FUEL CELL MANIFOLD AND FUEL CELL STACK INCLUDING THE SAME
20220407104 · 2022-12-22
Assignee
- Korea Institute Of Science And Technology (Seoul, KR)
- INDUSTRY-ACADEMIC COOPERATION FOUNDATION, YONSEI UNIVERSITY (Seoul, KR)
Inventors
- Jong Ho Lee (Seoul, KR)
- Kyung Joong Yoon (Seoul, KR)
- Sang Hyeok LEE (Seoul, KR)
- Min Jun OH (Seoul, KR)
- Jong Sup HONG (Seoul, KR)
- Woo Seok LEE (Seoul, KR)
Cpc classification
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0258
ELECTRICITY
H01M8/2485
ELECTRICITY
H01M8/12
ELECTRICITY
International classification
Abstract
Disclosed herein are a fuel cell manifold and a fuel cell stack including the same. The manifold may include a cover plate, an air guide plate configured to guide a flow of air in the manifold, a fuel guide plate configured to guide a flow of fuel in the manifold, and an auxiliary plate providing a passage for inflow of air and outflow of fuel.
Claims
1. A fuel cell stack comprising: a stack unit in which a plurality of unit cells are stacked; and a manifold disposed on one surface of the stack unit to provide an inflow path for air and an outflow path for fuel, wherein the manifold comprises: a cover plate comprising a first air flow hole through which air passes and a first fuel flow hole through which fuel passes; an air guide plate comprising a plurality of flow paths spaced apart from each other for guiding air introduced into one end thereof to flow toward the other end thereof; a fuel guide plate comprising a pattern section provided with a plurality of protrusions spaced apart from each other for guiding fuel introduced into one side thereof to flow toward the other side thereof; and an auxiliary plate comprising an air inflow section configured to communicate with the outside for inflow of air introduced from the outside and a fuel outflow section configured to communicate with the outside to discharge fuel in the manifold to the outside.
2. The fuel cell stack according to claim 1, wherein: the manifold is formed by stacking the cover plate, the air guide plate, the auxiliary plate, and the fuel guide plate in that order; and the air introduced into the air inflow section of the auxiliary plate from the outside moves to the flow paths through a second air flow hole formed through one end of the air guide plate, flows to the other end of the air guide plate along the flow paths, and is then supplied to the stack unit through the first air flow hole of the cover plate communicating with the other end of the air guide plate.
3. The fuel cell stack according to claim 1, wherein: the manifold is formed by stacking the cover plate, the air guide plate, the auxiliary plate, and the fuel guide plate in that order; and the fuel introduced into the first fuel flow hole of the cover plate from the stack unit is introduced to one side of the fuel guide plate through a second fuel flow hole formed through the air guide plate at a position corresponding to the first fuel flow hole and through a third fuel flow hole formed through the auxiliary plate at a position corresponding to the second fuel flow hole, flows to the other side of the fuel guide plate along the pattern section, and is then discharged to the outside through the fuel outflow section of the auxiliary plate connected to the pattern section.
4. The fuel cell stack according to claim 1, wherein: the manifold is formed by stacking the cover plate, the fuel guide plate, the air guide plate, and the auxiliary plate in that order; and the air introduced into the air inflow section of the auxiliary plate from the outside moves to the flow paths through a second air flow hole formed through one end of the air guide plate, flows to the other end of the air guide plate along the flow paths, and is then supplied to the stack unit through a third air flow hole formed through the fuel guide plate at a position corresponding to the other end of the air guide plate and through the first air flow hole of the cover plate communicating with the third air flow hole.
5. The fuel cell stack according to claim 1, wherein: the manifold is formed by stacking the cover plate, the fuel guide plate, the air guide plate, and the auxiliary plate in that order; and the fuel introduced into the first fuel flow hole of the cover plate from the stack unit is introduced into one side of the fuel guide plate, flows to the other side of the fuel guide plate along the pattern section, and is then discharged to the outside through the fuel outflow section of the auxiliary plate by passing through a third fuel flow hole formed through the other side of the fuel guide plate and a second fuel flow hole formed through the air guide plate at a position corresponding to the third fuel flow hole.
6. The fuel cell stack according to claim 1, wherein: the manifold is formed by stacking the cover plate, the air guide plate, the fuel guide plate, and the auxiliary plate in that order; and the air introduced into the air inflow section of the auxiliary plate from the outside moves to the flow paths through a third air flow hole formed through the fuel guide plate at a position corresponding to the air inflow section and through a second air flow hole formed through one end of the air guide plate at a position corresponding to the third air flow hole, flows to the other end of the air guide plate along the flow paths, and is then supplied to the stack unit through the first air flow hole of the cover plate communicating with the other end of the air guide plate.
7. The fuel cell stack according to claim 1, wherein: the manifold is formed by stacking the cover plate, the air guide plate, the fuel guide plate, and the auxiliary plate in that order; and the fuel introduced into the first fuel flow hole of the cover plate from the stack unit is introduced into one side of the fuel guide plate through a second fuel flow hole formed along the air guide plate at a position corresponding to the first fuel flow hole, flows to the other side of the fuel guide plate along the pattern section, and is then discharged to the outside through the fuel outflow section of the auxiliary plate by passing through a third fuel flow hole formed through the other side of the fuel guide plate.
8. The fuel cell stack according to claim 1, wherein: the pattern section of the fuel guide plate comprises a groove recessed to a predetermined width and a predetermined depth from one surface of the fuel guide plate, and the plurality of protrusions protruding to a predetermined height from the groove; a distance between adjacent protrusions is greater than a height of each protrusion.
9. The fuel cell stack according to claim 1, wherein a sum of a distance between adjacent flow paths of the air guide plate and a width of each flow path is greater than a depth of the associated flow path.
10. The fuel cell stack according to claim 1, wherein the stack unit and the manifold are stacked such that cathodes of the unit cells are directed toward the manifold.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0028] The above and other features of the present invention will now be described in detail with reference to certain exemplary embodiments thereof illustrated in the accompanying drawings which are given hereinbelow by way of illustration only, and thus are not limitative of the present invention, and wherein:
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[0058] It should be understood that the appended drawings are not necessarily to scale, presenting a somewhat simplified representation of various preferred features illustrative of the basic principles of the invention. The specific design features of the present invention as disclosed herein, including, for example, specific dimensions, orientations, locations, and shapes will be determined in part by the particular intended application and use environment.
[0059] In the figures, reference numbers refer to the same or equivalent parts of the present invention throughout the several figures of the drawing.
DETAILED DESCRIPTION
[0060] The above and other aspects, features, and advantages of the present invention will be easily understood with reference to the following preferred embodiments in conjunction with the accompanying drawings. The present invention may, however, be embodied in different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the present invention to those skilled in the art.
[0061] Throughout the disclosure, like reference numerals refer to like elements throughout the various figures. The drawings are not necessarily to scale and in some instances, proportions may have been exaggerated in order to clearly illustrate features of the present invention. Terms such as “first” and/or “second” may be used herein to describe various elements of the present invention, but these elements should not be construed as being limited by the terms. These terms will be used only for the purpose of differentiating one element from other elements of the present invention. For example, without departing from the scope and spirit of the present invention, a first element may be referred to as a second element, and, similarly, a second element may also be referred to as a first element. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.
[0062] It should be understood that the terms “comprises/includes” and/or “comprising/including”, when used in the specification, specify the presence of stated features, integers, steps, operations, elements, components, and/or groups thereof, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. When a part such as a layer, a film, a region, or a plate is referred to as being “on” another part, it not only refers to the case where the part is “directly on” the other part but also the case where a further part exists in between. Conversely, when a part such as a layer, a film, a region, or a plate is referred to as being “beneath” another part, it not only refers to the case where the part is “directly beneath” the other part but also the case where a further part exists in between.
[0063] Unless otherwise specified, all numbers, values, and/or expressions representing quantities of ingredients, reaction conditions, polymer compositions and formulations used herein are approximations that reflect various uncertainties in the measurement that arise in obtaining such values, among others, in nature as these numbers are inherently different, so the same should be understood as being modified by the term “about” in all cases. In addition, where numerical ranges are disclosed in the description, such ranges are continuous and include all values from the minimum to the maximum within the range, unless otherwise indicated. Furthermore, when such ranges refer to integers, they include all integers from the minimum to the maximum within the range, unless otherwise indicated.
[0064] A fuel cell stack according to the present invention includes a stack unit in which a plurality of unit cells are stacked, and a manifold disposed on one surface of the stack unit to provide an inflow path for air and an outflow path for fuel.
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[0066] When an oxidant such as air or oxygen is supplied to the cathode 710, the reaction as illustrated in the following Formula 1 occurs, thereby producing oxygen ions.
½O.sub.2+2e.sup.−.fwdarw.O.sup.2− [Formula 1]
[0067] The oxygen ions migrate to the anode 730 through the electrolyte membrane 720.
[0068] When fuel such as hydrogen or hydrocarbon is supplied to the anode 730, the oxygen ions react with the fuel to produce water and emit electrons, as illustrated in the following Formula 2.
O.sup.2−+H.sub.2.fwdarw.H.sub.2O+2e.sup.− [Formula 2]
[0069] The oxygen ions produced by the oxidant in the cathode 710 migrate toward the anode 730 due to the concentration gradient of the oxygen ions, and the electrons flow from the anode 730 to the cathode 710 along an external circuit electrically connecting the cathode 710 and the anode 730.
[0070] Here, the electrolyte membrane 720 may block the permeation of the oxidant and the fuel. The electrolyte membrane 720 does not conduct electrons, but may allow the oxygen ions to permeate.
[0071] As such, when the oxygen ions migrate from the cathode 710 to the anode 730 to maintain the overall charge equilibrium, useful power may be produced through the oxidation reaction of the fuel. In this case, only pure water and heat are discharged as by-products of the reaction, and may also be usefully utilized.
[0072] The manifold may include a cover plate, an air guide plate configured to guide a flow of air in the manifold, a fuel guide plate configured to guide a flow of fuel in the manifold, and an auxiliary plate providing a passage for inflow of air and outflow of fuel.
[0073] The present invention is characterized in that the manifold is formed by stacking a plurality of plates as described above, and effects such as minimizing the temperature gradient within the stack or minimizing the temperature of the system are realized by changing the stacking order of the plates. Hereinafter, various embodiments of the present invention will be described in detail.
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[0075] The manifold 100 may be formed by stacking a cover plate 110, an air guide plate 120, an auxiliary plate 140, and a fuel guide plate 130 in that order.
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[0080] The air inflow section 141 may include an air accommodation part 141a recessed therefrom to provide a space for the inflow of air introduced from the outside, and an air inflow path 141b configured to connect a side wall partitioning the air accommodation part 141a to a side surface of the auxiliary plate 140 so that the air accommodation part 141a communicates with the outside.
[0081] The fuel outflow section 142 may include a fuel accommodation part 142a recessed therefrom to provide a space for the inflow of fuel introduced into the auxiliary plate 140, and a fuel outflow path 142b configured to connect a side wall partitioning the fuel accommodation part 142a to the side surface of the auxiliary plate 140 so that the fuel accommodation part 142a communicates with the outside. The fuel accommodation part 142a may be a space recessed in the space defined by the other end of the auxiliary plate 140 and one side thereof that is connected to the other end at the other side thereof facing the third fuel flow hole 143.
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[0083] The pattern section 131 may include a groove 131a recessed to a predetermined width and a predetermined depth in the center of the fuel guide plate 130, and the plurality of protrusions 131b protruding to a predetermined height from the groove 131a.
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[0085] Each of the protrusions 131b may have a predetermined shape. However, the present invention is not limited thereto, and the protrusion 131b may have, for example, a cylindrical shape, a conical shape, or a square prism shape.
[0086] The present embodiment is characterized in that the distance d between adjacent protrusions 131b is greater than the height e of each protrusion 131b.
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[0090] The manifold 200 may be formed by stacking a cover plate 210, a fuel guide plate 230, an air guide plate 220, and an auxiliary plate 240 in that order.
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[0093] The pattern section 231 may include a groove 231a recessed to a predetermined width and a predetermined depth in the center of the fuel guide plate 230, and the plurality of protrusions 231b protruding to a predetermined height from the groove 231a. A detailed description thereof will be omitted below since the contents related thereto are the same as those described above.
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[0096] The air inflow section 241 may include an air accommodation part 241a recessed therefrom to provide a space for the inflow of air introduced from the outside, and an air inflow path 241b configured to connect a side wall partitioning the air accommodation part 241a to a side surface of the auxiliary plate 240 so that the air accommodation part 241a communicates with the outside.
[0097] The fuel outflow section 242 may include a fuel accommodation part 242a recessed therefrom to provide a space for the inflow of fuel introduced into the auxiliary plate 240, and a fuel outflow path 242b configured to connect a side wall partitioning the fuel accommodation part 242a to the side surface of the auxiliary plate 240 so that the fuel accommodation part 242a communicates with the outside. The fuel accommodation part 242a may be a space recessed in the space defined by the other end of the auxiliary plate 240 and one side thereof that is connected to the other end.
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[0101] The manifold 300 may be formed by stacking a cover plate 310, an air guide plate 320, a fuel guide plate 330, and an auxiliary plate 340 in that order.
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[0105] The pattern section 331 may include a groove 331a recessed to a predetermined width and a predetermined depth in the center of the fuel guide plate 330, and the plurality of protrusions 331b protruding to a predetermined height from the groove 331a. A detailed description thereof will be omitted below since the contents related thereto are the same as those described above.
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[0107] The air inflow section 341 may include an air accommodation part 341a recessed therefrom to provide a space for the inflow of air introduced from the outside, and an air inflow path 341b configured to connect a side wall partitioning the air accommodation part 341a to a side surface of the auxiliary plate 340 so that the air accommodation part 341a communicates with the outside.
[0108] The fuel outflow section 342 may include a fuel accommodation part 342a recessed therefrom to provide a space for the inflow of fuel introduced into the auxiliary plate 340, and a fuel outflow path 342b configured to connect a side wall partitioning the fuel accommodation part 342a to the side surface of the auxiliary plate 340 so that the fuel accommodation part 342a communicates with the outside. The fuel accommodation part 342a may be a space recessed in the space defined by the other end of the auxiliary plate 340 and one side thereof that is connected to the other end.
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[0111] The fuel cell stack according to the present invention may include the stack unit in which the plurality of unit cells 700 are stacked, and the manifold 100, 200, or 300 disposed on one surface of the stack unit to provide the inflow path for air and the outflow path for fuel. In this case, the stack unit and the manifold 100, 200, or 300 may be stacked such that the cathode 710 of each unit cell 700 is directed toward the manifold 100, 200, or 300. Due to the large heat capacity and low thermal conductivity of air, heat is mainly conducted toward the inlet of air. In addition, the substance in the end cell is transferred from the anode 730 to the cathode 710, and thermal convection occurs in the same direction. Therefore, the present invention can achieve the minimization of heat conduction by disposing the cathode 710 toward the manifold 100, 200, or 300 through which air is introduced.
[0112] As is apparent from the above description, according to the present invention, it is possible to uniformly distribute gas to each unit cell in the fuel cell stack.
[0113] According to the present invention, it is possible to minimize the temperature gradient in the fuel cell stack.
[0114] The present invention is not limited to the above-mentioned effects. It should be understood that the present invention includes all effects that can be inferred from the above description.
[0115] The invention has been described in detail with reference to preferred embodiments thereof. However, it will be appreciated by those skilled in the art that changes may be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.