SUSTAINABLE AIR CUSHION OR MAILER
20240198646 ยท 2024-06-20
Assignee
Inventors
Cpc classification
B65D65/403
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
D21H19/20
TEXTILES; PAPER
D21H27/00
TEXTILES; PAPER
B31D2205/0047
PERFORMING OPERATIONS; TRANSPORTING
D21H23/64
TEXTILES; PAPER
B32B29/002
PERFORMING OPERATIONS; TRANSPORTING
B65D81/03
PERFORMING OPERATIONS; TRANSPORTING
B65D65/466
PERFORMING OPERATIONS; TRANSPORTING
B32B7/05
PERFORMING OPERATIONS; TRANSPORTING
B32B2272/00
PERFORMING OPERATIONS; TRANSPORTING
B32B2270/00
PERFORMING OPERATIONS; TRANSPORTING
B65D2565/385
PERFORMING OPERATIONS; TRANSPORTING
B32B27/306
PERFORMING OPERATIONS; TRANSPORTING
B31D5/0078
PERFORMING OPERATIONS; TRANSPORTING
International classification
B65D65/40
PERFORMING OPERATIONS; TRANSPORTING
B31D5/00
PERFORMING OPERATIONS; TRANSPORTING
D21H19/20
TEXTILES; PAPER
D21H23/64
TEXTILES; PAPER
B32B27/30
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
B32B7/05
PERFORMING OPERATIONS; TRANSPORTING
B65D81/03
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A fluid-fillable air cushion or mailer comprising a first layer comprising a repulpable material, a laminate comprising at least two water-soluble material layers, the laminate adjacently affixed to the first layer; and an air fillable portion integral with the laminate, and method of making same are disclosed.
Claims
1. A fluid-fillable air cushion comprising: a first layer comprising a repulpable material; a laminate comprising at least one water-soluble material layer, the laminate adjacently affixed to the first layer; and an air fillable portion integral with the laminate.
2. The air cushion of claim 1, wherein the repulpable material is cellulosic sheet.
3. The air cushion of claim 1, wherein the repulpable material is kraft paper sheet.
4. The air cushion of claim 1, wherein the at least one water-soluble material layer comprises polyvinyl alcohol (PVOH).
5. The air cushion of claim 4, wherein the PVOH is plasticized.
6. The air cushion of claim 1, wherein the PVOH is plasticized with one or more of polyhydric alcohols, waxes, hydrocarbon oil, mineral oil, polyethylene glycol, propylene glycol, polyethylene oxide, polypropylene oxide, glycerine, mannitol, pentaerythritol, trimethylpropane, starch, chitosan, erythritol, polyethylene amines, ethanolamines, and ionic polymers.
7. The air cushion of claim 1, wherein the PVOH is a copolymer or blend.
8. The air cushion of claim 1, wherein the copolymer comprises at least one anionic monomer unit.
9. The air cushion of claim 1, wherein the PVOH is a blend of a first PVOH copolymer comprising a first anionic monomer unit, and a second PVOH copolymer comprising a second anionic monomer unit wherein the first anionic monomer unit and the second anionic monomer unit of the blend can be the same or different.
10. A repulpable mailer comprising the sustainable air cushion as defined in claim 1.
11. A method of forming an air cushion or mailer comprising: contacting a bottom major surface of a repulpable material with a top major surface of a laminate comprising at least one water-soluble material layer; and creating an fluid-fillable cushion between the at least one water-soluble material layers.
12. The method of claim 10, wherein the repulpable material is a paper sheet.
13. The method of claim 12, wherein the paper sheet is kraft paper.
14. The method of claim 10, wherein the at least one water-soluble material comprises polyvinyl alcohol (PVOH).
15. The method of claim 14, wherein the PVOH is plasticized.
16. The method of claim 14, wherein the PVOH is plasticized with one or more of polyhydric alcohols, waxes, hydrocarbon oil, mineral oil, polyethylene glycol, propylene glycol, polyethylene oxide, polypropylene oxide, glycerine, mannitol, pentaerythritol, trimethylpropane, starch, chitosan, erythritol, polyethylene amines, ethanolamines, and ionic polymers.
17. The method of claim 14, wherein the PVOH is a copolymer or blend.
18. The method of claim 14, wherein the copolymer comprises at least one anionic monomer unit.
19. The method of claim 14, wherein the PVOH is a blend of a first PVOH copolymer comprising a first anionic monomer unit, and a second PVOH copolymer comprising a second anionic monomer unit wherein the first anionic monomer unit and the second anionic monomer unit of the blend can be the same or different.
20. The method of claim 11, wherein the repulpable material and the water soluble material are contacted by solvent casting, extrusion lamination, calendaring, or extrusion coating.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] In order to understand and to see how the present disclosure may be carried out in practice, examples will now be described, by way of non-limiting examples only, with reference to the accompanying drawings, in which:
[0015]
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
[0022]
DETAILED DESCRIPTION
[0023] The advantage of the presently disclosed air cushion is that while it provides all of the benefits of a traditional polyolefin air pillow, e.g. inflatability, puncture-resistance, and the ability to protect goods from shifting, bruising and breaking, etc., it presents to the user to be made entirely of paper, yet it is inflatable like a traditional polyolefin air pillow. Moreover, after it has served its dunnage purpose, not only can it be subsequently disposed of in the same stream as a corrugated paper box and fully re-pulped, as defined by the FBA test method, it is intuitive to do so because of the presently disclosed air cushion appearance of being essentially paper. The reason this is possible is because the presently disclosed air cushion, in one example, is a composite comprised of a traditional kraft paper layer which has been married to a compounded polyvinyl alcohol (PVOH) layer. The PVOH compound provides good adhesion to the paper, weldability to form an air pillow, and supports inflation and retention of inflated properties, e.g. puncture resistance and minimal deflation, Moreover, it also provides the ability to be completely repulped along with paper.
[0024] The presently disclosed air cushion or mailer eliminates or reduces some or all of the disadvantages of conventional (and reinforced) air cushion or mailer structures that employ a polyolefin based or pressure sensitive adhesive and fiber glass, or polyethylene terephthalate (PET), reinforcing yarns, e.g., that are not sufficiently compatible with paper repulping and/or impede the downstream recycled paper-making process, if not filtered and removed from the pulp stream.
[0025] As used herein, the term fluid refers generally to liquid, gases, and combinations thereof unless specifically stated otherwise. In one example, fluid refers to air at or above atmospheric or ambient pressure.
[0026] As used herein, repulpable as used in the context of a material, is inclusive of a material substantially or completely derived from pulp. In one aspect, repulpable material is inclusive of a material capable of substantially or completely being turned into pulp again. In one example, the presently disclosed air cushion or mailer is at least 60% up to about 99% repulpable, using test procedure A that is specified in the 2013 Fibre Box Association Voluntary Standard for Repulping and Recycling Corrugated Fiberboard Treated to Improve Its Performance in the Presence of Water and Water Vapor (FBA Standard). In one example, the air cushion or mailer is at least 65%, 70%, 75%, 80%, 85%, 90%, 95%, 96%, 97%, 98%, or more than 99% repulpable. In one example, the presently disclosed air cushion or mailer is at least 60% up to about 99% repulpable, per the 2013 Fibre Box Association Voluntary Standard for Repulping and Recycling Corrugated Fiberboard Treated to Improve Its Performance in the Presence of Water and Water Vapor (FBA method).
[0027] In one example, the presently disclosed air cushion or mailer has a yield of at least 60% up to about 99% per the FBA Standard. In one example, the air cushion or mailer has a yield of is at least 65%, 70%, 75%, 80%, 85%, 90%, 95%, 96%, 97%, 98%, or more than 99%.
[0028] As used herein, water-soluble as used in the context of a material, filament, yarn or ribbon is inclusive of substantial or complete dissolution of the material, film, filament, yarn or ribbon in a repulping environment or process. In one aspect, as used herein, water-soluble as used in the context of a material, film, filament, yarn or ribbon is inclusive of substantial or complete dissolution of the material, filament, yarn or ribbon in an aqueous environment at a temperature of about 40-100? C. In another aspect, as used herein, water-soluble as used in the context of a material, film, filament, yarn or ribbon is inclusive of substantial or complete dissolution of the material, filament, yarn or ribbon in an aqueous environment of pH greater than about 7.5 and a temperature of about 40-100? C.
[0029] As used herein, derivatives as used in the context of a material, is inclusive of a physical or chemical modification to the material, such as grafting, co-polymerization, blending, and/or exposing to high-energy radiation sources (i.e., crosslinking or chain scissoring).
[0030] In one example, the presently disclosed air cushion or mailer provides an alternative to polyolefin air cushion or mailer by using a polyvinyl alcohol (PVOH) film. In yet another example, the presently disclosed air cushion or mailer provides an alternative to polyolefin air cushion or mailer by using a polyvinyl alcohol film. In one example the PVOH film is machine direction-oriented. Thus, the disclosed air cushion or mailer are an improvement over previous packaging cushions using a non-water soluble plastic film as an air cushion or mailer.
[0031]
[0032] It shall be understood that the air cushion 100, 200 as illustrated in
[0033] Referring now to
[0034] As used herein, affixed when used in the context of the repulpable layer 110 and water-soluble material layer 120, include, but not limited to, extrusion coating, calender lamination, casting, and the like such that physical separation of the repulpable layer 110 and laminate 101 irreparably alters the structural relationship between the layers thereof. Unless specifically indicated, affixed when used in the context of the repulpable layer 110 and laminate 101, excludes the use of a partial, continuous, or intermittent adhesive layer or of any adhesive material between the repulpable layer 110 and the laminate 101.
[0035] In one example, both the laminate 101 and the repulpable layer 110 are provided as sheet or film and/or brought together to form a liquid fillable air cushion. In one example, the laminate 101 is a cast or blown film of water-soluble material layers 120,122. In one example, laminate 101 is a repulpable layer 110 having affixed thereto at least one water-soluble material layer configured to receive another water-soluble material layer so as to create laminate 101 on repulpable layer 110.
[0036] In another example, laminate 101 and/or the repulpable layer 110 is activated prior to forming the laminate, layer, or web. In one example, the top major surface of the laminate 101, or the bottom major surface of the repulpable layer 110 can be activated prior to producing the paper/water-soluble material layer laminate liquid fillable air cushion. Suitable activation processes include corona discharge, flame treatment, spray or adhesive or using coupling agents such as polyamines, amino silanes, amino siloxanes and the like. In one example, activating either laminate 101 or the repulpable layer 110 is performed with brief exposure to water, steam, or other aqueous or humid conditions just prior to affixing the repulpable layer 110 and laminate 101 together.
[0037] In one example, the laminate 101 is formed by heating to a softened and/or melted state and extrusion coated, cast or calendered extruded to a bottom major surface of the repulpable layer 110 at least 1 of the water-soluble material layers 102,122. The air cushion 200, 400, as a result of the film/sheet joining, extrusion coating/casting/calendering of the laminate 101 comprising water-soluble material layers 120, 122 to the repulpable layer 110, the cellulosic layer is not easily strippable or separated therefrom. That is, once the cellulosic layer is coated, it is not easy, if not impossible without significant loss of structural integrity, to separate the repulpable layer 110 from the laminate 101. In one example, laminate and receiving surface of water-soluble material layer 120 are treated so as to eliminate or reduce tack of the two surfaces. Such treatment may include dusting, surface roughening and/or use of anti-tack agents in one or both layers 120,122.
[0038] With regard to
[0039] With reference to
[0040] With reference to
[0041] The extrusion laminating disposes the innermost lamination layer contiguous to the top major surface of the at least one water-soluble material layer 120 affixed to repulpable layer 110. The method can also include extrusion coating the water-soluble film and laminating the construct onto the repulpable layer 110.
[0042] Additives for inclusion in the extrusion or calendering coating or extrusion lamination process or for the water activated tape itself, can include one or more of UV inhibitors, antioxidants, pigments, fillers, and antistatic agents, anti-tack agents, but are not limited thereto. In one example, the top major surface of one or both of the at least one water-soluble material layers 120,122 can be dusted so as to avoid tacking or binding between the films during production and/or during gas filling.
[0043] Repulpable layer 110 may be any type of repulpable material, such as cellulosic material. In another example, repulpable layer 110 is printable using thermal or thermal transfer, offset, inkjet, or flexographic (flexo) printing methods. Examples of cellulosic materials include paper, such as, but not limited to, creped paper, non-creped paper, or release paper. In one example, the repulpable layer 110 is a Kraft paper. In another example Creped NBSK (Northern Bleached Softwood Kraft) paper web is used. In one example, a 20 to 57 lb Kraft paper is used. In one example, the repulpable layer 110 surface of the cushion is treated with a repulpable hydrophobic coating, for example, hydrogenated triglycerides of a carbon-chain-length of about 10-20 so as to resist alteration or degradation from exposure to precipitation and other expected environmental conditions experienced during packaging or shipping.
[0044] The at least one water-soluble material layer 120, 122 can be any water-soluble polymeric film mono- or multi-layer with sufficient tensile and tear properties to function as a gas fillable air cushion. In one example, the at least one water-soluble material layer 120,122 are the same or a different. The at least one water-soluble material layers 120,122 can be different with respect to one or more of chemical composition of monomers, low percentage of monomers present, molecular weight, viscosity, degree of hydrolysis, water solubility, thickness, etc.
[0045] In one example, suitable PVOH polymer films useful in the practice of the present disclosure in forming a sustainable air cushion or mailer have 12-18% crystallinity and is 70% or more hydrolyzed. In another example a suitable PVOH polymer has 30-50% crystallinity and is 80%, 90%, or 99% or more hydrolyzed. In one example, water-soluble films of the present disclosure can be any one or more of commercially available products, for example: 73% hydrolyzed PVOH, Kuraray Poval 505, number average molecular weight 28,000, 88% hydrolyzed PVOH Kuraray Poval 205, Nippon Gohsei GL05, 98% hydrolyzed PVOH, Nippon Gohsei N-300. Polyethylene/Polyvinyl Alcohol Terpolymer, and EXCEVAL (Kuraray LTD of Japan).
[0046] Polyvinyl alcohol (PVOH) as used herein can be partially or fully hydrolyzed, where PVOH is a synthetic resin generally prepared by hydrolysis or saponification of polyvinyl acetate. Both fully and partially hydrolyzed PVOH (also referred to as a vinyl alcohol-vinyl acetate copolymer) may be employed in the practice of the present disclosure.
[0047] As a representative exemplary example of a water-soluble film suitable for practicing the present disclosure, PVOH or PVOH derivative films (collectively PVOH films) are described. PVOH films are produced via melt extrusion and solution casting methods, for example. Typically, in both processes, a highly crystalline PVOH is mixed with a plasticizer to reduce the total amount of crystallinity of the finished, air cushion or mailer soluble film.
[0048] In one example, incorporation of high molecular weight plasticizers with the PVOH film reducing large crystalline regions within the film, and/or incorporation of low weight plasticizers reducing the small crystalline regions are used. The plasticizer system can be one, or a combination of conventional plasticizers including polyhydric alcohols, waxes, hydrocarbon oil, mineral oil, polyethylene glycol, propylene glycol, polyethylene oxide, polypropylene oxide, glycerine, mannitol, pentaerythritol, trimethylpropane, starch, chitosan, erythritol, polyethylene amines, ethanolamines, and ionic polymers. Additional components can be added to the PVOH for processing such as nucleating agents, anti-caking agents, anti-slip agents, fillers, such as calcium carbonate, organic and inorganic salts, and the like.
[0049] PVOH derivatives include, for example, PVOH blends or copolymers of vinyl alcohol. The PVOH blends or copolymers of vinyl alcohol, for example, can contain at least about 50 wt. %, 55 wt. %, 60 wt. %, 65 wt. %, 70 wt. %, 75 wt. %, 80 wt. %, 85 wt. %, or 90 wt. % and/or up to about 60 wt. %, 70 wt. %, 80 wt. %, 90 wt. %, 95 wt. %, or 99 wt. % of the PVOH. Blends of PVOH can include PVOH polymers of different viscosity, different average molecular weight, different vinyl acetate content, and/or different crystallinity as measured by direct scanning calorimetry (DSC). PVOH blends can include other water-soluble materials, for example, polyvinyl pyrrolidone, polyalkylene oxides, acrylamide, acrylic acid, cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides including starch and gelatine, natural gums such as xanthum and carragum, polyacrylates and water-soluble acrylate copolymers, methylcellulose, carboxymethyl cellulose salts (e.g., sodium carboxymethyl cellulose, calcium carboxymethyl cellulose), dextrin, ethylcellulose, ethylhydryoxyethyl cellulose (EHEC), hydroxyethyl cellulose (HEC), hydroxyethylmethyl cellulose (HEMC), hydroxypropyl cellulose (HPC), hydroxypropyl methyl cellulose (HPMC), maltodextrin, methyl cellulose (MC), polymethacrylates, and copolymers of PVOH, and mixtures thereof.
[0050] Copolymers of vinyl alcohol includes polymers that are derived by the hydrolysis of a copolymer of a vinyl ester, typically vinyl acetate, and another monomer. Copolymers of vinyl alcohol include, for example, one or more carboxylic monomer units, or one or more anionic monomers units, for example, acrylamido methylpropanesulfonic acids (e.g., AMPS comonomers such as 2-acrylamido-1-methylpropanesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid), alkali metal salts thereof (e.g., sodium salts), and combinations thereof. Blends of PVOH and copolymers of vinyl alcohol as described above can be used.
[0051] Polyvinyl alcohol (PVOH) blends can be used, for example, comprising a first PVOH copolymer comprising a first anionic monomer unit, and a second PVOH copolymer comprising a second anionic monomer unit. The first anionic monomer unit and the second anionic monomer unit of the blend can be the same or different. The molar or mass amounts of the first and the second PVOH copolymer can be the same or different. The amounts of plasticizer in the first and the second PVOH copolymer can be the same or different. The chemical nature of plasticizer in the first and the second PVOH copolymer can be the same or different. The first PVOH copolymer and the second PVOH copolymer can each independently have a degree of hydrolysis in a range of 75% to 99% (or residual acetate content) or have different degree of hydrolysis. The first PVOH copolymer and the second PVOH copolymer can each independently have a 4% solution viscosity at 20? C. or their viscosities can be different.
[0052] Extruded films of the aforementioned PVOH polymers produced from 98-99.9% hydrolyzed PVOH function similarly to EXCEVAL, but dissolve in water at 60? C., rather than 80? C., for example. The first PVOH copolymer and the second PVOH copolymer can each independently have temperature-based water solubilities that are the same or different.
[0053] If desired, the PVOH can be compounded into a thermoplastic pellet with a suitable film being produced via melt extrusion. In one example, the PVOH used to make extrudable pellets has less than 0.5% sodium acetate present and/or the extrudable pellets are dried to a level of less than 2% moisture prior to film formation.
[0054] With reference to
[0055] Folded air cushion 200 with sealed edges 116 can provide a suitable mailer 400 article for packaging. In one example, mailer 400 with sealed edges can have an extended portion 129, extending from opening 119 and opening edge 117, where extended portion is configured to fold over and seal the opening. In one example, an adhesive 130 is affixed extended portion 129. In one example, adhesive is water activated. The adhesive 130 can be presented to the extended portion as a continuous or discontinuous film, applied dry or as a solution, such as by spray or electrostatic coating. The adhesive 130 may be any conventional developed adhesive suitable for box sealing or carton sealing (also referred to as packaging adhesive). In one example, the adhesive 130 can be a starch or starch derivative. In one example, the starch, starch derivative or thermoplastic starch is derived from corn, sorghum, wheat, sago, tapioca, legumes, barley, rice, and/or potatoes. In one example, the starch or starch derivative comprises maize, waxy maize, wheat, potato, tapioca, or mixtures thereof. In another example, adhesive 130 is a pressure sensitive adhesive (PSA) with or without a release liner (not shown).
[0056] As a result of the construction of the presently disclosed air cushion 100, 200,300,400 the cushion (or mailer) remains with or is included through paper recycling and re-pulping processes with little if any negative impact to operational processes of repulping or downstream new paper-making processes. The presently disclosed air cushion or mailer possesses the physical and structural attributes of a traditional air cushion or mailer carton sealing tape, for example, the ability to be printed, the ability to be perforated, filled, and sealed using conventional air cushion/dunnage equipment. Furthermore, the presently disclosed air cushion or mailer is at least 75%, at least 80%, at least 90%, or at least 95-99% (by weight) re-pulpable, as measured by the Fiber Box Association's (FBA) re-pulpability test method. Moreover, at least 75%, at least 80%, at least 90%, or at least 95-99% of the weight of the air cushion or mailer presently disclosed is available for recycling, e.g., making recycled paper.
[0057] While certain embodiments of the present disclosure have been illustrated with reference to specific combinations of elements, various other combinations may also be provided without departing from the teachings of the present disclosure. Thus, the present disclosure should not be construed as being limited to the particular exemplary embodiments described herein and illustrated in the Figures, but may also encompass combinations of elements of the various illustrated embodiments and aspects thereof.