following structure:

(174) TABLE-US-00003 Layer Thickness No. Composition Wt. % (m) 2 Polymer A (Elite At 6101) 20.0 15 Polymer B (Lupolen 3220F) 76.5 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0 3 Polymer A (Elite At 6101) 98.0 7 Lubricant 2.0 4 Polymer A (Elite At 6101) 98.0 6 Lubricant 2.0 5 Polymer A (Elite At 6101) 98.0 7 Lubricant 2.0 6 Polymer A (Elite At 6101) 20.0 15 Polymer B (Lupolen 3220F) 76.5 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0

(175) The layers were fabricated by using a conventional blow-extrusion process into a 5-layered film. The film thus produced was applied to a bottle (7) using a conventional stretch-sleeve machine. The results corresponded to the results described in Example 1.

EXAMPLE 3

(176) A film is prepared with the structure shown in FIG. 1 as is described in example 1. The film 1 consists of a total of 5 layers. Inner layers, 3, 4 and 5 are arranged between the outer layers 2 and 6. The layers display the following structure:

(177) TABLE-US-00004 Layer Thickness No. Composition Wt. % (m) 2 Polymer A (Elite At 6101) 46.5 15 Polymer B (Lupolen 3220F) 50.0 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0 3 Polymer A (Elite At 6101) 80.0 7 Polymer B (Lupolen 3220F) 20.0 4 Polymer A (Elite At 6101) 78.0 6 Polymer B (Lupolen 3220F) 20.0 Lubricant 2.0 5 Polymer A (Elite At 6101) 80.0 7 Polymer B (Lupolen 3220F) 20.0 6 Polymer A (Elite At 6101) 46.5 15 Polymer B (Lupolen 3220F) 50.0 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0

(178) The layers were fabricated by using a conventional blow-extrusion process into a 5-layered film. The film thus produced was applied to a bottle (7) using a conventional stretch-sleeve machine. The results corresponded to the results described in Example 1.

EXAMPLE 4

(179) A film is prepared with the structure shown in FIG. 1 as is described in example 1. The film 1 consists of a total of 5 layers. Inner layers, 3, 4 and 5 are arranged between the outer layers 2 and 6. The layers display the following structure:

(180) TABLE-US-00005 Layer Thickness No. Composition Wt. % (m) 2 Polymer A (Elite At 6101) 50.0 15 Polymer B (Lupolen 3020F) 46.5 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0 3 Polymer C (Greenflex FF 35) 98.0 7 Lubricant 2.0 4 Polymer C (Greenflex FF 35) 58.0 6 Polymer B (Lupolen 3020F) 40.0 Lubricant 2.0 5 Polymer C (Greenflex FF 35) 98.0 7 Lubricant 2.0 6 Polymer A (Elite At 6101) 50.0 15 Polymer B (Lupolen 3020F) 46.5 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0

(181) The layers were fabricated by using a conventional blow-extrusion process into a 5-layered film. The film thus produced was applied to a bottle (7) using a conventional stretch-sleeve machine. The results corresponded to the results described in Example 1.

(182) For the films according to examples 3 and 4, the tensile elongation at break was determined according to ISO 527-3 at 23 C. and 50% RH in longitudinal and transversal direction. The following results were obtained (average of 3 to 6 measurements):

(183) TABLE-US-00006 tensile elongation at break tensile elongation at break longitudinal (%) transversal (%) Example 3 497.5 663.8 Example 4 377.9 656.6

(184) The film according to example 4, in which the inner layers comprise polymer C as main component, exhibit a significantly improved (lower) tensile elongation at break in longitudinal direction, with a comparable tensile elongation at break in transversal direction.

EXAMPLE 5

(185) A film is prepared with the structure shown in FIG. 1 as is described in example 1. The film 1 consists of a total of 5 layers. Inner layers, 3, 4 and 5 are arranged between the outer layers 2 and 6. The layers display the following structure:

(186) TABLE-US-00007 Layer Thickness No. Composition Wt. % (m) 2 Polymer A (Elite At 6101) 20.0 15 Polymer B (Lupolen 3020F) 76.5 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0 3 Polymer C (Greenflex FF 35) 98.0 7 Lubricant 2.0 4 Polymer C (Greenflex FF 35) 98.0 6 Lubricant 2.0 5 Polymer C (Greenflex FF 35) 98.0 7 Lubricant 2.0 6 Polymer A (Elite At 6101) 20.0 15 Polymer B (Lupolen 3020F) 76.5 Sliding/anti-blocking agent 2.0 Antistatic agent 0.5 ARX 601 AB 05 1.0

(187) The layers were fabricated by using a conventional blow-extrusion process into a 5-layered film. The film thus produced was applied to a bottle (7) using a conventional stretch-sleeve machine. The results corresponded to the results described in Example 1.

ADDITIONAL EXAMPLES

(188) 1. Materials

(189) Materials for the additional examples and comparative examples are listed in Table 1 below.

(190) TABLE-US-00008 TABLE 1 Designation Density (g/cc) I.sub.2 (dg/min) Mw/Mn ELITE AT Enhanced 0.904 0.7 2.62 6101 Polyethylene Resin ATTANE Ultra Low 0.905 1.0 SL4102G Density Polyethylene AFFINITY Polyolefins 0.918 1.6 PF 1140G Plastomer LDPE (HP- Polyethylene 0.918 2.3 tubular) Low Density INFUSE Ethylene/octene 0.877 0.5 Olefin block multi-block copolymer copolymer EVA Ethylene Vinyl 0.929 0.7 Acetate Copolymer

(191) ELITE AT 6101 (or 6101) is an ethylene/octene copolymer and an embodiment of the ethylene/-olefin copolymer (A). The properties for ELITE AT6101 are provided in Table 2 below.

(192) TABLE-US-00009 TABLE 2 Designation Units 6101 Density (g/cc) 0.904 I.sub.2 (dg/min) 0.7 I.sub.10/I.sub.2 7.7 M.sub.w/M.sub.n 2.62 M.sub.w 10.sup.3 M.sub.z 10.sup.3 223643 CDC 127.9 CDI 89.1 ZSVR 3.11 Vinyls/10.sup.3 C Less than 0.15

(193) Comparative samples A-E and inventive example 1 stretch-sleeve films with 50 micron total thickness are produced on a 7-layer Collin blown film line under standard processing conditions. The structural and compositional features of the stretch-sleeve films for comparative samples A-E and the inventive example 1 are provided in Table 3 below.

(194) TABLE-US-00010 TABLE 3 Comparative A Comparative B Inventive Example Attane SL 4102G (0.905; 1.0) Attane SL 4102G (0.905; 1.0) 6101 (0.905; 0.8) core layer 30% Versify 2300 core layer core layer Design Design Design Total Total Total Gauge 50 m Density Gauge 50 m Density Gauge 50 m Density Layer A Amount Component g/cm.sup.1 Layer A Amount Component g/cm.sup.1 Layer A Amount Component g/cm.sup.1 1 98.0% LDPE 770G 0.918 1 98.0% LDPE 770G 0.918 1 98.0% LDPE 770G 0.918 2 2.0% Polybatch 0.982 2 2.0% Polybatch FSU 0.982 2 2.0% Polybatch FSU 0.982 3 0.0% FSU 1051 0.000 3 0.0% 1051 0.000 3 0.0% 1051 0.000 4 0.0% 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.9192 Total 100.0% 0.9192 Total 100.0% 0.9192 Layer B Amount Component g/cm.sup.1 Layer B Amount Component g/cm.sup.1 Layer B Amount Component g/cm.sup.1 1 98.0% ATTANE 0.905 1 68.0% ATTANE SL 0.905 1 98.0% 6101 0.905 2 2.0% SL 4102G 0.922 2 30.0% 4102G 0.866 2 2.0% Polybatch CE 0.922 3 0.0% Polybatch 0.000 3 2.0% VERSIFY 2300 0.922 3 0.0% 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% Polybatch 0.000 4 0.0% 0.000 Total 100.0% 0.9053 Total 100.0% CE 505E 0.8933 Total 100.0% 0.9053 Layer C Amount Component g/cm.sup.1 Layer C Amount Component g/cm.sup.1 Layer C Amount Component g/cm.sup.1 1 98.0% ATTANE 0.906 1 68.0% ATTANE SL 0.905 1 98.0% 6101 0.905 2 2.0% SL 4102G 0.922 2 30.0% 4102G 0.866 2 2.0% Polybatch CE 0.922 3 0.0% Polybatch 0.000 3 2.0% VERSIFY 2300 0.922 3 0.0% 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% Polybatch 0.000 4 0.0% 0.000 Total 100.0% 0.9053 Total 100.0% CE 505E 0.8933 Total 100.0% 0.9053 Layer D Amount Component g/cm.sup.1 Layer D Amount Component g/cm.sup.1 Layer D Amount Component g/cm.sup.1 1 98.0% ATTANE 0.905 1 68.0% ATTANE SL 0.905 1 98.0% 6101 0.905 2 2.0% SL 4102G 0.922 2 30.0% 4102G 0.866 2 2.0% Polybatch CE 0.922 3 0.0% Polybatch 0.000 3 2.0% VERSIFY 2300 0.922 3 0.0% 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% Polybatch 0.000 4 0.0% 0.000 Total 100.0% 0.9053 Total 100.0% CE 505E 0.8933 Total 100.0% 0.9053 Layer E Amount Component g/cm.sup.1 Layer E Amount Component g/cm.sup.1 Layer E Amount Component g/cm.sup.1 1 98.0% ATTANE 0.905 1 68.0% ATTANE SL 0.905 1 98.0% 6101 0.905 2 2.0% SL 4102G 0.922 2 30.0% 4102G 0.866 2 2.0% Polybatch CE 0.922 3 0.0% Polybatch 0.000 3 2.0% VERSIFY 2300 0.922 3 0.0% 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% Polybatch 0.000 4 0.0% 0.000 Total 100.0% 0.9053 Total 100.0% CE 505E 0.8933 Total 100.0% 0.9053 Layer F Amount Component g/cm.sup.1 Layer F Amount Component g/cm.sup.1 Layer F Amount Component g/cm.sup.1 1 98.0% ATTANE 0.905 1 68.0% ATTANE SL 0.905 1 98.0% 6101 0.905 2 2.0% SL 4102G 0.922 2 30.0% 4102G 0.866 2 2.0% Polybatch CE 0.922 3 0.0% Polybatch 0.000 3 2.0% VERSIFY 2300 0.922 3 0.0% 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% Polybatch 0.0000 4 0.0% 0.000 Total 100.0% 0.9053 Total 100.0% CE 505E 0.8933 Total 100.0% 0.9053 Layer G Amount Component g/cm.sup.1 Layer G Amount Component g/cm.sup.1 Layer G Amount Component g/cm.sup.1 1 98.0% LDPE 770G 0.918 1 98.0% LDPE 770G 0.918 1 98.0% LDPE 770G 0.918 2 2.0% Polybatch 0.982 2 2.0% Polybatch FSU 0.982 2 2.0% Polybatch FSU 0.982 3 0.0% FSU 1051 0.000 3 0.0% 1051 0.000 3 0.0% 1051 0.000 4 0.0% 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.9192 Total 100.0% 0.9192 Total 100.0% 0.9192 Density Density Density Overall m Thickness g/cm.sup.1 Overall m Thickness g/cm.sup.1 Overall m Thickness g/cm.sup.1 Layer A 5 10.0% 0.9192 Layer A 5 10.0% 0.9192 Layer A 5 10.0% 0.9192 Layer B 8 16.0% 0.9053 Layer B 8 16.0% 0.8933 Layer B 8 16.0% 0.9053 Layer C 8 16.0% 0.9053 Layer C 8 16.0% 0.8933 Layer C 8 16.0% 0.9053 Layer D 8 16.0% 0.9053 Layer D 8 16.0% 0.8933 Layer D 8 16.0% 0.9053 Layer E 8 16.0% 0.9053 Layer E 8 16.0% 0.8933 Layer E 8 16.0% 0.9053 Layer F 8 16.0% 0.9053 Layer F 8 16.0% 0.8933 Layer F 8 16.0% 0.9053 Layer G 5 10.0% 0.9192 Layer G 5 10.0% 0.9192 Layer G 5 10.0% 0.9192 Total 50 100.0% 0.9081 Total 50 100.0% 0.8984 Total 50 100.0% 0.9081 Operation Instructions Operation Instructions Operation Instructions Film Gauge m 50 Film Gauge m 50 Film Gauge m 50 Specify BUR Specify BUR Specify BUR BUR/Layflat BUR/Layflat BUR/Layflat BUR 2.5 BUR 2.5 BUR 2.5 Layflat mm width 235.6 Layflat mm width 235.6 Layflat mm 235.6 Corona No Corona No Corona No Treatment Treatment Treatment Roll Length m length 250 Roll Length m length 250 Roll Length m length 250 Sample wt kg 5.3 Sample wt kg 5.3 Sample wt kg 5.3 Special Instructions Special Instructions Special Instructions Cut film to 180 mm width Cut film to 180 mm width Cut film to 180 mm width 200 m for customer 200 m for customer 200 m for customer 50 m for us 50 m for us 50 m for us Comparative C Comparative D Comparative E Affinity PF 1140G (0.8965; 1.6) Infuse OBC (0.877; 0.50) Reference Structure PEV; blend of core layer core layer Greenflex FF 35 and Riblene FF 34 Design Design Design Total Total Total Gauge 50 m Density Gauge 50 m Density Gauge 50 m Density Layer A Amount Component g/cm.sup.1 Layer A Amount Component g/cm.sup.1 Layer A Amount Component g/cm.sup.1 1 98.0% LDPE 770G 0.918 1 98.0% Infuse OBC 0.918 1 73.0% Greenflex FF 35 0.929 2 2.0% Polybatch 0.982 2 2.0% Polybatch 0.982 2 25.0% Riblene FF 34 0.924 3 0.0% FSU 1051 0.000 3 0.0% FSU 1051 0.000 3 2.0% Polybatch FSU 0.982 4 0.0% 0.000 4 0.0% 0.000 4 0.0% 1051 0.000 Total 100.0% 0.9192 Total 100.0% 0.9192 Total 100.0% 0.9287 Layer B Amount Component g/cm.sup.1 Layer B Amount Component g/cm.sup.1 Layer B Amount Component g/cm.sup.1 1 98.0% AFFINITY 0.897 1 98.0% Infuse OBC 0.877 1 98.0% Greenflex FF 35 0.929 2 2.0% PF 11400 0.922 2 2.0% Polybatch 0.922 2 2.0% Polybatch 0.922 3 0.0% Polybatch 0.000 3 0.0% CE 505E 0.000 3 0.0% CE 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.8975 Total 100.0% 0.8779 Total 100.0% 0.9289 Layer C Amount Component g/cm.sup.1 Layer C Amount Component g/cm.sup.1 Layer C Amount Component g/cm.sup.1 1 98.0% AFFINITY 0.897 1 98.0% Infuse OBC 0.877 1 98.0% Greenflex FF 35 0.929 2 2.0% PF 11400 0.922 2 2.0% Polybatch 0.922 2 2.0% Polybatch 0.922 3 0.0% Polybatch 0.000 3 0.0% CE 505E 0.000 3 0.0% CE 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.8975 Total 100.0% 0.8779 Total 100.0% 0.9289 Layer D Amount Component g/cm.sup.1 Layer D Amount Component g/cm.sup.1 Layer D Amount Component g/cm.sup.1 1 98.0% AFFINITY 0.897 1 98.0% Infuse OBC 0.877 1 98.0% Greenflex FF 35 0.929 2 2.0% PF 11400 0.922 2 2.0% Polybatch 0.922 2 2.0% Polybatch 0.922 3 0.0% Polybatch 0.000 3 0.0% CE 505E 0.000 3 0.0% CE 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.8975 Total 100.0% 0.8779 Total 100.0% 0.9289 Layer E Amount Component g/cm.sup.1 Layer E Amount Component g/cm.sup.1 Layer E Amount Component g/cm.sup.1 1 98.0% AFFINITY 0.897 1 98.0% Infuse OBC 0.877 1 98.0% Greenflex FF 35 0.929 2 2.0% PF 11400 0.922 2 2.0% Polybatch 0.922 2 2.0% Polybatch 0.922 3 0.0% Polybatch 0.000 3 0.0% CE 505E 0.000 3 0.0% CE 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.8975 Total 100.0% 0.8779 Total 100.0% 0.9269 Layer F Amount Component g/cm.sup.1 Layer F Amount Component g/cm.sup.1 Layer F Amount Component g/cm.sup.1 1 98.0% AFFINITY 0.897 1 98.0% Infuse OBC 0.877 1 98.0% Greenflex FF 35 0.929 2 2.0% PF 11400 0.922 2 2.0% Polybatch 0.922 2 2.0% Polybatch 0.922 3 0.0% Polybatch 0.000 3 0.0% CE 505E 0.000 3 0.0% CE 505E 0.000 4 0.0% CE 505E 0.000 4 0.0% 0.000 4 0.0% 0.000 Total 100.0% 0.8975 Total 100.0% 0.8779 Total 100.0% 0.9289 Laye G Amount Component g/cm.sup.1 Layer G Amount Component g/cm.sup.1 Layer G Amount Component g/cm.sup.1 1 98.0% LDPE 770G 0.918 1 98.0% LDPE 770G 0.918 1 73.0% Greenflex FF 35 0.929 2 2.0% Polybatch 0.982 2 2.0% Polybatch 0.982 2 25.0% Riblene FF 34 0.924 3 0.0% FSU 1051 0.000 3 0.0% FSU 1051 0.000 3 2.0% Polybatch FSU 0.982 4 0.0% 0.000 4 0.0% 0.000 4 0.0% 1051 0.000 Total 100.0% 0.9192 Total 100.0% 0.9192 Total 100.0% 0.9287 Density Density Density Overall m Thickness g/cm.sup.1 Overall m Thickness g/cm.sup.1 Overall m Thickness g/cm.sup.1 Layer A 5 10.0% 0.9192 Layer A 5 10.0% 0.9192 Layer A 5 10.0% 0.9287 Layer B 8 16.0% 0.8975 Layer B 8 16.0% 0.8779 Layer B 8 16.0% 0.9289 Layer C 8 16.0% 0.8975 Layer C 8 16.0% 0.8779 Layer C 8 16.0% 0.9289 Layer D 8 16.0% 0.8975 Layer D 8 16.0% 0.8779 Layer D 8 16.0% 0.9289 Layer E 8 16.0% 0.8975 Layer E 8 16.0% 0.8779 Layer E 8 16.0% 0.9289 Layer F 8 16.0% 0.8975 Layer F 8 16.0% 0.8779 Layer F 8 16.0% 0.9289 Layer G 5 10.0% 0.9192 Layer G 5 10.0% 0.9192 Layer G 5 10.0% 0.9287 Total 50 100.0% 0.9018 Total 50 100.0% 0.8861 Total 50 100.0% 0.9288 Operation Instructions Operation Instructions Operation Instructions Film Gauge m 50 Film Gauge m 50 Film Gauge m 50 Specify BUR Specify BUR Specify BUR BUR/Layflat BUR/Layflat BUR/Layflat BUR 2.5 BUR 2.5 BUR 2.5 Layflat mm width 235.6 Layflat mm width 235.6 Layflat mm 235.6 Corona No Corona No Corona No Treatment Treatment Treatment Roll Length m length 250 Roll Length m length 250 Roll Length m length 250 Sample wt kg 5.3 Sample wt kg 5.3 Sample wt kg 5.3 Special Instructions Special Instructions Special Instructions Cut film to 180 mm width Cut film to 180 mm width Cut film to 180 mm width 200 m for customer 200 m for customer 200 m for customer 50 m for us 50 m for us 50 m for us

(195) Properties for the stretch-sleeve films of Table 3 are provided in Table 4 below.

(196) TABLE-US-00011 TABLE 4 Inventive SAMPLE CODE Comp A Comp B Example Comp C Comp D Comp E Core layer Attane SL Attane SL 6101 Affinity PF OBC EVA 4102G 4102G + 1140G (9% VA) 30% Versify 2300 Film Thickness in m 50 50 50 50 50 50 ELASTIC RECOVERY Norm: Test Speed: 500 mm/min. 55% Specimen: 15 150 mm Gauge: 100 mm Machine: Lloyd LR 5K Max. Force N/15 mm CD 5.17 4.39 5.46 4.71 2.87 4.79 Permanent Deformation % CD 6.63 5.21 4.91 4.75 5.62 4.82 Elastic Recovery % CD 93.4 94.8 95.1 95.2 94.4 95.2 ELASTIC RECOVERY Conditions as above but final specimen length measured by hand. 55% Machine: Lloyd LR 5K Final Distance between N/15 mm CD 104.2 102.8 102.4 102 103.8 101.9 marks. Permanent Deformation % CD 4.20 2.80 2.40 2.00 3.80 1.90 Elastic Recovery % CD 95.8 97.2 97.6 98 96.2 98.1 ELASTIC RECOVERY Norm: Test Speed: 500 mm/min. 60% Specimen: 15 150 mm Gauge: 100 mm Machine: Lloyd LR 5K Max. Force N/15 mm CD 5.14 4.46 5.49 4.79 2.84 4.82 Permanent Deformation % CD 6.96 5.64 5.65 5.32 5.95 5.45 Elastic Recovery % CD 93.04 94.35 94.34 94.68 94.05 94.54 ELASTIC RECOVERY Conditions as above but final specimen length measured by hand. 60% Machine: Lloyd LR 5K Final Distance between N/15 mm CD 104.2 103 103 102 103.6 102.3 marks. Permanent Deformation % CD 4.20 3.00 3.00 2.00 3.60 2.30 Elastic Recovery % CD 95.8 97 97 98 96.4 97.7 Remarks: Speed to reach 55 or 60% Elongation and back to Zero Point = 500 mm/min. Waiting Time at Zero Point = 6 seconds. Speed to get a Force of 0.1 N/15 mm = 100 mm/min. ELASTIC RECOVERY Norm: Recovery per ASTM D5459 Test Speed: 500 mm/min. 55% Specimen: 25 150 mm Gauge: 100 mm Machine: Lloyd LR 5K A = Max. Force N/25 mm CD 7.68 7.91 B = Force after 3 seconds N/25 mm CD 6.84 6.99 D = Elongation at 0.1N % CD 5.23 5.28 Force Stress Relaxation % CD 10.97 11.66 Stress Retention % CD 89.03 88.34 Permanent Deformation % CD 9.51 9.60 Elastic Recovery % CD 90.49 90.40 Remarks: Speed to reach 55% Elongation = 500 mm/min. 1. waiting Time at 55% Elongation = 3 seconds. Speed to get back to Zero Point = 500 mm/min. 2. waiting Time at 0% Elongation = 6 seconds. Speed to get a Force of 0.1 N/15 mm = 100 mm/min. COEFFICIENT OF DYN. Norm: ISO 8295 Test Speed: 100 mm/min. FRICTION Specimen: 8 8 cm Sledge Weight: 200 g. Machine: Lloyd LR 5K Inside/Inside (Film/Film) 0.07 0.08 0.07 0.06 0.08 0.09 MODULUS Norm: ISO 527-3 Test Speed: 5 mm/min. Grips: Convex Machine: Zwick Z010 Specimen: TYPE 2 Grip Distance: 100 mm Thickness m MD 47.8 52.8 52.5 54.7 51.1 48.4 CD 48.4 52.7 49.8 53.8 49.1 49.1 Modulus of Elasticity MPa MD 109 82.9 99.1 72.5 48.6 82.6 CD 130 92.3 111 76.4 58.5 100 1% Secant Modulus MPa MD 99.9 80.5 96.1 69.7 49.1 91.3 CD 110 81.3 102 70.0 51.4 95.9 2% Secant Modulus MPa MD 89.1 75.1 87.4 65.2 44.7 85.1 CD 95.2 71.8 91.5 62.4 45.3 86.5 TENSILE PROPERTIES Norm: ISO 527-3 Test Speed: 5 mm/min. Grips: Convex Machine: Zwick Z010 Specimen: TYPE 2 Grip Distance: 100 mm Tensile Strength at 5% MPa MD 5.5 4.24 4.6 3.64 2.74 4.39 Elongation CD 5.47 4.18 4.56 3.37 2.65 4.45 Tensile Strength at 10% MPa MD 7.15 5.59 6.11 5.01 3.56 6.1 Elongation CD 6.58 5.12 5.8 4.49 3.26 5.74 Tensile Strength at 25% MPa MD 8.28 6.79 7.06 6.2 4.41 7.84 Elongation CD 6.89 5.56 6.33 5.1 3.54 6.13 Tensile Strength at 50% MPa MD 9.62 8.21 8.49 7.56 5.21 11.45 Elongation CD 7.33 5.99 7.29 5.84 3.76 6.74 Yield Stress MPa MD 10.21 8.87 9.45 8.07 5.63 no value CD 6.79 6.04 7.67 6.22 3.62 6.27 Yield Strain % MD 81.4 83.2 92.8 67.3 76.4 no value CD 16.9 55.2 70.6 80.5 32.6 29.8 Tensile Strength (max) MPa MD 33.7 26.7 30.3 34.0 25.5 23.3 CD 32.8 31.8 36.2 29.0 28.6 21.5 Tensile Strain at Tensile % MD 611 556 515 636 569 277 Strength CD 687 691 591 680 689 541 Tensile Stress at Break MPa MD 33.7 26.6 29.5 33.7 25.1 23.2 CD 32.6 24.3 36.0 28.5 28.5 21.5 Tensile Strain at Break % MD 611 556 517 637 569 278 CD 688 691 591 680 690 541 Toughness MJ/m.sup.3 MD 94.9 74.7 72.0 94.2 56.5 44.7 CD 88.3 81.1 79.5 75.4 56.8 57.4

(197) 2. Results Summary for Additional Examples

(198) Applicant discovered that the present stretch-sleeve film with ELITE AT 6101 in at least the core layer of a suitable blown film structure provides an unexpected property balance between elastic recovery and holding force. The present stretch-sleeve film is suitable for applications such as stretch sleeve labels for highly contoured bottles and highly contoured containers, where changes in sleeve diameter exceeds 50%.

(199) It is specifically intended that the present disclosure not be limited to the embodiments and illustrations contained herein, but include modified forms of those embodiments including portions of the embodiments and combinations of elements of different embodiments as come within the scope of the following claims.