High SPF, Photoprotective Anhydrous Zinc Oxide Sunscreen Compositions

Abstract

A broad spectrum, anhydrous sunscreen composition having an SPF value of at least 50 that (x) does not contain an organic sunscreen active that absorbs ultraviolet radiation and (y) contains only a physical sunscreen active ingredient, Zinc Oxide, having an average particle size of greater than about 100 nanometers, the composition being comprised of: (a) at least one SPF-boosting emollient selected from the group consisting of Octyldodecyl Neopentanoate, Butyl Octyl Salycilate, and Cetyl Dimethicone; (b) at least one powder that provides protection to the skin from photodamage induced by exposure to ultraviolet radiation; (c) at least one powder that provides protection of the skin from photodamage induced by exposure to infrared radiation; (d) at least one film-forming polymer, and at least one bulking agent or binding agent.

Claims

1. A broad spectrum, anhydrous sunscreen composition having an SPF value of at least 50 that (x) does not contain an organic sunscreen active that absorbs ultraviolet radiation and (y) contains only a physical sunscreen active ingredient, Zinc Oxide, having an average particle size of greater than about 100 nanometers, the composition being comprised of: a. at least one SPF-boosting emollient selected from the group consisting of Octyldodecyl Neopentanoate, Butyl Octyl Salycilate, and Cetyl Dimethicone, b. at least one powder that provides protection to the skin from photodamage induced by exposure to ultraviolet radiation, c. at least one powder that provides protection of the skin from photodamage induced by exposure to infrared radiation, d. at least one film-forming polymer, and e. at least one bulking agent or binding agent.

2. The sunscreen composition of claim 1, wherein the at least one powder that provides protection to the skin from photodamage induced by exposure to ultraviolet radiation is selected from the group of Styrene/Acrylates Copolymer or Polyhydroxystearic Acid.

3. The sunscreen composition of claim 1, wherein the at least one powder that provides protection of the skin from photodamage induced by exposure to infrared radiation is a mixture that contains Cerium Oxide and Aluminum Oxide.

4. The sunscreen composition of claim 1, further comprising at least one aesthetic enhancing powder that improves skin feel, is oil-absorbing, imparts silky texture, enhances slip, increases blendability, or reduces the appearance of fine lines and wrinkles on skin.

5. The sunscreen composition of claim 1, wherein the aesthetic enhancing powder is oil-absorbing.

6. The sunscreen composition of claim 5, wherein the oil-absorbing aesthetic enhancing powder is silica.

7. The sunscreen composition of claim 1, wherein the aesthetic enhancing powder is Nylon-12.

8. The sunscreen composition of claim 1, wherein the film-forming polymer is selected from the group consisting of (a) Acrylates/Dimethicone Copolymer and (b) Trimethylsiloxysilicate.

9. The sunscreen composition of claim 1, further comprising at least one bulking agent selected from the group consisting of Hectorite (and its reaction products), Kaolin and Polyethylene and at least one binding agent selected from the group of Ozokerite and Polybutene.

10. The sunscreen composition of claim 1, further comprising a water-in-oil emulsifier.

11. The sunscreen composition of claim 10, wherein the water-in-oil emulsifier is Polyglyceryl-3 Sorbityl Linseedate.

12. (canceled)

13. (canceled)

14. The sunscreen composition of claim 13, wherein the at least one occlusive skin conditioning agent is Tribehenin or a mixture of Hydrogenated Olive Oil and Hydrogenated Olive Oil Unsaponifiables.

15. The sunscreen composition of claim 1, further comprising an aesthetics modifier.

16. The sunscreen composition of claim 15, wherein the aesthetics modifier is a nonaqueous viscosity increasing agent.

17. The sunscreen composition of claim 16, wherein the nonaqueous viscosity increasing agent is Dimethicone/Vinyl Dimethicone Crosspolymer.

18. The sunscreen composition of claim 1, further comprising at least one environmental protectant.

19. The sunscreen composition of claim 18, wherein the at least one environmental protectant is selected from the group of Benzylidene Dimethoxydimethylindanone, Tocopheryl Acetate, Bisabolol and Zingiber Officinale Root Extract.

20. The sunscreen composition of claim 1, further comprising at least one coloring agent.

21. (canceled)

22. (canceled)

23. (canceled)

24. (canceled)

25. The sunscreen composition of claim 1, wherein the Zinc Oxide has a porous structure, such that when pores within Zinc Oxide particles are filled with an excipient, the refractive index of the Zinc Oxide particles is reduced.

26. The sunscreen composition of claim 1 having water resistance for 80 minutes as determined in accordance with the test method codified at 21 CFR 201.327(i)(7).

Description

DETAILED DISCUSSION OF THE INVENTION

[0019] The present invention is directed to anhydrous sunscreen compositions [0020] (i) having an SPF of at least 50, that are [0021] (ii) broad spectrum (according to regulations promulgated by both the US Food and Drug Administration (FDA) and the European Commission) [0022] (iii) photostable [0023] (iv) do not contain an organic sunscreen active that absorbs ultraviolet radiation, and [0024] (v) contain only a single physical sunscreen active ingredient Zinc Oxide having an average particle size of greater than about 0.1 microns.

Zinc Oxide

[0025] Sunscreen compositions of the present invention contain a single sunscreen active ingredientNon-Nano Zinc Oxideuncoated particles of Zinc Oxide having an average particle size of greater than about 0.1 microns, preferably having an average particle size of greater than about 0.2 microns, still more preferably having an average particle size of greater than about 0.4 microns, and even more preferably having an average particle size of greater than about 0.5 microns and less than about 0.8 microns.

[0026] In preferred embodiments, the Non-Nano Zinc Oxide particles have a porous structure, such that when the pores are filled with an excipient (carrier fluid), the refractive index of the particles is reduced to a value close to that of the excipient. Non-Nano Zinc Oxide particles are commercially available from Argan Co. under the tradename ARGA-SUN ZnO CLR-P.

SPF-Boosting Emollients

[0027] Emollients are cosmetic ingredients that help to maintain the soft, smooth appearance of skin and reduce flaking.

[0028] Compositions of the present invention include at least one, preferably at least two, and even more preferably at least three emollients that boost (i.e., increase) SPF, preferably selected from the group consisting of Octyldodecyl Neopentanoate, Butyl Octyl Salycilate, and Cetyl Dimethicone.

[0029] Octyldodecyl Neopentanoate (C.sub.25H.sub.50O.sub.2) is sold under the tradename Elefac I-205 by Alzo International Inc. (Sayreville, N.J.) is Octyldodecyl Neopentanoate. It is the ester of octyldodecanol (q.v.) and neopentanoic acid and conforms to the formula:

##STR00001##

[0030] Butyloctyl Salicylate, commercially available as HallBrite BHB from the Hallstar Company is a synthetically produced ester of Salicylic Acid and a branched C.sub.12 alcohol, 2-butyloctanol. Butyloctyl Salycilate has an empirical formula of C.sub.19H.sub.30O.sub.3 and the following structural formula:

##STR00002##

Use of Butyloctyl Salicylate in sunscreen products is described in the following U.S. Pat. Nos. 5,783,173; 5,788,954; 5,849,273; and 6,350,894.

[0031] Cetyl Dimethicone is a dimethyl siloxane polymer that conforms to the formula:

##STR00003##

[0032] It is commercially available from a number of specialty chemical companies, including under the tradename ABIL Wax 9801 is commercially available from Evonik Goldschmidt GmbH (Essen, Germany).

[0033] Compositions of the present invention may, and preferably do, include additional emollients, including, but not limited to Dimethicone and Caprylic/Capric Triglyceride.

[0034] Dimethicone is a mixture of fully methylated linear siloxane polymers end blocked with trimethylsiloxy units, that conforms to the formula:

##STR00004##

[0035] Caprylic/Capric Triglyceride is the mixed triester of glycerin and caprylic and capric acids.

Photodamage Reducing Ingredients (Ultraviolet and Infrared Radiation)

[0036] Photodamage can result from unprotected skin exposure to ultraviolet radiation (UVR) and infrared radiation (IR). Compositions of the present invention include (i) at least one particle (also referred to below as a powder) that increases protection of the skin from UVR-induced photodamage (a UVR-Protective Powder) and (ii) at least one particle that blocks, and therefore, provides protection from IR-induced photodamage (an IR-Protective Powder). In one aspect of the present invention, by the phrase increases protection of the skin from UVR-induced photodamage means increases SPF.

[0037] In paint embodiments of the present invention, one preferred UVR-Protective Powder is Styrene/Acrylates Copolymer, sold under the tradename Sunspheres from Dow. This polymer of styrene and a monomer consisting of acrylic acid, methacrylic acid or one of their simple esters is manufactured via emulsion polymerization creating what technical literature from Dow describes as hollow spheres . . . that raise the UV protection over the whole UVA/UVB spectrum and work equally well with organic and inorganic sunscreen actives . . . and is also compatible with a broad range of cosmetic ingredients, including emollients and skin conditioners.

[0038] The technical brochure from Dow continues to state generally, The ability of SUNSPHERES to boost the efficacy of UVA/UVB filters of formulations allows the formulator to use significantly less active to deliver the same level of SPF.

[0039] Another preferred UVR-Protective Ingredient is Polyhydroxystearic Acida polymer of Hydroxystearic Acid (q.v.) that is commercially available under the tradename Dispersun DSP OL 300 from Innospec Performance Chemicals (Salisbury, N.C.).

[0040] According to technical literature from the specialty chemical company Innospec, Polyhydroxystearic Acid increases UV absorption of sunscreens containing pigments, including by allowing higher concentrations of pigment to be used. Additionally, inclusion of Polyhydroxystearic Acid is described by Innospec as improving optical transparency and reduce whitening (when finished formulation is applied to skin).

[0041] One preferred IR-Protective Particle is ARG-SPHERE NIR-1/15BA000a combination of PMMA, Cerium Oxide, and Aluminum Oxide from Argan Co.

[0042] Poly(methyl methacrylate), also known in the art as PMMA, is a spherical ultra-fine texturizing powder, available in various sizes, used in powders to increase smoothness, fluidity and lubricity. More particularly, PMMA is a polymer of methyl methacrylate, has an empirical formula C.sub.5H.sub.8O.sub.2).sub.x and conforms to the following structure:

##STR00005##

[0043] Cerium Oxide (CeO) and Aluminum Oxide (Al.sub.2O.sub.3) are inorganic oxide compounds.

Aesthetic Enhancing Powders

[0044] Compositions of the present invention preferably include one powder that enhances skin feel, more preferably more than one powder. In preferred embodiments, the powder reduces the feeling of oiliness that is commonly associated with sunscreen formulations. Ingredients that provide skin-feel improving benefits are referred to in the present application as Aesthetic Enhancing Powders.

[0045] One Aesthetic Enhancing Powder that is preferably included in compositions of the present invention is oil-absorbing, by which is meant the powder has an internal porosity sufficient to absorb oils and esters and, thereby, contribute to a non-greasy skin-feel.

[0046] In one preferred embodiment, the oil-absorbing powder has an absorption capacity of at least about 20 ml/100 g as measured by the test method in US Pre-Grant Patent Application 2011/0293543 [0036]. In another preferred embodiment, oil absorption capacity is determined by weighing approximately 2 to 2.2 g of the powder (sieved through 200 mesh screen in advance) and adding liquid paraffin until loose and dry powder disappears, and expressed according to the following formula: final volume of liquid paraffin absorbed (in cm.sup.3)/weight of sample (in grams).

[0047] One particularly preferred oil absorbing Aesthetic Enhancing Powder is silica, commercially available from a number of speciality chemical suppliers, including under the tradename Silisphere LS-8H from Argan Co.

[0048] In addition, the oil-absorbing powder contributes to homogeneity (i.e., even dispersion of pigments), and also helps to provide soft focus and skin mattifying effects.

[0049] The oil-absorbing powder also provides additional processing/manufacturing benefits, including reducing agglomeration (clumping).

[0050] In certain preferred embodiments, the compositions of the present invention include, as an Aesthetic Enhancing Powder, Nylon 12 microbeads coated with a film of PMMA and available from Argan Co. as ARG-PMMA-10NYL.

[0051] Nylon-12 is known in the art to impart elegant silky texture to finished products, enhance slip, increase blendability, and reduce the appearance of fine lines and wrinkles on the skin. More particularly, Nylon-12 is a spherical, polymeric powder used in cosmetic applications; it is a polyamide derived from 12-aminododecanoic acid and conforms generally to the formula:

##STR00006##

Emulsifier

[0052] Compositions of the present invention are water-in-oil (W/O) emulsions. By the term W/O emulsion is to be understood a two-phase mixture of immiscible liquidsan inner phase containing water-soluble (hydrophilic) ingredients dispersed in a continuous outer phase on hydrophobic ingredients (oils, esters, and silicones).

[0053] A preferred W/O emulsifier is Polyglyceryl-3 Sorbityl Linseedate is a water-in-silicone emulsifier sold by Sinerga/Argan Co. under the tradename EWOCREAM. More Polyglyceryl-3 Sorbityl Linseedate is the product obtained by the reaction of Linseed Acid (q.v.) with the sorbitol ether of Polyglycerin-3 (q.v.).

Film-Forming Polymer

[0054] Compositions of the present invention contain at least one film-forming polymer that imparts water repellency and wash-off resistance.

[0055] One preferred film-forming polymer is Acrylates/Dimethicone Copolymera copolymer of dimethicone and one or more monomers of acrylic acid, methacrylic acid or one of their simple estersavailable from numerous suppliers, including Access Ingredients (South Pasadena, Calif.) under the tradename AccessSIL FF-16.

[0056] Another polymer that provides transfer resistance (of colored pigments) as well as repellency of water and sebum, is a mixture of trimethylsiloxysilicate and isododecane, available under the tradename JEESILC TMR-40.

[0057] Trimethylsiloxysilicate is the siloxane polymer that conforms generally to the formula:

[(CH.sub.3).sub.3SiO.sub.1/2].sub.x[SiO.sub.2].sub.y

[0058] Isododecane is a branched chain aliphatic hydrocarbon with 12 carbons.

Bulking and Binding Agents

[0059] Bulking agents are chemically inert, solid ingredients employed as diluents for other solids. Bulking agents can also serve as extenders of pigments.

[0060] Binding agents are ingredients added to compounded dry powder mixtures to provide adhesive qualities during and after compression.

[0061] Compositions of the present invention include one or more bulking agents, preferably selected from the group consisting of Hectorite (and its derivatives and reaction products), Kaolin and Polyethylene.

[0062] Hectorite is one of the montmorillonite minerals that are the principal constituents of bentonite clay.

[0063] Kaolin is a native hydrated aluminum silicate having the structure Al.sub.2O.sub.3.2SiO.sub.2.2H.sub.2O.

[0064] Disteardimonium Hectorite is the reaction product Hectorite and Distearyldimonium Chloride, a quaternary ammonium salt that conforms generally to the formula:

##STR00007##

[0065] Disteardimonium Hectorite is commercially available from Elementis Specialities, Inc. (Hightstown, N.J.) under the tradename Bentone 38V. A technical data sheet from Elementis describes Bentone 38 as a rheological additive for low to intermediate polarity organic systems, that increases viscosity, provides thixotropy while preventing synerisis, and prevents pigment settling during storage.

[0066] Polyethylene is a polymer of ethylene monomers conforming to the formula:

CH.sub.2CH.sub.2.sub.x

and is available in a number of forms/grades from a variety of suppliers to the personal care industry, including JEEN International under the tradenames JEENATE 3H and 5H.

[0067] One preferred binding agent is Ozokerite, a hydrocarbon wax derived from mineral or petroleum sources, and available from a number of suppliers of chemical raw materials to the personal care industry. A particularly preferred Ozokerite is sold by Koster Keunen under the tradename Ozokerite 2095, a high melt point wax blend consisting of branched and linear hydrocarbonsnamely, Microcrystalline Wax and Paraffin.

[0068] Another preferred binding agent is Polybutene, formed by the polymerization of a mixture of iso- and normal butenes.

Skin Conditioning Agents

[0069] Compositions of the present invention include at least one, preferably a plurality of skin conditioning agentsingredients that enhance the appearance of dry or damaged skin. Without wishing to be bound by a specific mechanism of action, conditioning agents adhere to the skin to reduce flaking and restore suppleness.

[0070] One non-limiting example of a skin conditioning agent that may be, and preferably is, included in compositions of the present invention is Helianthus Annus (Sunflower) Seed Wax, an article of commerce available from numerous chemical raw materials suppliers including JEEN International under the tradename JeeWax Sun.

[0071] Preferably at least one of the skin conditioning agents is occlusive, by which is meant the ingredient retards evaporation of water from the skin surface (i.e., transepidermal water loss); by blocking the evaporative loss of water, occlusive skin conditioning agents increase the water content of skin.

[0072] One preferred occlusive skin conditioning agent is Tribehenin (C.sub.69H.sub.134O.sub.6), the triester of glycerin and behenic acid, conforms to the formula:

##STR00008##

and is commercially available under the tradename Syncrowax HR-C from Croda Inc.

[0073] Another preferred occlusive skin conditioning agent is a mixture of Hydrogenated Olive Oil and Hydrogenated Olive Oil Unsaponifiables, that is commercially available from Sinerga/Argan Co. under the tradename Wax OLEA.

Aesthetics Modifier

[0074] As Aesthetics Modifiers, compositions of the present invention can, and preferably do contain, Nonaqueous Viscosity Increasing Agentsnamely, ingredient used to thicken or gel the water-insoluble portions of cosmetic products.

[0075] One preferred Aesthetics Modifier is Dimethicone/Vinyl Dimethicone Crosspolymer, a crosslinked dimethyl siloxane polymer (silicone elastomer) that is formed by the reaction between Hydrogen Dimethicone (q.v.) or Bis-Hydrogen Dimethicone (q.v.), and Vinyl Dimethicone (q.v.) or Bis-Vinyldimethicone (q.v.).

[0076] Hydrogen Dimethicone is a derivative of Dimethicone (q.v.) where some of the methyl groups have been replaced with a hydrogen atom. It conforms generally to the formula:

##STR00009##

where R can be either hydrogen or a methyl group.

[0077] Bis-Hydrogen Dimethicone is the siloxane compound that conforms to the formula:

##STR00010##

[0078] Vinyl Dimethicone is a derivative of Dimethicone (q.v.) where some of the methyl groups have been replaced with vinyl groups. The vinyl groups can occur at the ends of the siloxane chain or pendant to the siloxane chain. It conforms generally to the formula:

##STR00011##

where R is a methyl or vinyl group, and at least one vinyl group is present.

[0079] Bis-Vinyldimethicone is a derivative of Dimethicone (q.v.) where one methyl group at each end of the siloxane chain has been replaced with a vinyl group. It conforms generally to the formula:

##STR00012##

[0080] Emul-6081 from Access Ingredients is a mixture of Dimethicone/Vinyldimethicone Crosspolymer (and) Laureth-3 (and) Laureth-25.

Environmental Protectants

[0081] Compositions of the present invention include one or more Environmental Protectants selected from antioxidants/free-radical quenchers and anti-irritants/anti-inflammatory agents. Three particularly preferred Environmental Protectants are

[0082] Benzylidene Dimethoxydimethylindanone (C.sub.20H.sub.20O.sub.3) is an organic compound that conforms to the formula:

##STR00013##

and is commercially available under the tradename SymUrban from Symrise. SymUrban is marketed as an anti-pollution agent that reduces environmental damagenamely, collagen degradation, overproduction of melanin and inflammation resulting from exposure to airborne particulate matter found in vehicle exhaust and industrial emissions.

[0083] Tocopheryl Acetate is the ester of Tocopherol (q.v.) and acetic acid, and is an article of commerce supplied to the personal care industry by a several companies.

[0084] A mixture of Bisabolol and Zingiber Officinale (Ginger) Root Extract is commercially available under the tradename SymRelief 100 from Symrise.

[0085] Bisabolol is a terpene that conforms to the formula:

##STR00014##

Preservative System

[0086] Compositions of the present invention do not use parabens or formaldehyde-releasing ingredients.

[0087] In preferred embodiments, compositions of the present invention include Hydroxyacetophenone, 1,2 Hexanediol and Caprylyl Glycol.

[0088] Hydroxyacetophenone (C.sub.8H.sub.8O.sub.2) available under the tradename Symsave H from Symrise is the organic compound that conforms to the formula:

##STR00015##

[0089] A mixture of 1,2 Hexanediol and Caprylyl Glycol is commercially available under the tradename SymDiol 68 from Symrise.

Skin Coloring Agents

[0090] Compositions of the present invention may, and preferably do contain, as a skin protecting agent, one or more Iron Oxide pigment(s) and/or other natural colorants (e.g., Caramel).

[0091] When present, Iron Oxide pigments may be, and preferably are, coated.

[0092] One preferred coating is Hydrogenated Lecithin, the end-product of the controlled hydrogenation of Lecithin (q.v.).

Formulation Example 1Untinted Stick (SPF 50+)

[0093]

TABLE-US-00001 INCI Name Range % Octyldodecyl Neopentanoate 10.00-20.00 Caprylic/Capric Triglyceride 5.00-15.00 Butyl Octyl Salycilate 15.00-25.00 Polyhydroxystearic Acid 0.10-2.00 Dimethicone 50 cst 1.00-5.00 Disteardimonium Hectorite 0.10-2.00 Helianthus Annus Seed Wax 0.10-1.00 Ozokerite 3.00-7.00 Polyethylene 1.00-5.00 Tribehenin 0.10-1.00 Hydrogenated Olive Oil (and) Hydrogenated Olive Oil 3.00-7.00 Unsaponifiables Bisabolol and Zingiber Officinale (Ginger) Root Extract 0.10-1.00 Dimethicone (and) Acrylates/Dimethicone Copolymer 0.10-3.00 Dimethicone/Vinyldimethicone Crosspolymer (and) 0.10-3.00 Laureth-3 (and) Laureth-25 Tocopheryl Acetate 0.10-1.00 1,2 Hexanediol and Caprylyl Glycol 0.10-1.00 Benzylidene Dimethoxydimethylindanone 0.01-0.50 Zinc Oxide (non-nano) 20.00-25.00 Phenethyl Alcohol and Caprylyl Glycol 0.10-1.00 Silica 3.00-7.00 PMMA and Nylon 12 2.00-5.00 PMMA, Cerium Oxide, Aluminum Oxide 0.10-2.00

Formulation Example 2Untinted Compact/Pressed Powder (SPF 50+)

[0094]

TABLE-US-00002 INCI Name Range % Octyldodecyl Neopentanoate 10.00-20.00 Caprylic/Capric Triglyceride 3.00-7.00 Butyl Octyl Salycilate 15.00-25.00 Polyhydroxystearic Acid 0.10-2.00 Dimethicone 50 cst 1.00-5.00 Disteardimonium Hectorite 0.10-2.00 Helianthus Annus Seed Wax 0.10-1.00 Ozokerite 3.00-7.00 Polyethylene 0.10-3.00 Tribehenin 0.10-3.00 Hydrogenated Olive Oil (and) Hydrogenated Olive Oil 3.00-7.00 Unsaponifiables Bisabolol and Zingiber Officinale (Ginger) Root Extract 0.10-1.00 Dimethicone (and) Acrylates/Dimethicone Copolymer 0.10-3.00 Dimethicone/Vinyldimethicone Crosspolymer (and) 0.10-3.00 Laureth-3 (and) Laureth-25 Tocopheryl Acetate 0.10-1.00 1,2 Hexanediol and Caprylyl Glycol 0.10-1.00 Benzylidene Dimethoxydimethylindanone 0.01-0.50 Zinc Oxide (non-nano) 20.00-25.00 Phenethyl Alcohol and Caprylyl Glycol 0.10-1.00 Silica 3.00-7.00 PMMA and Nylon 12 3.00-7.00 PMMA, Cerium Oxide, Aluminum Oxide 0.10-2.00

Formulation Example 3Face/Body Paint

[0095]

TABLE-US-00003 INCI Name Range % Butyl Octyl Salycilate 15.00-25.00 Caprylic/Capric Triglyceride 4.00-8.00 Polyhydroxystearic Acid 0.10-2.00 Styrene/Acrylates Copolymer 1.00-5.00 Benzylidene Dimethoxydimethylindanone 0.01-0.50 Tocopheryl Acetate 0.10-1.00 1,2 Hexanediol and Caprylyl Glycol 0.10-1.00 Zinc Oxide (non-nano) 20.00-25.00 Kaolin 12.00-20.00 Polyglyceryl-3 Sorbityl Linseedate 0.10-1.00 Iron Oxides and Hydrogenated Lecithin 1.00-5.00 Titanium Dioxides and Hydrogenated Lecithin 2.00-6.00 Iron Oxides and Hydrogenated Lecithin 0.01-1.00 Iron Oxides and Hydrogenated Lecithin 0.01-1.00 Helianthus Annus (Sunflower) Seed Wax 0.10-1.00 Ozokerite 1.00-5.00 Polyethylene 1.00-5.00 Hydrogenated Olive Oil and Hydrogenated Olive Oil 0.10-1.00 Unsaponifiables Disteardimonium Hectorite 0.01-1.00 Polybutene 1.00-5.00 Isododecane and Trimethylsiloxysilicate 4.00-8.00 Bisabolol and Zingiber Officinale Root Extract 0.10-1.00 PMMA, Cerium Oxide, Aluminum Oxide 0.10-2.00 Polymethylsilsesesquioxane and Titanium Dioxide 0.10-5.00