Method for preparing aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite

Abstract

The present invention relates to a method for preparing an aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite, where the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is prepared with an aluminum alloy serving as a matrix and with aluminum-copper-iron quasicrystal and silicon carbide serving as reinforcement agents via smelting in an intermediate-frequency induction melting furnace through the process of intermediate-frequency induction heating, vacuumizing, bottom blowing argon, and casting molding in view of low hardness and low tensile strength of aluminum matrix materials. The prepared aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite has a hardness of 80.3 HB which is improved by 50.64% and tensile strength of 285 Mpa which is improved by 60.42%, and corrosion resistance thereof is improved by 40%.

Claims

1. A method of preparing an aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite, comprising chemical materials, with gram, milliliter and cubic centimeter as a unit of measurement, including 3800 g1 g of aluminum alloy which is ZAlSi.sub.7Mg and a solid bulk, 50 g1 g of aluminum-copper-iron quasicrystal which is Al.sub.63Cu.sub.25Fe.sub.12 and solid particles, 50 g1 g of silicon carbide which is SiC and solid particles, 100 g1 g of zinc oxide which is ZnO and solid powders, 25 g1 g of waterglass which is Na.sub.2SiO.sub.39H.sub.2O and solid powders, aluminum foil with the size of 2000 mm0.5 mm2000 mm which is Al and a solid, graphite with the size of 200 mm400 mm which is C and a solid bulk, 800 mL10 mL of acetone which is C.sub.3H.sub.6O and liquid, 1000 mL50 mL of deionized water which is H.sub.2O and liquid, and 100000 cm.sup.3100 cm.sup.3 of argon which is Ar and gas, the method comprising: preparing a casting mould, including making a cylindrical casting mould with a cavity having a size of 100 mm200 mm and a surface roughness of Ra0.08-0.16 m, using graphite materials; preparing a coating agent including weighing out 100 g1 g of zinc oxide and 25 g1 g of waterglass, measuring out 600 mL+5 mL of deionized water, and adding 100 g1 g of zinc oxide, 25 g1 g of waterglass and 600 mL5 mL of deionized water into a slurry mixer and stirring at 50 r/min for 100 min, thereby obtaining a suspending liquid as the coating agent after stirring; pretreating aluminum-copper-iron quasicrystal and silicon carbide, including ball-milling, including weighing out 50 g1 g of aluminum-copper-iron quasicrystal and 50 g1 g of silicon carbide, placing 50 g1 g of aluminum-copper-iron quasicrystal and 50 g1 g of silicon carbide into a jar of a ball mill, and mixing and ball-milling for 5 hours, thereby obtaining mixed fine powders after ball-milling, dispersing and washing by ultrasonic wave including placing the mixed fine powders obtained after ball-milling into a beaker, adding 400 mL of acetone and mixing, and placing the beaker in an ultrasonic dispersion instrument, and dispersing and washing by ultrasonic wave for 100 min at the frequency of 28 kHz, and obtaining a mixed liquid, filtrating, including placing the mixed liquid into a Buchner funnel of a suction flask, filtrating using a millipore membrane, keeping a filter cake and removing washing liquid, and vacuum drying, including placing the filter cake into a quartz container, and placing the quartz container in a vacuum drying oven and drying at the temperature of 200 C. for 60 min under the vacuum degree of 8 Pa, thereby obtaining aluminum-copper-iron quasicrystal and silicon carbide mixed fine powders after drying; pretreating aluminum alloy, including cutting the aluminum alloy bulk into small pieces of which the size is less than 50 mm50 mm50 mm using a machine, coating the aluminum alloy pieces obtained after cutting using aluminum foils, and preheating, including placing the coated aluminum alloy pieces into a heating furnace and preheating at the temperature of 200 C. for 60 min; smelting to obtain the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite, which is performed in an intermediate-frequency induction melting furnace through the process of intermediate-frequency induction heating, vacuumizing, bottom blowing argon, and casting molding, including pretreating the cylindrical graphite mould, including washing the cavity of the cylindrical graphite mould using acetone to be clean, uniformly applying the prepared coating agent to the surface of the cavity of the cylindrical graphite mould, and making the coating layer have the thickness of 1 mm, and placing the cylindrical graphite mould in a drying oven and preheating at the temperature of 200 C., opening the intermediate-frequency induction melting furnace, cleaning an inside of a graphite melting crucible, and washing using acetone to clean the inside of the crucible, placing 3800 g1 g of the aluminum alloy pieces coated by the aluminum foils at the bottom of the crucible, and placing 50 g1 g of aluminum-copper-iron quasicrystal and 50 g1 g of silicon carbide on the aluminum alloy pieces, closing and sealing the intermediate-frequency induction melting furnace, including opening a vacuum pump, removing the air from the furnace to make pressure in the furnace be less than 10 Pa, and opening a heater of the intermediate-frequency induction melting furnace and heating at the temperature of 600 C.5 C., passing a bottom blowing argon tube through the bottom of the graphite crucible, transmitting argon to the inside of the crucible at the speed of 1000 cm.sup.3/min, so as to keep the pressure in the furnace to be 0.045 Mpa, and controlling the pressure in the furnace by a gas outlet tube valve; and continuously heating, and smelting at the temperature of 720 C.5 C. for 20 min, so as to obtain an aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite melt, casting, including closing the bottom blowing argon tube and removing slag on the surface of melt in the crucible, and aligning a gate of the preheated cylindrical mould, and casting until filled, cooling the mould with alloy melt to 25 C. in the air, and opening the mould after cooling, thereby obtaining the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite; heat-treating casting, including placing the casting in a vacuum heat treatment furnace, and heat-treating at the temperature of 535 C.5 C. under vacuum degree of 8 Pa for 8 h to complete solid solution; placing the casting in a mesothermal cooling water tank after heat-treating and quenching using water of 65 C. for 45 s; placing the casting in a heat treatment furnace after quenching and performing aging-treatment at the temperature of 180 C.5 C. for 6 h; and washing the surface of the casting with acetone to clean each surface.

2. The method for preparing the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite according to claim 1, wherein the smelting to obtain the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is performed in the intermediate-frequency induction melting furnace through the process of intermediate-frequency induction heating, vacuumizing, bottom blowing argon, and casting molding; the intermediate-frequency induction melting furnace is vertical, of which the bottom is a furnace base, and of which the inside is a furnace chamber, a working table is provided at the bottom of the furnace chamber, a graphite melting crucible is placed on the working table, an intermediate-frequency induction heater is provided around the outside of the graphite melting crucible, the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite melt is placed in the graphite melting crucible, a gas outlet tube is provided at the upper right side of the intermediate-frequency induction melting furnace and is controlled by a gas outlet valve, an argon tank which is provided with an argon tube and an argon valve is provided at the left side of the intermediate-frequency induction melting furnace, the argon tube connects a bottom blowing motor which connects a bottom blowing tube, the bottom blowing tube passes through the furnace base and the working table and enters into the graphite melting crucible, so as to achieve bottom blowing smelting for the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite melt, a vacuum pump is provided at a lower right side of the furnace base and communicates with the furnace chamber through a vacuum tube, an electric cabinet is provided at a right side of the intermediate-frequency induction smelting furnace, a display screen, an indicator light, a power switch, an intermediate-frequency heat controller, a bottom blowing motor controller and a vacuum pump controller are provided on the electric cabinet, the electric cabinet connects the intermediate-frequency induction heater through a first cable and connects the bottom blowing motor and the vacuum pump through a second cable, and argon is filled in the furnace chamber in which the pressure is controlled by the gas outlet tube and the gas outlet valve.

3. The method for preparing the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite according to claim 1, further comprising: detecting, analyzing and representing color, microstructure and mechanical property of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite, including performing XRD analysis by X-ray diffractometer, performing analysis of tensile strength by a microcomputer control electron universal testing machine, performing hardness analysis by a Brinell hardness tester, and determining whether the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is bulk, the hardness of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite reaches 80.3 HB, and the tensile strength of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite reaches 285 Mpa.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a view in smelting state of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite;

(2) FIG. 2 is a diffraction intensity pattern of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite;

(3) FIG. 3 is a metallographic structure micrograph of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite;

DETAILED DESCRIPTION OF THE EMBODIMENTS

(4) As shown in the Figures, the list of reference numerals is as follows:

(5) the intermediate-frequency induction smelting furnace is represented by 1; the furnace base is represented by 2; the furnace chamber is represented by 3; the gas outlet tube is represented by 4; the gas outlet valve is represented by 5; the working table is represented by 6; the graphite melting crucible is represented by 7; the intermediate-frequency induction heater is represented by 8; the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite melt is represented by 9; argon is represented by 10; the bottom blowing motor is represented by 11; the bottom blowing tube is represented by 12; the vacuum pump is represented by 13; the vacuum tube is represented by 14; the argon tank is represented by 15; the argon tube is represented by 16; the argon valve is represented by 17; the electric cabinet is represented by 18; the display screen is represented by 19; the indicator light is represented by 20; the power switch is represented by 21; the intermediate-frequency heat controller is represented by 22; the bottom blowing motor controller is represented by 23; the vacuum pump controller is represented by 24; the first cable is represented by 25; the second cable is represented by 26.

(6) In combination with the drawings, the present application is further described in detail below.

(7) A view in smelting state of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is shown in FIG. 1, each part need be correct in position, ratio is conducted according to amount, and operation is conducted according to order.

(8) Usage amount of each of the chemical materials in preparation is determined on the basis of the range set in advance, with gram, milliliter and cubic centimeter as unit of measurement.

(9) Smelting to obtain the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is performed in an intermediate-frequency induction melting furnace through the process of intermediate-frequency induction heating, vacuumizing, bottom blowing argon, and casting molding.

(10) The intermediate-frequency induction melting furnace is vertical, of which the bottom is a furnace base 2, and of which the inside is a furnace chamber 3; a working table 6 is provided at the bottom of the furnace chamber 3, a graphite melting crucible 7 is placed on the working table 6, an intermediate-frequency induction heater 8 is provided around the outside of the graphite melting crucible 7, the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite melt 9 is placed in the graphite melting crucible 7; a gas outlet tube 4 is provided at the upper right side of the intermediate-frequency induction melting furnace 1 and is controlled by an gas outlet valve 5; an argon tank 15 which is provided with an argon tube 16 and an argon valve 17 is provided at the left side of the intermediate-frequency induction melting furnace 1; the argon tube 16 connects a bottom blowing motor 11 which connects a bottom blowing tube 12; the bottom blowing tube 12 passes through the furnace base 2 and the working table 6 and enters into the graphite melting crucible 7, so as to achieve bottom blowing smelting for the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite melt 9; a vacuum pump 13 is provided at a lower right side of the furnace base 2 and is communicated with the furnace chamber 3 through a vacuum tube 14; an electric cabinet 18 is provided at a right side of the intermediate-frequency induction smelting furnace 1; a display screen 19, an indicator light 20, a power switch 21, an intermediate-frequency heat controller 22, a bottom blowing motor controller 23 and a vacuum pump controller 24 are provided on the electric cabinet 18; the electric cabinet 18 connects the intermediate-frequency induction heater 8 through a first cable 25 and connects the bottom blowing motor 11 and the vacuum pump 13 through a second cable 26; and argon 10 is filled in the furnace chamber 3 in which the pressure is controlled by the gas outlet tube 4 and the gas outlet valve 5.

(11) A diffraction intensity pattern of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is shown in FIG. 2. Major peak shown in FIG. 2 is -Al matrix, secondary peak shown in FIG. 2 is silicon carbide and aluminum-copper-iron quasicrystal I phase.

(12) A metallographic structure micrograph of the aluminum-copper-iron quasicrystal and silicon carbide mixed reinforced aluminum matrix composite is shown in FIG. 3. As shown in FIG. 3, the aluminum-copper-iron quasicrystal and the silicon carbide powders are in compact combination with -Al matrix grain boundary, so that there are non-apparent aggregation phenomenon and less porosity defect after adding aluminum-copper-iron quasicrystal and silicon carbide powders.