Seamless steel tube for fuel injection

Abstract

A seamless steel tube has a particular composition and a structure with an average prior grain size of 150 m or less in an axial cross-section after cold drawing and heat treatment. The structure retards the growth of a fatigue crack. The steel tube has a tensile strength TS of 500 MPa or more and good internal pressure fatigue resistance and is suitable for use as a fuel injection tube under high injection pressures. The composition of the steel tube may further contain at least one of Cu, Ni, Cr, Mo, and B; at least one of Ti, Nb, and V; and/or Ca.

Claims

1. A seamless steel tube for fuel injection having a composition comprising, by mass, 0.155% to 0.21% C, 0.01% to 0.49% Si, 1.20% to 2.1% Mn, 0.005% to 0.25% Al, and 0.0010% to 0.010% N and containing, as impurities, 0.030% or less P, 0.025% or less S, and 0.005% or less O, the balance being Fe and incidental impurities, the composition satisfying condition (1):
[Al %][N %]2710.sup.5(1) wherein Al % and N % are the contents (% by mass) of Al and N, respectively, the steel tube having a structure with an average prior grain size of 150 m or less in an axial cross-section after cold drawing and heat treatment, and a tensile strength TS of 500 MPa or more.

2. The seamless steel tube according to claim 1, wherein the composition further comprises, by mass, at least one of 0.70% or less Cu, 1.00% or less Ni, 1.20% or less Cr, 0.50% or less Mo, and 0.0060% or less B.

3. The seamless steel tube according to claim 1, wherein the composition further comprises, by mass, at least one of 0.20% or less Ti, 0.050% or less Nb, and 0.20% or less V.

4. The seamless steel tube according to claim 2, wherein the composition further comprises, by mass, at least one of 0.20% or less Ti, 0.050% or less Nb, and 0.20% or less V.

5. The seamless steel tube according to claim 1, wherein the composition further comprises, by mass, 0.0040% or less Ca.

6. The seamless steel tube according to claim 2, wherein the composition further comprises, by mass, 0.0040% or less Ca.

7. The seamless steel tube according to claim 3, wherein the composition further comprises, by mass, 0.0040% or less Ca.

8. The seamless steel tube according to claim 4, wherein the composition further comprises, by mass, 0.0040% or less Ca.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a graph showing the effect of prior grain size on internal pressure fatigue strength.

(2) FIG. 2 is a graph showing the effect of [Al %][N %] on prior grain size.

DETAILED DESCRIPTION

(3) The term good internal pressure fatigue resistance refers to an endurance ratio of 30% or more, which is the ratio /TS of stress to tensile strength TS. Preferably, the endurance ratio is 35% or more. The stress is calculated by the following equation:
=inner diameter (mm)internal pressure fatigue strength (MPa)/(2wall thickness) (mm)
where the inner diameter and the wall thickness are the target inner diameter and wall thickness, respectively, of the fuel injection tube.

(4) Test specimens were taken from steel tubes (34 mm in outer diameter and 25 mm in inner diameter) containing, by mass, about 0.17% C, about 0.26% Si, about 1.27% Mn, about 0.03% Cr, about 0.013% Ti, about 0.036% Nb, about 0.037% V, about 0.004% to 0.30% Al, and about 0.0005% to 0.011% N. The test specimens were repeatedly cold-drawn to obtain as-drawn tubes (6.4 mm in outer diameter and 3.0 mm in inner diameter). The as-drawn tubes were heat-treated (heated to 1,000 C. and then allowed to cool) to obtain steel tubes with a tensile strength TS of 560 MPa. The resulting steel tubes had prior grain sizes (average prior grain sizes) of 80 to 200 m in an axial cross-section. These steel tubes were subjected to an internal pressure fatigue test.

(5) In the internal pressure fatigue test, the internal pressure fatigue strength was determined as the maximum internal pressure at which no fatigue failure occurred after a sinusoidal pressure (minimum internal pressure: 18 MPa, maximum internal pressure: 250 to 190 MPa) was applied for 10.sup.7 cycles.

(6) The results are shown in FIG. 1 as the relationship between internal pressure fatigue strength and prior grain size. As can be seen from FIG. 1, smaller prior grain sizes result in higher internal pressure fatigue strengths. Examination of the growth behavior of a fatigue crack initiated from an inclusion also revealed that even a fatigue crack initiated from an inclusion with a maximum diameter of more than 20 m does not substantially grow and becomes non-propagating if the prior grain size is 150 m or less (plots for compositions within the scope of the disclosure lie in a range of prior grain sizes of 150 m or less).

(7) Although the mechanism has yet to be fully understood, we believe that the following mechanism applies.

(8) A crack (fatigue crack) grows while breaking the material at the tip thereof under repeated stress perpendicular to the crack growth direction. Due to the repeated stress, the material generally hardens around the tip of the crack and breaks without being substantially elongated. The material, however, may deform to some extent before breaking if the hardened zone around the tip of the crack is small. The deformed, elongated region around the tip of the crack closes the crack and retards the growth thereof so that it may become non-propagating, i.e., stop propagating. If the material has a fine structure with a prior grain size of 150 m or less, the hardened zone around the tip of the crack becomes smaller since the stress transferred to the surrounding region is reduced by factors such as subgrain boundaries, grain boundaries, crystal misorientations, and precipitates. This facilitates deformation in the breaking zone during crack growth and thus increases the amount of elongation so that the crack is more likely to become non-propagating.

(9) However, heat treatment after cold drawing tends to coarsen grains. Accordingly, we used Test Specimens B to Q of the Examples in Table 1 and discovered that, to achieve a small prior grain size, i.e., 150 m or less, after cold drawing and heat treatment, it is necessary to control the Al content and the N content to proper ranges and to control [Al %][N %] to a proper range.

(10) FIG. 2 shows the relationship between prior grain size and [Al %][N %]. As can be seem from FIG. 2, [Al %][N %] needs to be controlled to 2710.sup.5 or less to achieve a prior grain size of 150 m or less (plots for compositions within the scope of the disclosure lie in a range of [Al %][N %] of 2710.sup.5 or less). Preferably, [Al %][N %] is 210.sup.5 or more.

(11) Our seamless steel tube for fuel injection (herein also referred to as seamless steel tube) has a composition containing, by mass, 0.155% to 0.38% C, 0.01% to 0.49% Si, 0.6% to 2.1% Mn, 0.005% to 0.25% Al, and 0.0010% to 0.010% N and containing, as impurities, 0.030% or less P, 0.025% or less S, and 0.005% or less O, the balance being Fe and incidental impurities. The composition satisfies [Al %][N %]2710.sup.5 (where Al % and N % are the contents (% by mass) of Al and N, respectively).

(12) The seamless steel tube also has a structure with a prior grain size of 150 m or less in an axial cross-section after cold drawing and heat treatment.

(13) The seamless steel tube also has a tensile strength TS of 500 MPa or more.

(14) The reasons for the limitations on the composition of the seamless steel tube will now be described, where percentages are by mass unless otherwise indicated.

(15) C: 0.155% to 0.38%

(16) C is an element that increases the strength of the steel tube by dissolving, precipitating, and improving hardenability. To achieve the desired high hardness through these effects, C needs to be present in an amount of 0.155% or more. A C content exceeding 0.38%, however, deteriorates the hot workability and makes it difficult to form a steel tube of predetermined size and shape. The C content is therefore limited to 0.155% to 0.38%. A preferred C content is 0.16% to 0.21%.

(17) Si: 0.01% to 0.49%

(18) Si is an element that serves as a deoxidizer. Si needs to be present in an amount of 0.01% or more to achieve this effect. A Si content exceeding 0.49%, however, has no further effect and is economically disadvantageous. The Si content is therefore limited to 0.01% to 0.49%. A preferred Si content is 0.15% to 0.35%.

(19) Mn: 0.6% to 2.1%

(20) Mn is an element that increases the strength of the steel tube by dissolving and improving hardenability. Mn needs to be present in an amount of 0.6% or more to achieve the desired high hardness through these effects. A Mn content exceeding 2.1%, however, promotes segregation and thus deteriorates the toughness of the steel tube. The Mn content is therefore limited to 0.6% to 2.1%. A preferred Mn content is 1.20% to 1.40%.

(21) Al: 0.005% to 0.25%

(22) Al is an element that serves as a deoxidizer and also contributes effectively to the refinement of crystal grains, particularly grains, by combining with N to precipitate AlN, which refines the crystal grains and thereby improves the internal pressure fatigue resistance. Al needs to be present in an amount of 0.005% or more to achieve these effects. An Al content exceeding 0.25%, however, coarsens AlN precipitates. Such precipitates cannot refine the crystal grains to the desired level and thus cannot provide the desired high toughness and good internal pressure fatigue resistance. A preferred Al content is 0.015% to 0.050%.

(23) N: 0.0010% to 0.010%

(24) N is an element that contributes effectively to the refinement of crystal grains, particularly grains, by combining with Al to precipitate AlN, which refines the crystal grains and thereby improves the internal pressure fatigue resistance. N needs to be present in an amount of 0.0010% or more to achieve this effect. A N content exceeding 0.010%, however, coarsens AlN precipitates. Such precipitates cannot refine the crystal grains to the desired level. The N content is therefore limited to 0.0010% to 0.010%. A N content of 0.0020% to 0.0050% is preferred for reasons of age hardening, which deteriorates the cold drawability.
[Al %][N %]2710.sup.5(1)

(25) Satisfying condition (1) by controlling the product of the Al content [Al %] and the N content [N %] ([Al %][N %]) reduces the prior grain size to a predetermined level or lower and thus improves the toughness and internal pressure fatigue resistance of the steel tube. A value of [Al %][N %] exceeding 2710.sup.5, which does not satisfy condition (1), coarsens AlN precipitates. Such precipitates are less effective in refining the crystal grains and thus cannot provide the desired internal pressure fatigue resistance. The Al content [Al %] and the N content [N %] are therefore controlled so that [Al %][N %] satisfies condition (1). A preferred value of [Al %][N %] is 2010.sup.5 or less.

(26) The composition of the seamless steel tube contains, as impurities, 0.030% or less P, 0.025% or less S, and 0.005% or less O.

(27) It is desirable to minimize the contents of P, S, and O, which are detrimental to hot workability and toughness. 0.030% or less P, 0.025% or less S, and 0.005% or less O can be tolerated. The contents of P, S, and O, which are impurities, are therefore controlled as follows: the P content is 0.030% or less, the S content is 0.025% or less, and the O content is 0.005% or less.

(28) In addition to the basic constituents described above, the composition of the seamless steel tube may optionally contain at least one of 0.70% or less Cu, 1.00% or less Ni, 1.20% or less Cr, 0.50% or less Mo, and 0.0060% or less B; at least one of 0.20% or less Ti, 0.050% or less Nb, and 0.20% or less V; and/or 0.0040% or less Ca.

(29) At Least One of 0.70% or Less Cu, 1.00% or Less Ni, 1.20% or Less Cr, 0.50% or Less Mo, and 0.0060% or Less B

(30) Cu, Ni, Cr, Mo, and B are elements that contribute to increased strength by improving hardenability. At least one of these elements may optionally be added.

(31) Cu is an element that contributes to improved toughness in addition to increased strength and may optionally be added. A Cu content of 0.03% or more is preferred to achieve these effects. Cu needs to be present in an amount of 0.10% or more to achieve sufficient effectiveness. A Cu content exceeding 0.70% deteriorates the hot workability and also increases the residual content and thus decreases the strength. If Cu is added, therefore, the Cu content is preferably limited to 0.03% to 0.70%. A more preferred Cu content is 0.20% to 0.60%.

(32) Ni is an element that contributes to improved toughness in addition to increased strength and may optionally be added. Ni needs to be present in an amount of 0.10% or more to achieve these effects. In view of this, a Ni content of 0.10% or more is preferred. A Ni content exceeding 1.00% increases the residual content and thus decreases the strength. If Ni is added, therefore, the Ni content is preferably limited to 0.10% to 1.00%. A more preferred Ni content is 0.20% to 0.60%.

(33) Cr is an element that contributes to increased strength and may optionally be added. A Cr content of 0.02% or more is preferred to achieve this effect. Cr needs to be present in an amount of 0.1% or more to achieve sufficient effectiveness. A Cr content exceeding 1.20% results in formation of extremely coarse carbonitrides and may thus decrease the fatigue strength of the seamless steel tube, even though the steel tube is less susceptible to coarse precipitates and inclusions. If Cr is added, therefore, the Cr content is preferably limited to 0.02% to 1.20%. A more preferred Cr content is 0.02% to 0.40%.

(34) Mo is an element that contributes to improved toughness in addition to increased strength and may optionally be added. Mo needs to be present in an amount of 0.03% or more to achieve these effects. A Mo content of 0.03% or more is preferred. A Mo content exceeding 0.50% results in formation of extremely coarse carbonitrides and may thus decrease the fatigue strength of the seamless steel tube even though the steel tube is less susceptible to coarse precipitates and inclusions. If Mo is added, therefore, the Mo content is preferably limited to 0.03% to 0.50%. A more preferred Mo content is 0.04% to 0.35%.

(35) B is an element that contributes to improved hardenability even when present in very small amounts and may optionally be added. B needs to be present in an amount of 0.0005% or more to achieve this effect. A B content of 0.0005% or more is preferred. A B content exceeding 0.0060% has no further effect and may deteriorate hardenability. If B is added, therefore, the B content is preferably limited to 0.0005% to 0.0060%. A more preferred B content is 0.0010% to 0.0030%.

(36) At Least One of 0.20% or Less Ti, 0.050% or Less Nb, and 0.20% or Less V

(37) Ti, Nb, and V are elements that contribute to increased strength by precipitation strengthening. At least one of these elements may optionally be added.

(38) Ti is an element that contributes to improved toughness in addition to increased strength and may optionally be added. Ti needs to be present in an amount of 0.005% or more to achieve these effects. A Ti content of 0.005% or more is preferred. A Ti content exceeding 0.20% results in formation of extremely coarse carbonitrides and may thus decrease the fatigue strength of the seamless steel tube even though the steel tube is less susceptible to coarse precipitates and inclusions. If Ti is added, therefore, the Ti content is preferably limited to 0.005% to 0.20%. A more preferred Ti content is 0.005% to 0.020%.

(39) Nb, as with Ti, is an element that contributes to improved toughness in addition to increased strength and may optionally be added. Nb needs to be present in an amount of 0.005% or more to achieve these effects. An Nb content of 0.005% or more is preferred. A Nb content exceeding 0.050% results in formation of extremely coarse carbonitrides and may thus decrease the fatigue strength of the seamless steel tube even though the steel tube is less susceptible to coarse precipitates and inclusions. If Nb is added, therefore, the Nb content is preferably limited to 0.005% to 0.050%. A more preferred Nb content is 0.020% to 0.050%.

(40) V is an element that contributes to increased strength and may optionally be added. V needs to be present in an amount of 0.005% or more to achieve this effect. A V content of 0.005% or more is preferred. A V content exceeding 0.20% results in formation of extremely coarse carbonitrides and may thus decrease the fatigue strength of the seamless steel tube even though the steel tube is less susceptible to coarse precipitates and inclusions. If V is added, therefore, the V content is preferably limited to 0.005% to 0.20%. A more preferred V content is 0.025% to 0.060%.

(41) Ca: 0.0040% or Less

(42) Ca is an element that contributes to the morphology control of inclusions and may optionally be added.

(43) Ca is an element that contributes to improved ductility, toughness, and corrosion resistance by controlling the morphology of inclusions so that they are finely dispersed. Ca needs to be present in an amount of 0.0005% or more to achieve this effect. A Ca content of 0.0005% or more is preferred. A Ca content exceeding 0.0040% results in formation of extremely coarse inclusions and may thus decrease the fatigue strength of the seamless steel tube even though the steel tube is less susceptible to coarse precipitates and inclusions. Such a high Ca content may also deteriorate the corrosion resistance. If Ca is added, therefore, the Ca content is preferably limited to 0.0005% to 0.0040%. A more preferred Ca content is 0.0005% to 0.0015%.

(44) In addition to the constituents described above, the balance is Fe and incidental impurities.

(45) The structure of the seamless steel tube will now be described.

(46) The seamless steel tube, which has the composition described above, has a structure composed of at least one of ferrite, pearlite, bainitic ferrite (including acicular ferrite), bainite, and martensite phase (including tempered martensite) with a prior grain size of 150 m or less in an axial cross-section after cold drawing and heat treatment.

(47) The prior grain size is limited to 150 m or less, which means a fine structure. Such a fine structure improves the internal pressure fatigue resistance since an internal pressure fatigue crack grows slowly through the structure and may become non-propagating, i.e., stop propagating. A prior grain size exceeding 150 m coarsens the structure and thus deteriorates the internal pressure fatigue resistance. The prior grain size is therefore limited to 150 m or less. A preferred prior grain size is 100 m or less.

(48) The prior grain size is determined in accordance with JIS G 0511 as follows. The prior grain size of a structure composed of bainitic ferrite phase (including acicular ferrite phase), bainite phase, or martensite phase (including tempered martensite) is determined by etching the structure with a saturated aqueous picric acid solution and examining the revealed structure. The prior grain size of a structure where ferrite-pearlite structure and proeutectoid ferrite are observed is determined by etching the structure with nital and measuring the cell size of the revealed ferrite network.

(49) A preferred method of manufacturing the seamless steel tube will now be described.

(50) The seamless steel tube is manufactured using a steel tube material having the composition described above as a starting material. The steel tube material used may be manufactured by any process, and any common process may be used. For example, a molten steel having the composition described above is preferably prepared by a common melting process such as using a steel making converter or vacuum melting furnace and then cast into a semi-finished product (steel tube material) such as a round billet by a common casting process such as continuous casting. Alternatively, the steel tube material may be manufactured by hot-working a continuously cast semi-finished product to the desired size and shape. It should also be understood that the steel tube material may be manufactured by ingot casting and cogging.

(51) The resulting steel tube material is preferably heated, pierced and elongated through a Mannesmann plug mill type or Mannesmann mandrel mill type rolling mill, and optionally subjected to a process such as sizing through a stretch reducer to form a seamless steel tube of predetermined size.

(52) For piercing and elongating, the steel tube material is preferably heated to 1,100 C. to 1,300 C.

(53) A steel tube material heated below 1,100 C. has high deformation resistance and is thus difficult to pierce or cannot be pierced to a suitable size. A steel tube material heated above 1,300 C. gives a low manufacturing yield due to increased oxidation loss and also has poor properties due to coarse crystal grains. A heating temperature preferred for piercing is therefore 1,100 C. to 1,300 C. A more preferred heating temperature is 1,150 C. to 1,250 C.

(54) In the tube-forming process, the steel tube material is pierced and elongated through a common Mannesmann plug mill type or Mannesmann mandrel mill type rolling mill and then optionally subjected to a process such as sizing through a stretch reducer to form a seamless steel tube of predetermined size. Alternatively, the steel tube material may be hot-extruded through a press to form a seamless steel tube.

(55) The resulting seamless steel tube is optionally repeatedly subjected to a process such as cold drawing to a predetermined size and then heat-treated to obtain a seamless steel tube having the desired high tensile strength, i.e., 500 MPa or more. Prior to cold drawing, the as-formed tube is preferably subjected to a process such as boring to remove initial surface defects. The inner surface of the cold-drawn tube is preferably subjected to a process such as chemical polishing to remove surface defects such as wrinkles resulting from cold drawing.

(56) In the heat treatment process, the steel tube may be normalized or hardened and tempered to achieve a predetermined strength.

(57) In the normalizing process, the steel tube is preferably heated to 850 C. to 1,150 C. for 30 minutes or less and then cooled at a cooling rate similar to that of air cooling, i.e., about 2 C./sec. to 5 C./sec. A heating temperature below 850 C. does not give the desired strength. A high heating temperature above 1,150 C. and a long heating time exceeding 30 minutes coarsen the crystal grains and thus decrease the fatigue strength.

(58) In the hardening process, the steel tube is preferably heated to 850 C. to 1,150 C. for 30 minutes or less and then cooled at a cooling rate exceeding 5 C./sec. A hardening heating temperature below 850 C. does not give the desired high strength. A high heating temperature above 1,150 C. and a long heating time exceeding 30 minutes may coarsen the crystal grains and may thus decrease the fatigue strength.

(59) In the tempering process, the steel tube is preferably heated to the Ac.sub.1 transformation temperature or lower, more preferably 450 C. to 650 C., and then air-cooled. A tempering temperature exceeding the Ac.sub.1 transformation temperature does not stably give the desired properties. To achieve a high strength of 780 MPa or more, the steel tube is preferably hardened and tempered.

(60) The heat treatment conditions are properly controlled to achieve a prior grain size of 150 m or less. As discussed above, heat treatment following repeated cold drawing tends to coarsen grains, unlike simple heat treatment of hot-rolled or cold-rolled sheets. There would therefore be no proper heat treatment conditions unless the chemical composition is properly controlled.

EXAMPLES

(61) Steel tube materials having the compositions shown in Table 1 were heated to 1,150 C. to 1,250 C., pierced and elongated through a Mannesmann mandrel mill type rolling mill, and sized through a stretch reducer to form seamless steel tubes (34 mm in diameter and 25 mm in inner diameter). These seamless steel tubes were repeatedly cold-drawn to form cold-drawn steel tubes (6.4 mm in outer diameter and 3.0 mm in inner diameter). The resulting cold-drawn steel tubes were heat-treated as shown in Table 2.

(62) Test specimens were taken from the resulting seamless steel tubes (cold-drawn steel tubes) and subjected to structural examination, a tensile test, and an internal pressure fatigue test. The test procedures are as follows.

(63) (1) Structural Examination

(64) Test specimens for structural examination were taken from the resulting steel tubes. These test specimens were polished so that they could be examined in a cross-section perpendicular to the axial direction (axial cross-section) and were etched with an etchant (saturated aqueous picric acid solution or nital) in accordance with JIS G 0511. The revealed structure was observed and imaged under an optical microscope (at 200 magnification). The image was analyzed to calculate the average prior grain size of the steel tube. Nos. 1 to 17 and Nos. 20 to 26 were etched with a saturated aqueous picric acid solution. Nos. 18 and 19 were etched with nital, and the prior grain size was determined as the cell size of the ferrite network.

(65) (2) Tensile Test

(66) JIS No. 11 test specimens were taken from the resulting steel tubes so that they could be pulled in the axial direction. These test specimens were subjected to a tensile test in accordance with JIS Z 2241 to determine the tensile properties (tensile strength TS).

(67) (3) Internal Pressure Fatigue Test

(68) Test specimens (tubes) for an internal pressure fatigue test were taken from the resulting steel tubes. These test specimens were subjected to an internal pressure fatigue test. In the internal pressure fatigue test, the internal pressure fatigue strength was determined as the maximum internal pressure at which no failure occurred after a sinusoidal pressure (internal pressure) was applied to the interior of the tube for 10.sup.7 cycles. The sinusoidal pressure (internal pressure) had a minimum internal pressure of 18 MPa and a maximum internal pressure of 250 to 190 MPa.

(69) The results are summarized in Table 2.

(70) TABLE-US-00001 TABLE 1 Steel Chemical composition (% by mass) No. C Si Mn Al N P S O [Al %] [N %] A 0.17 0.26 1.27 0.030 0.0032 0.014 0.002 0.0016 10 10.sup.5 B 0.17 0.26 1.28 0.004 0.0030 0.016 0.003 0.0015 1 10.sup.5 C 0.17 0.27 1.28 0.005 0.0031 0.016 0.004 0.0017 2 10.sup.5 D 0.17 0.26 1.27 0.015 0.0030 0.014 0.004 0.0014 5 10.sup.5 E 0.17 0.26 1.27 0.035 0.0033 0.017 0.001 0.0017 12 10.sup.5 F 0.18 0.27 1.27 0.050 0.0032 0.015 0.003 0.0013 16 10.sup.5 G 0.17 0.26 1.27 0.060 0.0033 0.016 0.002 0.0014 20 10.sup.5 H 0.18 0.26 1.28 0.250 0.0010 0.015 0.002 0.0016 25 10.sup.5 I 0.18 0.27 1.27 0.300 0.0010 0.017 0.002 0.0017 30 10.sup.5 J 0.17 0.26 1.28 0.030 0.0005 0.015 0.002 0.0017 2 10.sup.5 K 0.18 0.26 1.28 0.030 0.0010 0.016 0.003 0.0017 3 10.sup.5 L 0.17 0.27 1.27 0.030 0.0022 0.013 0.003 0.0013 7 10.sup.5 M 0.17 0.27 1.28 0.032 0.0040 0.015 0.001 0.0013 13 10.sup.5 N 0.17 0.26 1.28 0.029 0.0049 0.016 0.001 0.0017 14 10.sup.5 O 0.17 0.27 1.28 0.027 0.0100 0.013 0.003 0.0014 27 10.sup.5 P 0.17 0.26 1.28 0.043 0.0068 0.015 0.003 0.0014 29 10.sup.5 Q 0.18 0.27 1.27 0.030 0.0110 0.016 0.001 0.0014 33 10.sup.5 R 0.08 0.26 1.28 0.030 0.0030 0.015 0.004 0.0016 9 10.sup.5 S 0.17 0.26 0.50 0.030 0.0030 0.017 0.004 0.0015 9 10.sup.5 T 0.17 0.27 2.20 0.030 0.0030 0.015 0.002 0.0014 9 10.sup.5 U 0.16 0.15 1.45 0.028 0.0032 0.014 0.004 0.0015 9 10.sup.5 V 0.21 0.44 1.44 0.034 0.0030 0.016 0.005 0.0014 10 10.sup.5 W 0.18 0.34 1.47 0.030 0.0043 0.014 0.003 0.0017 13 10.sup.5 X 0.13 0.29 1.46 0.036 0.0046 0.014 0.001 0.0015 17 10.sup.5 Y 0.23 0.28 1.57 0.015 0.0076 0.013 0.003 0.0013 11 10.sup.5 Z 0.18 0.21 0.75 0.035 0.0076 0.016 0.005 0.0015 27 10.sup.5 Steel Chemical composition (% by mass) No. Cu, Ni, Cr. Mo, B Ti, Nb. V Ca Remarks A Example B Cr: 0.04, Ti: 0.013, Nb: 0.036, V: 0.037 Comparative Example C Cr: 0.04, Ti: 0.014, Nb: 0.036, V: 0.036 Example D Cr: 0.04, Ti: 0.014, Nb: 0.035, V: 0.036 Example E Cr: 0.03, Ti: 0.014, Nb: 0.036, V: 0.036 Example F Cr: 0.03, Ti: 0.014, Nb: 0.037, V: 0.038 Example G Cr: 0.04, Ti: 0.013, Nb: 0.035, V: 0.036 Example H Cr: 0.03, Ti: 0.014, Nb: 0.035, V: 0.038 Example I Cr: 0.04, Ti: 0.013, Nb: 0.036, V: 0.038 Comparative Example J Cr: 0.04, Ti: 0.014, Nb: 0.036, V: 0.037 Comparative Example K Cr: 0.04, Ti: 0.013, Nb: 0.036, V: 0.036 Example L Cr: 0.04, Ti: 0.014, Nb: 0.036, V: 0.036 Example M Cr: 0.03, Ti: 0.014, Nb: 0.036, V: 0.038 Example N Cr: 0.03, Ti: 0.013, Nb: 0.035, V: 0.037 Example O Cr: 0.04, Ti: 0.014, Nb: 0.035, V: 0.037 Example P Cr: 0.03, Ti: 0.014, Nb: 0.036, V: 0.038 Comparative Example Q Cr: 0.04, Ti: 0.014, Nb: 0.035, V: 0.037 Comparative Example R Cr: 0.03, Ti: 0.014, Nb: 0.037, V: 0.037 Comparative Example S Cr: 0.04, Ti: 0.014, Nb: 0.036, V: 0.037 Comparative Example T Cr: 0.04, Ti: 0.014, Nb: 0.036, V: 0.036 Comparative Example U Cu: 0.42, Ni: 0.37 Ti: 0.012, V: 0.067 Example V Cr: 0.28, Ti: 0.010, V: 0.084 Example W Mo: 0.18, B: 0.0056 Ti: 0.023, V: 0.063 Example X Cu: 0.03, V: 0.046 0.0013 Example Ni: 0.10, Cr: 0.05 Y B: 0.0029 V: 0.148 0.0016 Example Z Cr: 0.97, Mo: 0.18 Example

(71) TABLE-US-00002 TABLE 2 Heat treatment Normalizing Hardening Tempering Heating Heating Heating Steel temper- Holding temper- Holding temper- Holding tube Steel ature time ature time ature time No. No. ( C.) (min) ( C.) (sec) ( C.) (min) 1 A 1000 600 500 20 2 B 1000 8 3 C 1000 8 4 D 1000 8 5 E 1000 8 6 F 1000 8 7 G 1000 8 8 H 1000 8 9 I 1000 8 10 J 1000 8 11 K 1000 8 12 L 1000 8 13 M 1000 8 14 N 1000 8 15 O 1000 8 16 P 1000 8 17 Q 1000 8 18 R 1000 8 19 S 1000 8 20 T 1000 8 21 U 1100 20 22 V 900 20 23 W 1150 1 450 20 24 X 850 30 25 Y 1000 20 26 Z 1000 600 450 20

(72) TABLE-US-00003 TABLE 3 Structure Tensile Internal pressure Prior properties fatigue resistance Steel Type of grain Tensile Internal pres- tube Steel main size strength sure fatigue /TS No. No. phase* (m) TS (MPa) strength (MPa) ** (%) Remarks 1 A M 90 780 334 295 37.8 Example 2 B BF 200 564 190 168 29.7 Comparative Example 3 C BF 150 562 230 203 36.1 Example 4 D BF 100 561 230 203 36.2 Example 5 E BF 90 562 240 212 37.7 Example 6 F BF 100 561 230 203 36.2 Example 7 G BF 120 561 230 203 36.2 Example 8 H BF 140 563 230 203 36.0 Example 9 I BF 200 564 180 159 28.1 Comparative Example 10 J BF 180 562 180 159 28.2 Comparative Example 11 K BF 120 563 230 203 36.1 Example 12 L BF 100 562 230 203 36.1 Example 13 M BF 90 563 240 212 37.6 Example 14 N BF 100 561 230 203 36.2 Example 15 O BF 150 563 230 203 36.0 Example 16 P BF 190 563 180 159 28.2 Comparative Example 17 Q BF 210 562 180 159 28.3 Comparative Example 18 R F + P 90 370 159 140 37.8 Comparative Example 19 S F + P 90 370 159 140 37.8 Comparative Example 20 T BF 90 495 212 187 37.8 Comparative Example 21 U BF 90 560 240 212 37.8 Example 22 V BF 90 565 240 212 37.5 Example 23 W M 90 980 420 371 37.8 Example 24 X B 90 910 380 335 36.8 Example 25 Y B 90 908 380 335 36.9 Example 26 Z M 90 905 380 335 37.0 Example *M: martensite, B: bainite, BF: bainitic ferrite, F: ferrite, P: pearlite ** = inner diameter internal pressure fatigue strength/(2 wall thickness), where the inner diameter is 3.0 mm and the wall thickness is 1.7 mm.

(73) The seamless steel tubes of all our Examples had high strength, i.e., tensile strengths TS of not less than 500 MPa, and good internal pressure fatigue resistance, i.e., endurance ratios (/TS) of not less than 30%, which are sufficient for use as steel tubes for fuel injection in diesel engines. In contrast, the seamless steel tubes of the Comparative Examples had a tensile strength of less than 500 MPa or an internal pressure fatigue resistance /TS of less than 30%.