Manufacturing method for glass film with resin tape, and manufacturing method for glass film

Abstract

Provided is a method comprises: continuously forming an elongated, glass film having marginal portions from molten glass into a given shape having two marginal portions, in width-directional opposite edge regions thereof, wherein the glass film having marginal portions has the marginal portions, and an effective portion formed in a width-directional central region of the glass film having marginal portions; annealing the glass film having marginal portions; continuously forming resin tapes on the glass film having marginal portions at positions adjacent to and away by a given distance from the respective marginal portions, to extend in a length direction of the glass film having marginal portions; and continuously removing each of the marginal portions from the glass film having marginal portions, along a position between the marginal portion and a corresponding one of the resin tapes, or at a given width-directional position within the corresponding resin tape.

Claims

1. A manufacturing method of glass film with resin tape comprising: a forming step of continuously forming an elongated glass film having marginal portions in width-directional opposite edge regions thereof from molten glass, wherein an effective portion is formed in a width-directional central region of the glass film between the marginal portions; an annealing step of annealing the glass film; a resin tape forming step of continuously forming resin tapes on the glass film in a length direction of the glass film, each of the resin tapes being formed at a position adjacent to a respective one of the marginal portions and separated from the respective marginal portions by a given distance from the respective marginal portions with at least a portion of the effective portion between the resin tapes being free from being covered by the resin tapes, wherein the resin tape forming step comprises a resin tape attaching step of attaching the resin tapes to a surface of the glass film while continuously feeding the resin tapes from a corresponding resin tape roll, and the resin tape attaching step includes applying an adhesive to an interface between each of the resin tapes and the glass film; a marginal portion removal step of continuously removing each of the marginal portions from the glass film by cutting the glass film at a position between each marginal portion and a corresponding one of the resin tapes to form the glass film with resin tape; and applying a protective sheet to the glass film between the resin tapes, the protective sheet having a thickness greater than a total thickness of the resin tapes and the adhesive.

2. The manufacturing method of glass film with resin tape as recited in claim 1, wherein the resin tape forming step includes forming the resin tapes at positions away from edge sides of the glass film by 40% or less of a width of the glass film.

3. The manufacturing method of glass film with resin tape as recited in claim 1, wherein the forming step includes using one of a float process, an overflow downdraw process, and a slot downdraw process.

4. The manufacturing method of glass film with resin tape as recited in claim 1, wherein the effective portion has a thickness of 20 to 500 ?m.

5. The manufacturing method of glass film with resin tape as recited in claim 1, which comprises a winding step of winding the glass film with resin tape in the form of a roll.

6. The manufacturing method of glass film with resin tape as recited in claim 5, wherein the resin tape forming step includes continuously forming the resin tapes on only one surface of the glass film, and the winding step includes winding the glass film with resin tape in the form of the roll, in a posture where the one surface of the glass film with resin tape faces outwardly.

7. The manufacturing method of glass film with resin tape as recited in claim 6, wherein the winding step includes continuously feeding the protective sheet from a protective sheet roll, and winding the glass film with resin tape in the form of the roll, together with the protective sheet.

8. A finished glass film manufacturing method comprising: a step of obtaining the glass film with resin tape as recited in claim 1; and a resin tape removal step of continuously cutting width-directional opposite sides of the effective portion of the glass film with resin tape that is free from being covered by the resin tapes to remove width-directional opposite edge regions of the glass film with resin tape on which the resin tapes are formed thereby forming the finished glass film.

9. The finished glass film manufacturing method as recited in claim 8, which comprises a winding step of winding the finished glass film in the form of a roll.

10. The finished glass film manufacturing method as recited in claim 9, which comprises a step of cutting the finished glass film in a width direction to form sheets of the finished glass film.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a process flow chart of a manufacturing method of glass film with resin tape according to the present invention.

(2) FIG. 2 is a schematic diagram for explaining one example of the overall process of the manufacturing method of glass film with resin tape according to the present invention.

(3) FIG. 3A is a schematic diagram for explaining the details of one example of a forming step in the manufacturing method of glass film with resin tape according to the present invention, and FIG. 3B is a sectional view taken along the line A-A in FIG. 3A.

(4) FIGS. 4A to 4C are schematic diagrams for explaining respective steps of the manufacturing method of glass film with resin tape according to the present invention.

(5) FIG. 5 is a schematic diagram for explaining the details of one example of a glass film winding step in the manufacturing method of glass film with resin tape according to the present invention.

(6) FIG. 6 is a schematic diagram for explaining one example of a glass film manufacturing method according to the present invention.

DESCRIPTION OF EMBODIMENTS

(7) FIG. 1 is a process flow chart of a manufacturing method of glass film with resin tape according to the present invention. As depicted in FIG. 1, the manufacturing method of glass film with resin tape according to the present invention comprises a forming step (P1), an annealing step (P2), a resin tape forming step (P3), and a marginal portion removal step (P4), and may further comprises a winding step (P5). Specific examples of these steps will be described in detail below.

(8) FIG. 2 is a schematic diagram for explaining one example of the overall process of a manufacturing method for a glass film with resin tape Ga, according to the present invention. FIGS. 3A and 3B are schematic diagrams for explaining the details of one example of a forming step in the manufacturing method for the glass film with resin tape Ga, according to the present invention.

(9) <Forming Step (P1)>

(10) The forming step (P1) is a step of continuously forming an elongated, glass film having marginal portions Gc from molten glass into a given shape having two marginal portions Gb, respectively, in width-directional opposite edge regions thereof.

(11) According classification by composition, examples of a raw material for the molten glass include soda-lime glass, borosilicate glass, aluminosilicate glass, and quartz glass. Further, according classification by alkaline component, examples thereof include alkali-free glass, and low-alkali glass. Preferably, alkali-free glass is used. This is because alkali-free glass is excellent in strength and chemical durability. The molten glass is used in a molten state after heating at an arbitrary appropriate temperature (1400? C. to 1700? C.).

(12) Examples of a technique to continuously form the molten glass into a film shape include an overflow downdraw process, a slot downdraw process, and a float process. Even by employing any one of the above processes, it is possible to continuously form the elongated, glass film having marginal portions Gc into a given shape having the marginal portions Gb in the respective width-directional opposite edge regions thereof. It is to be understood that the present invention is not limited to the above forming processes as long as the marginal portions Gb are formed in the respective width-directional opposite edge regions of the glass film having marginal portions Gc.

(13) In particular, the overflow downdraw process is preferable as a technique to continuously form a thinned glass film. A glass film obtainable through this process has a feature that each surface thereof has excellent smoothness, i.e., this process is less likely to cause in-plane defects, and suitable for continuously forming a glass film.

(14) With reference to FIGS. 2 and 3, a specific example of the forming step using the overflow downdraw process will be described.

(15) As depicted in FIG. 2, a forming apparatus 10 has a forming region 10A in which a forming body 11 having a wedge-shaped outer surface in vertical section is disposed. When glass melted in a non-depicted melting kiln (molten glass) is supplied into the forming body 11, the molten glass overflows from a top opening of the forming body 11. Then, forming of the molten glass into a glass film ribbon Gd is started such that the overflowed molten glass flows downwardly along opposite lateral surfaces of the forming body 11 having a wedge shape in vertical section, and merges at a lower end of the forming body 11. After merging at the lower end, width-directional opposite edge regions of the glass film ribbon Gd are held, respectively, by two cooling roller pairs 12, so that two thick marginal portions Gb (see FIG. 3B) are formed, respectively, in the width-directional opposite edge regions of the glass film ribbon Gd. By forming the marginal portions Gb, it is possible to suppress aggregation due to surface tension and thermal shrinkage, and promote thinning and curing while maintaining the form of a film. This makes it possible to form a glass film having marginal portions Gc into a given shape. Although metal roller pairs are typically used as the cooling roller pairs 12, the present invention is not limited thereto.

(16) (P2) Annealing Step

(17) The annealing step (P2) is a step of annealing the glass film having marginal portions Gc.

(18) As depicted in FIGS. 2 and 3, a plurality of sets of two annealer roller pairs 13 and a non-depicted heater are arranged in an annealing region 10B. The annealing region 10B is set such that a given temperature gradient is formed by the non-depicted heater, so that, as the glass film having marginal portions Gc flows downwardly along the annealing region 10B, the temperature thereof is gradually lowered and thus thermal strain generated thereinside is removed. In this example, the annealer roller pairs 13 in the annealing region 10B are made of an inorganic material comprising ceramic fibers and a binder. However, the present invention is not limited thereto. Further, all the annealer roller pairs 13 need not hold the glass film having marginal portions Gc, but part of the annealer roller pairs 13 may be an idle roller pair.

(19) As depicted in FIGS. 3A and 3B, in the glass film having marginal portions Gc, each of the edge regions which are being held is maintained thick (as the marginal portion Gb), whereas an inward thinned region (thinned portion Ge) is stretched in a flow direction, in principle. As a result, a difference in size (area difference) between the marginal portion Gb and the thinned portion Ge occurs. This is assumed to cause generation of wrinkles Gf in the thinned portion Ge. However, if the marginal portions Gb are removed, the wrinkles Gf in the thinned portion Ge are relieved, and thus it becomes possible to form a glass film with resin tape or glass film and continuously wind it.

(20) (P3) Resin Tape Forming Step

(21) The resin tape forming step is roughly classified into the following two processes. Specifically, (1) process of attaching at least two tape-shaped resin films onto a surface of the glass film having marginal portions, while continuously feeding the tape-shaped resin films (resin tape attaching step), and (ii) continuously applying resin in solution form to a surface of the glass film, and curing the resin to form at least two tape-shaped resin films on the surface (resin solution application step).

(22) (i) Process of Laminating Tape-Shaped Resin Films (Resin Tapes) to Glass Film Having Marginal Portions (Resin Tape Attaching Step)

(23) Examples of a laminating method includes a technique of laminating tape-shaped resin films (resin tapes), while forming resin films into a tape shape, and a technique of laminating resin films each preliminarily formed into a tape shape. As a technique to develop adhesiveness between each of the tape-shaped resin films and the glass film having marginal portions, an adhesive or pressure-sensitive adhesive is preferably interposed between the resin tape and the glass film having marginal portions. Alternatively, each of the resin tapes may be thermally fused before or after lamination of the resin tape to develop adhesiveness with respect to the glass, based on an anchor effect.

(24) In a particularly preferred embodiment, the lamination is performed while the resin tapes each wound into a roll are continuously unrolled and fed, and an adhesive or pressure-sensitive adhesive is interposed between each of the resin tape and the glass.

(25) The resin tapes are arranged and laminated at positions adjacent to and away by a given distance from the respective marginal portions of the glass film having marginal portions.

(26) Examples of a material for the resin tapes include polyethylene, polyvinyl chloride, polyethylene terephthalate, polyvinylidene chloride, polypropylene, polyvinyl alcohol, polyester, polycarbonate, polystyrene, polyacrylonitrile, an ethylene vinyl acetate copolymer, an ethylene-vinyl alcohol copolymer, an ethylene-methacrylic acid copolymer, nylon, cellophane, and a silicone resin. The resin tape may be formed as a mixture or a laminate thereof. From an industrial viewpoint, polyethylene terephthalate resin is preferable.

(27) As a production method for resin tapes made of the above materials, it is possible to use an inflation process, a T-die process, a melt casting process, a calender process, etc. From an industrial viewpoint, it is preferable to produce a resin tape roll by, after forming a wide-width resin film through one of the above processes, slitting the wide-width resin film into a given width, and winding the resulting tape-shaped resin film.

(28) The resin film laminated through an adhesive or pressure-sensitive adhesive are preferably subjected to cross-linking reaction, and stabilized, using a device for radiating ultraviolet light or electron beam. In this way, the glass film having marginal portions and the resin tapes are strongly fixed together, so that it can be expected to enhance the effect of suppressing crack development in the glass.

(29) A technique to interpose an adhesive or pressure-sensitive adhesive between each of the resin tapes and the glass film having marginal portions may comprise: dropping or continuously applying liquid adhesive or pressure-sensitive adhesive to one or each of the resin tape and the glass film having marginal portions; or laminating a sheet-shaped adhesive film or pressure-sensitive adhesive film to the resin tape or the glass film having marginal portions successively to or currently with the lamination of the resin tape. Alternatively, a roll formed by winding a laminate of a resin tape preliminarily applied with an adhesive or pressure-sensitive adhesive and a release film (separator) attached onto the adhesive or pressure-sensitive adhesive may be used.

(30) FIGS. 4A to 4C are schematic diagrams for explaining respective steps of the manufacturing method of glass film with resin tape according to the present invention. Specifically, FIG. 4A, FIG. 4B and FIG. 4C are, respectively, a sectional view taken along the line B-B in FIG. 2, a sectional view taken along the line C-C in FIG. 2, and a sectional view taken along the line D-D in FIG. 2.

(31) With reference to FIGS. 2 and FIGS. 4A to 4C, a particularly preferred embodiment will be described. Each of two resin tapes 21 is continuously fed from a resin tape roll 20. Then, after applying an adhesive (not depicted) to each of the resin tapes 21, the resin tapes 21 are laminated to the glass film having marginal portions Gc at positions adjacent to and away by a given distance from the respective marginal portions Gb, and irradiated with ultraviolet light from an ultraviolet light irradiation device 22 to continuously form the resin tapes 21 in a length direction of the glass film having marginal portions Gc.

(32) As depicted in FIG. 4B, the glass film having marginal portions Gc normally has the thick marginal portions Gb, and an effective portion Gg formed in a width-directional central region of the glass film having marginal portions Gc. Here, the effective portion Gg is a portion of the glass film having marginal portions Gc formed between the resin tapes 21. The effective portion Gg includes a region which is guaranteed in terms of a desired thickness and is capable of shipment as a product. Considering that the effective portion Gg includes a region to be used as a product, the thickness of the effective portion Gg is preferably 20 ?m to 500 ?m, more preferably 20 ?m to 300 ?m, still more preferably 20 ?m to 150 ?m, from the viewpoint of handling and flexibility.

(33) On the other hand, a non-effective portion Gh is resin tapes 21 and a portion of the glass film having marginal portions Gc outside each of the resin tapes 21. Specifically, the non-effective portion Gh include the marginal portions Gb and a portion whose thickness gradually decreases from the marginal portions Gb toward the effective portion Gg, i.e., includes a region which is not guarantee in terms of a desired thickness as a product, and is incapable of shipment as a product. In a case where it is necessary to set the width of the effective portion Gg to a relatively small, a region guaranteed as a product may be partially included in the non-effective portion Gh.

(34) In this embodiment, the given distance means a distance h1 between one of opposite edges 21a of each of the resin tapes 21 on the side of a corresponding one of the marginal portions Gb, and an edge Gb1 of the corresponding marginal portion Gb on the side of the resin tape 21, as depicted in FIG. 4B. In this embodiment, from the view point of widely ensuring the effective portion Gg, a distance h2 between the edge side Gc1 of the glass film having marginal portions Gc and the edge 21a of the resin tapes 21 is preferably 40% or less, more preferably 30% or less, still more preferably 20% or less, particularly preferably 10% or less, of the width w1 of the glass film having marginal portions Gc.

(35) Further, from the viewpoint of effectively preventing crack development, in a case where, in the marginal portion removal step (P4) descried in detail later, each of the marginal portions Gb is continuously removed along a given width-directional position between the marginal portion Gb and a corresponding one of the resin tapes 21, the width w2 of each of the resin tapes 21 is preferably 3 mm or more, more preferably 10 mm or more. On the other hand, in a case where, in the marginal portion removal step (P4) descried in detail later, each of the marginal portions Gb is continuously removed at a given width-directional position within the corresponding resin tape, the width w2 of each of the resin tapes 21 is selected such that the width of a part of the resin tape to be left on the glass film with resin tape Ga preferably becomes 3 mm or more, more preferably 10 mm or more. Further, from the viewpoint of ensuring the width of the effective portion Gg, the width w2 is preferably 100 mm or less, more preferably 50 mm or less.

(36) Further, from the viewpoint of effectively preventing crack development, the thickness t1 of each of the resin tapes 21 is preferably 25 ?m to 500 ?m, more preferably 50 ?m to 200 ?m. It should be noted here that, in case of using a non-depicted adhesive layer, the thickness t1 of each of the resin tapes 21 is a thickness as measured after removing the adhesive layer.

(37) In a case where the adhesive is liquid form, when the resin tapes are laminated to the glass film having marginal portions, the adhesive has good wettability and spreading with respect to the glass, so that air bubbles or the like are less likely to be entrained between the glass and each of the resin tapes. Further, before the adhesive is cured, there is a chance for each of the adhesive tapes to freely slide on the surface of the glass. Thus, slight wrinkles and meandering irregularly occurring during the lamination are advantageously self-corrected before curing of the adhesive.

(38) Examples of the adhesive include an epoxy-based adhesive, an acrylic-based adhesive, a urethane-based adhesive, a rubber-based pressure-sensitive adhesive, an acrylic-based pressure-sensitive adhesive, a silicone-based pressure-sensitive adhesive and a urethane-based pressure-sensitive adhesive, and any mixture thereof. From the viewpoint of effectively preventing crack development, the thickness of the adhesive layer is preferably 1 ?m to 10 ?m, more preferably 1 ?m to 40 ?m.

(39) (ii) Process of Continuously Applying Resin in Solution Form to Surface of Glass Film (Resin Solution Application Step)

(40) As a resin material, it is possible to use a solvent-dissolvable resin, or a thermo- or photo-curable resin.

(41) As the solvent-dissolvable resin, it is possible to use polyimide, polyamide, polyarylate, polyethylene, polyvinyl chloride, polyethylene terephthalate, polyvinylidene chloride, polypropylene, polyvinyl alcohol, polyester, polycarbonate, polystyrene, polyacrylonitrile, polyvinyl alcohol, triacetylcellulose, an ethylene vinyl acetate copolymer, an ethylene-vinyl alcohol copolymer, an ethylene-methacrylic acid copolymer, nylon, cellophane, or silicone resin, or any mixture thereof.

(42) Examples of the thermo- or photo-curable resin include an epoxy-based resin, an acrylic-based adhesive, a urethane-based adhesive, and a rubber-based resin, and any mixture thereof.

(43) In a preferred embodiment, the solution-form solvent-dissolvable resin or the thermo- or photo-curable resin is continuously applied onto the surface of the glass film at positions adjacent to and away by a given distance from the respective marginal portions, and irradiated with heat, light or electron beam to continuously form two resin tapes in the length direction of the glass film.

(44) In this preferred embodiment, the width and position of each of the resin tapes are the same as those in the above resin tape attaching step.

(45) (P4) Marginal Portion Removal Step

(46) The marginal portion removal step (P4) is process of continuously removing each of the marginal portions Gb from the glass film having marginal portions Gc, along a position between the marginal portion Gb and a corresponding one of the resin tapes 21, or at a given width-directional position within the corresponding resin tape 21, to form a glass film with resin tape Ga.

(47) As a technique to remove the marginal portions Gb, it is possible to use a technique of mechanically cutting the glass, a technique of flawing (scribing) the surface of the glass, and glowing a crack (breaking the glass) by heat or bending stress, or a technique of volatilizing the glass or fragmenting the chemical bonding of the glass by light. Referring FIG. 2 again, as a technique to continuously remove the marginal portions Gb, it is preferable to use, as an energy source, light, particularly a laser light source 30 capable of radiating laser light as collimated and coherent light. It is preferable to select laser light having a wavelength bend in which light absorption by a glass is significant. Further, for increasing irradiation energy, it is effective to focus the laser light inside the glass by using an optical system such as lenses. As the laser light source 30, it is possible to use a CO.sub.2 laser, a YAG laser or the like. As depicted in FIG. 4C, in order to adequately perform the marginal portion removal step P4, a distance h3 from the one edge of the resin tape 21a of the resin tape 21 to a cut line by the laser light source 30 is preferably set to 1 mm or more, more preferably 3 mm or more. In this manner, each of the marginal portions Gb can be continuously removed from the glass film having marginal portions Gc, along a given position between the marginal portion Gb of the glass film having marginal portions Gc and a corresponding one of the resin tapes 21, as depicted in FIG. 4C (or within the corresponding resin tape 21), to produce a glass film with resin tape Ga. As a result of cutting and removal of the marginal portions Gb, the wrinkles Gf generated in the glass film having marginal portions Gc are relieved. Here, from the viewpoint of more simply performing the continuous removal of the marginal portions, it is preferable to continuously remove each of the marginal portions Gb from the glass film having marginal portions Gc, along a given width-directional position between the marginal portion Gb and a corresponding one of the resin tapes 21, as depicted in FIG. 4C.

(48) The manufacturing method of glass film with resin tape according to the present invention may further comprise the winding step (P5) to produce a roll of the glass film with resin tape Ga (hereinafter referred to as resin tape-attached glass roll Gi).

(49) (P5) Winding Step

(50) The winding step (P5) depicted in FIG. 1 is process of winding the glass film with resin tape Ga in the form of a roll to produce a resin tape-attached glass roll Gi.

(51) As depicted in FIGS. 2 to FIG. 5, in a case where the resin tapes 21 are formed on only one surface (upper surface Gj) of the glass film with resin tape Ga, it is preferable to wind the glass film with resin tape Ga around a winding core 40, in a posture where the upper surface Gj of the glass film with resin tape Ga on which the resin tapes 21 are formed, face outwardly.

(52) Thus, even when a curvature arises in the glass film with resin tape Ga during winding, it becomes possible to effectively block growth of a crack starting from an edge of the glass film with resin tape Ga in a tearing direction by a corresponding one of the resin tapes 21.

(53) Further, it is preferable to, during winding the glass film with resin tape Ga, continuously feed a protective sheet 51 from a protective sheet roll 50, and wind the glass film with resin tape Ga in the form of a roll, together with the protective sheet 51. This makes it possible to protect the surface of the glass film, and prevent winding displacement from being fixed due to blocking caused by smoothness of the surface of the glass film. Although the protective sheet 51 is not particularly limited, but examples thereof includes: a resin sheet such as polyethylene terephthalate, polystyrene, polyethylene, polypropylene, polyimide, nylon, polyvinyl chloride, polyester, polycarbonate, cellophane, or silicone; a foamable resin sheet; and paper.

(54) From the view point of continuing good winding without winding displacement, it is preferable to dispose the protective sheet 51 between the resin tapes 21. This makes it possible to prevent interference between the protective sheet 51 and the resin tapes 21. In this case, in order to prevent the resin tapes 21 on a previously-wound part of the glass film with resin tape Ga from coming into contact with a subsequently-wound part of the glass film in the glass film with resin tape Ga, it is preferable that the thickness of the protective sheet 51 is greater than the thickness of each of the resin tapes 21 (when using the adhesive layer, the total thickness of the resin tape as a substrate and the adhesive layer). Thus, even when the thickness of the adhesive layer becomes uneven when each of the resin tape 21 is bonded to the glass film having marginal portions Gc, the resin tapes 21 never come into contact with the glass film, during production of the resin tape-attached glass roll Gi. This makes it possible to prevent the occurrence of winding displacement due to the unevenness of the thickness of the adhesive layer, during production of the resin tape-attached glass roll Gi.

(55) On the other hand, from the viewpoint of protecting edge faces of the resin tape-attached glass roll Gi after the winding, it is preferable that the width of the protective sheet 51 is greater than the width of the glass film with resin tape Ga.

(56) FIG. 2 depicts a production system constructed by selectively combining desirable examples of the above process elements (P1 to P5). However, the present invention is not limited thereto. Further, the schematic diagram depicts a process in which, after the glass film having marginal portions Gc is formed into a given shape and solidified through the overflow downdraw process, while being conveyed in a vertical direction, and further conveyed by feed roller pairs 60, the direction of the glass film having marginal portions Gc is changed in a transverse direction by direction-change rollers 70, and then the wounding step is performed. However, the glass film having marginal portions Gc may be conveyed only in the vertical direction by omitting the direction-change rollers 70, or may be conveyed only in the transverse direction in a case where the float process is employed. The process elements P1 to P5 are not limited to those in FIG. 2, as long they are an optimal arrangement in terms of productivity under restrictions of principle.

(57) In the resin tape forming step (P3) depicted in FIG. 2, the resin tapes 21 are formed on only the upper surface Gj of the glass film having marginal portions Gc. However, the present invention is not limited thereto, but the resin tapes 21 may be formed on only a lower surface or each of the upper and lower surfaces of the glass film having marginal portions Gc.

(58) FIG. 6 is a schematic diagram for explaining one example of a glass film manufacturing method according to the present invention.

(59) For example, as depicted in FIG. 6, a glass film Gk according to the present invention is produced by: unrolling the glass film with resin tape Ga from the resin tape-attached glass roll Gi; and performing a resin tape removal step of continuously removing, from the glass film with resin tape Ga, width-directional opposite edge regions G1 of the glass film with resin tape Ga on which the resin tapes are formed, by cutting means such as a laser light source 31. As depicted in FIG. 6, the glass film Gk may be further wound into a roll of the glass film Gk (glass roll Gm), or may be cut in a width direction by a non-depicted width-directional cutting device, to produce a sheet-shaped glass film Gk. Further, a feeding source is not limited to the the resin tape-attached glass roll Gi, but may be the sheet-shaped glass film with resin tape Ga in an unrolled state. The glass film with resin tape Ga is free of wrinkles Gf, as mentioned above. Thus, the width-directional opposite edge regions G1 of the glass film with resin tape Ga can be continuously removed adequately by the laser light source 31, without further firming the resin tapes 21.

EXAMPLES

(60) Although the manufacturing method of glass film with resin tape according to the present invention will be described in detail based on an example, it should be noted that the present invention is not limited to such an example.

Inventive Example

(61) A glass film with resin tape was produced using the method described in connection with FIG. 2. Specifically, a glass film having marginal portions was formed into a given shape through the overflow downdraw process, to have a width of 1500 mm. The thickness of each of two marginal portions was 1 mm, the thickness of an effective portion was 100 ?m. After annealing the glass film having marginal portions, the direction of the glass film having marginal portions was changed to a transverse direction. Each of two resin tapes made of polyethylene terephthalate (PET) and formed to have a width of 25 mm was laminated to an upper of the glass film having marginal portions after being subjected to the direction change, while an ultraviolet-curing resin was interposed therebetween at a thickness of 20 ?m. After the lamination, the resin tapes were irradiated with ultraviolet light to bond the resin tapes to the upper surface of the glass film having marginal portions. Here, each of the resin tapes was attached at a position where the h1 in FIG. 4B is 130 mm. Subsequently, the marginal portions were continuously removed by radiating a CO.sub.2 laser having a wavelength of 10.6 ?m from the upper surface of the glass film having marginal portions. The CO.sub.2 laser is radiated to a position where the h3 in FIG. 4C is 5 mm. A glass film with resin tape obtained after the cutting and removal was wound around a winding core through a protective sheet to produce a resin tape-attached glass roll. As a result, a glass film with resin tape having a length of 1 km could be wound into a roll 10 times without breakage. That is, even when laser cutting of the marginal portions was continuously performed over 10 km, no breakage occurred.

(62) Further, the above resin tape-attached glass roll having a length of 1 km was unrolled, and subjected to cutting using a CO.sub.2 laser having a wavelength of 10.6 ?m to continuously remove width-directional opposite edge regions of the glass film with resin tape on which the resin tapes were formed, thereby producing a glass film. The CO.sub.2 laser is radiated to a position away inwardly from an edge of the glass film with resin tape by 35 mm (5 mm inward from an outer edge of the resin tapes). The produced glass film was further wound through a protective film to form a glass roll. The above ten resin tape-attached glass rolls were unrolled, and each of the resulting ten tape-attached glass films was used to produce a glass roll. As a result, all of the ten glass films could be wound without breakage.

Comparative Example

(63) Except that no resin tape was used, a glass roll was produced in the same manner as that in Inventive Example. As a result, it was unable to produce a glass roll having a length of 1 km. Laser cutting of the marginal portions was tried over a cumulative distance of 10 km. However, breakage occurred 53 times.

LIST OF REFERENCE SIGNS

(64) 10: forming apparatus 21: resin tape 30: laser light source 40: winding core 51: protective sheet Ga: glass film with resin tape Gb: marginal portion Gc: glass film having marginal portions Gf: wrinkle Gg: effective portion Gh: non-effective portion Gi: resin tape-attached glass roll Gj: upper surface Gk: glass film Gl: width-directional opposite edge region on which resin tapes are formed Gm: glass roll