FLUIDIZED BED REGENERATOR, DEVICE FOR PREPARING LOW-CARBON OLEFINS, AND USE THEREOF

Abstract

A fluidized bed regenerator, a device for preparing low-carbon olefins, and a use thereof are provided. The fluidized bed regenerator includes a second activation zone, a first activation zone, and a gas-solid separation zone from bottom to top; the second activation zone axially communicates with the gas-solid separation zone; the first activation zone is arranged on a periphery of a junction between the second activation zone and the gas-solid separation zone; the first activation zone is an annular cavity; n baffles are radially arranged in the first activation zone, and the n baffles divide the first activation zone into n first activation zone subzones; and a catalyst circulation hole is formed in each of n−1 of the baffles such that a catalyst entering the first activation zone flows in an annular direction.

Claims

1. A fluidized bed regenerator for activating a catalyst to prepare low-carbon olefins from an oxygen-containing compound, wherein the fluidized bed regenerator comprises a second activation zone, a first activation zone, and a gas-solid separation zone from bottom to top; the second activation zone axially communicates with the gas-solid separation zone; the first activation zone is arranged on a periphery of a junction between the second activation zone and the gas-solid separation zone; the first activation zone is an annular cavity; n baffles are radially arranged in the first activation zone, and the n baffles divide the first activation zone into n first activation zone subzones; and a catalyst circulation hole is formed in each of n−1 of the baffles, and a catalyst entering the first activation zone flows in an annular direction.

2. The fluidized bed regenerator according to claim 1, wherein in the first activation zone, the n baffles comprise a 1.sup.st baffle, and a 2.sup.nd baffle to an n.sup.th baffle; no catalyst circulation hole is formed in the 1st baffle; a catalyst circulation hole is formed in each of the 2.sup.nd baffle to the n.sup.th baffle; a spent catalyst inlet is formed in a 1.sup.st first activation zone subzone formed through division by the 1.sup.st baffle and the 2.sup.nd baffle; a first activation zone catalyst delivery pipe is arranged in an n.sup.th first activation zone subzone formed through division by the 1.sup.st baffle and the n.sup.th baffle; a first activation zone distributor is arranged beneath the first activation zone subzones; a first activation zone gas delivery pipe is arranged at tops of the first activation zone subzones; n has a value range of 2≤n≤10; and a cross section of each of the first activation zone subzones is sector-annular.

3. The fluidized bed regenerator according to claim 2, wherein a first gas-solid separation unit of the regenerator is arranged in an upper part of the first activation zone; and the first gas-solid separation unit of the regenerator communicates with the first activation zone through the spent catalyst inlet.

4. (canceled)

5. (canceled)

6. The fluidized bed regenerator according to claim 1, wherein m perforated plates are horizontally arranged in the second activation zone, wherein 1≤m≤10; the perforated plates have a porosity of 5% to 50%; and second activation zone distributor is arranged at a bottom of the second activation zone.

7. (canceled)

8. (canceled)

9. The fluidized bed regenerator according to claim 1, wherein the fluidized bed regenerator comprises a regenerator gas collection chamber and a fluidized bed regenerator cooler; the regenerator gas collection chamber is located at a top of the fluidized bed regenerator; a top of the regenerator gas collection chamber is provided with a regenerator product gas delivery pipe; the gas-solid separation zone is provided with a second gas-solid separation unit; the regenerator gas collection chamber is connected to an outlet of the second gas-solid separation unit; and the fluidized bed regenerator cooler is located in a lower part of the second activation zone.

10. A device for preparing low-carbon olefins from an oxygen-containing compound, comprising a fluidized bed reactor and the fluidized bed regenerator of claim 1.

11. The device according to claim 10, wherein the device comprises a spent catalyst inclined pipe, a fluidized bed reactor stripper, a spent catalyst delivery pipe, a regenerated catalyst inclined pipe, and a regenerated catalyst delivery pipe; a spent catalyst zone, the spent catalyst inclined pipe, the fluidized bed reactor stripper, the spent catalyst delivery pipe, and the first gas-solid separation unit of the regenerator communicate with each other in sequence; and the second activation zone, the regenerated catalyst inclined pipe, the regenerated catalyst delivery pipe, and a reaction zone of the fluidized bed reactor communicate with each other in sequence.

12. The device according to claim 11, wherein the fluidized bed reactor comprises a lower shell, a delivery pipe, and an upper shell; the lower shell encloses the reaction zone; the delivery pipe is located above the reaction zone and communicates with the reaction zone; the upper shell is arranged on a periphery of the delivery pipe; the upper shell and the delivery pipe enclose a cavity; the cavity is divided into a spent catalyst zone and a gas-solid separation zone from bottom to top; the reaction zone is a fast fluidized zone; the spent catalyst zone is a bubbling fluidized zone; the gas-solid separation zone is provided with a first gas-solid separation unit of the fluidized bed reactor; an upper part of the delivery pipe is connected to an inlet of the first gas-solid separation unit of the fluidized bed reactor; the fluidized bed reactor comprises a fluidized bed reactor distributor, a fluidized bed reactor cooler, a spent catalyst zone gas distributor, a fluidized bed reactor gas collection chamber, and a second gas-solid separation unit of the fluidized bed reactor; the fluidized bed reactor distributor is located at a bottom of the reaction zone; the fluidized bed reactor cooler is located in a lower part of the spent catalyst zone; the spent catalyst zone gas distributor is located in the lower part of the spent catalyst zone; gas outlets of the second gas-solid separation unit of the fluidized bed reactor and the first gas-solid separation unit of the fluidized bed reactor are connected to the fluidized bed reactor gas collection chamber; the fluidized bed reactor gas collection chamber is provided with a product gas delivery pipe; catalyst outlets of the first gas-solid separation unit of the fluidized bed reactor and the second gas-solid separation unit of the fluidized bed reactor are connected to the spent catalyst zone; and the reaction zone and the spent catalyst zone communicate with each other through a spent catalyst circulation pipe.

13-28. (canceled)

29. A method for preparing low-carbon olefins from an oxygen-containing compound using the device according to claim 10, comprising: activating a catalyst to prepare the low-carbon olefins from the oxygen-containing compound using the fluidized bed regenerator; wherein a method activating the catalyst to prepare the low-carbon olefins from the oxygen-containing compound comprises: feeding a first activation zone raw material and a spent catalyst into the first activation zone, wherein the spent catalyst chemically reacts with the first activation zone raw material while flowing in an annular direction along the first activation zone subzones to generate a partially-activated catalyst; and feeding the partially-activated catalyst and a second activation zone raw material into the second activation zone, and allowing a chemical reaction to generate a regenerated catalyst; wherein a coke composition in the partially-activated catalyst comprises oxygen-containing hydrocarbon species and oxygen-free hydrocarbon species; the method for preparing the low-carbon olefins from the oxygen-containing compound further comprises: feeding a raw material with the oxygen-containing compound and the regenerated catalyst into the reaction zone, and allowing a reaction to obtain a first stream with the low-carbon olefins and the spent catalyst; subjecting the first stream to gas-solid separation, and conveying the spent catalyst to the spent catalyst zone; and returning a part of the spent catalyst in the spent catalyst zone to a fluidized bed reaction zone, and allowing the remaining part of the spent catalyst to enter the fluidized bed regenerator.

30. (canceled)

31. The method according to claim 29, a fluidizing gas of the spent catalyst zone is at least one from the group consisting of nitrogen and water vapor.

32. The method according to claim 29, wherein the raw material with the oxygen-containing compound is at least one from the group consisting of methanol and dimethyl ether (DME).

33. The method according to claim 29, wherein a ratio of a mass flow rate of the regenerated catalyst to a feed amount of the oxygen-containing compound is 0.3 to 1.0 ton of catalyst/ton of methanol.

34. (canceled)

35. The method according to claim 29, wherein process operating conditions of the reaction zone of the fluidized bed reactor are as follows: apparent gas linear velocity: 0.5 m/s to 7.0 m/s; reaction temperature: 350° C. to 550° C.; reaction pressure: 100 kPa to 500 kPa; and bed density: 100 kg/m.sup.3 to 500 kg/m.sup.3.

36. The method according to claim 29, wherein process operating conditions of the spent catalyst zone of the fluidized bed reactor are as follows: apparent gas linear velocity: 0.1 m/s to 1.0 m/s; reaction temperature: 350° C. to 550° C.; reaction pressure: 100 kPa to 500 kPa; and bed density: 200 kg/m.sup.3 to 800 kg/m.sup.3.

37. The method according to claim 29, wherein the first activation zone raw material comprises oxygen, air, and water vapor; a mass fraction of the oxygen is 0 wt % to 10 wt %; a mass fraction of the air is 0 wt % to 20 wt %; and a mass fraction of the water vapor is 80 wt % to 100 wt %.

38. The method according to claim 29, wherein the second activation zone raw material is water vapor;

39. The method according to claim 29, wherein a coke content in the spent catalyst is 9 wt % to 13 wt %; the spent catalyst comprises an SAPO-34 molecular sieve.

40. The method according to claim 29, wherein a coke content in the regenerated catalyst is 5 wt % to 11 wt; a quartile deviation of a coke content distribution in the regenerated catalyst is less than 1.0 wt %; in the regenerated catalyst, coke species comprise polymethylbenzene and polymethylnaphthalene; a total mass of the polymethylbenzene and the polymethylnaphthalene accounts for greater than or equal to 60 wt % of a total mass of coke; a mass of coke species with a molecular weight greater than 184 accounts for less than or equal to 30 wt % of the total mass of coke; and the total mass of coke refers to a total mass of coke species.

41. The method according to claim 29, wherein process operating conditions of the first activation zone of the fluidized bed regenerator are as follows: apparent gas linear velocity: 0.1 m/s to 0.5 m/s; temperature: 650° C. to 750° C.; pressure: 100 kPa to 500 kPa; and bed density: 400 kg/m.sup.3 to 700 kg/m.sup.3.

42. The method according to claim 29, wherein process operating conditions of the second activation zone of the fluidized bed regenerator are as follows: apparent gas linear velocity: 0.1 m/s to 0.5 m/s; temperature: 550° C. to 700° C.; pressure: 100 kPa to 500 kPa; and bed density: 400 kg/m.sup.3 to 700 kg/m.sup.3.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0180] FIG. 1 is a schematic diagram of a DMTO device for preparing low-carbon olefins from an oxygen-containing compound according to an embodiment of the present application.

[0181] FIG. 2 is a schematic diagram of a cross section of the first activation zone in FIG. 1.

[0182] Reference Numerals in FIG. 1 and FIG. 2:

[0183] 1 represents a fluidized bed reactor; 1-1 represents a fluidized bed reactor shell; 1-2 represents a fluidized bed reactor distributor; 1-3 represents a delivery pipe; 1-4 represents a first gas-solid separation unit of the fluidized bed reactor; 1-5 represents a fluidized bed reactor gas collection chamber; 1-6 represents a spent catalyst zone gas distributor; 1-7 represents a fluidized bed reactor cooler; 1-8 represents a second gas-solid separation unit of the fluidized bed reactor; 1-9 represents a product gas delivery pipe; 1-10 represents a spent catalyst circulation pipe; 1-11 represents a spent catalyst circulation slide valve; 1-12 represents a spent catalyst inclined pipe; 1-13 represents a fluidized bed reactor stripper; 1-14 represents a spent catalyst slide valve; 1-15 represents a spent catalyst delivery pipe;

[0184] 2 represents a fluidized bed regenerator; 2-1 represents a regenerator shell; 2-2 represents a first gas-solid separation unit of the regenerator; 2-3 represents a first activation zone distributor; 2-4 represents a baffle; 2-5 represents a first activation zone catalyst delivery pipe; 2-6 represents a first activation zone gas delivery pipe; 2-7 represents a second activation zone distributor; 2-8 represents a perforated plate; 2-9 represents a fluidized bed regenerator cooler; 2-10 represents a second gas-solid separation unit of the regenerator; 2-11 represents a regenerator gas collection chamber; 2-12 represents a regenerator product gas delivery pipe; 2-13 represents a regenerated catalyst inclined pipe; 2-14 represents a regenerated catalyst slide valve; and 2-15 represents a regenerated catalyst delivery pipe.

DETAILED DESCRIPTION OF THE EMBODIMENTS

[0185] The present application will be described in detail below with reference to examples, but the present application is not limited to these examples.

[0186] Unless otherwise specified, the raw materials and catalysts in the examples of the present application are all purchased from commercial sources.

[0187] As an embodiment of the present application, a schematic diagram of a DMTO device is shown in FIG. 1 and FIG. 2, and the device includes a fluidized bed reactor (1) and a fluidized bed regenerator (2). Specifically:

[0188] As shown in FIG. 1, the fluidized bed reactor (1) includes a fluidized bed reactor shell (1-1), a fluidized bed reactor distributor (1-2), a delivery pipe (1-3), a first gas-solid separation unit (1-4) of the fluidized bed reactor, a fluidized bed reactor gas collection chamber (1-5), a spent catalyst zone gas distributor (1-6), a fluidized bed reactor cooler (1-7), a second gas-solid separation unit (1-8) of the fluidized bed reactor, a product gas delivery pipe (1-9), a spent catalyst circulation pipe (1-10), a spent catalyst circulation slide valve (1-11), a spent catalyst inclined pipe (1-12), a fluidized bed reactor stripper (1-13), a spent catalyst slide valve (1-14), and a spent catalyst delivery pipe (1-15); a lower part of the fluidized bed reactor (1) is a reaction zone, a middle part thereof is a spent catalyst zone, and an upper part thereof is a gas-solid separation zone; the fluidized bed reactor distributor (1-2) is located at a bottom of the reaction zone of the fluidized bed reactor (1), the delivery pipe (1-3) is located in central zones of the middle and upper parts of the fluidized bed reactor (1), and a bottom end of the delivery pipe (1-3) is connected to a top end of the reaction zone; an upper part of the delivery pipe (1-3) is connected to an inlet of the first gas-solid separation unit (1-4) of the fluidized bed reactor, and the first gas-solid separation unit (1-4) of the fluidized bed reactor is located in the gas-solid separation zone of the fluidized bed reactor (1); a gas outlet of the first gas-solid separation unit (1-4) of the fluidized bed reactor is connected to the fluidized bed reactor gas collection chamber (1-5), and a catalyst outlet of the first gas-solid separation unit (1-4) of the fluidized bed reactor is formed in the spent catalyst zone; a spent catalyst zone gas distributor (1-6) is located at a bottom of the spent catalyst zone, and the fluidized bed reactor cooler (1-7) is located in the spent catalyst zone; the second gas-solid separation unit (1-8) of the fluidized bed reactor is located in the gas-solid separation zone of the fluidized bed reactor (1), an inlet of the second gas-solid separation unit (1-8) of the fluidized bed reactor is formed in the gas-solid separation zone of the fluidized bed reactor (1), a gas outlet of the second gas-solid separation unit (1-8) of the fluidized bed reactor is connected to the fluidized bed reactor gas collection chamber (1-5), and a catalyst outlet of the second gas-solid separation unit (1-8) of the fluidized bed reactor is formed in the spent catalyst zone; the fluidized bed reactor gas collection chamber (1-5) is located at a top of the fluidized bed reactor (1), and the product gas delivery pipe (1-9) is connected to a top of the fluidized bed reactor gas collection chamber (1-5); an inlet of the spent catalyst circulation pipe (1-10) is connected to the spent catalyst zone, and an outlet of the spent catalyst circulation pipe (1-10) is connected to a bottom of the reaction zone of the fluidized bed reactor (1); a spent catalyst circulation slide valve (1-11) is arranged in the spent catalyst circulation pipe (1-10), an inlet of the spent catalyst inclined pipe (1-12) is connected to the spent catalyst zone, and an outlet of the spent catalyst inclined pipe (1-12) is connected to an upper part of the fluidized bed reactor stripper (1-13); the fluidized bed reactor stripper (1-13) is arranged outside the fluidized bed reactor shell (1-1); an inlet of the spent catalyst slide valve (1-14) is connected to a bottom of the fluidized bed reactor stripper (1-13) through a pipeline, and an outlet of the spent catalyst slide valve (1-14) is connected to an inlet of the spent catalyst delivery pipe (1-15) through a pipeline; and an outlet of the spent catalyst delivery pipe (1-15) is connected to the fluidized bed regenerator (2). The first gas-solid separation unit (1-4) of the fluidized bed reactor may adopt multiple sets of gas-solid cyclone separators, and each of the multiple sets of gas-solid cyclone separators may include a first-stage gas-solid cyclone separator and a second-stage gas-solid cyclone separator; and the second gas-solid separation unit (1-8) of the fluidized bed reactor may adopt multiple sets of gas-solid cyclone separators, and each of the multiple sets of gas-solid cyclone separators may include a first-stage gas-solid cyclone separator and a second-stage gas-solid cyclone separator.

[0189] As shown in FIG. 1, the fluidized bed regenerator (2) includes a regenerator shell (2-1), a first gas-solid separation unit (2-2) of the regenerator, a first activation zone distributor (2-3), a baffle (2-4), a first activation zone catalyst delivery pipe (2-5), a first activation zone gas delivery pipe (2-6), a second activation zone distributor (2-7), a perforated plate (2-8), a fluidized bed regenerator cooler (2-9), a second gas-solid separation unit (2-10) of the regenerator, a regenerator gas collection chamber (2-11), a regenerator product gas delivery pipe (2-12), a regenerated catalyst inclined pipe (2-13), a regenerated catalyst slide valve (2-14), and a regenerated catalyst delivery pipe (2-15); the fluidized bed regenerator (2) is divided into a second activation zone, a first activation zone, and a gas-solid separation zone from bottom to top; the first activation zone is located in an annular zone above the second activation zone, n baffles (2-4) are arranged in the first activation zone, and the baffles (2-4) divide the first activation zone into n first activation zone subzones; a bottom of each of the first activation zone subzones is independently provided with a first activation zone distributor (2-3); a cross section of the first activation zone is annular, and a cross section of each of the first activation zone subzones is sector-annular; the 1.sup.st to n.sup.th first activation zone subzones are concentrically arranged in sequence; a catalyst circulation hole is formed in the baffles (2-4), and no catalyst circulation hole is formed in a baffle between the 1.sup.st first activation zone subzone and the n.sup.th first activation zone subzone; the first gas-solid separation unit (2-2) of the regenerator is located in the gas-solid separation zone of the fluidized bed regenerator (2); an inlet of the first gas-solid separation unit (2-2) of the regenerator is connected to an outlet of the spent catalyst delivery pipe (1-15), a gas outlet of the first gas-solid separation unit (2-2) of the regenerator is formed in the gas-solid separation zone, and a catalyst outlet of the first gas-solid separation unit (2-2) of the regenerator is formed in the 1.sup.st first activation zone subzone; an inlet of the first activation zone catalyst delivery pipe (2-5) is connected to the n.sup.th first activation zone subzone, and an outlet of the first activation zone catalyst delivery pipe (2-5) is formed in the second activation zone; a top of each of the first activation zone subzones is independently provided with a first activation zone gas delivery pipe (2-6), and an outlet of the first activation zone gas delivery pipe (2-6) is formed in the gas-solid separation zone; a second activation zone distributor (2-7) is located at a bottom of the second activation zone of the fluidized bed regenerator (2), m perforated plates (2-8) are arranged in the second activation zone, and a fluidized bed regenerator cooler (2-9) is located in the second activation zone; the second gas-solid separation unit (2-10) of the regenerator and the regenerator gas collection chamber (2-11) are located in the gas-solid separation zone of the fluidized bed regenerator (2); an inlet of the second gas-solid separation unit (2-10) of the regenerator is formed in the gas-solid separation zone of the fluidized bed regenerator (2), a gas outlet of the second gas-solid separation unit (2-10) of the regenerator is connected to the regenerator gas collection chamber (2-11), and a catalyst outlet of the second gas-solid separation unit (2-10) of the regenerator is formed in the second activation zone; the regenerator product gas delivery pipe (2-12) is connected to a top of the regenerator gas collection chamber (2-11); an inlet of the regenerated catalyst inclined pipe (2-13) is connected to a lower part of the second activation zone, an inlet of the regenerated catalyst slide valve (2-14) is connected to an outlet of the regenerated catalyst inclined pipe (2-13), and an outlet of the regenerated catalyst slide valve (2-14) is connected to an inlet of the regenerated catalyst delivery pipe (2-15) through a pipeline; an outlet of the regenerated catalyst delivery pipe (2-15) is connected to the reaction zone of the fluidized bed reactor (1); the second gas-solid separation unit (2-10) of the regenerator adopts multiple sets of gas-solid cyclone separators; and each of the multiple sets of gas-solid cyclone separators includes a first-stage gas-solid cyclone separator and a second-stage gas-solid cyclone separator.

[0190] As a specific embodiment of the present application, the method for preparing low-carbon olefins from an oxygen-containing compound in the present application includes:

[0191] a raw material with an oxygen-containing compound is fed into the reaction zone of the fluidized bed reactor (1) from the fluidized bed reactor distributor (1-2) and contacts a regenerated catalyst from the regenerated catalyst delivery pipe (2-15) to generate a stream A with low-carbon olefins and a spent catalyst; the stream A enters the first gas-solid separation unit (1-4) of the fluidized bed reactor through the delivery pipe (1-3) to undergo gas-solid separation to obtain a gas-phase stream B and a solid-phase stream C, where the gas-phase stream B is a gas with low-carbon olefins and the solid-phase stream C is a spent catalyst; the gas-phase stream B enters the fluidized bed reactor gas collection chamber (1-5), and the solid-phase stream C enters the spent catalyst zone; a spent catalyst zone fluidizing gas is fed into the spent catalyst zone from the spent catalyst zone gas distributor (1-6) and contacts the spent catalyst, and the spent catalyst zone fluidizing gas and a spent catalyst carried thereby form a stream D; the stream D enters the second gas-solid separation unit (1-8) of the fluidized bed reactor to undergo gas-solid separation to obtain a gas-phase stream E and a solid-phase stream F, where the gas-phase stream E is the spent catalyst zone fluidizing gas and the solid-phase stream F is the spent catalyst; the gas-phase stream E enters the fluidized bed reactor gas collection chamber (1-5), and the solid-phase stream F is returned to the spent catalyst zone; the gas-phase stream B and the gas-phase stream E are mixed in the fluidized bed reactor gas collection chamber (1-5) to produce a product gas, and the product gas enters a downstream working section through the product gas delivery pipe (1-9); a part of the spent catalyst in the spent catalyst zone is returned to a bottom of the reaction zone of the fluidized bed reactor (1) through the spent catalyst circulation pipe (1-10) and the spent catalyst circulation slide valve (1-11), and the remaining part of the spent catalyst enters the fluidized bed reactor stripper (1-13) through the spent catalyst inclined pipe (1-12) to undergo stripping, and then enters the fluidized bed regenerator (2) through the spent catalyst slide valve (1-14) and the spent catalyst delivery pipe (1-15);

[0192] a first activation zone raw material is fed into the first activation zone of the fluidized bed regenerator (2) from the first activation zone distributor (2-3); a spent catalyst is fed into the first gas-solid separation unit (2-2) of the regenerator from the spent catalyst delivery pipe (1-15) to undergo gas-solid separation, a resulting gas is discharged into the gas-solid separation zone of the fluidized bed regenerator (2) through the gas outlet of the first gas-solid separation unit (2-2) of the regenerator, and a resulting spent catalyst is discharged into the first activation zone of the fluidized bed regenerator (2) through the catalyst outlet of the first gas-solid separation unit (2-2) of the regenerator; the first activation zone raw material contacts and chemically reacts with the spent catalyst in the first activation zone, such that the inactive coke and active coke in the spent catalyst are converted into oxygen-containing hydrocarbon species and oxygen-free hydrocarbon species with a small molecular weight and a first activation zone product gas is generated; a catalyst in the first activation zone passes through the 1.sup.st to n.sup.th first activation zone subzones in sequence through catalyst circulation holes on the baffles (2-4) and then enters the second activation zone of the fluidized bed regenerator (2) through the first activation zone catalyst delivery pipe (2-5); the first activation zone product gas enters the gas-solid separation zone of the fluidized bed regenerator (2) through the first activation zone gas delivery pipe (2-6); a second activation zone raw material is fed into the second activation zone of the fluidized bed regenerator (2) from the second activation zone distributor (2-7) to contact and chemically react with a catalyst from the first activation zone, such that catalytically-inactive oxygen-containing hydrocarbon species in the coke are converted into catalytically-active oxygen-free hydrocarbon species, a molecular weight of the coke is further reduced (that is, the coke in the catalyst is converted into species mainly composed of polymethylbenzene and polymethylnaphthalene; and a catalyst discharged from the second activation zone is called a regenerated catalyst), and the second activation zone raw material is converted into a second activation zone product gas in the second activation zone and then enters the gas-solid separation zone of the fluidized bed regenerator (2); the first activation zone product gas and the second activation zone product gas are mixed in the gas-solid separation zone to produce a regenerator product gas, and the regenerator product gas carries a catalyst and enters the second gas-solid separation unit (2-10) of the regenerator to undergo gas-solid separation to obtain a regenerator product gas and a catalyst; the regenerator product gas enters the regenerator gas collection chamber (2-11) and then enters a downstream regenerator product gas recycling system through the regenerator product gas delivery pipe (2-12), and the catalyst is returned to the second activation zone of the fluidized bed regenerator (2); the regenerated catalyst in the second activation zone is cooled, and then enters the fluidized bed reactor (1) through the regenerated catalyst inclined pipe (2-13), the regenerated catalyst slide valve (2-14), and the regenerated catalyst delivery pipe (2-15).

[0193] In order to well illustrate the present application and facilitate the understanding of the technical solutions of the present application, typical but non-limiting examples of the present application are as follows:

Example 1

[0194] The device shown in FIG. 1 and FIG. 2 is adopted in this example, where the first gas-solid separation unit (2-2) of the regenerator is a gas-solid cyclone separator; 2 baffles (2-4) are arranged in the first activation zone of the fluidized bed regenerator (2), that is, n=2; the baffles (2-4) divide the first activation zone into 2 first activation zone subzones; and 10 perforated plates (2-8) are arranged in the second activation zone of the fluidized bed regenerator (2), that is, m=10; and the perforated plates (2-8) have a porosity of 50%.

[0195] In this example, the oxygen-containing compound is methanol; the spent catalyst zone fluidizing gas is nitrogen; the first activation zone raw material includes 10 wt % of oxygen and 90 wt % of water vapor; the second activation zone raw material is water vapor; an active component in the catalyst is an SAPO-34 molecular sieve; a coke content in the regenerated catalyst is about 5 wt %, where coke species include polymethylbenzene and polymethylnaphthalene, a mass of polymethylbenzene and polymethylnaphthalene accounts for about 72 wt % of a total mass of coke, a mass of coke species with a molecular weight greater than 184 accounts for about 19 wt % of a total mass of coke, and a quartile deviation of coke content distribution in the regenerated catalyst is about 0.9 wt %; a coke content in the spent catalyst is about 9 wt %; the reaction zone of the fluidized bed reactor (1) is a fast fluidized zone, and process operating conditions of the reaction zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 7.0 m/s, reaction temperature: about 550° C., reaction pressure: about 100 kPa, and bed density: about 100 kg/m.sup.3; process operating conditions of the spent catalyst zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 1.0 m/s, reaction temperature: about 550° C., reaction pressure: about 100 kPa, and bed density: about 200 kg/m.sup.3; process operating conditions of the first activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.5 m/s, temperature: 750° C., pressure: 100 kPa, and bed density: 400 kg/m.sup.3; and process operating conditions of the second activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.5 m/s, temperature: 700° C., pressure: 100 kPa, and bed density: 400 kg/m.sup.3.

[0196] In this example, the catalyst-to-alcohol ratio is about 0.3 ton of catalyst/ton of methanol; the product gas is composed of 55 wt % of ethylene, 37 wt % of propylene, 5 wt % of C.sub.4-C.sub.6 hydrocarbon compounds, and 3 wt % of other components, where the other components include methane, ethane, propane, hydrogen, CO, CO.sub.2, and the like; and the unit consumption of production is 2.50 tons of methanol/ton of low-carbon olefins. The utilization rate of C atoms in the whole process is 99.0%.

Example 2

[0197] The device shown in FIG. 1 and FIG. 2 is adopted in this example, where the first gas-solid separation unit (2-2) of the regenerator is a gas-solid cyclone separator; 10 baffles (2-4) are arranged in the first activation zone of the fluidized bed regenerator (2), that is, n=10; the baffles (2-4) divide the first activation zone into 10 first activation zone subzones; and 1 perforated plate (2-8) is arranged in the second activation zone of the fluidized bed regenerator (2), that is, m=1; and the perforated plate (2-8) has a porosity of 5%.

[0198] In this example, the oxygen-containing compound includes 82 wt % of methanol and 18 wt % of DME; the spent catalyst zone fluidizing gas is water vapor; the first activation zone raw material includes 20 wt % of air and 80 wt % of water vapor; the second activation zone raw material is water vapor; an active component in the catalyst is an SAPO-34 molecular sieve; a coke content in the regenerated catalyst is about 7 wt %, where coke species include polymethylbenzene and polymethylnaphthalene, a mass of polymethylbenzene and polymethylnaphthalene accounts for about 66 wt % of a total mass of coke, a mass of coke species with a molecular weight greater than 184 accounts for about 26 wt % of a total mass of coke, and a quartile deviation of coke content distribution in the regenerated catalyst is about 0.6 wt %; a coke content in the spent catalyst is about 11 wt %; process operating conditions of the reaction zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 0.5 m/s, reaction temperature: about 350° C., reaction pressure: about 500 kPa, and bed density: about 500 kg/m.sup.3; the spent catalyst zone of fluidized bed reactor (1) is a bubbling fluidized zone, and process operating conditions of the spent catalyst zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 0.1 m/s, reaction temperature: about 350° C., reaction pressure: about 500 kPa, and bed density: about 800 kg/m.sup.3; process operating conditions of the first activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.3 m/s, temperature: 700° C., pressure: 500 kPa, and bed density: 510 kg/m.sup.3; and process operating conditions of the second activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.3 m/s, temperature: 550° C., pressure: 500 kPa, and bed density: 510 kg/m.sup.3.

[0199] In this example, the catalyst-to-alcohol ratio is about 0.5 ton of catalyst/ton of methanol; the product gas is composed of 38 wt % of ethylene, 54 wt % of propylene, 6 wt % of C.sub.4-C.sub.6 hydrocarbon compounds, and 2 wt % of other components, where the other components include methane, ethane, propane, hydrogen, CO, CO.sub.2, and the like; and the unit consumption of production is 2.50 tons of methanol/ton of low-carbon olefins. The utilization rate of C atoms in the whole process is 99.3%.

Example 3

[0200] The device shown in FIG. 1 and FIG. 2 is adopted in this example, where the first gas-solid separation unit (2-2) of the regenerator is a gas-solid rapid separator; 4 baffles (2-4) are arranged in the first activation zone of the fluidized bed regenerator (2), that is, n=4; the baffles (2-4) divide the first activation zone into 4 first activation zone subzones; and 6 perforated plates (2-8) are arranged in the second activation zone of the fluidized bed regenerator (2), that is, m=6; and the perforated plate (2-8) has a porosity of 30%.

[0201] In this example, the oxygen-containing compound is DME; the spent catalyst zone fluidizing gas includes 5 wt % of nitrogen and 95 wt % of water vapor; the first activation zone raw material includes 1 wt % of oxygen and 99 wt % of water vapor; the second activation zone raw material is water vapor; an active component in the catalyst is an SAPO-34 molecular sieve; a coke content in the regenerated catalyst is about 9 wt %, where coke species include polymethylbenzene and polymethylnaphthalene, a mass of polymethylbenzene and polymethylnaphthalene accounts for about 79 wt % of a total mass of coke, a mass of coke species with a molecular weight greater than 184 accounts for about 13 wt % of a total mass of coke, and a quartile deviation of coke content distribution in the regenerated catalyst is about 0.2 wt %; a coke content in the spent catalyst is about 12 wt %; process operating conditions of the reaction zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 3.0 m/s, reaction temperature: about 450° C., reaction pressure: about 300 kPa, and bed density: about 230 kg/m.sup.3; process operating conditions of the spent catalyst zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 0.2 m/s, reaction temperature: about 450° C., reaction pressure: about 300 kPa, and bed density: about 600 kg/m.sup.3; process operating conditions of the first activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.2 m/s, temperature: 680° C., pressure: 300 kPa, and bed density: 580 kg/m.sup.3; and process operating conditions of the second activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.2 m/s, temperature: 630° C., pressure: 300 kPa, and bed density: 580 kg/m.sup.3.

[0202] In this example, the catalyst-to-alcohol ratio is about 0.8 ton of catalyst/ton of methanol; the product gas is composed of 45 wt % of ethylene, 51 wt % of propylene, 3 wt % of C.sub.4-C.sub.6 hydrocarbon compounds, and 1 wt % of other components, where the other components include methane, ethane, propane, hydrogen, CO, CO.sub.2, and the like; and the unit consumption of production is 2.42 tons of methanol/ton of low-carbon olefins. The utilization rate of C atoms in the whole process is 99.5%.

Example 4

[0203] The device shown in FIG. 1 and FIG. 2 is adopted in this example, where the first gas-solid separation unit (2-2) of the regenerator is a gas-solid rapid separator; 8 baffles (2-4) are arranged in the first activation zone of the fluidized bed regenerator (2), that is, n=8; the baffles (2-4) divide the first activation zone into 8 first activation zone subzones; and 4 perforated plates (2-8) are arranged in the second activation zone of the fluidized bed regenerator (2), that is, m=4; and the perforated plate (2-8) has a porosity of 20%.

[0204] In this example, the oxygen-containing compound is methanol; the spent catalyst zone fluidizing gas is water vapor; the first activation zone raw material includes 5 wt % of air and 95 wt % of water vapor; the second activation zone raw material is water vapor; an active component in the catalyst is an SAPO-34 molecular sieve; a coke content in the regenerated catalyst is about 11 wt %, where coke species include polymethylbenzene and polymethylnaphthalene, a mass of polymethylbenzene and polymethylnaphthalene accounts for about 88 wt % of a total mass of coke, a mass of coke species with a molecular weight greater than 184 accounts for about 7 wt % of a total mass of coke, and a quartile deviation of coke content distribution in the regenerated catalyst is about 0.1 wt %; a coke content in the spent catalyst is about 13 wt %; process operating conditions of the reaction zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 4.0 m/s, reaction temperature: about 500° C., reaction pressure: about 200 kPa, and bed density: about 160 kg/m.sup.3; process operating conditions of the spent catalyst zone of the fluidized bed reactor (1) are as follows: apparent gas linear velocity: about 0.5 m/s, reaction temperature: about 500° C., reaction pressure: about 200 kPa, and bed density: about 300 kg/m.sup.3; process operating conditions of the first activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.1 m/s, temperature: 650° C., pressure: 200 kPa, and bed density: 700 kg/m.sup.3; and process operating conditions of the second activation zone of the fluidized bed regenerator (2) are as follows: apparent gas linear velocity: 0.1 m/s, temperature: 600° C., pressure: 200 kPa, and bed density: 700 kg/m.sup.3.

[0205] In this example, the catalyst-to-alcohol ratio is about 1.0 ton of catalyst/ton of methanol; the product gas is composed of 51 wt % of ethylene, 46 wt % of propylene, 2 wt % of C.sub.4-C.sub.6 hydrocarbon compounds, and 1 wt % of other components, where the other components include methane, ethane, propane, hydrogen, CO, CO.sub.2, and the like; and the unit consumption of production is 2.40 tons of methanol/ton of low-carbon olefins. The utilization rate of C atoms in the whole process is 99.6%.

[0206] The above examples are merely few examples of the present application, and do not limit the present application in any form. Although the present application is disclosed as above with preferred examples, the present application is not limited thereto. Some changes or modifications made by any technical personnel familiar with the profession using the technical content disclosed above without departing from the scope of the technical solutions of the present application are equivalent to equivalent implementation cases and fall within the scope of the technical solutions.