Optical flash point detection on an automated open cup flash point detector

Abstract

An open cup flash point detector is shown that rapidly increases the temperature of the substance being tested until temperature is close to a theoretical flash point. Thereafter, as temperature is slowly increased, an igniter flame moves in an arc over the upper lip of the test cup while simultaneously a UV sensor senses a wedge-shaped area, also immediately over the upper lip of the test cup. The arc of the igniter flame and the wedge-shaped area do not overlap. By incremental increases in temperature and repeating the arc movement of the igniter flame, the flash point can be detected by the UV sensor.

Claims

1. A flash point detector for determining a flash point of a substance being tested using an open cup method, said flash point detector having a source of power and a source of gas, said flash point detector including: a stand having an upper surface with an opening in said upper surface; a test cup located in said opening; a heater connected to said source of power and located below said test cup for heating said test cup and said substance contained therein; insulation for thermally insulating said test cup and said heater from said stand; a test cup holder adjacent said test cup for picking up said test cup when hot; an igniter connected to said gas source for generating an ignitor flame immediately above said test cup; and an ultraviolet (UV) detector in a collumator located on said upper surface beside said opening; said ignitor flame periodically swinging in an arc immediately above said test cup; said collumator restricting a monitoring area of said UV detector to a wedge-shaped area immediately above said test cup; said arc being adjacent to, but not overlapping, said wedge-shaped area; and said UV detector detecting when said substance reaches the flash point.

2. The flash point detector as recited in claim 1 wherein said collumator has a chamber where said UV detector is located, and a slot from said chamber to a lens with a beam opening therein, said beam opening allowing the receiving of light from said wedge-shaped area.

3. The flash point detector as recited in claim 2 wherein between said periodically swinging of said igniter flame, a temperature of said substance is incrementally increased.

4. The flash point detector as recited in claim 3, wherein the flash point detector is configured to: recording record each temperature where said igniter flame swings immediately above said test cup and record at what temperature said UV detector detects said flash point.

5. A method of operation of an open cup flash point detector to determine a flash point of a substance, said method of operation including: placing a test cup of said substance in an upper opening of a test stand; continuously measuring a temperature of said substance in said test cup; rapidly increasing the temperature of said substance in said test cup until said substance approaches a theoretical flash point; thereafter, slowly increasing temperature of said substance in said test cup; periodically swinging an igniter flame in an arc just above said test cup; monitoring a wedge-shaped area just above said test cup with a UV detector to detect when said substance flashes; and recording the temperature of said substance when said substance flashes; said arc and said wedge-shaped area are adjacent and above said test cup, but not overlapping.

6. The method of operation of an open cup flash point detector as recited in claim 5 wherein said monitoring step includes locating said UV detector in a chamber of a collumator connected by a slot to a lens with a beam opening to allow ultraviolet light from said wedge-shaped area to enter said collumator, said wedge-shaped area being just above said test cup.

Description

DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a perspective view of the mechanical portion of an open cup flash point detector.

(2) FIG. 2 is a top view of FIG. 1, illustrating movement of the ignitor flame and viewing area of a UV sensor from a collumator.

(3) FIG. 3 is a vertical cross-sectional view of the collumator shown in FIGS. 1 and 2.

(4) FIG. 4 is an illustrative block diagram of controls for the open cup flash point detector shown in FIGS. 1 and 2.

DESCRIPTION OF THE PREFERRED EMBODIMENT

(5) Referring to FIGS. 1 and 2 in combination, an open cup flash point detector 10 is shown. More detail on open cup flash point detectors can be found in ASTM D92-16A, entitled Standard Test Method for Flash and Fire Points by Cleveland Open Cup Tester.

(6) The open cup flash point detector 10 has a stand 12 with an upper surface 14. Vertical walls 16 enclose the stand 12 and support the upper surface 14.

(7) Thermal insulation arranged in a cylinder shape with an upper rim 20 is inserted in a circular opening (not shown) in the upper surface 14 of the open cup flash point detector 10. The upper rim 20 holds the thermal insulation extending there below, which upper rim 20 is supported by the upper surface 14.

(8) A retaining ring 22 is located inside of the upper rim 20, which retaining ring 22 has a center opening just large enough to receive therein a test cup 24, which test cup 24 meets the requirement of ASTM D92-16A.

(9) Below the test cup 24 inside of the enclosure 16 is a heater (not shown) that is used to heat the test cup 24. Because the test cup 24 gets hot, a test cup holder 26 is provided. The test cup holder 26 has an insulated handle 28, connecting rod 30 and pick-up ring 32. The pick-up ring 32 is part of the test cup 24.

(10) Located just above the upper lip 34 of the test cup 24 is an igniter arm 36. The igniter arm 36 periodically swings back and forth in the arc 38 illustrated in FIG. 2. On the tip 40 of the igniter arm 36 will be an igniter flame. The reach of the igniter flame is defined by the arc 38, which igniter flame is just above the upper lip 34 of the test cup 24.

(11) Also located on the upper surface 14 of the open cup flash point detector 10 is a collumator 42. The internal design of the collumator 42 is shown in the vertical cross-sectional view of FIG. 3. The collumator 42 includes an ultraviolet (UV) sensor 44 located inside of chamber 46. Connecting to the chamber 46 and the UV sensor 44 is a slot 48 in the collumator 42. At one end of the slot 48 is located the UV sensor 44. At the other end of the slot 48 are located lens 50, which lens 50 have a beam opening 52 therein. The beam opening 52 will allow light outside the collumator 42 that travels through beam opening 52 to reach the UV detector 44. A wedge-shaped area 54 defines the area sensed by the UV sensor 44 in collumator 42. The arc 38 of the igniter flame never touches the wedge-shaped area 54. This prevents any false triggering of the UV sensor 44 by the igniter flame from tip 40.

(12) While many different types of UV sensors 44 may be used, the Hamamatsu R286A flame sensor sold under the mark UVTRON has been found to work satisfactorily in the present invention. R2868 is a UVTRON ultraviolet ON/OFF detector that makes use of photo electric effect. It has a narrow spectrum sensitivity of between 185 nm to 260 nm and is insensitive to visible light.

(13) While not shown in FIGS. 1 and 2, a thermometer would be inserted inside of the test cup 24. The substance to be measured would fill the test cup 24 so that the tip 40 of the igniter arm 36 swings back and forth just above a surface of the liquid being tested.

(14) The open cup flash point detector 10, as shown in FIGS. 1-3, can be automated as shown in FIG. 4 by having a gas supply 56 turned on by computer 58 and ignited by igniter 60. The fluid being measured in the test cup 24 is continually monitored by a temperature measurement 62.

(15) Initially, the computer 58 will turn on a heater 64 that will heat the liquid contained in the test cup 24. The heater 64 may be a resistance type heater or may use gas from the gas supply 56. Initially, the substance being tested in the test cup is raised in temperature very rapidly by the heater 64. As the substance being tested in the test cup 24 nears the theoretical flash point, the amount of heat being applied by the heater 64 is reduced. Thereafter, as the substance being tested is increased in temperature a slight amount (such as one or two degrees), by further application of heat from the heater 64. An igniter motor 66 is turned ON to swing the igniter 60 over the test cup 24, which igniter 60 has a flame on the tip 40 thereof.

(16) If the substance being tested does not ignite as is determined by UV sensor 44, computer 58 causes the heater 64 to continue to slowly increase the temperature of the substance in the test cup 24 as is determined by temperature measurement 62. After the temperature of the substance being tested is raised another increment, the process is repeated where the igniter motor 66 again swings the tip 40 of the igniter arm 36 over the upper surface of the test cup 24.

(17) Again, if the UV sensor 44 does not detect a flash of the substance being tested, the process will again be repeated. These steps are repeated in incremental increases of temperature until the substance being tested flashes as detected by the UV sensor 44. All of the steps undertaken in the open cup flash point detector 10 are recorded in a recording display 68 or a similar electronic storage device.

(18) The UV sensor 44 receives light from a wedge-shaped area 54 that extends just over the upper lip 34 of the test cup 24. The wedge-shaped area 54 is immediately adjacent to the arc 38 of the igniter flame, but the two do not overlap. In this manner, the igniter flame moving in an arc 38 can never cause a false triggering of the UV detector 44. The shape of the wedge-shaped area 54 is determined by the lens 50 and the beam opening 52 as contained in the collumator 42.