SEPARATOR FOR FUEL BATTERY
20220407087 ยท 2022-12-22
Assignee
Inventors
Cpc classification
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0267
ELECTRICITY
International classification
Abstract
A separator for a fuel cell includes protrusions and gas passage portions. The protrusions each include a contact surface configured to contact a power generation portion. The gas passage portions are each arranged between two adjacent ones of the protrusions. An upstream side and a downstream side are defined with reference to a direction in which reactant gas flows through the gas passage portions. The protrusions each include a downstream end. The contact surfaces of the protrusions each include a first groove extending along an extending direction of the protrusions. The downstream end of each of the protrusions includes a separation surface. The separation surface is continuous with the contact surface on the downstream side and separated from the power generation portion. The separation surface includes a second groove that is continuous with the first groove.
Claims
1. A separator for a fuel cell, the separator being configured to contact a power generation portion of the fuel cell, the separator comprising: protrusions that extend in parallel and are spaced apart from each other, the protrusions being configured to contact the power generation portion, and the protrusions each including a contact surface configured to contact the power generation portion; and gas passage portions arranged between two adjacent ones of the protrusions such that reactant gas flows through the gas passage portions, wherein: an upstream side and a downstream side are defined with reference to a direction in which reactant gas flows through the gas passage portions, the protrusions each include a downstream end, the contact surfaces of the protrusions each include a first groove extending along an extending direction of the protrusions, the downstream end of each of the protrusions includes a separation surface, the separation surface being continuous with the contact surface on the downstream side and separated from the power generation portion, and the separation surface includes a second groove that is continuous with the first groove.
2. The separator for the fuel cell according to claim 1, wherein the separation surface is an inclined surface inclined such that the downstream side of the separation surface becomes farther from the power generation portion.
3. The separator for the fuel cell according to claim 1, wherein: the protrusions are arranged in series and spaced apart from each other, and the second groove is arranged in the separation surface of each of the protrusions.
4. The separator for the fuel cell according to claim 1, wherein the contact surface includes a third groove that connects the first groove to the gas passage portions.
5. The separator for the fuel cell according to claim 4, wherein: the third groove is one of third grooves arranged in the contact surface, and the third groove accounts for a smaller proportion of the contact surface on the downstream side than on the upstream side.
6. The separator for the fuel cell according to claim 2, wherein: the protrusions are arranged in series and spaced apart from each other, and the second groove is arranged in the separation surface of each of the protrusions.
7. The separator for the fuel cell according to claim 6, wherein the contact surface includes a third groove that connects the first groove to the gas passage portions.
8. The separator for the fuel cell according to claim 7, wherein: the third groove is one of third grooves arranged in the contact surface, and the third groove accounts for a smaller proportion of the contact surface on the downstream side than on the upstream side.
9. The separator for the fuel cell according to claim 2, wherein the contact surface includes a third groove that connects the first groove to the gas passage portions.
10. The separator for the fuel cell according to claim 9, wherein: the third groove is one of third grooves arranged in the contact surface, and the third groove accounts for a smaller proportion of the contact surface on the downstream side than on the upstream side.
11. The separator for the fuel cell according to claim 3, wherein the contact surface includes a third groove that connects the first groove to the gas passage portions.
12. The separator for the fuel cell according to claim 11, wherein: the third groove is one of third grooves arranged in the contact surface, and the third groove accounts for a smaller proportion of the contact surface on the downstream side than on the upstream side.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
DESCRIPTION OF EMBODIMENTS
[0026] A separator for a fuel cell according to an embodiment will now be described with reference to
[0027] For illustrative purposes, some parts of the structures in the drawings may be exaggerated or simplified. Further, the dimensional ratios of portions may be different among the drawings.
[0028] As shown in
[0029] The stack 100 includes a structure in which cells 10 are stacked. Each cell 10 includes a power generation portion 11 held by the first separator 30, which is on an anode side, and the second separator 50, which is on a cathode side.
[0030] The power generation portion 11 includes a membrane electrode assembly 12, an anode-side gas diffusion layer 15, and a cathode-side gas diffusion layer 16. The anode-side gas diffusion layer 15 and the cathode-side gas diffusion layer 16 hold the membrane electrode assembly 12. The anode-side gas diffusion layer 15 is located between the membrane electrode assembly 12 and the first separator 30. The cathode-side gas diffusion layer 16 is located between the membrane electrode assembly 12 and the second separator 50. The anode-side gas diffusion layer 15 and the cathode-side gas diffusion layer 16 are made of carbon fibers.
[0031] The electrolyte membrane assembly 12 includes an electrolyte membrane 13, which is made of a solid polymer material that has an excellent proton conductivity in a wet state, and two catalytic electrode layers 14 that hold the electrolyte membrane 13. Each catalytic electrode layer 14 supports a catalyst (e.g., platinum) in order to expedite the electrochemical reaction of reactant gas in the fuel cell.
[0032] The first separator 30 is formed by pressing a metal (e.g., stainless steel) plate. The portion of the first separator 30 opposing the power generation portion 11 includes a distributing section 40 that distributes reactant gas to the entire power generation portion 11. The distributing section 40 includes protrusions 41 and gas passage portions 42. The protrusions 41 are configured to extend in parallel and be spaced apart from each other. Further, the protrusions 41 are configured to contact the power generation portion 11. The gas passage portions 42 are configured to be arranged between two adjacent ones of the protrusions 41 such that reactant gas flows through the gas passage portions 42. Each protrusion 41 is in contact with the anode-side gas diffusion layer 15. The protrusions 41 and the gas passage portions 42 extend in the direction that is orthogonal to the sheet of
[0033] The second separator 50 is formed by pressing a metal (e.g., stainless steel) plate. The portion of the second separator 50 opposing the power generation portion 11 includes a distributing section 60 that distributes reactant gas to the entire power generation portion 11. The distributing section 60 includes protrusions 61 and gas passage portions 62. The protrusions 61 are configured to extend in parallel and be spaced apart from each other. Further, the protrusions 61 are configured to contact the power generation portion 11. The gas passage portions 62 are configured to be arranged between two adjacent ones of the protrusions 61 such that reactant gas flows through the gas passage portions 62. Each protrusion 61 is in contact with the cathode-side gas diffusion layer 16. The protrusions 61 and the gas passage portions 62 extend in the direction that is orthogonal to the sheet of
[0034] The section of the first separator 30 defined by each gas passage portion 42 of the first separator 30 and the anode-side gas diffusion layer 15 includes a fuel gas passage through which fuel gas (reactant gas) flows. The section of the second separator 50 defined by each gas passage portion 62 of the second separator 50 and the cathode-side gas diffusion layer 16 is an oxidizing gas passage through which oxidizing gas (reactant gas) flows. In the present embodiment, the fuel gas passing through the fuel gas passage is hydrogen, and the oxidizing gas flowing through the oxidizing gas passage is air.
[0035] The bottom of each gas passage portion 42 of the first separator 30 and the bottom of the corresponding gas passage portion 62 of the second separator 50 are joined to each other through, for example, laser welding. The section defined by the rear surface of each protrusion 41 of the first separator 30 and the rear surface of the corresponding protrusion 61 of the second separator 50 is a coolant passage through which coolant flows.
[0036] In the stack 100 of the present embodiment, the fuel gas supplied to the fuel gas passage electrochemically reacts with the oxidizing gas supplied to the oxidizing gas passage so as to generate power. This generates water (hereinafter referred to as generated water) through electrochemical reaction of the fuel gas and oxygen (i.e., hydrogen and oxygen) in the cathode-side electrode catalytic electrode layer 14 and the cathode-side gas diffusion layer 16. The pressure of the oxidizing gas flowing through each gas passage portion 62 of the second separator 50 moves such a generated water toward the downstream side so that the generated water is discharged to the outside through an oxidizing gas discharge manifold 53b (described later).
[0037] The second separator 50 will now be described in detail.
[0038] As shown in
[0039] In the following description, the direction in which the long sides of the second separator 50 extend is referred to as the longitudinal direction. The direction in which the short sides of the second separator 50 extend and which is orthogonal to the longitudinal direction is referred to as the width direction. The right side and the left side in
[0040] The end of the second separator 50 on the first side in the longitudinal direction includes a fuel gas discharge manifold 51b, a coolant discharge manifold 52b, and an oxidizing gas supply manifold 53a in this order from the first side in the width direction. The end of the second separator 50 on the second side in the longitudinal direction includes a fuel gas supply manifold 51a, a coolant supply manifold 52a, and the oxidizing gas discharge manifold 53b in this order from the second side in the width direction.
[0041] Fuel gas is supplied through the fuel gas supply manifold 51a to the fuel gas passage and discharged out of the fuel gas discharge manifold 51b. Coolant is supplied through the coolant supply manifold 52a to the coolant gas passage and discharged out of the coolant discharge manifold 52b. Oxidizing gas is supplied through the oxidizing gas supply manifold 53a to the oxidizing gas passage and discharged out of the oxidizing gas discharge manifold 53b.
[0042] The distributing section 60 is located at the middle of the second separator 50. The distributing section 60 of the present embodiment is connected to the oxidizing gas supply manifold 53a by a diffusing portion 54a and connected to the oxidizing gas discharge manifold 53b by a diffusing portion 54b. The distributing section 60 extends along the longitudinal direction and is folded back twice. Thus, the protrusions 61 and the gas passage portions 62 extend along the longitudinal direction and are folded back twice.
[0043] The diffusing portion 54a diffuses the reactant gas that flows toward the distributing section 60. The diffusing portion 54b diffuses the reactant gas that flows toward the oxidizing gas discharge manifold 53b. The diffusing portions 54a, 54b each include hemispherical protuberances that protrude in the thickness direction of the second separator 50.
[0044] In the following description, the upstream side and the downstream side are simply defined with respect to the direction in which reactant gas flows through the gas passage portions 62, which define the oxidizing gas passages.
[0045] A seal frame 55 is arranged on the outer side of each of the manifolds 51a, 51b, 52a, 52b. Each seal frame 55 individually surrounds the corresponding one of the manifolds 51a, 51b, 52a, 52b. A seal frame 56 is arranged on the outer side of the oxidizing gas supply manifold 53a, the diffusing portion 54a, the distributing section 60, the diffusing portion 54b, and the oxidizing gas discharge manifold 53b to collectively surround these components. The seal frames 55, 56 protrude in the thickness direction of the second separator 50. The seal frames 55, 56 limit leakage of reactant gas by contacting another cell 10 that is adjacent to the seal frames 55, 56.
[0046] As shown in
[0047] As shown in
[0048] The inclined surface 64 includes a second groove 66. The second groove 66 is continuous with the first groove 65 and extends toward the downstream side. The second groove 66 is arranged in the entire inclined surface 64 in the extending direction.
[0049] The contact surface 63 includes third grooves 67 that connect the first groove 65 to the gas passage portions 62. More specifically, two third grooves 67 are spaced apart from each other in the extending direction such that the third grooves 67 branch from the first groove 65 toward the opposite sides in the arrangement direction and connect to the gas passage portions 62 on the opposite sides. The third grooves 67 each extend in a direction orthogonal to the first groove 65 and are located on the same position in the extending direction. The width and depth of each third groove 67 in the present embodiment are the same over the entire protrusion 61.
[0050] As shown in
[0051] The operation of the present embodiment will now be described.
[0052] Generated water, generated through the generation of power in a fuel cell, flows into the first groove 65, which is located in the contact surface 63 of each protrusion 61 of the second separator 50 in contact with the power generation portion 11. Further, the generated water moves toward the downstream side. Then, the generated water that has reached the downstream end of the first groove 65 flows into the second groove 66, which is located in the inclined surface 64 continuous with the contact surface 63. The inclination of the inclined surface 64 allows the generated water to smoothly move toward the downstream side.
[0053] The advantages of the embodiment will now be described.
[0054] (1) The contact surface 63 in contact with the power generation portion 11 of the protrusion 61 of the second separator 50 includes the first groove 65, which extends along the extending direction of the protrusion 61. The downstream end of each protrusion 61 includes the inclined surface 64, which is continuous with the contact surface 63 on the downstream side. The inclined surface 64 is inclined such that the downstream side of the inclined surface 64 becomes farther from the power generation portion 11. The inclined surface 64 includes the second groove 66, which is continuous with the first groove 65.
[0055] Such a structure produces the above-described operation and thus improves the performance of discharging generated water.
[0056] (2) The contact surface 63 includes the third grooves 67, which connect the first groove 65 to the gas passage portions 62.
[0057] In this structure, since the contact surface 63 includes the third grooves 67 connecting the first groove 65 to the gas passage portions 62, a portion of the generated water that has flowed from the power generation portion 11 into the first groove 65 flows toward the second groove 66 whereas another portion of the generated water flows through the third grooves 67 toward the gas passage portions 62. Thus, the generated water that has flowed from the power generation portion 11 to the first groove 65 flows toward the downstream side through the second groove 66 and the gas passage portions 62. This further improves the performance of discharging generated water. In addition, such an arrangement of multiple discharge passages for generated water prevents the generated water from remaining in a part of the second separator 50.
[0058] (3) The third grooves 67 account for a smaller proportion of the contact surface 63 on the downstream side than on the upstream side.
[0059] The generated water in the power generation portion 11 flows through the gas passage portions 62 from the upstream side toward the downstream side. Thus, the generated water easily remains in the parts of the passage portions 62 closer to the downstream side.
[0060] In the above-described structure, the third grooves 67 account for a smaller proportion of the contact surface 63 on the downstream side than on the upstream side. Thus, the amount of the generated water flowing from the third grooves 67 from the first groove 65 toward the gas passage portions 62 is smaller on the downstream side than on the upstream side. Accordingly, the generated water on the upstream side in the first groove 65 is easily discharged toward the gas passage portions 62 through the third grooves 67, rather than flowing toward the downstream side. Further, the generated water on the downstream side in the first groove 65 is discharged through the second groove 66 toward the downstream side more easily than through the third grooves 67 toward the gas passage portions 62. These configurations prevent situations in which an excessive amount of generated water flows into the first groove 65 so that the first groove 65 is closed by the generated water, and prevents an excessive amount of generated water from remaining on the downstream side of the gas passage portions 62. Accordingly, when the generated water in the first groove 65 is discharged, the amount of the generated water discharged through the third grooves 67 and the amount of the generated water discharged through the second groove 66 can be adjusted by changing the proportion of the third grooves 67 accounting for the contact surface 63. As a result, generated water is efficiently discharged.
[0061] Modifications
[0062] The present embodiment may be modified as follows. The present embodiment and the following modifications can be combined as long as they remain technically consistent with each other.
[0063] In the following first to third modifications respectively shown in
[0064] As shown in
[0065] As shown in
[0066] As shown in
[0067] The proportion of the third grooves 67 accounting for the contact surface 63 may gradually become smaller from the upstream side toward the downstream side or may become smaller from the upstream side toward the downstream side in a stepwise manner.
[0068] The proportion of the third grooves 67 accounting for the contact surface 63 may be the same along the entire direction in which reactant gas flows.
[0069] The width and depth of each third groove 67 in the present embodiment do not have to be the same over the entire protrusion 61. Instead, for example, the width and depth of each third groove 67 may be smaller on the downstream side than on the upstream side. This produces an advantage similar to the above-described advantage (3).
[0070] Each third groove 67 does not have to extend in the direction orthogonal to the first groove 65. Instead, each third groove 67 may extend in a direction intersecting the first groove 65 at an angle. For example, as compared with when each third groove 67 extends in the direction orthogonal to the first groove 65, the third groove 67 is provided over a longer range when the third groove 67 is extended and inclined with respect to the first groove 65 such that the third groove 67 becomes closer to the downstream side as the third groove 67 becomes closer to the gas passage portions 62.
[0071] One of two third grooves 67 may be omitted.
[0072] The third grooves 67 may be omitted.
[0073] Multiple first grooves 65 may be located in one contact surface 63 in the arrangement direction. In this case, the first grooves 65 may merge at a point in the protrusion 61 in the extending direction.
[0074] In one contact surface 63, multiple first grooves 65 may be arranged in series and spaced apart from each other in the extending direction. In this case, the second groove 66 is connected to one of the first grooves 65 that is located on the most downstream side.
[0075] The first groove 65 may be extended and inclined with respect to the extending direction.
[0076] The first groove 65, the second groove 66, and the third groove 67 may each have a right-angle corner or a curved corner.
[0077] The first separator 30 may include the first groove 65, the second groove 66, and the third groove 67. That is, the first separator 30 may have the same shape as the second separator 50.
[0078] The separator 20 does not have to be formed using a metal plate. Instead, the separator 20 may be made of, for example, a carbon-containing material.
REFERENCE SIGNS LIST
[0079] 11) Power Generation Portion [0080] 50) Second Separator [0081] 61) Protrusion [0082] 62) Gas Passage Portion [0083] 63) Contact Surface [0084] 64) Inclined Surface [0085] 65) First Groove [0086] 66) Second Groove [0087] 67) Third Groove