Dye composition comprising a para-phenylenediamine oxidation base, a nonionic surfactant in a medium rich in fatty substances

Abstract

The present invention relates to a composition for dyeing keratin fibers, in particular keratin fibers such as the hair, comprising: a) at least one oxidation base 3-(2,5-diaminophenyl)-1-propanol and/or acid salts thereof or solvates thereof such as hydrates; b) at least one coupler; c) at least 10% by weight of the total weight of the composition of a fatty substance which is preferably liquid and non-silicone-based; d) at least one nonionic surfactant chosen from alkyl(poly)glycoside surfactants, esters of oxyalkylenated sorbitan and fatty acids and oxyalkylenated fatty alcohols; e) optionally at least one basifying agent; and f) optionally at least one chemical oxidizing agent. The invention also relates to a process for dyeing keratin fibers such as the hair using the composition of the invention, and to a multi-compartment device for using the composition of the invention.

Claims

1. A composition comprising: a) at least one oxidation base chosen from 3-(2,5-diaminophenyl)-1-propanol, acid salts thereof, or solvates thereof; b) at least one coupler; c) at least one fatty substance, wherein the total amount of fatty substance is at least about 10% by weight, relative to the total weight of the composition; d) at least one nonionic surfactant chosen from alkyl(poly)glycoside surfactants, fatty acid esters of oxyalkylenated sorbitan, or oxyalkylenated fatty alcohols; e) optionally at least one basifying agent; and f) optionally at least one chemical oxidizing agent.

2. The composition according to claim 1, wherein the at least one fatty substance is chosen from C.sub.6-C.sub.16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, plant oils of triglyceride type, synthetic triglycerides, fluoro oils, fatty alcohols, esters of fatty acids and/or of fatty alcohols other than triglycerides and plant waxes, non-silicone waxes, and silicones.

3. The composition according to claim 1, wherein the at least one fatty substance is liquid at room temperature and at atmospheric pressure.

4. The composition according to claim 1, wherein the at least one fatty substance is chosen from C.sub.6-C.sub.16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, triglycerides, fatty alcohols, esters of fatty acids and/or of fatty alcohols other than triglycerides, or mixtures thereof.

5. The composition according to claim 1, wherein the total amount of fatty substance ranges from about 15% to about 80% by weight, relative to the total weight of the composition.

6. The composition according to claim 1, wherein the at least one nonionic surfactant is chosen from alkylpolyglycosides according to formula (Ia) below:
R.sub.1O(R.sub.2O).sub.t(G).sub.v(Ia) wherein: R.sub.1 is chosen from a linear or branched alkyl or alkenyl radical comprising 6 to 24 carbon atoms, or an alkylphenyl radical whose linear or branched alkyl radical comprises 6 to 24 carbon atoms; R.sub.2 is an alkylene radical comprising 2 to 4 carbon atoms; G is a sugar unit comprising 5 to 6 carbon atoms; t is an integer ranging from 0 to 10; and v is an integer ranging from 1 to 15.

7. The composition according to claim 6, wherein in formula (Ia): R.sub.1 is a saturated or unsaturated, linear or branched alkyl radical comprising from 8 to 18 carbon atoms; R.sub.2 is an alkylene radical comprising 2 to 4 carbon atoms; G is chosen from glucose, fructose, or galactose; t is an integer ranging from 0 to 3; and v is an integer ranging from 1 to 15.

8. The composition according to claim 1, wherein the at least one nonionic surfactant is chosen from fatty acid esters of oxyalkylenated sorbitan.

9. The composition according to claim 8, wherein the fatty acid esters of oxyalkylenated sorbitan are chosen from esters of polyoxyethylenated sorbitan and of a C.sub.8-C.sub.14 saturated fatty acid.

10. The composition according to claim 1, wherein the at least one nonionic surfactant is chosen from oxyalkylenated fatty alcohols according to formula (IIa) below: ##STR00004## wherein: R is chosen from a saturated or unsaturated, linear or branched radical comprising from 6 to 40 carbon atoms; Z is an oxyethylenated radical; and m is the number of ethylene oxide units ranging from 1 to 50.

11. The composition according to claim 1, wherein the at least one nonionic surfactant is chosen from C.sub.16-C.sub.18 polyoxyethylenated fatty alcohols comprising from 2 to 20 oxyethylene units.

12. The composition according to claim 1, wherein the total amount of nonionic surfactant ranges from about 0.1% to about 30%, relative to the total weight of the composition.

13. The composition according to claim 1, wherein the amount of the at least one oxidation base chosen from 3-(2,5-diaminophenyl)-1-propanol, acid salts thereof, or solvates thereof ranges from about 0.0001% to about 20% by weight, relative to the total weight of the composition.

14. The composition according to claim 1, wherein the at least one coupler is chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers and heterocyclic couplers, or addition salts thereof.

15. The composition according to claim 1, comprising the at least one basifying agent chosen from ammonia, alkali metal carbonates or bicarbonates, sodium hydroxide or potassium hydroxide, organic amines, amino acids, or the compounds corresponding to formula (II), or mixtures thereof: ##STR00005## wherein: W is chosen from a divalent C.sub.1-C.sub.6 alkylene radical optionally substituted with at least one hydroxyl group or a C.sub.1-C.sub.6 alkyl radical, and/or optionally interrupted with at least one heteroatom chosen from 0 or NR.sub.u; and R.sub.x, R.sub.y, R.sub.z, R.sub.t, and R.sub.u, are independently chosen from hydrogen, a C.sub.1-C.sub.6 alkyl, a C.sub.1-C.sub.6 hydroxyalkyl, or C.sub.1-C.sub.6 aminoalkyl radical.

16. The composition according to claim 15, wherein the basifying agent is chosen from ammonia or alkanolamines, or neutral or ionic amino acids.

17. The composition according to claim 1, comprising the at least one chemical oxidizing agent.

18. A process for dyeing keratin fibers comprising applying to the keratin fibers a composition comprising: a) at least one oxidation base chosen from 3-(2,5-diaminophenyl)-1-propanol, acid salts thereof, or solvates thereof; b) at least one coupler; c) at least one fatty substance, wherein the total amount of fatty substance is at least about 10% by weight, relative to the total weight of the composition; d) at least one nonionic surfactant chosen from alkyl(poly)glycoside surfactants, fatty acid esters of oxyalkylenated sorbitan, or oxyalkylenated fatty alcohols; e) optionally at least one basifying agent; and f) optionally at least one chemical oxidizing agent.

19. The process of claim 18, wherein the composition applied to the keratin fibers is obtained by mixing: a first composition (A) comprising at least one oxidation base chosen from 3-(2,5-diaminophenyl)-1-propanol, acid salts thereof, or solvates thereof; and a second composition (B) comprising at least one chemical oxidizing agent; wherein at least one of the compositions (A) or (B) comprises at least one fatty substance and at least one nonionic surfactant, in the same or different compositions; and wherein the total amount of fatty substance in the composition resulting from the mixing of compositions (A) and (B) is at least about 10%, relative to the weight of the composition obtained from the mixing of (A) and (B).

20. The process of claim 19, wherein the composition applied to the keratin fibers is obtained by mixing: a first composition (A) comprising at least one oxidation base; a second composition (B) comprising at least one chemical oxidizing agent; and a third composition comprising at least one fatty substance; wherein at least one of the compositions (A) or (B) comprises at least one fatty substance and at least one nonionic surfactant, in the same or different compositions; wherein the fatty substance in compositions (A) or (B) is the same or different than the fatty substance it the third composition; and wherein the total amount of fatty substance in the composition resulting from the mixing of the first composition (A), the second composition (B), and the third composition is at least about 10%, relative to the weight of the composition obtained from the mixing of the first composition (A), the second composition (B), and the third composition.

21. A multi-compartment device comprising: a first compartment containing composition (A) comprising at least one oxidation base chosen from 3-(2,5-diaminophenyl)-1-propanol and/or one of acid salts or solvates; and a second compartment containing composition (B) comprising at least one chemical oxidizing agent; wherein at least one of the compositions (A) or (B) comprises at least one fatty substance and the at least one nonionic surfactant; wherein the total amount of fatty substance in the composition resulting from the mixing of compositions (A) and (B) is at least about 10%, relative to the weight of the composition obtained from the mixing of (A) and (B).

Description

EXAMPLES

Example 1

(1) The following compositions are prepared in which the amounts are expressed in grams of active materials.

(2) Dye compositions (g %)

(3) TABLE-US-00001 Ingredients A B Sodium metabisulfite in powder form 0.45 0.45 Pure monoethanolamine 4.57 4.65 Ethylenediaminetetraacetic acid 0.2 0.2 6-Hydroxybenzomorpholine 0.04 1--Hydroxyethyloxy-2,4-diaminobenzene 0.16 dihydrochloride 2-Methyl-1,3-dihydroxybenzene (2- 0.17 methylresorcinol) N,N-Bis(2-hydroxyethyl)-p-phenylenediamine 0.13 sulfate monohydrate 1,3-Dihydroxybenzene (resorcinol) 0.2 1 1-Hydroxy-3-aminobenzene 0.025 0.16 3-(2,5-Diaminophenyl)propan-1-ol hydrochloride 0.75 2.83 Mineral oil (INCI name) 60 60 Perfume 0.72 0.72 Cationic hydroxyethylcellulose (Polyquaternium- 0.19 0.19 67) marketed under the name Softcat Polymer SL-100 by Dow Chemical water Qs 100 Qs 100 Oxyethylenated stearyl alcohol (2 OE) 1.13 1.13 Oxyethylenated stearyl alcohol (20 OE) 3.88 3.88 Caprylyl/capryl glucoside (alkyl (C8/C10 50/50) 2.4 2.4 polyglucoside (2) in 60% buffered aqueous solution) Oxyethylenated sorbitan monolaurate (4 OE) 2.4 2.4 Vitamin C: ascorbic acid 0.25 0.25

(4) Oxidizing composition C (g % of active material)

(5) TABLE-US-00002 Ingredients C Pentasodium pentetate 0.06 Hydrogen peroxide 6 Sodium stannate 0.04 Phosphoric acid qs pH = 2.2 Tetrasodium pyrophosphate 0.03 Mineral oil 20 Hexadimethrine chloride 0.15 Polyquaternium-6 0.2 Water qs 100 Glycerol 0.5 Cetearyl alcohol 6 Steareth-20 5 PEG-4 Rapeseedamide 1.2 Tocopherol 0.1

(6) At the time of use, each of the compositions A and B is mixed with one time its own weight of oxidizing composition C.

(7) The mixtures thus obtained are applied to natural hair containing 90% white hairs.

(8) After a leave-on time of 35 minutes at room temperature, the hair is rinsed and washed with a standard shampoo, then dried. An attractive Blonde shade is obtained with formula A and a Chestnut shade is obtained with formula B.

Example 2

(9) The following compositions have been prepared in which the amounts are expressed in grams of active materials.

(10) TABLE-US-00003 B B inven- compar- tion ative Sodium metabisulfite 0.45 0.45 Monoethanolamine 4 4 Ethylenediaminetetraacetic acid 0.2 0.2 6-HYDROXY BENZOMORPHOLINE 0.04 0.04 1-BETA-HYDROXYETHYLOXY-2,4- 0.16 0.16 DIAMINOBENZENE 2 Hcl 2-METHYL-1,3-DIHYDROXYBENZENE 0.17 0.17 (2-METHYL RESORCINOL) Para aminophenol 0.13 0.13 1,3-DIHYDROXYBENZENE (RESORCINOL) 0.21 0.21 1-HYDROXY-3-AMINO-BENZENE 0.16 0.16 3-(2,5-DIAMINOPHENYL)PROPAN-1-OL HCl 4.18 10.sup.3 mol 2-b hydroxyethyl para phenylenediamine 4.18 10.sup.3 mol MINERAL OIL 60 60 PERFUME 0.72 0.72 Cationic Hydroxyethylcellulose 0.19 am* 0.19 am (Polyquaternium-67) SOFTCAT SL-100 WATER qs qs Oxyethylenated stearyl alcohol (2 OE) 1.13 1.13 Oxyethylenated stearyl alcohol (20 OE) 3.88 3.88 (50/50 C.sub.8/C.sub.10) Alkyl (2)-polyglucoside as a 60% 2.4 am 2.4 am aqueous solution (Oramix CG 110 from SEPPIC) Oxyethylenated sorbitan monolaurate (4 OE) 2.4 2.4 Vitamin C 0.25 0.25 *Active material

(11) At the time of use, each composition B and B is mixed with the oxidizing composition C of example 1 at a weight ratio of 1/1.

(12) The resulting mixture are each applied on natural hair locks (BN), which represents the hair root, and permed hair locks (BP), which represents the hair tips, in an amount of 10 g of composition per 1 g of hair, and left for 35 minutes at room temperature (25 C.).

(13) Then the hair was rinsed with water, washed with the Pro Classics concentrated shampoo (L'Oral Professionnel), diluted at 10%, and dried.

(14) Selectivity Evaluation

(15) The color of the hair was determined using the CIE L*a*b* system with a Minolta CM2006D spectrophotometer (illuminant D65, angle 10, specular component included) in the CIELab system.

(16) According to this system, L* indicates the lightness of the color of the hair. The chromaticity coordinates are expressed by the parameters a* and b*, a* indicating the axis of red/green shades and b* the axis of yellow/blue shades.

(17) The selectivity of the dyeing is measured by calculating the variation of E according to the formula:
E={square root over ((L*L.sub.o*).sup.2+(a*a.sub.o*).sup.2+(b*b.sub.o*).sup.2)}

(18) In which L, a* and b* represent the values measured on natural hair and L0*, a0* and b0* represent the values measured on permed hair.

(19) The selectivity is represented by the difference of color between the colored natural hair and permed hair: the more is the E value, the more the difference of color between natural and permed hair is important, which is representative of the homogeneity of the coloration between the roots and the tips along the lock of hair.

(20) The following results are obtained:

(21) TABLE-US-00004 Hair type L* a* b* E B + C BN 22.14 1.16 0.36 3.85 (invention) BP 18.39 0.54 0.24 B + C BN 26.24 2.18 2.04 5.94 (comparative) BP 20.64 1.28 0.28

(22) The mixtures B+C according to the invention provide less selective colorations (lower E value) than the mixture of compositions B+C (comparative):the difference between the raw and the tips is lower with B+C than with B+C: the coloration along the lock of hair is more homogenous with B+C.