Tire tread and a tire comprising a tread
12005740 ยท 2024-06-11
Assignee
Inventors
- Claude Schweitzer (Colmar-Berg, LU)
- Jean-Louis Marie Felicien Thomas (Arlon, BE)
- Bodo Ahrens (Trier, DE)
- William Alain Francis Ghislain Talbot (Bastogne, BE)
- Germain Dehez (Montleban, BE)
- Hubert Anna Johanes Cox (Eschdorf, LU)
Cpc classification
B60C11/0058
PERFORMING OPERATIONS; TRANSPORTING
B60C11/1346
PERFORMING OPERATIONS; TRANSPORTING
C08L2205/035
CHEMISTRY; METALLURGY
C08L9/00
CHEMISTRY; METALLURGY
B60C11/0008
PERFORMING OPERATIONS; TRANSPORTING
B60C2011/0016
PERFORMING OPERATIONS; TRANSPORTING
International classification
B60C11/00
PERFORMING OPERATIONS; TRANSPORTING
B60C1/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
In a first aspect of the present invention, a tire tread is provided, the tread comprising a tread cap comprising a first rubber compound for contacting the road when driving, at least one circumferential groove reinforcement forming at least one of the grooves in the tread cap, the groove reinforcement comprising a second rubber compound for reinforcing an area adjacent the grooves formed by the groove reinforcement, wherein the groove reinforcement comprises for at least one of the grooves formed by the groove reinforcement two groove sidewall layers, each sidewall layer extending from the outer radial surface of the unworn tread down into the direction of the bottom of the groove formed by the groove reinforcement and wherein each sidewall layer has an essentially uniform thickness along its length, and wherein the groove reinforcement comprises a groove support portion forming a bottom portion of the groove and having a radially inner base side as well as a radially outer top side, wherein the groove support portion tapers from its base side to its top side.
Claims
1. A tire tread having circumferential grooves, each circumferential groove having a bottom, and an outer radial surface, the tread further comprising: a tread cap comprising a first rubber compound which is adapted to be ground contacting when driving, at least one circumferential groove reinforcement forming at least one reinforced groove in the tread cap, the groove reinforcement comprising a second rubber compound for reinforcing an area adjacent the grooves formed by the groove reinforcement, wherein the groove reinforcement comprises for at least one reinforced groove formed by the groove reinforcement: two groove sidewall layers, each of the two groove sidewall layers extending from the outer radial surface of the tread down into the direction of the bottom of the groove formed by the groove reinforcement and wherein each of the two groove sidewall layers of the groove reinforcement has an essentially uniform thickness along its length, and a groove support portion forming a bottom portion of the groove and having a radially inner base side as well as a radially outer top side, wherein the groove support portion tapers from its base side to its top side, wherein the groove support portion has an essentially trapezoidal shape tapering from the base side to the top side wherein the base side and the top side are interconnected at their lateral edges by lateral sides, wherein the lateral sides are at an angle ? to the base side which is smaller than 90?, wherein the support portion has a radial height which is at least 15% of the distance between the bottom of the groove and the inner radial side of the tread base layer as measured radially below the reinforced groove, and wherein the angle ? between the lateral side of the support portion and each of the two groove sidewall layers of the groove reinforcement is smaller than 180?.
2. The tire tread of claim 1, wherein the tread further comprises a tread base layer arranged radially inwards of the tread cap, the tread base layer comprising a third rubber compound, wherein the groove reinforcement extends in a radially inner direction at least onto the radially outer surface of the base layer.
3. The tire tread of claim 1, wherein the groove support portion extends in a radially outer direction at most up to 1 mm above the upper radial surface of a tread wear indicator of the groove reinforced by the groove reinforcement, and wherein the sidewall layers having essentially uniform thickness extend to the radial outer side of the tapering groove support portion.
4. The tire tread of claim 1, wherein the groove support portion and the sidewall layers are integrally formed.
5. The tire tread of claim 1, wherein the base side is longer than the top side, and wherein the groove support portion further has two lateral sides connecting the base side and the top side, and wherein the angle between at least one of the lateral sides and the base side is at most 85?.
6. The tire tread of claim 1, wherein the tread further has a tread base layer arranged radially inwards of the tread cap and the groove reinforcement, wherein the radial height of the groove support portion is at least 50% larger than the radial distance between the bottom of the groove and a radial upper side of the tread base layer.
7. The tire tread of claim 1, wherein the base side of the support portion is from 1.1 to 5 times longer than the axial width of the bottom of the reinforced groove.
8. The tire tread of claim 1, wherein the sidewall layer has an essentially uniform thickness which is within the range of 0.5 mm to 4 mm.
9. The tire tread of claim 1, wherein the groove sidewall layers extend from the top of the unworn tread at least over 70% of the depth of the groove when viewed in parallel to the sidewall of the groove.
10. The tire tread of claim 1, wherein a ratio between thickness of the sidewall layer and length of the sidewall layer having essentially uniform thickness is at most 1:10.
11. The tread of claim 1, wherein all grooves of the tire tread are reinforced with said groove reinforcement.
12. The tread of claim 1, wherein both sidewall layers have essentially the same thickness.
13. The tread according to claim 1, wherein at least one of the sidewall layers and a line connecting an axial edge of the top side and an axial edge of the base side at said sidewall layer intersect with an angle of between 175? and 90?.
14. The tread of claim 1, wherein the groove reinforcement compound has a Shore A hardness of at least 75 and an elongation at break of at least 300%, and wherein the tread cap compound has a Shore A hardness of between 40 and 75, and wherein the Shore A hardness of the groove reinforcement compound is higher than the Shore A hardness of the tread cap compound.
15. The tread according to claim 1, wherein the support portion has a radial height which is at least 20% of the distance between the bottom of the groove and the inner radial side of the tread base layer as measured radially below the reinforced groove.
16. The tread according to claim 1, wherein the tread cap is comprised of a rubber which is softer than rubber of the groove reinforcement and wherein the rubber in the tread base is softer than the rubber in the tread cap.
17. The tread according to claim 16 wherein the tread cap is comprised of a thio-functionalized tin coupled solution styrene-butadiene rubber and natural rubber, wherein the groove reinforcement is comprised of polybutadiene rubber and styrene-butadiene rubber, and wherein the tread base is comprised of polybutadiene rubber, natural rubber, and a pre-silanized silica.
18. A tire having a tread comprising: a tread cap comprising a first rubber compound which is adapted to be ground contacting when driving, at least one circumferential groove reinforcement forming at least one groove in the tread cap having a bottom and an outer radial surface, the groove reinforcement comprising a second rubber compound for reinforcing an area adjacent the grooves formed by the groove reinforcement, wherein the groove reinforcement comprises for at least one of the grooves formed by the groove reinforcement: two groove sidewall layers, each of the two groove sidewall layers extending from the outer radial surface of the tread down into the direction of the bottom of the groove formed by the groove reinforcement and wherein each of the two groove sidewall layers has an essentially uniform thickness along its length, and a groove support portion forming a bottom portion of the groove and having a radially inner base side as well as a radially outer top side, wherein the groove support portion tapers from its base side to its top side, wherein the groove support portion has an essentially trapezoidal shape tapering from the base side to the top side wherein the base side and the top side are interconnected at their lateral edges by lateral sides, wherein the lateral sides are at an angle ? to the base side which is smaller than 90?, wherein the support portion has a radial height which is at least 15% of the distance between the bottom of the groove and the inner radial side of the tread base layer as measured radially below the reinforced groove, and wherein the angle ? between the lateral side of the support portion and each of the two groove sidewall layers of the groove reinforcement is smaller than 180?.
19. The tire of claim 18, wherein the tire is a pneumatic tire.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The structure, operation and advantages of the invention will become more apparent upon contemplation of the following description taken in conjunction with the accompanying drawings, wherein:
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DETAILED DESCRIPTION OF THE EMBODIMENTS
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(19) In the example shown in
(20) The three compounds in the example of
(21) In addition to the above-mentioned different stiffness values, the shape and or extension of the reinforcement 3, cap compound 2 and base layer 4 can help to further improve the above-mentioned effects. Further examples are given in the description of
(22) In the example of
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(28) In order to further demonstrate some effects of the present invention in comparison with the prior art,
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(32) As shown in
(33) The cushion portion 709, 709 has a (maximum) thickness which is about between 110% and 30%, preferably between 95% and 50%, of the radial distance between the groove bottom of the center groove(s) and the radially inner side of the base layer 704 at the respective position of the groove(s). The cushion portion 709, 709 may extend axially over at least 30% (preferably at least 40% and/or at most 80%) of the distance d.sub.S, d.sub.S between an axial outer edge of the base layer 704 in the shoulder region 706 and the groove closest to that shoulder region 706. In other words, the cushion portion 709, 709 may be considered as a circumferential portion of the base layer 704 which has a larger thickness than a portion of the base layer 704 adjacent the equatorial plane or in a portion radially below the grooves. In the example of
(34) The cushion portion 709 may have essentially a trapezoidal shape having a radially inner broader support portion and a radially outer narrower portion. In other words, the cushion portion may taper in the radial outer direction. Similarly, the base layer 704 may taper in the skirt portion 707 in the radially outer direction. Moreover, the base layer 704 may extend in the skirt portion 707 beyond the maximum radial thickness of the cushion portion 9 as shown in
(35) While the present invention does not focus on the chemical composition of the tread compounds in the groove reinforcement, tread cap compounds or tread base layers, a few examples are given herein below. Those shall however not be understood as necessarily limiting the invention to these examples. In this context, Table 1 provides examples of suitable base layer compounds. However, it shall be re-emphasized that the main focus of the invention is not directed to the specific compounds used. These base layer compound examples shall not automatically limit the invention.
(36) TABLE-US-00001 TABLE 1 Base layer compound examples Sample number i ii iii iv Polybutadiene 65 50 0 0 Natural Rubber 35 50 100 100 Carbon Black 50 45 0 0 Pre-Silanized Silica.sup.1 0 0 30 30 Phenol Formaldehyde resins 3 0 5 5 TDAE Oil 11.3 16 10 45 Waxes 2 1.5 3.8 3.8 Antidegradants 7 5.5 6.7 6.7 Stearic Acid 1 0.75 1 1 Sulfenamide Accelerator 0.6 1.4 0.9 0.9 Zinc oxide 3.5 2 2 2 Sulfur 2.8 1.9 2.5 2.5 .sup.1Agilon 400? pre-silanized silica from PPG Industries.
Table 2 shows Shore A hardness values of the samples shown above in Table 1.
(37) TABLE-US-00002 TABLE 2 Base layer compound examples Sample number i ii iii iv Shore A Hardness .sup.a 49 54 29 17 .sup.a Shore A hardness measured according to ASTM D2240.
(38) Table 3 gives examples of suitable tread cap compounds. As mentioned already in the context of tread base layer compounds, it is emphasized again that such tread cap compounds mentioned herein are essentially considered as examples while other tread cap compounds could be used as long as they fall within the scope of the present invention.
(39) TABLE-US-00003 TABLE 3 Tread cap compound examples Sample number v vi vii Functionalized SSBR .sup.1 60 49 0 Natural Rubber 40 21 60 ESBR.sup.2 0 0 40 Non-functionalized SSBR.sup.3 0 30 0 Tackifier Resin.sup.4 0 0 6 Carbon Black 3 1 0 Silica 80 66 30 Oils 16 12 0 Waxes 1.5 2 1.5 Fatty Acid Soap 0 0 2 Silane 6.4 5.2 5 Fatty Acid 0 0 3 Antidegradants 3.5 0 3.5 Stearic Acid 2 4 0 Sulfenamide Accelerator 2.4 2.4 3 Dithiophosphate Zinc Salt 0.8 0.8 0 Zinc oxide 3 3 3 Sulfur 1.5 1.5 1.2 Diphenylguanidine 0 0 1.5 .sup.1 Thio-functionalized, tin coupled, solution polymerized copolymer of butadiene and styrene .sup.2Emulsion Styrene Butadiene Rubber, 50.8% (by weight) styrene, 8.2% vinyl 1,2; 4.2% cis 1,4; 36.8% trans 1,4; Tg (inflection) = ?13? C.; 1% styrene sequences ?5; from The Goodyear Tire & Rubber Company .sup.3Non-functionalized solution polymerized copolymer of butadiene and styrene .sup.4unreactive alkylphenol/formaldehyde resin, as SP 1068 from SI Group
Table 4 shows Shore A hardness values of the example compositions of Table 3.
(40) TABLE-US-00004 TABLE 4 Tread cap compound examples Sample number v vi vii Shore A Hardness .sup.a 50 55 60 .sup.a Shore A hardness measured according to ASTM D2240.
(41) Examples for suitable groove reinforcement rubber compounds may for instance be found in U.S. Pat. No. 10,427,463 B2, see in particular in Examples 1, 2, 3, 4 and 5. The teachings of U.S. Pat. No. 10,427,463 B2 are incorporated herein by reference for the purpose of describing such suitable groove reinforcement rubber formulations that can be utilized in the practice of this invention. Such compounds have a high Shore A hardness which are covered by the ranges of some embodiments of the subject invention as delineated herein. For the sake of illustration, two of the examples of that publication are listed herein below in Tables 5 to 8 Moreover, the whole content of U.S. Pat. No. 10,427,463 B2 is incorporated herein by reference in its entirety.
(42) TABLE-US-00005 TABLE 5 Groove reinforcement compounds Sample number 1 2 3 4 polybutadiene 10 10 10 10 styrene-butadiene copolymer 97.5 97.5 97.5 97.5 (oil extended) carbon black 50 50 50 50 silica 20 20 20 20 silane 2 2 2 2 phenol-formaldehyde resin.sup.1 20 20 20 20 hexamethylene tetramine 3 3 3 3 styrene-alpha methyl styrene resin.sup.2 8 12 16 8 carbamic resin.sup.3 0 0 0 4 wax 1.5 1.5 1.5 1.5 antioxidants 3 3 3 3 stearic acid 3 3 3 3 processing aid 2 2 2 2 zinc oxide 2.5 2.5 2.5 2.5 sulfur 1.6 1.6 1.6 1.6 N-tertbutyl-2benzothiazolesulfenamide 1.63 1.63 1.63 1.63 N-Cyclohexylthiophthalimide 0.3 0.3 0.3 0.3 .sup.1SMD 30207 from Schenectedy Chemicals .sup.2Resin 2336 from Eastman .sup.3Alnovol? UF410, from Allnex
Table 6 shows high Shore A hardness values above 80 as well as considerable elongation at break values over 300% for the compounds 1 to 4 of Table 5.
(43) TABLE-US-00006 TABLE 6 Groove reinforcement compounds Sample number 1 2 3 4 Shore A .sup.a 83.3 81.8 83 85.6 Elongation at break (%) .sup.b 329 359 390 426 .sup.a Shore A hardness measured according to ASTM D2240. .sup.b Ring sample test based on ASTM D412 and DIN 53504.
(44) Table 7 lists further examples of potential compounds that could be used as groove reinforcement rubber compounds.
(45) TABLE-US-00007 TABLE 7 Groove reinforcement compounds continued Sample number 5 6 7 8 9 Polybutadiene 20 20 20 20 20 Natural Rubber 80 80 80 80 80 Carbon Black 50 50 50 50 50 Waxes 1.5 1.5 1.5 1.5 1.5 Antidegradant 2.5 2.5 2.5 2.5 2.5 Ricon 184.sup.5 0 15 0 35 0 Ricon 100.sup.6 0 0 15 0 35 Oil 15 0 0 0 0 Stearic Acid 3 3 3 3 3 Silica 20 20 20 20 20 silane disulfide 2 2 2 2 2 phenol formaldehyde resin 20 20 20 20 20 fatty acid soap 2 2 2 2 2 hexamethylenetetramine 3 3 3 3 3 Antidegradant 0.5 0.5 0.5 0.5 0.5 Sulfenamide Accelerator 2.36 2.36 2.36 2.36 2.36 zinc oxide 2.5 2.5 2.5 2.5 2.5 sulfur 1.6 1.6 1.6 1.6 1.6 vulcanization inhibitor 0.3 0.3 0.3 0.3 0.3 .sup.5liquid styrene-butadiene, Mn = 8600 .sup.6liquid styrene-butadiene, Mn = 4000
(46) Table 8 shows again high Shore A hardness values as well as considerable elongation at break values for the materials 5-9 of Table 7.
(47) TABLE-US-00008 TABLE 8 Groove reinforcement compounds continued Sample number 5 6 7 8 9 Shore A Hardness 86 85.4 86.6 89.3 90.6 Elongation at Break (%) 508 518 508 481 502
(48) As visible in these examples for the groove reinforcement compounds, Shore A hardness values may, if desired, be higher than in the base layer compound or the tread cap compound. Moreover, elongation at break is higher than 300% in all samples. However, this shall not be indispensable for the scope of the present invention.
(49) In general, the tread cap layer, the groove reinforcement and the tread base layer may be extruded together to form the tread as known to the person skilled in the art of extrusion and/or tire building. Thus, as non-limiting examples, gear pumps and/or triplex or quadruplex extruders could be used.
(50) Variations in the present invention are possible in light of the provided description. While certain representative embodiments, examples and details have been shown for the purpose of illustrating the subject invention, it will be apparent to those skilled in this art that various changes and modifications can be made therein without departing from the scope of the invention. It is, therefore, to be understood that changes may be made in the particular example embodiments described which will be within scope of the invention as defined by the following appended claims. In any case the above described embodiments and examples shall not be understood in a limiting sense. In particular, the features of the above embodiments may also be replaced or combined with one another.