Abstract
The method includes: a first step of forming, at a weld site of laminated layers of a metal foil, using a cutter having a longitudinal cross-sectional shape of a substantially V shape, a notch penetrating the laminated metal foil along a lamination direction and having a linear shape in a plan view, to cause the laminated layers of the metal foil closely contact each other in the lamination direction at an end of the notch; a second step of bringing a welding electrode into pressure contact with the weld site and then energizing the weld site via the welding electrode to perform resistance welding, and a forming step, performed between the first and second steps, of crushing the notch and a raised portion around the notch, to form a recess to thereby compress the notch and the raised portion in the lamination direction.
Claims
1. A method for manufacturing a laminated metal foil, comprising: a first step of forming, at a weld site of laminated layers of a metal foil, by the use of a cutter having a longitudinal cross-sectional shape that is a substantially V shape, a notch penetrating the laminated layers of the metal foil along a lamination direction and having a linear shape in a plan view, to cause the laminated layers of the metal foil closely contact each other in the lamination direction at an end of the notch having the linear shape; a second step of bringing a welding electrode into pressure contact with the weld site and then energizing the weld site via the welding electrode, to perform resistance welding on the laminated metal foil, and a forming step, that is performed between the first step and the second step, of crushing the notch formed in the first step and a raised portion formed around the notch, to form a recess to thereby compress the notch and the raised portion in the lamination direction.
2. The method for manufacturing the laminated metal foil as claimed in claim 1, wherein in the second step, in a state in which the notch is compressed in the lamination direction by the forming step, an electrode terminal is further laminated on the weld site of the laminated layers of the metal foil and the welding electrode is brought into pressure contact with the electrode terminal, and in this state, the weld site and the electrode terminal are energized via the welding electrode, to perform resistance welding on the laminated metal foils and the electrode terminal so as to form a nugget having an elliptic shape extending in a longitudinal direction of the electrode terminal along the notch having the linear shape.
3. The laminated metal foil manufacturing method as claimed in claim 1, wherein a pressing area of a pressing body for forming the recess in the forming step is set to be larger than an end area of the welding electrode in the second step.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0017] In any event, the present invention will become more clearly understood from the following description of preferred embodiments thereof, when taken in conjunction with the accompanying drawings. However, the embodiments and the drawings are given only for the purpose of illustration and explanation, and are not to be taken as limiting the scope of the present invention in any way whatsoever, which scope is to be determined by the appended claims. In the accompanying drawings, like reference numerals are used to denote like parts throughout the several views, and:
[0018] FIG. 1A is a sectional front view showing a laminated metal foil manufacturing method according to one embodiment of the present invention;
[0019] FIG. 1B is a perspective view showing a cutter;
[0020] FIG. 2 is a sectional front view showing the laminated metal foil manufacturing method;
[0021] FIG. 3 is a plan view showing a first step;
[0022] FIG. 4 is a sectional front view showing a second step;
[0023] FIG. 5 is a sectional front view showing the second step;
[0024] FIG. 6 is a perspective view showing the structure of a battery obtained using the laminated metal foil manufacturing method;
[0025] FIG. 7 is an enlarged view showing the second step;
[0026] FIG. 8 is an enlarged view showing a joining portion between a laminated metal foil and an electrode terminal;
[0027] FIG. 9 is a sectional front view showing a state that can occur in the first step;
[0028] FIG. 10 is an enlarged view showing a joining portion between the laminated metal foil and the electrode terminal in FIG. 9;
[0029] FIG. 11 is a sectional front view showing a state that can occur in the second step;
[0030] FIG. 12 is a flowchart showing a laminated metal foil manufacturing process according to the present invention;
[0031] FIG. 13 is a sectional front view showing a forming step; and
[0032] FIG. 14 is an enlarged view showing a joining portion between the laminated metal foil and the electrode terminal in FIG. 13.
DESCRIPTION OF EMBODIMENTS
[0033] Hereinafter, embodiments of the present invention will be described with reference to the drawings. In a method for manufacturing a laminated metal foil according to one embodiment of the present invention, a laminated metal foil in the form of a plurality of laminated layers of a metal foil is manufactured through resistance welding. FIG. 1A shows a laminated state of a plurality of layers of metal foils 2, and the resultant laminated metal foil 1 having been subjected to resistance welding is used as an electrode body of a battery such as a lithium ion battery, for example. As the metal foils 2, for example, an aluminum foil may be used for a positive electrode foil, and a copper foil may be used for a negative electrode foil. As the electrode terminal, for example, aluminum may be used for the material of a positive electrode terminal, and copper may be used for the material of a negative electrode terminal. The present manufacturing method includes a forming step as well as a first step and a second step.
[0034] First Step
[0035] First, as shown in FIG. 1A, a cutter C is caused to penetrate a weld site A of the laminated metal foil 1 along a lamination direction S. FIG. 1B shows the cutter C having a longitudinal cross-sectional shape that is a substantially V shape. A blade tip angle is not less than 10, and preferably, not less than 15. A blade length is not less than 3 mm, and preferably, not less than 5 mm.
[0036] Next, as shown in FIG. 2, the cutter C is caused to penetrate the laminated metal foils 2 in the lamination direction S, to form a notch 3 (FIG. 3) having a linear shape in a plan view extending in a longitudinal direction L perpendicular to a width direction W of the laminated metal foil 1, whereby the metal foils 2 adjacent to each other in the vertical direction are caused to firmly and closely contact each other at notch ends 3a.
[0037] As shown in FIG. 3, in the first step, at both end portions (left and right in the drawing) in the width direction W of the metal foils 2, the linear notches 3 are formed so as to extend in the direction L perpendicular to the width direction W. Thus, it becomes possible to ensure sufficient areas for the notches 3 which are main parts of the weld sites A, without reducing the width-direction dimension of the center part in the width direction W of the metal foils excluding the weld sites A.
[0038] Second Step
[0039] In the second step, as shown in FIG. 4, at the weld site A centered on the notch 3, the laminated metal foil 1 is subjected to pressure contact with welding electrodes E, E of a resistance welding machine (not shown) by being pressed in a sandwich form by the welding electrodes E, E, and the weld site A is energized via the electrodes E, thereby performing resistance welding on the laminated metal foil 1. In the resistance welding, for example, energization is performed while an electrode terminal 4 is laminated on the laminated metal foil 1, whereby the laminated metal foil 1 and the electrode terminal 4 are welded. As shown in FIG. 5, by the resistance heat generation, a nugget (alloy layer) 5 is formed in the notch 3, whereby the laminated metal foil 1 and the electrode terminal 4 are melted and joined with each other. As shown in FIG. 4, current flows through a conduction part R in the lamination direction S (Z direction).
[0040] As shown in FIG. 6, for example, in manufacturing of a lithium ion battery 7, an electrode body 20 serving as an electric power generation element is accommodated in an exterior case 10. A positive electrode terminal 31 and a negative electrode terminal 32 which are electrode terminals connected to the electrode body 20 are provided at both ends in the width direction W so as to protrude in an outward direction (upward direction in the drawing) L of the exterior case 10. The electrode body 20 is a wound body obtained by winding a positive electrode foil 21 and a negative electrode foil 22 in a laminated manner with a separator 23 interposed therebetween.
[0041] An uncoated portion (collecting portion) of the positive electrode foil 21 and the positive electrode terminal 31 are joined with each other via the nugget (alloy layer) 5 formed by resistance heat generation in resistance welding. As shown in FIG. 7, the nugget 5 is formed in an elliptic shape extending in the longitudinal direction L at the weld site A (nugget formation allowable area) in the positive electrode foil 21 at which the positive electrode terminal 31 is welded to the positive electrode foil 21. Thus, even though the size in the width direction W of the weld site A is small, it is possible to ensure a nugget area having an elliptic shape extending in the longitudinal direction L of the positive electrode terminal 31 (electrode terminal) along the linear notch 3, whereby, in this example, the lithium ion battery 7 can be downsized.
[0042] In this drawing, joining between the positive electrode foil 21 made of aluminum and the positive electrode terminal 31 made of aluminum is shown as an example. However, the case of joining between the negative electrode foil 22 made of copper and the negative electrode terminal 32 made of copper is carried out in a similar way.
[0043] As shown in FIG. 8, in the first step, in a state in which the positive electrode foil 21 and the positive electrode terminal 31 are overlapped with each other and a pad plate 51 is placed on the outer side surface on the positive electrode foil 21 side, the cutter C having a longitudinal cross-sectional shape that is a substantially V shape for forming the notch 3 having a linear shape in a plan view is pressed thereon, whereby the notch 3 is formed in the pad plate 51 and the positive electrode foil 21. The notch 3 is linearly formed at the center in the width direction W of the uncoated portion. By forming the notch 3, a surface coating film of aluminum oxide existing on the surface of the positive electrode foil 21 can be removed. The part where the oxide film has been removed has a lower resistance than the other part, and therefore can be used as the conduction part R (FIG. 4) through which current easily flows in the second step. Also in the case of the negative electrode foil 22 made of copper, the conduction part R is formed in the same manner
[0044] In the first step in FIG. 2, when the notch 3 penetrating the laminated metal foil 1 along the lamination direction S and having a linear shape in a plan view is formed by the cutter C, in actuality, the outer periphery of the notch 3 may be raised in a loop shape as shown in FIG. 9 to form a raised portion 52. FIG. 10 shows the raised portion 52 around the notch 3 when the notch 3 is provided in the positive electrode foil 21 of the battery.
[0045] In this case, as shown in FIG. 11, in the second step, if the welding electrode E is directly brought into contact to perform resistance welding, the inside of a substantially triangular gap 53 based on the notch 3, which is formed between the end of the welding electrode E and the electrode terminal 4, is heated, whereby metal (e.g., aluminum) of the laminated metal foil that is exposed on the inner wall of the notch 3 is melted, and then spattered and scattered, so that the scattered metal can adhere to the end peripheral area of the welding electrode E. Thus, the welding electrode E is worn and the life thereof is shortened, and as a result, the frequency of exchange of the welding electrode E increases, and it takes time to perform the exchange each time. Thus, it becomes difficult to improve production efficiency.
[0046] Accordingly, in the present invention, as shown in FIG. 12, between the first step (S1) and the second step (S3), a forming step (S2) is provided in which a recess 55 is formed by crushing the notch 3 and the raised portion 52 around the notch and thus the notch 3 and the raised portion 52 are compressed in the lamination direction S. As shown in FIG. 13, after the notch 3 penetrating the laminated metal foil 1 along the lamination direction S and having a linear shape in a plan view is formed in the first step (S1), the recess 55 is formed by crushing the notch 3 and the raised portion 52 around the notch 3 in the forming step (S2), before joining is performed by resistance welding in the second step (S3).
[0047] As shown in FIG. 13, by a pressing body 54 having a pressing surface the area of which is slightly larger than the end area of the welding electrode E, the notch 3 and the raised portion 52 around the notch 3 are crushed to form the recess 55, and thus the notch 3 and the raised portion 52 are compressed in the lamination direction S. As a result, the gap 53 based on the notch 3 is compressed into a gap 56.
[0048] Thus, the distance between the welding electrode E and the electrode terminal 4 is shortened, so that spattering of the melted metal from the inner wall of the compressed gap 56 is decreased and scattering thereof is suppressed. As a result, the amount of adhesion thereof to the welding electrode E is decreased. In addition, since the welding electrode E can be assuredly brought into contact in a state in which the recess 55 is formed and the notch 3 is compressed, adhesion of the melted metal can be further decreased. FIG. 14 shows a state in which, in the case where the linear notch 3 is provided in the positive electrode foil 21 to be joined to the positive electrode terminal (electrode terminal), the recess 55 is formed by crushing the notch 3 and the raised portion around the notch, and the gap 56 is formed which is compressed in the lamination direction S and extends in the longitudinal direction L of the electrode terminal along the linear notch 3.
[0049] In this state, the welding electrode E is energized, and a nugget (alloy layer) 5 is formed in the gap 56 by resistance heat generation in resistance welding. Thus, even if the size in the width direction W of the weld site A of the laminated metal foil is small, the nugget 5 is formed in an elliptic shape extending in the longitudinal direction L of the electrode terminal along the notch 3, whereby a sufficient nugget area can be obtained.
[0050] As described above, in the present invention, by the forming step, the weld site of the laminated metal foils is compressed in the lamination direction. Therefore, scattering of melted metal is suppressed and adhesion thereof to the welding electrode is decreased. Thus, it is possible to improve production efficiency by decreasing the frequency of exchange of the welding electrode. In addition, even if the size in the width direction of the weld site of the laminated metal foil is small, it is possible to ensure a nugget area having an elliptic shape extending in the longitudinal direction of the electrode terminal along the linear notch.
[0051] Although the present invention has been fully described in connection with the preferred embodiments thereof with reference to the accompanying drawings, those skilled in the art will readily conceive numerous changes and modifications within the framework of obviousness upon the reading of the specification herein presented of the present invention. Accordingly, such changes and modifications are to be construed as included in the scope of the invention defined by claims annexed thereto.
REFERENCE NUMERALS
[0052] 1 . . . Laminated metal foil
[0053] 2 . . . Metal foil
[0054] 3 . . . Notch
[0055] 3a . . . Notch end
[0056] 4 . . . Electrode terminal
[0057] 5 . . . Nugget
[0058] 20 . . . Electrode body
[0059] 52 . . . Raised portion
[0060] 53 . . . Gap
[0061] 54 . . . Pressing body
[0062] 55 . . . Recess
[0063] 56 . . . Gap
[0064] a . . . Weld site
[0065] E . . . Welding electrode
[0066] S . . . Lamination direction of metal foil
