ONLINE CONTROL OF RHEOLOGY OF BUILDING MATERIAL FOR 3D PRINTING

Abstract

A method of placing a flowable construction material including a hydraulic binder for building structural components layer-by-layer, such as for 3D concrete printing, the method including preparing a fresh flowable construction material made of Portland cement, fine limestone filler materials, fine sands, water, and water reducing admixture and possibly a set or hardening accelerating admixture, conveying the flowable construction material to a deposition head, placing the construction material through an outlet of the deposition head in order to form a layer of construction material, before placing the construction material, adding a rheology-modifying agent to the construction material so that the placed material has an increased yield stress when compared to the material during the conveying step.

Claims

1. A method of placing a flowable construction material comprising a hydraulic binder for building structural components layer-by-layer, such as for 3D concrete printing, said method comprising: conveying the flowable construction material to a deposition head, placing the construction material through an outlet of the deposition head in order to form a layer of construction material, before placing the construction material, adding a rheology-modifying agent to the construction material so that the placed material has an increased yield stress before setting occurs when compared to the material during the conveying step, wherein the placing of the construction material comprises extruding the construction material in a pasty form through a nozzle of the deposition head, and wherein successive layers of the construction material are placed on top of each other.

2. (canceled)

3. The method according to claim 1, wherein, after the placement of a first layer of construction material, at least one subsequent layer of construction material is placed onto the first layer, wherein the amount of rheology-modifying agent added to the construction material is selected so as to increase the yield stress so that the first layer does not collapse under the load of said at least one subsequent layer.

4. The method according to claim 1, wherein the yield stress of the freshly placed construction material is 600-4.000 Pa.

5. The method according to claim 1, wherein the construction material of a first layer is allowed to rest during a time period of not more than 2 minutes, before the construction material of a subsequent layer is placed onto the said construction material of the first layer.

6. The method according to claim 1, wherein the rheology-modifying agent is continuously added to the flow of conveyed construction material.

7. The method according to claim 1, wherein the rheology-modifying agent and the construction material are mixed with each other before placing the construction material.

8. The method according to claim 1, wherein a water reducer is added to the hydraulic binder before the conveying step, wherein the conveying of the construction material is performed by pumping.

9. The method according to claim 1, wherein a setting accelerator is added to the hydraulic binder before the conveying step.

10. The method according to claim 1, wherein a thickening agent or a viscosity enhancer is used as said rheology-modifying agent.

11. The method according to claim 1, wherein starch ether, celluloses ether, water soluble polyacrylamide, casein, and/or welan gum is used as or in the rheology-modifying agent.

12. The method according to claim 1, wherein the construction material is concrete or a cement mortar.

13. The method according to claim 1, wherein the construction material is a ultrahigh performance concrete.

14. The method according to claim 5, wherein the time period is 30-60 sec.

15. The method according to claim 7, wherein a static mixer is used for mixing.

16. The method according to claim 8, wherein the water reducer is a plasticizer or a super-plasticizer.

17. The method according to claim 16, wherein the water reducer is a plasticizer based on polyoxy polycarboxylate or phosphonates.

18. The method according to claim 9, wherein the setting accelerator is sodium chloride, calcium chloride, aluminum hydroxide, aluminum-potassium sulfate, sodium silicate, calcium nitrate and/or calcium nitrite, sodium and/or calcium thiocyanate.

Description

EXAMPLE 1

[0044] A mortar was prepared having the following composition: [0045] 2058.6 g of NAG3 Ductal premix [0046] 11.33 g of CHRYSOOptima 100 [0047] 201.7 g of water

[0048] This mortar has a slump flow of 140 mm measured according to the flow table method (ASTM C230). As the fresh mortar is self compacting, its yield stress is low and below 400 Pa.

[0049] The material was pumped at a flow rate of between 0.7 and 1.3 L/min. In the deposition head of a robot, an amount of Sika 40 AF was mixed with the mortar at a dosage of between 21 and 36 g/L of mortar.

[0050] The yield stress measured with a scissometer of the placed material was estimated between 800 and 1200 Pa.

[0051] Successive layers of the material were placed on top of each other, for a total height of approximately 1 meter, on a duration of 2 hours.

[0052] It was observed that the layers did not collapse, and the intended shape of the printed object was fully respected.

[0053] The layers were allowed to set and harden for 24 hours before the printed element could be manipulated.

EXAMPLE 2

[0054] A mortar was prepared having the following composition: [0055] 569.3 g of white cement CEM I 52.5N Le Teil [0056] 350.1 g of limestone filler BL 200 from Omya [0057] 1004.8 g of sand Sablon 0/0.315 from Sibelco [0058] 11.16 g of Glenium 27 from BASF [0059] 270.0 g of water

[0060] This mortar has a slump flow of 210 mm measured according to the flow table Marsh Cone method (ASTM C230). As the fresh mortar is self compacting, its yield stress is low and below 400 Pa.

[0061] This formulation was tested on pumping system, without any robotic deposition device.

[0062] The material was pumped at a flow rate of 1.9 L/min. In the extrusion head, Foxcrete 5200 was added at a dosage of 0.4 g/L of mortar.

[0063] The yield stress of the placed material was measured at 2500 Pa.

[0064] The material was self-sustaining after the extrusion step. Up to 4 layers were put one atop another manually after 20 min, and the layers did not collapse.

[0065] FIG. 1 shows an equipment that is suitable for carrying out the method of the invention. In FIG. 1 self-leveling mortar 1 is supplied from a storage facility or from an on-site batching plant. The mortar is conveyed to a mortar pump 2, which conveys the mortar through a pipe 3. The pipe 3 leads through a security zone 4, which comprises various connections to the pipe 3. A first connection serves to connect a rinsing water source 5 to the pipe 3 in order to clean the piping of the conveying system from time to time. Further, an emergency outlet 6 is connected to the pipe 3 for removing mortar in case of occurrence of overpressure in the pipe 3. The pressure in pipe 3 is measured by means of a pressure gauge 7. Further, a rupture disc 8 is provided, which may be designed as a non-reclosing pressure relief device that protects the pipe 3 from overpressurization.

[0066] After leaving the security zone 4 the pipe 3 leads to a robot 9, which comprises a deposition head 10. The robot 9 comprises a drive unit (not shown) that moves the deposition head 10 along a path that is determined by an electronic control module based on 3D model data for the object to be constructed. The robot 9 comprises a static mixer 11 to which the mortar is conveyed through the pipe 3. The mixer 11 serves to mix the mortar with a rheology-modifying agent that is fed to the robot 9 from a storage tank 12. The rheology-modifying agent is supplied to a pump 13, which conveys the agent through a pipe 14 to the robot 9. The pipe 14 comprises several connections that are arranged downstream of the pump 13, namely one connection for an emergency outlet 15, one connection for a rupture disc 16 and one connection for a pressure gauge 17.

[0067] The pipe 14 leads into the pipe 3 with an check valve 18 being interposed. The pressure after the mixer 11 is measured by means of a pressure gauge 19. The mixture exiting the mixer 11 may either be fed to a pipe 20 that serves to discharge a waste portion of the mixture or to a pipe 21 which leads to the deposition head for extruding the mixture through a nozzle.