ELECTRON SOURCE AND ELECTRON BEAM IRRADIATION DEVICE
20190198284 ยท 2019-06-27
Assignee
Inventors
- Soichiro MATSUNAGA (Tokyo, JP)
- Yasunari Sohda (Tokyo, JP)
- Souichi KATAGIRI (Tokyo, JP)
- Hajime KAWANO (Tokyo, JP)
- Takashi Doi (Tokyo, JP)
Cpc classification
H01J37/244
ELECTRICITY
H01J37/073
ELECTRICITY
International classification
H01J37/073
ELECTRICITY
H01J37/244
ELECTRICITY
Abstract
Provided is a high-brightness, high-current electron source including a wire-like member. The wire-like member has an electron emission plane at the tip of the wire-like member. The electron emission plane has a projectingly curved surface. At least the surface of the electron emission plane is formed of an amorphous material.
Claims
1. An electron beam irradiation device comprising: an electron source including a wire-like base material and a surface material, the wire-like base material being formed of a conductive material, the surface material being formed of an amorphous material at a tip of the base material and used as an electron emission plane having a projectingly curved surface; and an electron optical system that irradiates a sample with primary electrons extracted from the electron source.
2. The electron beam irradiation device according to claim 1, wherein the surface material has a film thickness of 1 nm or more and not more than 5 m.
3. The electron beam irradiation device according to claim 1, wherein the surface material is formed of carbon or silicon.
4. The electron beam irradiation device according to claim 1, wherein the surface material is formed of a carbon-containing compound.
5. The electron beam irradiation device according to claim 1, wherein the electron emission plane having a projectingly curved surface is configured such that a curvature radius of the projectingly curved surface increases with an increase in a distance from a center of the electron emission plane.
6. The electron beam irradiation device according to claim 1, wherein the base material is a metal having a melting point of 1500 C. or higher.
7. The electron beam irradiation device according to claim 1, wherein the amorphous material is formed of a group 14 element, a carbon-containing compound, a compound of a group 13 element and a group 15 element, or glass.
8. The electron beam irradiation device according to claim 1, further comprising: a detector for detecting secondary electrons that are generated when the sample is irradiated with the primary electrons.
9. The electron beam irradiation device according to claim 1, further comprising: a spectrometer for analyzing energy of secondary electrons that are generated when the sample is irradiated with the primary electrons.
10. The electron beam irradiation device according to claim 1, further comprising: a detector for measuring a diffraction pattern of secondary electrons that are generated when the sample is irradiated with the primary electrons.
11. An electron beam irradiation device comprising: an electron source including a wire-like member that is formed of a conductive amorphous material, a tip of the wire-like member acting as an electron emission plane having a projectingly curved surface; and an electron optical system that irradiates a sample with primary electrons extracted from the electron source.
12. The electron beam irradiation device according to claim 11, wherein the electron emission plane having a projectingly curved surface is configured such that a curvature radius of the projectingly curved surface increases with an increase in a distance from a center of the electron emission plane.
13. The electron beam irradiation device according to claim 11, wherein the amorphous material is formed of a group 14 element, a carbon-containing compound, a compound of a group 13 element and a group 15 element, or glass.
14. The electron beam irradiation device according to claim 11, further comprising: a detector for detecting secondary electrons that are generated when the sample is irradiated with the primary electrons.
15. The electron beam irradiation device according to claim 11, further comprising: a spectrometer for analyzing energy of secondary electrons that are generated when the sample is irradiated with the primary electrons.
16. The electron beam irradiation device according to claim 11, further comprising: a detector for measuring a diffraction pattern of secondary electrons that are generated when the sample is irradiated with the primary electrons.
17. An electron source including: a wire-like member that has an electron emission plane having a projectingly curved surface at a tip of the wire-like member, and at least a surface of the electron emission plane being formed of an amorphous material.
18. The electron source according to claim 17, wherein the wire-like member includes a base material and a surface material, the base material being formed of a conductive material, the surface material being formed of an amorphous material on the electron emission plane, the amorphous material having a film thickness of 1 nm or more and not more than 5 m.
19. The electron source according to claim 17, wherein the electron emission plane having a projectingly curved surface is configured such that a curvature radius of the projectingly curved surface increases with an increase in a distance from a center of the electron emission plane.
20. The electron source according to claim 17, wherein the amorphous material is formed of a group 14 element, a carbon-containing compound, a compound of a group 13 element and a group 15 element, or glass.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0021]
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[0036]
MODE FOR CARRYING OUT THE INVENTION
[0037] The inventors and the like studied a method of providing a high-brightness, high-current electron source, that is, a method of reducing the size of a virtual source and increasing the angular current density. As a result, it was found that the method is made implementable by adopting a configuration including a base material and a surface material. The base material is formed of a conductive material. The surface material is formed of an amorphous material disposed to cover the tip of the base material and is provided with a region having a curved surface and acting as an electron emission plane. When the electron emission plane is a curved surface, a virtual trajectory converges to one point. This makes it possible to reduce the size of the virtual source. Further, when the surface material is formed of an amorphous material, it is possible to obtain a curved electron emission plane and suppress intensity distribution irregularity of electron emission. That is to say, even when the angular current density is high, the virtual source is small in size. It signifies that a high-brightness, high-current electron source can be obtained. Using such an electron source makes it possible to obtain an electron microscope image having a high signal-to-noise ratio and a high spatial resolution.
[0038] Embodiments of the present invention will now be described with reference to the accompanying drawings. Like elements are designated by like reference characters.
First Embodiment
[0039] A first embodiment of the present invention is described below with reference to the accompanying drawings.
[0040] The tip of the electron source base material is coated by vapor-depositing amorphous carbon 202 onto the surface of the base material (wire) 201 of the electron source. The thickness 205 of the applied coating is 0.01 m or greater so that the crystal structure of the surface remains unaffected. An extraction electrode 203 is installed to face the electron source. Although the extraction electrode depicted in
[0041] Although the present embodiment adopts tungsten that is used as a material for a conventional high-brightness electron source, the tungsten may be substituted by an electrically conductive substance. The amorphous carbon may be deposited by using a sputter or ion beam deposition method. The curved surface of the tip of the electron source may alternatively be shaped by an ion beam. The electron source need not always be entirely coated with the amorphous carbon. Coating only an electron emission section will suffice. Although the present embodiment uses carbon as an amorphous substance for coating, the carbon may be substituted by a carbon compound, a group 14 element such as silicon, a group 13-15 compound, glass, or other material capable of maintaining an amorphous state at room temperature. However, when a non-conductive material is used, it needs to be thin enough to permit electron tunneling.
[0042] Although the coating thickness is 0.01 m in the present embodiment, a coating thickness of 1 m or less is feasible. The reason will now be described with reference to
[0043] The strength of an electric field generated at the tip of the electron source is inversely proportional to the above-mentioned curvature radius (R+T) and is proportional to an extraction voltage. That is to say, when an electric field having the same strength as in a case where no coating is applied is to be generated at the tip of the electron source that is coated with an amorphous material, an extraction voltage higher than when no coating is applied needs to be applied to the extraction electrode 203.
[0044] However, when the extraction voltage is raised, a discharge is highly likely to occur in an electron gun. In a case where a clean surface of tungsten is used for field emission, electrons are emitted by applying an extraction voltage of approximately 4 kV to an electron source with a tip having a curvature radius R=0.1 m. When the extraction voltage for generating an electric field having approximately the same strength for the electron source according to the present embodiment is to be reduced to 50 kV or lower, R needs to be 1 m or less. However, the intended effects are achieved as far as the thickness of an amorphous coating is 1 nm to 5 m. A practical range of the amorphous coating thickness is 1 nm to 1 m, and a suitable range is 1 nm to 0.1 m.
[0045] The reason why coating with amorphous carbon is necessary will now be described. The virtual source can be reduced in size by curving the electron emission plane. However, shaping the tip of the electron source into a curved surface in a simple manner is insufficient. The reason is that even if the tip of an amorphous substance used as a field emission electron source, such as metal or diamond, is shaped into a spherical surface, a stable crystal plane is formed over the spherical surface. That is to say, the surface of the electron source is configured as a crystal plane aggregate having a size of approximately several tens of nanometers. In this instance, the work function depends on the orientation of the crystal plane. Therefore, electron emission is likely to occur only in a particular direction so that the intensity distribution of an electron beam is not uniform. If the intensity distribution is not uniform, electron emission density decreases so that high brightness cannot be achieved. Under such circumstances, the electron emission plane is formed of a non-crystalline substance, that is, an amorphous substance. This reduces the non-uniformity of electron beam emission, which is dependent on the orientation of the crystal plane.
[0046] When the spatial distribution pattern of electron emission is measured, it is found that electron emission is no longer dependent on crystal orientation. The spatial distribution pattern can be obtained by installing a fluorescent screen downstream of the extraction electrode and capturing an image of the fluorescent screen with a digital camera.
[0047] When a conventional high-brightness electron source, such as a CFE or a Schottky electron source, is used, electrons are selectively emitted from the (310) or (100) plane of tungsten so that an electron emission pattern corresponding to such a crystal plane is obtained as depicted in
[0048] The relationship between the virtual source and typical electron trajectories of electrons emitted from the above-mentioned electron source will now be described with reference to
[0049] Even if the electron emission plane is shaped into a curved surface to increase the angular current density in a case where the electron source is configured as depicted in
[0050] As described above, the present embodiment provides a high-brightness, high-current electron source.
Second Embodiment
[0051] The electron source according to a second embodiment of the present invention will now be described with reference to
[0052]
[0053] Next, as is the case with the first embodiment, an extraction electrode 503 is installed so as to face the electron source in order to extract electrons. The extraction electrode depicted in
[0054] As described above, the second embodiment provides the same advantageous effects as the first embodiment. Additionally, using the fluid carbon-containing compound as the coating agent makes it easy to control the film thickness and uniformity of the coating. Moreover, heating the coating agent containing an organic substance for carbonization makes it easy to implement the amorphous carbon coating.
Third Embodiment
[0055] The electron source according to a third embodiment of the present invention will now be described with reference to
[0056]
[0057] Meanwhile, an electron gun in an actual electron beam irradiation device emits an electron beam in one direction. Therefore, the extraction electrode has a non-spherical surface in most cases. The third embodiment will be described with reference to a case where the extraction electrode has a planar surface as an example in which the surface of the extraction electrode is not spherical. When an extraction electrode 623 has a planar surface as depicted in
[0058] In order to reduce the size of the virtual source by suppressing the extension of the virtual trajectory even when a planar electrode is used for extraction, the present embodiment changes the shape of the electron source from the spherical surface. More specifically, as depicted in
[0059] Even when the extraction electrode is not spherical in shape, the present embodiment reduces the size of the virtual source. The above-mentioned advantageous effects remain unchanged even when such an extraction electrode is bored to acquire a current.
[0060] As described above, the third embodiment provides the same advantageous effects as the first embodiment. Additionally, as the tip of the base material is shaped so that the curvature radius of the tip forms an increasingly large curved surface with an increase in the distance from the center of the electron emission plane, the size of the virtual source can be further reduced.
Fourth Embodiment
[0061] The electron source according to a fourth embodiment of the present invention will now be described with reference to
[0062]
[0063] As is the case with the first embodiment, the surface of the base material is coated with amorphous carbon 702, and an extraction electrode 703 is installed so as to face the electron source. The extraction electrode depicted in
[0064] As described above, the fourth embodiment provides the same advantageous effects as the first embodiment. Additionally, using a high-melting point metal or its compound as the base material for the electron source suppresses the deformation of the tip of the electron source.
Fifth Embodiment
[0065] The electron source according to a fifth embodiment of the present invention will now be described with reference to
[0066]
[0067] Next, an extraction electrode 803 is installed so as to face the electron source, as is the case with the first embodiment. The extraction electrode 803 depicted in
[0068] As described above, the fifth embodiment provides the same advantageous effects as the first embodiment. Additionally, as an amorphous material is used as the base material, the base material need not be coated with an amorphous material. This simplifies a manufacturing process.
Sixth Embodiment
[0069] An electron beam irradiation device according to a sixth embodiment of the present invention will now be described with reference to
[0070]
[0071] The electron beam (primary electron beam) 908 extracted from the electron source 901 is converged to the measurement sample 907 by using the objective lens 906. A SEM image is obtained by scanning the measurement sample with the converged primary electron beam 908 through the use of the scanning deflector 909 and detecting the generated secondary electrons 910 with the detector 911. The sixth embodiment uses the electron source that is described in conjunction with the first embodiment. Alternatively, however, the electron source described in conjunction with any one of the second to fifth embodiments may be used.
[0072] As the dimensions of the virtual source for the electron source can be decreased, the spot diameter of the electron beam to be emitted onto the measurement sample can be decreased. Therefore, when the measurement sample is observed with the SEM depicted in
[0073] As described above, the sixth embodiment provides an electron beam irradiation device having a high spatial resolution. Further, as the current to be incident on a sample can be increased, SEM images having a high SNR and a high spatial resolution can be obtained. Moreover, high-throughput and high-spatial-resolution SEM images can be obtained.
Seventh Embodiment
[0074] The electron beam irradiation device according to a seventh embodiment of the present invention will now be described with reference to
[0075]
[0076]
[0077] As described above, the seventh embodiment provides an electron beam irradiation device having a high spatial resolution. Further, as the current to be incident on a sample can be increased, analysis can be made at a high SNR and at a high spatial resolution. Moreover, analysis can be made at a high measurement speed and at a high spatial resolution.
[0078] The present invention is not limited to the foregoing embodiments, but includes various modifications. For example, the foregoing embodiments are described in detail in order to facilitate the understanding of the present invention. The present invention is not necessarily limited to a configuration that includes all the above-described elements. Further, some elements of a certain embodiment may be replaced by elements of another embodiment, and elements of a certain embodiment may be added to the elements of another embodiment. Furthermore, some elements of each embodiment may be subjected to the addition of other elements, deleted, or replaced by other elements.
DESCRIPTION OF REFERENCE CHARACTERS
[0079] 101: Sharpened tungsten (310) monocrystalline wire [0080] 102: (310) plane acting as electron emission plane [0081] 103: Typical electron trajectory of electrons emitted from electron source [0082] 104: Virtual trajectory obtained by armoring electron trajectory [0083] 103 [0084] 105: Virtual source [0085] 106: Sharpened tungsten (100) monocrystalline wire [0086] 107: (100) plane acting as electron emission plane [0087] 108: Typical electron trajectory of electrons emitted from electron source [0088] 109: Virtual trajectory obtained by armoring electron trajectory 108 [0089] 110: Virtual source [0090] 201: Sharpened tungsten wire [0091] 202: Amorphous carbon [0092] 203: Extraction electrode [0093] 204: Tip curvature radius of tungsten wire [0094] 205: Film thickness of amorphous carbon [0095] 301: Sharpened tungsten wire [0096] 302: Amorphous material [0097] 303: Extraction electrode [0098] 304-312: Typical trajectory of electrons emitted from electron source [0099] 313-321: Virtual trajectory obtained from electron trajectories [0100] 304 to 312 [0101] 322: Virtual source (convergence point of virtual trajectories) [0102] 323: Size of virtual source [0103] 501: Sharpened tungsten wire [0104] 502: Organic polymer [0105] 503: Extraction electrode [0106] 601: Electron trajectory [0107] 602: Virtual trajectory [0108] 603: Electron trajectory [0109] 604: Virtual trajectory [0110] 605: Electron trajectory [0111] 606: Virtual trajectory [0112] 611: Base material [0113] 613: Extraction electrode [0114] 621: Base material [0115] 623: Extraction electrode [0116] 701: Sharpened molybdenum wire [0117] 702: Amorphous carbon [0118] 703: Extraction electrode [0119] 801: Sharpened amorphous silicon wire [0120] 803: Extraction electrode [0121] 901: Electron source described in conjunction with first embodiment [0122] 902: Extraction electrode [0123] 903: Accelerating electrode [0124] 904: Condenser lens [0125] 905: Diaphragm [0126] 906: Objective lens [0127] 907: Measurement sample [0128] 908: Converged primary electrons [0129] 909: Scanning deflector [0130] 910: Generated secondary electrons [0131] 911: Detector [0132] 1011: Energy spectrometer [0133] 1111: Two-dimensionally disposed electron detectors [0134] 1112: Interference pattern