Slip-resistant garments and manufacturing processes thereof

Abstract

A slip-resistant garment may include: at least one textile structure; and/or at least one slip-resistant portion coupled to the at least one textile structure. The at least one slip-resistant portion may include at least one thermoplastic polymer selected from among: (a) block copolymers of styrene; (b) copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin; (c) copolymers of at least one butene with at least one diene; or (d) copolymers of ethylene with at least one ester having an ethylene unsaturation selected from among: C.sub.1-C.sub.8 alkyl acrylate, C.sub.1-C.sub.8 alkyl methacrylates, or vinyl C.sub.2-C.sub.8 carboxylates. The copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin further include at least one dienic termonomer.

Claims

1. A slip-resistant garment, comprising: at least one textile structure; and at least one slip-resistant portion coupled to the at least one textile structure; wherein the at least one slip-resistant portion comprises at least one thermoplastic polymer selected from the group consisting of: (a) block copolymers of styrene; (b) copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin; (c) copolymers of at least one butene with at least one diene; or (d) copolymers of ethylene with at least one ester having an ethylene unsaturation selected from the group consisting of: C.sub.1-C.sub.8 alkyl acrylate, C.sub.1-C.sub.8 alkyl methacrylates, or vinyl C.sub.2-C.sub.8 carboxylates; and wherein the at least one slip-resistant portion further comprises at least one tape coupled to the at least one textile structure by hot pressing the at least one tape on the at least one textile structure.

2. The garment of claim 1, wherein the at least one thermoplastic polymer is a block copolymer of styrene selected from the group consisting of: styrene/butadiene/styrene (SBS); styrene/ethylene/butadiene/styrene (SEBS); styrene/ethylene/propylene/styrene (SEPS); styrene/ethylene/butadiene/propylene/styrene (SEBPS); styrene/isoprene/styrene (SIS); styrene/isobutylene/styrene (SIBS); or mixtures thereof.

3. The garment of claim 1, wherein the at least one thermoplastic polymer is a block copolymer of styrene having Shore A hardness (measured according to ASTM 2240 or ISO 7619) greater than or equal to 20 and less than or equal to 90.

4. The garment of claim 1, wherein the at least one slip-resistant portion further comprises greater than or equal to 1 per hundred rubber (phr) and less than or equal to 50 phr of at least one polyisobutene.

5. The garment of claim 1, wherein the at least one slip-resistant portion further comprises greater than or equal to 1 per hundred rubber (phr) and less than or equal to 50 phr of at least one hydrocarbon resin.

6. The garment of claim 1, wherein the at least one slip-resistant portion comprises greater than or equal to 10 per hundred rubber (phr) and less than or equal to 250 phr of at least one plasticiser selected from the group consisting of paraffinic oils, naphthenic oils, or polyolefinic oils.

7. The garment of claim 1, wherein the at least one slip-resistant portion comprises greater than or equal to 0.5 per hundred rubber (phr) and less than or equal to 50 phr of at least one functionalized polyolefin.

8. The garment of claim 1, wherein the at least one tape has a thickness greater than or equal to 0.02 mm and less than or equal to 5 mm.

9. The garment of claim 1, wherein the at least one slip-resistant portion is at an edge of at least one access opening of the garment.

10. The garment of claim 1, wherein the garment is a jersey, trousers, stockings, pantyhose, shapewear garment, a containment garment, a formal garment, or a brace for immobilising or supporting joints.

11. A process for manufacturing a slip-resistant garment, the process comprising: providing at least one textile structure; and coupling at least one slip-resistant portion to the at least one textile structure; wherein the at least one slip-resistant portion comprises at least one thermoplastic polymer selected from the group consisting of: (a) block copolymers of styrene; (b) copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin; (c) copolymers of at least one butene with at least one diene; or (d) copolymers of ethylene with at least one ester having an ethylene unsaturation selected from the group consisting of: C.sub.1-C.sub.8 alkyl acrylates, C.sub.1-C.sub.8 alkyl methacrylates, or vinyl C.sub.2-C.sub.8 carboxylates; wherein the at least one slip-resistant portion further comprises at least one tape, and wherein the coupling of the at least one slip-resistant portion to the at least one textile structure comprises hot pressing the at least one tape on the at least one textile structure.

12. A process for using polymeric material, the process comprising: incorporating the polymeric material into a garment; wherein the polymeric material is configured to reduce or prevent slipping of the garment on skin or on a textile substrate, and wherein the polymeric material comprises at least one thermoplastic polymer selected from the group consisting of: (a) block copolymers of styrene; (b) copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin; (c) copolymers of at least one butene with at least one diene; or (d) copolymers of ethylene with at least one ester having an ethylene unsaturation selected from the group consisting of: C.sub.1-C.sub.8 alkyl acrylates, C.sub.1-C.sub.8 alkyl methacrylates, or vinyl C.sub.2-C.sub.8 carboxylates; and wherein the polymeric material further comprises at least one tape coupled to the garment by hot pressing the at least one tape on the garment.

13. The garment of claim 1, wherein the copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin further comprise at least one dienic termonomer.

14. The garment of claim 1, wherein the at least one thermoplastic polymer is a block copolymer of styrene having Shore A hardness (measured according to ASTM 2240 or ISO 7619) greater than or equal to 35 and less than or equal to 70.

15. The garment of claim 4, wherein the at least one polyisobutene has a molecular weight (Mw) greater than or equal to 100 and less than or equal to 2,500,000.

16. The garment of claim 1, wherein the at least one slip-resistant portion comprises greater than or equal to 0.5 per hundred rubber (phr) and less than or equal to 50 phr of a maleated polyolefin.

17. The garment of claim 1, wherein the at least one tape has a thickness greater than or equal to 0.1 mm and less than or equal to 2 mm.

18. The garment of claim 1, wherein the at least one tape has a width greater than or equal to 5 mm and less than or equal to 200 mm.

19. The process of claim 11, wherein the copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin further comprise at least one dienic termonomer.

20. The process of claim 12, wherein the copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin further comprise at least one dienic termonomer.

Description

(1) The characteristics and the advantages of the present invention shall be more apparent from the following exemplifying and non-limiting description with reference to the attached schematic drawings wherein:

(2) FIG. 1 is a schematic representation of a half foot sock or invisible socks in the worn condition;

(3) FIG. 2 is a schematic representation of a short sock, also worn;

(4) FIG. 3 is a schematic representation of a pantyhose or thigh high stocks, also worn;

(5) FIG. 4 is a schematic representation of a medical band or brace, also worn;

(6) FIG. 5 is a schematic representation of a jersey.

(7) With reference to the attached figures, a slip-resistant garment, according to the present invention is indicated in its entirety with 1.

(8) The slip-resistant garment according to the present invention is suitable for several uses, mainly in the clothing industry and in the medical textile industry, in particular the stockings industry, underwear industry, containment and shapewear garments industry as well as sports garments industry.

(9) Examples of garments that can be conferred the slip-resistant effect according to the present invention are: long socks, short socks (FIG. 2), pantyhose (FIG. 3), half-foot socks (so-called invisible socks) (FIG. 1), thigh high stocks (FIG. 3), shape-wear or containment garments (e.g. sheaths, girdle, etc.), formal garments (e.g. shirt waist fastener) or, in the sports garments industry, cycling or racing shorts. Further examples of garments that may be conferred slip-resistant effect according to the present invention are fabric braces (FIG. 4), for example for immobilising or supporting joints (e.g. ankle, knee, wrist and elbow).

(10) According to a preferred embodiment, the slip-resistant garment 1 is a half foot sock, commonly referred to as invisible socks.

(11) As observable in FIG. 1, the slip-resistant garment 1 comprises a textile structure 2 which delimits a cavity for engaging a part of the body C of a user U, in the specific case of the lower portion of the foot of the same.

(12) The cavity of the textile structure 2 terminates at an access opening 3 defined by a respective edge 4 of the textile structure 2 which, with reference to the invisible sock illustrated in FIG. 1, is arranged to engage the foot of the user U below the malleolus.

(13) With the aim of guaranteeing stable engagement between the textile structure 2 and the body C of the user U, the slip-resistant garment 1 advantageously comprises at least one slip-resistant portion 5 adapted to engage, preferably directly, the skin of the body C of the user U.

(14) In detail, the slip-resistant portion 5 of the slip-resistant garment 1 is preferably arranged on the textile structure 2 inside the cavity defined thereby so as to directly engage the foot of the user U.

(15) As observable in FIG. 1 the slip-resistant portion 1 is preferably applied to the textile structure 2 at the edge 4 of the access opening 3 to guarantee the stable position thereof during the use of the garment 1.

(16) However, it is not excluded, still for the sake of stability between the garment 1 and the body C of the user U, that the slip-resistant portion 5 be applied in other parts of the cavity of the garment 1.

(17) In addition, it is possible to provide for that the garment 1 be provided with several slip-resistant portions 5 cooperating to increase the stability of the garment 1 with respect to the body C of the user U.

(18) Advantageously, the slip-resistant portion 5 extends along the entire development of the edge 4 of the opening 3 of the garment 1.

(19) Advantageously, the slip-resistant portion is applied to the garment in the form of a continuous layer. However, it is not excluded that the slip-resistant portion can be obtained by applying the slip-resistant polymeric material in a discontinuous manner, i.e. by applying the material on a given portion of the garment (application portion) so as to have a plurality of areas of said application portion covered by said slip-resistant material (slip-resistant areas), each of said slip-resistant areas being adjacent to areas of the same non-slip-resistant application portion.

(20) The slip-resistant portion 5 has a width L sufficient to guarantee a stable engagement between the garment 1 and the body C of the user U, preferably comprised between 1 mm and 50 mm, preferably equivalent to 20 mm.

(21) According to the embodiment solution illustrated in FIG. 2, the slip-resistant garment 1 is a short sock, whose textile structure 2 is quite similar to the textile structure 2 of the slip-resistant garment 1 illustrated in FIG. 1.

(22) Actually, even the textile structure 2 of the short sock of FIG. 2, has a cavity which terminates with an access opening 3 defined by a respective edge 4, arranged to lie at or above the malleolus of the foot of the user U.

(23) Even as regards the embodiment illustrated in FIG. 2, it is possible to identify an identical slip-resistant portion 5.

(24) According to the embodiment solution illustrated in FIG. 3, the slip-resistant garment 1 is a pantyhose or thigh high stockings, whose structural characteristics are similar to the structural characteristics of the garments 1 represented in FIGS. 1 and 2.

(25) Actually, even the slip-resistant garment 1 of FIG. 3 is provided with a textile structure 2 which delimits a cavity for the engagement of the leg of the user U. The cavity terminates with an access opening 3 defined by a respective edge 4 at which there is engaged a slip-resistant portion 5 identical to that of the other embodiments.

(26) According to the embodiment illustrated in FIG. 4, the slip-resistant garment 1 is a medical band or a brace or a similar garment, whose textile structure 2 is substantially tubular-shaped, in that it provides for the introduction, with the complete traversing of the garment 1, of a part of the body C of the user U.

(27) In this case, the textile structure 2, defines a cavity which terminates with two access openings 3, arranged on opposite sides, each of which is defined by a respective edge 4.

(28) As observable in FIG. 4, the garment 1 is provided with at least one slip-resistant portion 5 arranged at a respective access opening 3, preferably of a slip-resistant portion 5 arranged at each of the access openings 3 of the garment 1.

(29) Preferably, the slip-resistant portions 5 of the garment 1 subject of FIG. 4 are identical to the slip-resistant portions provided for on the embodiments subject of FIGS. 1 to 3.

(30) According to the embodiment subject of FIG. 5, the slip-resistant garment 1 is a jersey or a similar garment.

(31) In this case, the textile structure 2 of the garment 1 has three substantially tubular portions 1a, 1b, respectively a central portion 1a and two lateral portions 1b corresponding to sleeves, joined to each other to define a cavity provided with four openings 3, each portion being defined by a respective edge 4 for the insertion of the relative parts of the body of the user.

(32) Still with reference to FIG. 5, the garment 1 is provided with at least one slip-resistant portion 5 arranged at at least one of the openings 3 provided for. Preferably, the garment 1 comprises two slip-resistant portions 5, one for each sleeve.

(33) It is not excluded that the other openings 3 of the garment 1 be provided with a respective slip-resistant portion 5 capable of directly engaging the body of the user.

(34) Each slip-resistant portion 5 may extend along the entire development of the edge 4 of the respective opening 3 (left sleeve 1a) or only along one part of thereof (right sleeve 1a) depending on the type of engagement intended to be established between the textile structure 2 of the garment 1 and the body of the user.

(35) Though the illustrated embodiments refer to particular embodiments of garments, it should be observed that the aforementioned slip-resistant portions 5 may be applied to any type of garment, clothes or wearable items, which provide for areas at direct contact with the body of the users or at contact with an underlying textile substrate (for example, another garment).

(36) Advantageously, the position and conformation of such slip-resistant portions 5 may vary depending on the type of garments on which they should be applied and the friction action intended to be produced between the body of the user and the textile structure of the garment.

(37) According to the present invention, the slip-resistant portion comprises at least one thermoplastic polymer selected from among:

(38) (a) block copolymers of styrene;

(39) (b) copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin (EPR), possibly with at least one dienic termonomer (EPDM);

(40) (c) copolymers of at least one butene with at least one diene, namely saturated or semi-saturated copolymers of the 1-butene, 2-butene or isobutene (butyl rubbers);

(41) (d) copolymers of ethylene with at least one ester having an ethylene unsaturation selected from among: C.sub.1-C.sub.8 alkyl acrylates, C.sub.1-C.sub.8 alkyl methacrylates and vinyl C.sub.2-C.sub.8 carboxylates.

(42) Within the present description and claims, the expression phr (per hundred rubber) is used to indicate the amount of a given component present in the thermoplastic material, expressed in parts per weight with respect to 100 parts by weight of the thermoplastic polymer.

(43) In some applications the thermoplastic polymer may be a cross-linked or partly cross-linked elastomeric material. The degree of the cross-link determines the elastic return performance of the slip-resistant portion.

(44) Preferably, the thermoplastic polymer is a block copolymer of styrene selected from among: styrene/ethylene/butadiene/styrene (SEBS), styrene/ethylene/propylene/styrene (SEPS), styrene/ethylene/butadiene/propylene/styrene (SEBPS), styrene/butadiene/styrene (SBS), styrene/isoprene/styrene (SIS), styrene/isobutylene/styrene (SIBS), or their mixtures.

(45) Even more preferably, the elastomeric material is selected from among SEBS, SEPS, SBS and their mixtures. SEBS and SEPS are particularly preferred, in that the slip-resistant portion which is obtained has a greater resistance to age and yellowing, for example, following exposure to UV rays.

(46) Preferably, the thermoplastic polymer is a copolymer with blocks of styrene having Shore hardness A (measured according to ASTM 2240 or ISO 7619) from 20 to 90, preferably from 35 to 70.

(47) The styrene block copolymers preferably have a styrene content variable between 5% and 50% by weight with respect to the weight of the elastomer more preferably between 8% and 40%, even more preferably between 15% and 35%.

(48) SEBS elastomers particularly adapted for the present invention are available in the market under the trade names Kraton-G (Shell Chemical Co.), Tuftec-H (Asahi Kasei Chemicals Co.), Calprene-H (Dynasol), Europrene SOL TH (Versalis), Septon (Kuraray).

(49) Alternatively, the thermoplastic polymer may be selected from among the copolymers of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin (b). Among these, the following shall be preferred: ethylene-propylene (EPR), ethylene-propylene-diene (EPDM), ethylene-1-butene, ethylene-1-octene and their mixtures.

(50) As regards the copolymers (c)butyl rubbersof at least one butene (e.g. 1-butene, 2-butene or isobutene) with at least one diene, particularly preferred are copolymers from among isobutene and isoprene. In these copolymers isoprene is present preferably at amounts equal to or lesser than 5% by weight, more preferably equal to or less than 3% by weight.

(51) The dienic termonomers possibly present in the copolymers (b) of ethylene with at least one C.sub.3-C.sub.12 alpha-olefin may be conjugated or not conjugated. Said termonomers, may be selected, for example, from among: 1,3-butadiene, 1,4-hexadiene, 1-6-octadiene and the like; monocylic or polycyclic dienes, such as for example 1,4-ciclohexadiene and 5-ethylidene-2-norbornene.

(52) As regards the copolymers (d) of ethylene obtained from the polymerisation of ethylene with at least one ester having an ethylene unsaturation, they are preferably copolymers of ethylene with at least one ester selected from among C.sub.1-C.sub.8 (preferably C.sub.1-C.sub.4) alkyl acrylates, C.sub.1-C.sub.8 (preferably C.sub.1-C.sub.4) alkyl methacrylates, and vinyl C.sub.2-C.sub.8 (preferably C.sub.2-C.sub.6) carboxylates. The amount of ester present in the copolymer is preferably in the range between 5%-50% by weight, preferably 15%-40% by weight.

(53) Examples of C.sub.1-C.sub.8 acrylates and methacrylates are: ethyl acrylate, methyl acrylate, methyl methacrylate, tert-butyl acrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, and the like.

(54) Examples of vinyl C.sub.2-C.sub.8 carboxylates are: vinyl acetate, vinyl propionate, vinyl butyrate, and the like.

(55) Advantageously, the slip-resistant properties of the thermoplastic material according to the present invention, may be modulated according to the application needs, adding to the thermoplastic polymer one or more further compounds.

(56) The properties of the slip-resistant portion according to the present invention may be modulated, for example, by adding to said thermoplastic material one or more hydrocarbon resins. Preferably, the slip-resistant portion comprises from 1 to 50 phr, more preferably from 5 to 30 phr, even more preferably from 5 to 20 phr of at least one hydrocarbon resin. The hydrocarbon resin may be solid or liquid at room temperature. Preferably, the hydrocarbon resin has a maximum softening point not exceeding 150 C., more preferably between 90 C. and 110 C. (measured according to the ASTM E-28 method, Ring-and-ball Softening Point). In the case of liquid hydrocarbon resins, the concentration thereof in the slip-resistant portion is preferably comprised in the range between 1-25 phr.

(57) The hydrocarbon resin, which is a tackifier compound, allows modifying the surface friction of the thermoplastic material of the slip-resistant portion with respect to the surface of the material with which this comes to contact, thus varying the slipping capacity thereof with respect to the latter.

(58) The hydrocarbon resins are generally aliphatic and/or aromatic resins obtained through the polymerisation of hydrocarbon cuts deriving from the oil refinery processes. The resins may be at least partly hydrogenated. They are available in the market for example under the trade names Regalite, Eastotac (Eastman), Norsolene (Total), Escorez (Exxon), ecc.

(59) The slip-resistant portion may further comprise from 10 to 250 phr, preferably from 30 to 120 phr, of at least one plasticiser selected from among: paraffinic oils, naphthenic oils, polyolefin oils and their mixtures. Generally, these are products of petroleum origin, available in the market for example under the trade name Nyflex or Nytex (Nynas), Ondina (Shell), OB (Roloil).

(60) The plasticiser allows modulating the Shore hardness A and the elasticity module of the thermoplastic material, so as to adapt the characteristics of the slip-resistant portion to the softness and extensibility characteristics of the textile structure on which it is applied.

(61) The slip-resistant portion may also comprise from 1 to 50 phr, more preferably from 5 to 30 phr, of at least one polyisobutene (PIB), having preferably an average molecular weight (weight average Mw measured through GPC) from 100 to 2500000, more preferably between 200 and 500000, even more preferably between 800 and 100000. Polyisobutenes useable for the present invention are available in the market under the trade names Oppanol B (Basf), Indopol (Ineos) and Poly Butene (Daelym).

(62) The PIB allows modulating the degree of friction exerted by the slip-resistant portion on the material with which it comes to contact. In addition, the PIB, in combination with the hydrocarbon resin, confers to the slip-resistant portion water repellent characteristics, and thus resistance to washing; furthermore the slip-resistant portion tends to accumulate lower amounts of impurities (e.g. fabric threads, dust, etc.).

(63) By adding suitable amounts of the aforementioned plasticisers, as well as the hydrocarbon and/or polyisobutene resins, also allow regulating the viscosity of the formulate. This is useful, for example, for regulating the degree of sinking of the material which forms the slip-resistant portion in the textile support or the force of adhesion thereof to the same support, in particular upon application through hot pressing.

(64) In order to further facilitate the anchoring of the slip-resistant portion to some textile substrates, the slip-resistant portion may also comprise one or more functionalised olefin polymers, for example with maleic functionalities or the like. Examples of olefin polymers that can be functionalised are polyethylene, polypropylene, EPDM and EVA. Typically, in the polymers having maleic functionalities, such functionalities are comprised in variable percentages in the range between 0.1%-3% by weight, preferably in the range between 0.3%-1.5% by weight with respect to the weight of the functionalised polymer. These polymers are available in the market for example under the trade names Orevac-Lotader (Archema), Exxelor (Exxon), Bynel-Fusabond-Elvaloy (Du Pont), etc.

(65) Preferably, the slip-resistant portion comprises one or more functionalised olefin polymers at an overall amount of 0.5-50 phr.

(66) The slip-resistant portion may also comprise other additives, such as: antioxidants, colouring agents, pigments, UV stabilisers, reinforcing fillers, etc.

(67) The production of the slip-resistant portion according to the present invention may occur according to the conventional techniques in the thermoplastic products processing industry (extruders, blenders, mixers, drawers, dissolvers, etc.). For example, the slip-resistant portion may be produced through mixing at the molten state of the thermoplastic polymer with possibly one or more additives from among those mentioned above, and subsequently extruded, co-extruded, calendared, spread with a doctor blade or moulded in form of a thin layer (film), so as to obtain a thermoplastic product having the desired thickness and from which it is possible to obtain the slip-resistant portion with suitable dimensions and shape.

(68) The thickness of the slip-resistant portion is preferably comprised in the range between 20 micrometers and 5 mm, preferably in the range between 100 micrometers and 0.5 mm. The shape and dimension of the slip-resistant portion may vary as a function of the specific application it is intended for.

(69) In a preferred embodiment, the slip-resistant portion is obtained in form of a tape. The dimensions of the tape may vary within wide intervals as a function of the specific use. For example, the tape may have length in the range between 1 cm-100 cm, more preferably in the range between 10 cm-80 cm, and a width preferably in the range between 0.5 cm-20 cm, more preferably in the range between 1 cm-5 cm.

(70) The tape may be cut into slip-resistant portions with desired shape and dimensions.

(71) One of the main advantages of the slip-resistant portions according to the present invention lies in the fact that they can be directly fixed on the textile structure of the garment intended to be conferred slip-resistant properties by hot pressing the aforementioned slip-resistant portion on the surface of the textile structure. For such purpose there can be used conventional apparatuses, such as for example continuous thermowelding apparatuses, heated pressing plate flat presses or other techniques using similar devices.

(72) The material of the slip-resistant portion may also be deposited on the textile structure in fluid form, through extrusion, and then cooled up to solidification. Further techniques of application of the slip-resistant portions to the textile structures are calendering and spreading with a doctor blade.

(73) In an alternative embodiment, the slip-resistant portion may be applied through the aforementioned techniques on a support substrate (e.g. a TNT, cotton, jersey, Lycra leaf etc.) before being applied to the garment.

(74) The slip-resistant portion together with the support substrate may thus be fixed to the garment in various ways, for example with mechanical means, such as sewing, hemming, or using an adhesive. Possibly, the support substrate may be removed before fixing the slip-resistant portion to the garment.

(75) The present invention shows various advantages with respect to the prior art. The slip-resistant portions according to the present invention are efficient at maintaining the garments on which they are applied in the position in which they are worn, preventing or reducing the slipping thereof on the skin or on other textile substrates.

(76) In particular, when the slip-resistant garment is worn at direct contact with the skin, it remains in the worn position mainly due to friction on the skin exerted by the polymeric material of the slip-resistant portion.

(77) In case of tight garments (e.g. stockings, pantyhose, braces), such a property of the anti-slipping material according to the present invention allows the use of slip-resistant portions which exert a considerably low compression action on the body of the user, though efficiently countering the slipping of the garment, thus avoiding the tourniquet effect.

(78) Given that the material that forms the slip-resistant portion has high elasticity, it can be advantageously applied to elastic garments, without altering the original elastic characteristics of the latter. In addition, the material which forms the slip-resistant portion is characterised by a high resistance to wear and washing, so that the performance characteristics substantially last unaltered over the entire useful life of the garment.

(79) Being made of a silicone polymer-free material, the slip-resistant garments according to the present invention may also be worn by people allergic or hypersensitive to these materials.

(80) In addition, when applied to the garments in the form of a continuous, flat and low thickness layer, the slip-resistant portions have surfaces that are very smooth and substantially without harshness. The absence of harshness reduces skin irritation even when the slip-resistant garment is used for performing long duration activities or activities that imply considerable sweating. In addition, such characteristics of the slip-resistant portion allow obtaining high quality slip-resistant garments in that the fixing thereof to the textile structure does not considerably alter the initial characteristics of the garment (e.g. hand and thickness).

(81) In addition, the slip-resistant properties of the slip-resistant portion according to the present invention may be advantageously modulated as a function of the application needs of the slip-resistant portion.

(82) The processes for manufacturing and fixing of the slip-resistant material according to the present invention to the garments are extremely simple to obtain and does not produce bad smelling or hazardous emissions, like it instead occurs in the processes for manufacturing the silicone slip-resistant materials.

(83) The following examples are provided solely for the sake of exemplification of the present invention and thus they shall not be deemed as limiting with respect to the scope of protection defined by the attached claims.

EXAMPLES

(84) Through a co-rotating twin-screw mixer, there were prepared the polymer compositions as indicated in Table 1 (amounts expressed in phr):

(85) TABLE-US-00001 TABLE 1 Sample 1 Sample 2 Sample 3 phr wt % phr wt % phr wt % Europrene SOL TH 31 11.7 31 11.7 32.7 11.7 2315 .sup.(1) Kraton G1651 .sup.(1) 69 26 69 26 67.3 24 Nytex 820 .sup.(2) 164 62 151 57 140 50 Indopol H-1200 .sup.(3) 13.3 5 Eastotac H-100W.sup.(4) 39 14 Irganox 1010 .sup.(5) 0.8 0.3 0.8 0.3 0.8 0.3 .sup.(1) copolymer SEBS (about 32% by weight of bounded styrene); .sup.(2) paraffinic/naphthenic oil; .sup.(3) polyisobutene (medium molecular weight M.sub.w equivalent to 2100 g/mol); .sup.(4) hydrogenated hydrocarbon resin, having a softening point (measured according to the ASTM method E-28, Ring-and-ball Softening Point) = 100 C.; .sup.(5) sterically hindered primary phenolic antioxidant.

(86) Each of the three formulations of Table 1 was extruded in form of a tape with thickness equivalent to about 200 m. From the tape there were obtained specimens measuring about 8080 mm.

(87) On each of the Samples 1-3 there were determined, the coefficient of static and dynamic friction and the average dynamic load according to the ASTM D1894-11 method, evaluating the slipping friction, over a metal surface, of a slide of pre-established dimensions and weight, whose slipping base was previously covered by each of the specimens prepared previously. The results are indicated in Table 2.

(88) On each of the three samples it was further determined the percentage value of elongation at break, the modulus of elongation for a 100% and 300% extension according to the UNI EN ISO 527-3/2/200 method. The results are indicated in Table 3.

(89) TABLE-US-00002 TABLE 2 Coefficient Coefficient Average Sample of static of dynamic dynamic load No friction friction (N) 1 4.30 3.98 8.78 2 5.03 4.52 9.71 3 6.79 5.26 13.86

(90) TABLE-US-00003 TABLE 3 Modulus of Modulus of Elongation elongation elongation Sample at break 100% 300% No (%) (MPa) (MPa) 1 1080 0.22 0.36 2 1012 0.29 0.41 3 958 0.33 0.56

(91) The experimental results confirm that the materials according to the present invention have an optimal coefficient of static and dynamic friction for use as slip-resistant portion for preventing the slipping of garments on the skin or textile substrates.

(92) In addition, the elastic properties of these materials are such to allow the use also on elastic textile substrates.

(93) In addition, the friction, and thus the slip-resistant properties, may be modulated according to the application needs, as shown by the increase of the friction value with respect to sample 1 (which can for example be used for stockings and pantyhose) which can be obtained by addition of polyisobutene or hydrocarbon resins (samples 2 and 3, which can for example be used for sports attire and braces in the medical industry) in the formulation.