Miniaturized and compact probe for atomic force microscopy
10302673 ยท 2019-05-28
Assignee
- VMICRO (Villeneuve d'Ascq, FR)
- Centre National De La Recherche Scientifique (Paris, FR)
- UNIVERSITE LILLE-1 (Villeneuve d'Ascq, FR)
Inventors
Cpc classification
G01Q20/04
PHYSICS
G01Q60/38
PHYSICS
International classification
Abstract
A probe for atomic force microscopy comprises a tip for atomic force microscopy oriented in a longitudinal direction, wherein: the tip is arranged at one end of a sensitive part of the probe, which is movable or deformable and linked to a support structure, which is anchored to the main surface of the substrate; the sensitive portion and the support structure are planar elements, extending mainly in planes that are parallel to the main surface of the substrate; the sensitive portion is linked to the support structure via at least one element allowing the sensitive portion to be displaced or to be extended in this direction; and the tip, the sensitive part and the support structure protrude from an edge of the substrate in the longitudinal direction. An atomic force microscope comprising at least one such probe is also provided.
Claims
1. A probe for atomic force microscopy comprising a tip for atomic force microscopy borne by a planar substrate having a main surface, said tip being oriented in a direction referred to as the longitudinal direction, parallel to said main surface, wherein: the tip is arranged at one end of a sensitive part of the probe, which is movable or deformable and linked to a support structure, which is anchored to the main surface of the substrate; the sensitive part and the support structure are planar elements, extending mainly in planes that are parallel to the main surface of the substrate; the sensitive part is linked to the support structure via at least one element allowing said sensitive part to be displaced or to be extended in this direction; the tip, the sensitive part and the support structure protrude from an edge of the substrate in said longitudinal direction; the sensitive part of the probe is at least partly formed by a portion of a layer of a first material, referred to as the first layer, separated from the main surface of the substrate, and the support structure is formed by a portion of a layer of a second material, referred to as the second layer, that is thicker than the first layer and arranged either above the first layer with respect to the substrate or between the first layer and the substrate.
2. The probe for atomic force microscopy according to claim 1, wherein: the sensitive part of the probe is at least partly formed by a portion of said first layer, separated from the main surface of the substrate; at least one other portion of said first layer, referred to as the anchoring portion is rigidly connected to the main surface of the substrate; and the support structure, formed by a portion of said second layer, links the sensitive part of the probe to said anchoring portion of the first layer.
3. The probe for atomic force microscopy according to claim 2, wherein the first layer is a device layer of a silicon-on-insulator substrate and the anchoring portion is rigidly connected to the main surface of the substrate by a buried oxide layer of said substrate.
4. The probe for atomic force microscopy according to claim 2, wherein said support structure is made of polycrystalline silicon.
5. The probe for atomic force microscopy according to claim 2, wherein said sensitive part of the probe comprises an element formed by a portion of said second layer.
6. The probe for atomic force microscopy according to claim 1, wherein at least one said element linking the sensitive part of the probe to the planar support structure is a flexible beam, extending in a direction referred to as the transverse direction, perpendicular to the longitudinal direction and parallel to the main surface of the substrate, allowing said sensitive part to be displaced in said longitudinal direction.
7. The probe for atomic force microscopy according to claim 6, also comprising a transducer configured to detect a displacement of the sensitive part of the probe with respect to the support structure in the longitudinal direction.
8. The probe for atomic force microscopy according to claim 7, wherein said transducer is an optical transducer.
9. The probe for atomic force microscopy according to claim 6, also comprising an actuator, referred to as the first actuator, configured to bring about a displacement of the sensitive part of the probe with respect to the support structure in the longitudinal direction.
10. The probe for atomic force microscopy according to claim 9, wherein h said first actuator is a thermal actuator.
11. The probe for atomic force microscopy according to claim 1, wherein the sensitive part of the probe comprises a micromechanical resonator having a vibration mode exhibiting a longitudinal component, as well as at least one actuator suitable for exciting said vibration mode.
12. The probe for atomic force microscopy according to claim 1, also comprising an actuator, referred to as the second actuator, configured to bring about a displacement of the support structure with respect to the substrate in the longitudinal direction.
13. The probe for atomic force microscopy according to claim 12, wherein said second actuator is a thermal actuator.
14. The probe for atomic force microscopy according to claim 1, also comprising an optical transducer configured to detect a displacement of the sensitive part of the probe with respect to the support structure in the longitudinal direction and at least one actuator, referred to as the second actuator, configured to bring about a displacement of the support structure with respect to the substrate in the longitudinal direction, wherein said optical transducer comprises at least one planar waveguide having a first section that is rigidly connected to the substrate, a second section that is rigidly connected to the support structure and, between the first and the second sections, a section that is flexible in the longitudinal direction.
15. The probe for atomic force microscopy according to claim 1, wherein the thickness of the sensitive part of the probe is less than or equal to 500 nm and the thickness of the support structure is more than or equal to 1 m.
16. An atomic force microscope comprising at least one probe according to claim 1.
17. The atomic force microscope according to claim 16, configured to operate in force curve imaging mode.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Other features, details and advantages of the invention will become apparent upon reading the description provided with reference to the appended drawings, which are given by way of example and show, respectively:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17) In the various figures, the same references denote identical, or at least functionally equivalent, elements.
DETAILED DESCRIPTION
(18) A probe according to the invention may for example be fabricated on the basis of an SOI (silicon-on-insulator) structure, comprising
(19) a silicon substrate (denoted by SU in the figures), in general from 20 m to 1 mm thick, preferably between 50 and 600 m thick;
(20) a buried SiO.sub.2 oxide layer (denoted by BOX), the thickness of which is generally comprised between 0.1 m and 5 m, preferably between 0.2 m and 2 m; and
(21) a thin layer of silicon called the device layer, the thickness of which may in principle reach a few micrometers, but in the case of the invention generally does not exceed 500 nm, or even 200 nm.
(22) In accordance with one embodiment of the invention, an additional layer, for example made of polycrystalline silicon (polysilicon), is deposited on top of the device layer. The thickness of this layer is at least twice, preferably at least five times greater than or even ten times greater than that of the device layer. The choice of polysilicon is advantageous for technological reasons, since it is easy to deposit a layer of polycrystalline silicon on top of a monocrystalline silicon device layer, but this is not exclusive.
(23) The additional layer, which is thicker and hence stiffer, is used to produce the support structure, while the sensitive part of the probe, comprising the AFM tip, is produced on the basis of the device layer, which is less massive. The buried oxide allows the probe to be anchored to the substrate.
(24) The use of a polysilicon additional layer deposited on an SOI substrate constitutes a preferred solution since it makes it possible to make use of tried and tested technologies, but numerous alternatives are possible. For example, the device layer may be produced in a material other than silicon, such as SiN. It is also possible to produce some parts of the probe in the device layer of an SOI substrate and others in a material such as Si.sub.3N.sub.4 or any other material having suitable mechanical properties. Similarly, the additional layer does not necessarily have to be made of polysilicon. Whatever the case, a stack is produced that is formed from a substrate, a first, thin layer intended to produce the sensitive part of the probe and a second, thicker layer intended to form the support structure. As will be explained in greater detail with reference to
(25) Hereinafter, in order to simplify the description, only the case of a probe produced on an SOI substrate, on which a polysilicon additional layer is deposited, will be considered. This generalization does not present any particular difficulty.
(26) In the figures, the second layer is white, the first layer (for example, device layer) is gray, the metallizations are hatched and a dashed line delimits the buried oxide regions that are left for the purpose of anchoring the probe to the substrate. The substrate is also white, since this does not lead to any confusion.
(27)
(28) In the probe of
(29) In its rear portionopposite the tip PT1the shuttle PCE has a transverse element EG forming a planar optical guide. Two planar waveguides GOP1 and GOP2 are arranged on either side of this element. These waveguides have ends that are oriented in the transverse direction and face each other. Their terminal portions are parallel to the transverse element of the shuttle and are separated from the latter, in the longitudinal direction, by a gap, the width of which is comprised between a few nanometers and a few hundreds of nanometers. This arrangement is such that the two waveguides are coupled, by evanescent waves, to the transverse element EG of the shuttle. Thus, luminous radiation propagating through one guide is coupled in the transverse element and, through the latter, reaches the other guide. The intensity of the coupling heavily depends on the width of the gap separating the waveguides from the element EG in the longitudinal direction. The overall assembly thus forms an optical transducer TO1, making it possible to accurately measure the position of the shuttle in the longitudinal direction.
(30) The waveguides GOP1, GOP2 extend in the longitudinal direction, in the opposite direction to the direction of the tip, over the substrate. They terminate in optical ports POP1, POP2 allowing the injection of light.
(31) In the case of producing the probe on the basis of an SOI substrate, the waveguides may be produced in the silicon device layer, but the luminous radiation used must be infrared. It is also possible to use waveguides made of silicon oxide or of any other transparent dielectric material deposited on top of a silicon carrier structure.
(32) The shuttle PCE extends beyond the edge B of the substrate in the longitudinal direction; preferably, as in the case of
(33) The shuttle PCE, including its portion SMM2a, the anchoring portions APT1, APT2 and the transverse elements ET1, ET2, ET3, ET4, along with the transverse element EG, form the sensitive part SMS of the probe. As is conventional, hereinafter the tip PT1 will be considered to be separate from said shuttle PCE, even though in certain embodiments these two elements may be produced as one piece.
(34) The anchoring portions APT1, APT2 are linked to the support structure SMM2 by linkages LSP3, represented in the figure by boxed crosses. Similar linkages, denoted by the reference LSP2, link the waveguides GOP1, GOP2, which themselves also have anchoring portions AOP1, to the structure SMM2.
(35) The structure SMM2 is in turn anchored to the substrate SU via the device layer. More specifically, the device layer has anchoring portions APS1, APS2 which are linked both to the substrate by residual portions AS1, AS2 of the buried oxide layer (represented by a dashed border) and to the structure SMM2 by linkages LSP of the type described above (reference LSP1). This is more clearly apparent in
(36) The waveguides GOP1, GOP2 are also anchored to the substrate, at the optical ports POP1, POP2, via the buried oxide. The anchors are denoted by the references AS3, AS4.
(37) The angle , which can be seen in
(38) In order to decrease the angle at a later stage, it is also possible to thin the substrate SU by etching its back face.
(39)
(40) A probe according to the invention may be fabricated by means of entirely conventional technological processes, described for example in the aforementioned thesis of B. Walter. Typically, the components of the probe (beams, resonators, etc.) are defined in the device layer by means of anisotropic etching. Schematically, the procedure may be as follows: The tip PT1, the anchoring portions APT1, APT2, the transverse elements ET1, ET2, ET3, ET4 and the transverse element EG of the shuttle, along with the waveguides GOP1, GOP2, are produced by anisotropically etching the device layer DL of an SOI substrate. A sacrificial layer, for example of silicon oxide, is deposited on top thereof. Openings are made in the sacrificial layer which correspond to the linkages LSP. A polysilicon layer is deposited on top of the sacrificial layer (the polysilicon penetrates the openings in order to form the linkages LSP). The support structure and the element SMM2a are produced by anisotropically etching this polysilicon layer. The sacrificial layer and the BOX are removed by means of isotropic etching (however, the BOX is left at the anchors, cf.
(41) As explained above, etching the substrate from its back face may also be envisaged, in order to thin it for the purpose of decreasing the bulk constraints. The tip PT1, with a radius of curvature of the order of 10 nm, may be obtained by exposing, by means of a suitable etching step, crystal planes of the device layer.
(42) It has been mentioned above that the order in which the layers are deposited could be reversed, in which case the support structure would be arranged between the device layer and the substrate.
(43)
(44) The movability of the structure SMM2 is achieved by virtue of the use of flexible transverse elements BAC1, BAC2, ET5 (on the left of the figure) and BAC3, BAC4, ET6 (on the right) to link said structure to the anchoring portions for anchoring to the substrate AS1a, AS1b, AS1c (left) AS2a, AS2b, AS2c (right). The elements BAC1, BAC2 form a thermal actuator AC1. Metal contact pads PM1, PM3 are deposited on the anchoring portions AS1a, AS1b. The element BAC2, referred to as the cold arm, is wider than BAC1 (hot arm) and is covered by a metal track LM1 that is linked to the contact pad PM3; the hot arm BAC1, made of doped silicon, exhibits a relatively high resistivity. When a potential difference is applied to the pads PM1, PM3, a current flows through the elements BAC1 and BAC2. Power is dissipated (Joule heating) mainly in the more resistive element BAC1. The resulting thermal expansion produces an increase in its length, while that of the cold arm BAC2 remains unchanged. This differential thermal expansion causes the two transverse elements of the actuator to bend. On the right-hand portion of the probe, the actuator AC2, consisting of the hot arm BAC3, the cold arm BAC4 with the metal track LM2 and the contact pads PM2, PM4, functions in exactly the same way.
(45) The transverse elements ET5, ET7 are passive, and their function is solely to support and to guide the longitudinal displacement of the structure SMM2. The element ET5 also bears a metal track LMP linking a connection pad PM5 deposited on the anchoring portion AS1C to the structure SMS, which has been made partially conductive through doping, in order to hold the tip PT1 at a desired electrical potential.
(46) It is important that the waveguides GOP10, GOP20, the function of which is equivalent to that of the waveguides GOP1 and GOP2 of
(47)
(48) The probe of
(49)
(50)
(51) The actuator AC3 of the shuttle is a thermo-optical actuator: a planar waveguide GOP4 transports luminous radiation, injected by virtue of an optical port POP4, and directs it towards one (ET1) of the transverse elements holding the shuttle; the heating produced by the radiation causes the element to expand, and hence to bend. This actuator is especially suitable for exciting a resonant mode of the structure, rather than for near-static operation.
(52) The actuators AC1, AC2 of the structure SMM2 are also of thermo-optical type. The actuator AC2 has two transverse arms, one hot arm BAC1 and one cold arm BAC2. A planar waveguide GOP6 transports luminous radiation, injected by virtue of an optical port POP6, and directs it towards the hot arm BAC1, which is heated and expands. The actuator AC1 functions in a similar manner (the waveguide associated with this actuator is denoted by the reference GOP5, and the corresponding optical port by POPS).
(53) The invention is not limited to the embodiments that have just been described. For example, other types of transducers and actuators may be used. The transducers do not have to be optical transducers, but could, for example, be piezoelectric or electrostatic (capacitive) transducers; similarly, the actuators do not have to be thermal actuators, but could, for example, be piezoelectric or electrostatic actuators. A bidirectional actuation of the support structure (cf.
(54)
(55)
(56) In the embodiment of
(57) As in the embodiments of
(58) In the embodiment of
(59) In the embodiment of
(60)
(61) In the embodiment of
(62) The passage of an electric current through the arms BR1, BR2 of the resonator causes them to heat up, and hence to extend, thereby making it possible to excite the vibration. Typically, the frequency of the actuation current is f/2, f being the resonant frequency of the resonator. Measuring the signal generated at the frequency f enables detection, for example via piezoresistive effect.
(63) Especially in the case of force curve microscopy, it may be advantageous to cool the AFM probe. Specifically, thermal noise limits the smallest measurable displacement value, and this effect increases as the stiffness of the probe decreases. However, cooling by means of conventional cryogenic techniques is not always possible, or convenient.
(64) Now, it is known that a micro- or nanomechanical element placed inside an optical cavity, forming one of its mirrors or coupled to the cavity via evanescent wave, is subject to various forces of optical origin. Under certain conditions, these forces may damp the vibrations of the mechanical object, and hence cool it. For example, the article by G. Anetsberger, E. M. Weig, J. P. Kotthaus, and T. J. Kippenberg, Cavity optomechanics and cooling nanomechanical oscillators using microresonator enhanced evanescent near-field coupling Comptes Rendus Physique, vol. 12, pp. 800-816 describes the optical cooling of nanomechanical oscillators via evanescent coupling with a disk-shaped optical resonator.
(65) These concepts may be applied to the invention for those embodiments in which an optical resonator is used to measure the movement of the tip (for example the embodiments of
(66) In particular, it would be advantageous to carry out a force measurement in the following manner:
(67) preparing the movable structure including the tip so that it is in an effective temperature state that is lower than the ambient temperature of the AFM microscope by making use of the optical cooling principle;
(68) using an embedded or external actuator to bring the tip down to the surface, then to retract it, while carrying out a force measurement (force curve tracing);
(69) measuring, in real time, the displacement of the tip by means of optical readout while keeping the effective temperature of the tip as low as possible.