DECAL ELECTRONICS FOR PRINTED HIGH PERFORMANCE CMOS ELECTRONIC SYSTEMS

Abstract

High performance complementary metal oxide semiconductor (CMOS) electronics are critical for any full-fledged electronic system. However, state-of-the-art CMOS electronics are rigid and bulky making them unusable for flexible electronic applications. While there exist bulk material reduction methods to flex them, such thinned CMOS electronics are fragile and vulnerable to handling for high throughput manufacturing. Here, we show a fusion of a CMOS technology compatible fabrication process for flexible CMOS electronics, with inkjet and conductive cellulose based interconnects, followed by additive manufacturing (i.e. 3D printing based packaging) and finally roll-to-roll printing of packaged decal electronics (thin film transistors based circuit components and sensors) focusing on printed high performance flexible electronic systems. This work provides the most pragmatic route for packaged flexible electronic systems for wide ranging applications.

Claims

1. A method for fabricating a flexible electronic decal, comprising: fabricating a flexible electronic device; fabricating a first part of a flexible package to house the flexible electronic device; embedding the flexible electronic device in the first part of the flexible package; fabricating a second part of the flexible package to house the flexible electronic device; and sealing the flexible electronic device in the flexible package using the second part of the flexible package.

2. The method of claim 1, in which the step of fabricating the second part of the flexible package comprises printing the second part onto the first part of the flexible electronic device using a 3D printer, in which the printing step also seals the flexible electronic device in the flexible package.

3. The method of claim 1, in which the step of sealing the flexible electronic device comprises attaching the second part of the flexible package to the first part of the flexible package to encase the flexible electronic device.

4. The method of claim 1, in which the flexible electronic device comprises at least one of a NAND gate, NOR gate, inverter, and buffer.

5. The method of claim 1, in which the flexible electronic device comprises a flexible sensor.

6. The method of claim 1, in which the flexible electronic device comprises a ring oscillator.

7. The method of claim 1, in which the step of fabricating a first part of the flexible package comprises printing a first layer of a decal using a 3D printer.

8. The method of claim 1, in which the step of embedding the flexible electronic device in the first part of the flexible package comprises placing the flexible electronic device in a cavity in the first part of the flexible package and bonding a plurality of flexible conductive strips to a plurality of contacts of the flexible electronic device.

9. The method of claim 8, wherein the plurality of flexible conductive strips are formed using one or more of inkjet printing, conductive cellulose, and sputtering.

10. The method of claim 1, in which the electronic device comprises circuitry and contacts, and in which the step of fabricating the flexible electronic device comprises the fabricating circuitry with semiconductor processing and fabricating contacts 708 with conductor processing.

11. The method of claim 10, wherein the semiconductor processing comprises performing a ZnO process and the fabricating of contacts comprises performing an Al process.

12. The method of claim 1, in which at least one step of the fabricating of the flexible electronic decal is performed with roll-to-roll printing.

13. The method of claim 10, wherein the step of fabricating a flexible electronic device comprises: oxidizing a semiconductor wafer to form an oxide layer on a substrate layer; depositing and patterning a metal gate on the oxide layer; depositing a gate dielectric layer on the metal gate; depositing a source and drain on the dielectric layer; depositing and patterning a channel; removing the dielectric layer to reveal the oxide layer; depositing a passivation layer; and removing at least a portion of the substrate layer.

14. The method of claim 10, wherein the contacts are formed by: Oxidizing a substrate to form an oxide layer; forming a dielectric layer on the oxide layer; forming contacts on the dielectric layer; forming a sensing film; and removing a portion of the substrate.

15. A flexible electronic decal, comprising: a flexible electronic device; a flexible package including a first part to house the flexible electronic device, the flexible electronic device being embedded in the first part of the flexible package; the flexible package including a second part to house the flexible electronic device, wherein the flexible electronic device is sealed in the flexible package using the second part of the flexible package.

16. The flexible electronic decal of claim 15, wherein the second part of the flexible package is printed onto the first part of the flexible package using a 3D printer, said printing sealing the flexible electronic device in the flexible package.

17. The flexible electronic decal of claim 15, wherein the flexible electronic device is sealed in the flexible package by attaching the second part of the flexible package to the first part of the flexible package to encase the flexible electronic device.

18. The flexible electronic decal of claim 15, wherein the flexible electronic device comprises at least one of a NAND gate, NOR gate, inverter, and buffer.

19. The flexible electronic decal of claim 15, wherein the flexible electronic device comprises a sensor;

20. The flexible electronic decal of claim 15, wherein the flexible electronic device comprises a ring oscillator.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0014] For a more complete understanding of the disclosed system and methods, reference is now made to the following descriptions taken in conjunction with the accompanying drawings.

[0015] FIG. 1 is a block diagram illustrating conventional manufacturing of electronic devices according to the prior art.

[0016] FIG. 2 is a block diagram illustrating manufacturing of packaged flexible electronic devices according to one embodiment of the disclosure.

[0017] FIG. 3A is an illustration of a packaged flexible electronic device according to one embodiment of the disclosure.

[0018] FIG. 3B is an illustration comparing a packaged flexible electronic device according to one embodiment of the disclosure with a conventional rigid electronic device.

[0019] FIG. 4 is a flow chart illustrating one exemplary method for manufacturing a packaged flexible electronic device according to one embodiment of the disclosure.

[0020] FIGS. 5A-I are perspective views of an electronic device at various stages of manufacturing using a zinc oxide (ZnO) process according to one embodiment of the disclosure.

[0021] FIG. 6 is a flow chart illustrating one exemplary method for manufacturing using a zinc oxide (ZnO) process according to one embodiment of the disclosure.

[0022] FIGS. 7A-E are perspective views of an electronic device at various stages of manufacturing using an aluminum (Al) process according to one embodiment of the disclosure.

[0023] FIG. 8 is a flow chart illustrating one exemplary method for manufacturing using an aluminum (Al) process according to one embodiment of the disclosure.

[0024] FIGS. 9A-H are illustrations of a flexible packaged electronic device having an inverter according to one embodiment of the disclosure and measured characteristics of the inverter.

[0025] FIGS. 10A-K are illustrations of a flexible packaged electronic device made from multiple decals according to one embodiment of the disclosure and measured characteristics of the decals.

[0026] FIGS. 11A-I are illustrations of a flexible packaged electronic device having a bi-axial strain sensor according to one embodiment of the disclosure and measured characteristics of the inverter.

[0027] FIGS. 12A-B are graphs illustrating and comparing I-V characteristics of a flexible device having an inverter according to one embodiment of the disclosure and a conventional inverter.

[0028] FIGS. 13A-B are graphs illustrating and comparing gain characteristics of a flexible device having an inverter according to one embodiment of the disclosure and a conventional inverter.

[0029] FIGS. 14A-B are graphs illustrating and comparing AC response characteristics of a flexible device having an inverter according to one embodiment of the disclosure and a conventional inverter.

[0030] FIGS. 15A-B are graphs illustrating and comparing AC response characteristics of a flexible device having a NAND gate according to one embodiment of the disclosure and a conventional inverter.

[0031] FIGS. 16A-B are graphs illustrating and comparing AC response characteristics of a flexible device having a NOR gate according to one embodiment of the disclosure and a conventional inverter.

[0032] FIG. 17 is graphs illustrating and comparing RO response characteristics of a flexible device according to one embodiment of the disclosure and a conventional inverter.

DETAILED DESCRIPTION

[0033] FIG. 2 is a block diagram illustrating manufacturing of packaged flexible electronic devices according to one embodiment of the disclosure. Blocks 102, 104, and 106 as described regarding the prior art may be performed to form a silicon die on a substrate. Although prior art manufacturing techniques were discussed for blocks 102, 104, and 106, embodiments of this invention may use a die manufactured by any manufacturing technique for forming flexible electronics. Rather than perform conventional IC packaging on the silicon die of block 106, the silicon die is reported to a processing flow for flexible electronics. At block 202, a flexible integrated circuit (IC) may be manufactured from the silicon die of block 106. To make the silicon die flexible, a substrate of the silicon die may be thinned to form a flexible integrated circuit. In one embodiment, the thinning may be performed by grinding or otherwise etching back the substrate from a bottom side of the substrate that does not contain the electronics. In another embodiment, the thinning may be performed by releasing a top portion of the silicon die and substrate from a bulk of the substrate, such as described in U.S. patent application Ser. No. 14/238,526 to Hussain et al., the content of which is hereby incorporated by reference in its entirety. Separately, a printed package may be formed at block 204, such as by 3D printing. At block 206, the flexible IC of block 202 and the 3D printed package of block 204 may be combined, such as by embedding the flexible IC into the 3D printed package. The flexible IC in the flexible package may be formed into decals using a system scale roll-print process at block 208 to form decals. The decals may be wearable as shown in block 210 or used as flexible circuit boards as shown in block 212.

[0034] One example of a flexible IC in a flexible package is shown in FIGS. 3A-3B. FIG. 3A is an illustration of a packaged flexible electronic device according to one embodiment of the disclosure. A flexible package 300 may include a 3D printed package 302 in the shape of a butterfly, an electronic device 304, and contacts connected to strips 306. The electronic device 304 may be, for example, one of an inverter, a NOR gate, a NAND gate, a buffer, or a combination of any of these. Combinations of these basic components may be used to build more complex circuitry, such as logic circuitry or circuitry for performing arithmetic. The strips 306 may lead from contacts of the device to contact points at the ends of the flexible package 300. The contacts and strips 306 may be used to couple the electronic device 304 on the flexible package 300 to other electronic devices, such as other devices that may be built on other flexible packages and interconnected together. In one embodiment, the electronic device 304 may be fabricated using a ZnO process and the contacts 708 (see FIG. 7) may be fabricated using an Al process.

[0035] FIG. 3B is an illustration comparing a packaged flexible electronic device according to one embodiment of the disclosure with a conventional rigid electronic device. The flexible package 300 is shown next to a conventional CMOS electronic device 320. The conventional device 320 is much larger, less flexible, and clearly an electronic device. In contrast the flexible package 300 is smaller, more flexible, and can camouflage the electronic device 304 by appearing as something much more pleasing to the human eye.

[0036] A method for manufacturing flexible packages with flexible devices is shown in FIG. 4. FIG. 4 is a flow chart illustrating one exemplary method for manufacturing a packaged flexible electronic device according to one embodiment of the disclosure. A method 400 may begin at block 402 with fabricating a flexible electronic device 304, such as may be performed according to blocks 102, 104, 106, and 202 of FIG. 1. The flexible electronic device 304 may include an electronic circuit and connections to the circuit. In some embodiments, the electronic circuit may be a sensor, such as a sensor for monitoring an environment around the flexible electronic device or a sensor for monitoring the health of a person wearing the flexible electronic device as a decal. In one embodiment, an electronic circuit of the electronic device may be fabricated with a ZnO process, such as one described in the embodiment of FIGS. 5-6, and the connections to the circuit may be fabricated with an Al process, such as one described in the embodiment of FIGS. 7-8.

[0037] Then, at block 404, a first part 308 of a flexible package 300 is fabricated, wherein the flexible package 300 includes space to house the flexible electronic device 304 manufactured at block 402. Next, the flexible electronic device 304 of block 402 may be embedded in the flexible package 300 of block 406. Then, at block 408, a second part 310 of a flexible package 300 may be fabricated to match the first part 308 of the flexible package of block 404. At block 410, the second part 310 of the flexible package 300 may be sealed against the first part 308 to house the electronic device. In some embodiments, the first part 308 and the second part 310 of the flexible package of blocks 404 and 408 may be fabricated separately and joined together at block 410. In some embodiments, the second part 310 may be fabricated at block 408 directly on the first part of the flexible package 300 from block 404 and the sealing of the flexible electronic device of block 410 occurs when sufficient amounts of the second part of the flexible package have been fabricated on the first part.

[0038] A size of the flexible package and electronic device fabricated using the method of FIG. 4, or other methods to form decal electronics, may be selected based on an intended use of the electronic device. Compared to RFID stamps, the flexible devices fabricated according to FIG. 4 have complex electronics embedded in them with more functionalities and higher performance Additionally, with increased complexity and data management requirement, the size of the bare die is continuously increasing even with ultra-scaled devices projected for sub-10 nm technology node. The process of FIG. 2 and FIG. 4 make use of semiconductor manufacturing techniques to form portions of the electronic device, and thus the capabilities of a flexible device may match or exceed those of conventional rigid electronic devices. Lastly, the flexibility in wiring (irrespective of whether the wiring is fabricated using inkjet, conductive cellulose, sputtering, etc.) allows the decal electronics to be attached or printed on nearly any surface, which widens the range of applications for the flexible electronic devices. As one example application, a creative innovator or an educator can place the flexible devices as they want and can check the resultant functionality without the need for a conventional breadboard or a PCB to interconnect and support the components.

[0039] One embodiment for manufacturing electronic circuitry for formation of flexible electronic devices is a ZnO process described with reference to FIGS. 5A-I and FIG. 6. FIGS. 5A-I are perspective views of an electronic device at various stages of manufacturing using a zinc oxide (ZnO) process according to one embodiment of the disclosure. FIG. 6 is a flow chart illustrating one exemplary method for manufacturing using a zinc oxide (ZnO) process according to one embodiment of the disclosure. A method 600 begins at block 602 with oxidizing a semiconductor wafer 502 to form oxide layer 504 as shown in FIG. 5A. Next, at block 604, a metal gate 506 may be deposited and patterned as shown in FIG. 5B, such as through lift-off deposition of aluminum or through deposition and mask-based etching of aluminum. At block 606, a gate dielectric 508 may be deposited, as shown in FIG. 5C. In one embodiment, the gate dielectric 508 may be aluminum oxide (Al.sub.2O.sub.3). At block 608, source and drains 510 may be deposited on the dielectric layer 508, as shown in FIG. 5D. In one embodiment, the source and drains 510 may be deposited and patterned, such as through lift-off deposition of gold or through deposition and mask-based etching of gold. Next, at block 610, a channel 512 may be deposited and patterned, such as shown in FIG. 5E, such as through lift-off deposition of Zinc oxide (ZnO) or through deposition and mask-based etching of ZnO. Then, at block 612, the dielectric layer 508 may be removed in portions of the substrate to reveal oxide layer 504 as shown in FIG. 5F. Next, at block 614, a passivation layer 514, such as a thick photoresist (PR) may be deposited, such as shown in FIG. 5G. At block 616, the substrate may be flipped and a portion of the substrate 502 etched away to form a flexible electronic device as shown by removing portion 502A of the substrate 502 in FIG. 5H. A final flexible electronic device is shown in FIG. 5I. Although certain materials and implementations of processes are described with reference to the embodiment of FIGS. 5A-I and FIG. 6, other materials and processes may be used to form similar or same flexible electronic device as shown in FIG. 5I.

[0040] One embodiment for manufacturing electronic connections for formation of flexible electronic devices is an Al process described with reference to FIGS. 7A-E and FIG. 8. FIGS. 7A-E are perspective views of an electronic device at various stages of manufacturing using an aluminum (Al) process according to one embodiment of the disclosure. FIG. 8 is a flow chart illustrating one example method for manufacturing using an aluminum (Al) process according to one embodiment of the disclosure. A method 800 begins at 802 with oxidizing a substrate to form an oxide layer 704 on substrate 702, as shown in FIG. 7A. Next at block 804, a dielectric layer 706, such as Polyimide, may be formed on the oxide layer 704, such as shown in FIG. 7B. Then, at block 806, contacts 708 may be formed, such as shown in FIG. 7C, by depositing and patterning or lift-off deposition of Aluminum. Next, at block 808, a sensing film 710, such as Polyimide, is formed over a portion of the contacts 708, as shown in FIG. 7D. The sensing film 710 may be deposited, for example, by spin coat and mask-based patterning. Then, at block 810, a portion of the substrate 702 is removed to form a flexible device, such as by etching to release a top portion of the substrate 702 and connections formed thereon from a bulk portion 702A of the substrate 702, as shown in FIG. 7E.

[0041] Performance of electronic devices manufactured as flexible electronics and packaged in flexible packaging may nearly match performance of conventional rigid silicon-based ICs. Some examples of various electronic devices and measured characteristics of those devices are presented in FIGS. 9-17 below.

[0042] In physiological (e.g., epidermal), environmental, and organic measurements, noise immunity of the circuits is desired to improve measurement accuracy and signal conditioning of the sensing mechanisms. FIGS. 9A-H are illustrations of a flexible packaged electronic device having an inverter according to one embodiment of the disclosure and measured characteristics of the inverter. FIGS. 9A and 9B show DC and AC characteristics of a fabricated inverter. From the voltage transfer curve (VTC), the switching threshold of the inverter (VM) was calculated to be 2.9 V at the point where V.sub.out=V.sub.in. The obtained values for VM together with the relative high gains (>6.5) of the inverter shown in FIG. 9C show that the circuits can be used for applications where high noise immunity margins are desired. Here, the inverters are able to process the input signal with strong noise immunity in both high- and low-voltage regions. The fabricated inverters also show an average propagation delay in the range of 21 s. In digital circuits, switching speed is an important consideration as it can be on factor in dictating the amount of data that can be processed in a given period of time. In the case of these fabricated inverters, the obtained propagation delay shows the fast switching nature of circuit and its potential for use in high performance Internet of Everything analog and digital electronics. Furthermore, results from extended testing show stable performance of the circuit after packaging within flexible 3D printed structures.

[0043] Additionally, circuits may use zinc oxide (ZnO)-based transistors with low ON voltages (V.sub.ON) for low power consumption applications, such as those in wearable and implantable electronics where battery life is a challenging concern due to difficulty in power delivery as well as real time sensing. FIGS. 9D and 9E show the pull down transistor transfer and output curves. The fabricated transistors show effective mobilities (pal) in the range of 0.93 cm.sup.2V.sup.1s.sup.1, threshold voltage (V.sub.th) of 1.05 V, subthreshold swings (SS) of 700 mVdec1, and I.sub.ON/I.sub.OFF currents ratio of 10.sup.5. I.sub.OFF was calculated by calculating I.sub.OFF at V.sub.th minus one third of V.sub.DD. The high ratio between the I.sub.ON and I.sub.OFF currents show that the transistors are able to provide stable circuits with low stand-by power consumption. In order to provide a complete study on the effects of stress and bending limits of decal electronics, finite element analysis (FEA) was conducted for the final packaged structures and results are shown in FIGS. 9F and 9H. In wearable and implantable electronics, curvature radii far below 3 cm are required to achieve intimate contact between biological tissue and sensing mechanisms. Simulation results show that for a 1.5 cm bending radius, the packaged silicon chips are subjected 0.15 GPa of tensile stress, confirming that the electronic components can survive extreme mechanical bending conditions at a silicon thickness of 40 m. The vertical position (z-axis) of the electronic chip inside the final packaged structure is of critical importance for reducing mechanical strain on the circuit. In some embodiments, the flexible silicon platform may be embedded close to the neutral axis (center) of the structure in order to reduce the elongation percentage (strain) of the chip when uniaxial or biaxial stress is applied to the system.

[0044] Characteristics for other embodiments of electronic devices are shown in FIGS. 10A-K. FIGS. 10A-K are illustrations of a flexible packaged electronic device made from multiple decals according to one embodiment of the disclosure and measured characteristics of the decals. Data acquisition, amplification, and storage are parameters of relatively high importance that should be taken into account during the design of wearable, implantable, and other physiological and/or environmental sensing electronic devices. In some embodiments, this may be achieved with ring oscillators, NAND, and/or NOR universal gates with low-power zinc oxide-based thin film transistors. ZnO-based devices on flexible silicon may have decreased system cost and complexity and industry compatibility with silicon as a host substrate. Performance of the fabricated circuits was tested under extreme bending conditions (e.g., >1.5 cm) to obtain a complete understanding of the capabilities of the circuitry for Internet of Everything applications. A three-stage ring oscillator may be fabricated using emerging additive manufacturing technologies, such as inkjet printing and roll-to-roll printing techniques. In the case of physiological and/or environmental capacitive and resistive sensing, ring oscillators may be used as a readout circuit because the sensor load can introduce a shift in the intrinsic oscillation frequency of the circuit. In one embodiment, a ring oscillator may have an intrinsic oscillation frequency and peak-to-peak voltage (V.sub.PP) of the circuit of 7 kHz and 2 V, respectively.

[0045] In some embodiments, inkjet printing may be fused for interconnecting. The inkjet droplet formation was carefully studied to minimize parasitic drops, which is an important consideration for water-based silver nanoparticle inks. Inkjet droplet formation may be performed with a special pulse-form may include 2 bursts (e.g., 65 s each) with short trailing retention pulses and a final retention pulse. The obtained drop size for the described pulse-form was found to be approximately 10 L, but other drop sizes are possible. The nozzle voltage may be set at 50 V in order to allow correct droplet formation and full range control over the piezoelectric actuator. The printing speed was selected as 0.1 mm/sec in order to allow initial surface wetting and adhesion. The printing speed may be selected, in part, based on expected ink drift on the substrate. Once the drop reaches the substrate, it is necessary to allow enough time for the surface energy of the substrate to decrease to stable levels before new drops are printed. The printing distance from the nozzle to the substrate was set as 9 mm in order to allow precise positioning of the drop on the printed surface.

[0046] In current CMOS technology, sequential placing and bonding of ICs is used to produce high-level electronics systems in PCBs. In some embodiments, roll-to-roll printing of silicon and amorphous oxide semiconductor ICs may be used to increase the throughput of manufacturing of electronic systems. By using a low adhesive tape as a temporary host substrate and a manual roll printer as shown in FIGS. 10A-10E, decal electronics may be printed in a parallel fashion on a substrate containing inkjet-printed interconnects. The printing speed and force may be set, in one embodiment, to 1 mm/sec and 50 N, respectively. During roll printing, sufficient force may be applied between the decals and the final substrate in order to allow complete adhesion and prevent the decals from being delaminated from the final substrate during adhesive tape removal. The direction in which the tape is delaminated may impact final decal printing. In one embodiment, removal can be made parallel to the horizontal axis. In another embodiment, delamination may be performed with an inclination of 450 with respect to the horizontal axis of the final substrate to prevent decal delamination. The NAND gates shown in FIGS. 10H and 10I and NOR gates shown in FIGS. 10J and 10K demonstrate the ability of decal electronics to provide complete data storage and processing capabilities in Internet of Everything applications. Characterization of the gates shows low-to-high and high-to-low propagation delays in the range of 28 s and 25 s respectively for the NAND gate and 23 s and 29 s respectively for the NOR gate. Also, the gates show frequency responses in the range of 200 Hz without performance degradation.

[0047] Another embodiment of an electronic device may include a sensor, such as a bi-axial strain sensor. FIGS. 11A-I are illustrations of a flexible packaged electronic device having a bi-axial strain sensor according to one embodiment of the disclosure and measured characteristics of the inverter. Seamless integration of devices and systems for Internet of Everything applications may need reliable, flexible, and stretchable sensing mechanisms that can provide real-time and accurate information about different physiological and environmental processes. Strain and humidity sensors may be fabricated on a flexible polyimide film and embedded in flexible and inexpensive 100 micrometers thick 3D printed packages. One embodiment for strain sensors may be to detect physiological functions, such as breath speed and depth. FIG. 11A shows an aluminum-based bi-axial strain sensor, allowing simultaneous sensing of strain in the y- and x-axis directions. Real-time resistance measurements took place as the decal containing the embedded sensor was bent from 10 to 0.5 cm. As strain is induced in the structure of the decals as shown in FIG. 11B, deformation within the elastic limits of the metallic sensor induces a change in the end-to-end resistance of the sensing resistor. Results show the high sensitivity of the fabricated sensors even at extreme bending conditions with a change of resistance in sensor 1 from 2.996 k to 3.11 k for 10 cm and 0.5 cm bending radii respectively for the x-axis, and from 2.996 k to 3.12 k for 10 cm and 0.5 cm bending radii respectively in the y-axis. Sensor 2 shows a change in resistance from 3.432 k to 3.443 k for 10 cm and 0.5 cm bending radii respectively in the x-axis, and from 3.432 k to 3.442 k for 10 cm and 0.5 cm bending radii respectively in the y-axis direction.

[0048] Humidity sensors, as shown in FIGS. 11C and 11E, can be used to detect different sweat levels of highly active persons, such as athletes and soldiers. In some embodiments, the sensors may be worn on clothing to provide accurate information about the activity levels and real time diagnostics for health professionals. We have studied the behavior of the fabricated humidity sensors by exposing them to different values of known relative humidity (RH) levels ranging from a dry controlled environment (10% RH) to a controlled high-humidity environment based on water vapor (97% RH). As water molecules get absorbed in the polyimide film, capacitance of the sensor increases due to a change in the relative permittivity of the structure. In this sense, the capacitance changes according to different values of RH levels. We have noticed that the capacitance change (AC) follows an exponential response for low operation frequencies (1 kHz) as shown in FIG. 11D and a linear response in the case of high operation frequencies (1 MHz) as shown in FIG. 11F due to the moisture capacity and diffusion resistance of the sensing material and the air surrounding the sensors.

[0049] Depending on the application, the operation frequency of the sensor can be selected with some tradeoffs in terms of sensitivity and linearity. In the case of low operation frequencies, the sensors exhibit larger sensitivities, in the range of 2 to 22 fF/% RH, than the sensors operated at high frequencies, which exhibit sensitivities in the range of 1 to 1.7 fF/% RH. However, sensors at high frequencies exhibit a better linearity in the response with respect to the RH value, in this sense, calibration of the sensor is easier for high operation frequencies.

[0050] In free-form electronics, contact and test pad formation is one of the highest concerns in the field due to challenges such as increased contact resistance and contact break between flexible chips and input and output pins. FIGS. 11G and 11H show one embodiment of an interconnection method for very large scale integration (VLSI) of flexible electronics. A 61-pin flexible silicon bare die chip may create an electronic system on a flexible sheet such as Polyimide. Polyimide was chosen due to inherited flexibility and advantages over flexible PCBs. Advantages when compared to FPCBs include extreme bending radii (below 3 cm), low cost, ease of fabrication, high temperature (300 C.) compatibility, and specially due to elastic moduli which allows intimate contact with isometric surfaces for future IoE devices. The connections between the bonded chip and the flexible circuit board show resistances in the range of m for most of the contact pads as shown in FIG. 11I.

[0051] Another embodiment of a flexible electronic device may include an inverter. FIGS. 12A-B are graphs illustrating and comparing I-V characteristics of a flexible device having an inverter according to one embodiment of the disclosure and a conventional inverter. FIG. 12A illustrates a VTC characteristics comparison between bulk and flexible ZnO-based inverter. FIG. 12B illustrates a VTC characteristics comparison for flexible ZnO-based inverter at different bending radii. As shown in FIGS. 12A-B, the conventional bulk and flexible devices of this disclosure share nearly identical characteristics, thus allowing the flexible electronic devices to offer similar performance as conventional rigid electronic devices.

[0052] FIGS. 13A-B are graphs illustrating and comparing gain characteristics of a flexible device having an inverter according to one embodiment of the disclosure and a conventional inverter. FIG. 13A illustrates gain comparison between bulk and flexible ZnO-based inverters. FIG. 13B illustrates gain comparison for flexible ZnO-based inverter at different bending radii. As shown in FIGS. 13A-B, the conventional bulk and flexible devices of this disclosure share nearly identical characteristics, thus allowing the flexible electronic devices to offer similar performance as conventional rigid electronic devices.

[0053] FIGS. 14A-B are graphs illustrating and comparing AC response characteristics of a flexible device having an inverter according to one embodiment of the disclosure and a conventional inverter. FIG. 14A illustrates an AC response comparison between bulk and flexible ZnO-based inverters at f=1 kHz. FIG. 14B illustrates an AC response comparison for flexible ZnO-based inverter at different bending radii at f=1 kHz. As shown in FIGS. 14A-B, the conventional bulk and flexible devices of this disclosure share nearly identical characteristics, thus allowing the flexible electronic devices to offer similar performance as conventional rigid electronic devices.

[0054] FIGS. 15A-B are graphs illustrating and comparing AC response characteristics of a flexible device having a NAND gate according to one embodiment of the disclosure and a conventional inverter. FIG. 15A illustrates an AC response comparison between bulk and flexible ZnO-based NAND gates. FIG. 15B illustrates an AC response comparison for flexible ZnO-based NAND gate at different bending radii. As shown in FIGS. 15A-B, the conventional bulk and flexible devices of this disclosure share nearly identical characteristics, thus allowing the flexible electronic devices to offer similar performance as conventional rigid electronic devices.

[0055] FIGS. 16A-B are graphs illustrating and comparing AC response characteristics of a flexible device having a NOR gate according to one embodiment of the disclosure and a conventional inverter. FIG. 16A illustrates an AC response comparison between bulk and flexible ZnO-based NOR gates. FIG. 16B illustrates an AC response comparison for a flexible ZnO-based NOR gate at different bending radii. As shown in FIGS. 16A-B, the conventional bulk and flexible devices of this disclosure share nearly identical characteristics, thus allowing the flexible electronic devices to offer similar performance as conventional rigid electronic devices.

[0056] Additional data regarding the flexible electronic devices is shown in FIG. 17. FIG. 17 includes graphs illustrating and comparing RO response characteristics of a flexible device according to one embodiment of the disclosure and a conventional inverter.

[0057] In embodiments of this disclosure, a combination of CMOS technology-compatible flexing of CMOS electronics, inkjet printing, and conductive cellulose for interconnecting, 3D printing for packaging, and roll-to-roll printing of decal electronic systems are combined to devise a high-throughput manufacturable system embodying batch processing for wide deployment of new age sleek consumer electronics for integration with asymmetric surfaces commonly available in natural species. The decal flexible electronic systems show uncompromising electrical performance, large-scale-integration density, and functionality under extreme mechanical conditions. The fabrication process is simple, affordable, and reliable. Some embodiments of the flexible electronic devices described above include use in future Internet of Everything (IoE) electronics to produce highly complex physically flexible stretchable-reconfigurable consumer electronics systems at reduced costs and production times while preserving the advantages provided by CMOS technology for data processing and storage.

[0058] Some embodiments of manufacturing methods and testing methods are described in further detail below. In one embodiment, circuit fabrication begins with standard silicon (Si) (100) wafers. First, 500 nm thermal silicon dioxide (SiO.sub.2) is grown in order to isolate the ZnO devices from the host wafers. Then, the gate metal is deposited using aluminum sputtering (e.g., at Power: 400 W; time: 600 seconds; pressure: 5 mTorr; pre-sputtering time: 100 seconds; gas: 25 sccm Ar) to achieve a thickness of 200 nm. Then, the gate metal is patterned using standard photolithography and wet etching. Next, the wafers are cleaned using acetone, isopropyl alcohol, and plasma ashing. Then, 40 nm Al.sub.2O.sub.3 are deposited on top of the wafer using atomic layer deposition (ALD) with a deposition rate of 1 per cycle at a temperature of 300 C. Next, the source and drain contacts are patterned using lift-off technique and a deposition of 10 nm/200 nm of chrome/gold (Cr/Au) on top of the wafers using sputtering (e.g., Chrome at: Power: 400 W; time: 80 seconds; pressure: 5 mTorr; pre-sputtering time: 10 seconds; gas: 25 sccm Ar; and Gold at: 400 W; time: 200 seconds; pressure: 5 mTorr; pre-sputtering time: 10 seconds; gas: 25 sccm Ar). Next, 40 nm ZnO are deposited on top of the wafers using ALD at a temperature of 100 C. in order to allow enough oxygen vacancies to be present in the semiconducting film and enhance the performance of the TFTs. Following this, photolithography is performed on the wafers to pattern the channel of the devices and the gate dielectric. Then, the ZnO and AlO.sub.2 films are patterned using diluted hydrofluoric acid (10:1 dilution for 5 seconds) and reactive ion etching (30 seconds in CHF.sub.3 and Ar plasma), respectively. A 40 nm low-temperature (100 C.) Al.sub.2O.sub.3 is deposited on top of the wafers as passivation layer for the fabricated devices. Finally, the passivation layer is removed from the test pads to allow ohmic contact between the aluminum-based interconnects and the pads.

[0059] In one embodiment, sensor fabrication may start with standard Si (100) wafers. First, 300 nm thermal SiO.sub.2 are grown on top of the wafers in order to allow peeling of future films from the host substrate. Then, 10 m polyimide is spin-coated on top of the wafers with a speed of 3000 rpm. Next, the polyimide film is cured at 350 C. for 30 minutes. Afterwards, the sensor metal is deposited on top of the cured films using Al sputtering (e.g., at Power: 400 W; time: 900 seconds; pressure: 5 mTorr; pre-sputtering time: 100 seconds; gas: 25 sccm Ar) to target a thickness of 300 nm. Finally, the polyimide film is removed from the host Si substrate by simply peeling the polymer from the wafers. At this point, the sensors are diced and the remaining Si wafer can be recycled for future fabrication processes.

[0060] In one embodiment, circuit flexing may include, first, dicing the wafers using a semi-automated diamond tip dicing saw to allow processing of single dies. Next, each die is coated with thick photoresist (7 m) to protect the front part of the devices during future back etching steps. Next, the dies are mounted upside down on top of a carrier wafer with thermal oil and are processed using BOSCH process (regenerative reactive ion etching process) at a temperature of 20 C. The flexing process is performed in 4 different etch steps. The first step reduces the thickness of the dies from 500 m to 200 m in a single etch step. Next, the dies are cleaned and coated with fresh PR to prevent permanent PR adhesion of to the dies due to the low processing temperatures. Then, the dies are processed in 3 more etch steps that reduce 55 m each until the required silicon thickness is obtained (<50 m). In between each etch step mechanical and optical profilometer measurements are performed in order to confirm the substrate thickness and prevent over etching of the devices. Finally, the dies are cleaned to remove the PR and are ready to be flexed below 1.5 cm.

[0061] In one embodiment, 3D printed packaging and embedding may include, first, the decals are designed using SolidWorks CAD software. The sensor decals are designed using a meshed structure with a separation between lines of 100 m in order to allow the sensors to have intimate contact with the sensing surfaces. The electronics decals are designed using a solid model in order to prevent environmental factors from damaging the performance of the fabricated devices. Next, the decals are printed on a 3D printer. The electronics and sensor decals are printed in two steps in order to allow embedding of the devices inside the structure of the 3D printed package. In the case of sensors, the first layer consists of 100 m of meshed flexible polymer (PLA) while for electronics the first layer consists of 300 m solid flexible polymer. Afterwards, the first layer is printed the 3D printer is paused and the devices are embedded into the structure by placing a 3M high temperature adhesive tape on the back of the devices. Then, the printed Al foil strips are bonded to the circuit testing pads with silver epoxy in order to allow good electrical contact and low contact resistance. Next, the printing process is resumed and the second layer prints the remaining of the package on top of the embedded devices. Extra protection may be provided during embedding of ZnO circuits to prevent the high temperature polymer (210 C.) from damaging the devices. In some embodiments, the decals were designed with a small cavity (e.g., 100 m height) in the zone where the active part of the devices is located.

[0062] In one embodiment, ring oscillator printing may include, first, printing a green background on a standard A4 photography level glossy paper. Next, the paper is loaded into the inkjet printer and the interconnections are printed using silver nanoparticles based ink. The inkjet printing is done using a 50 m piezoelectric nozzle and the drops are optimized using a pulse developer. The printing pulse consists of 2 main bursts for 65 s with short trailing retention pulses and a final retention pulse. The drop size was found to be 10 pL. for an operation voltage of the nozzle at 50 V. The printing speed was selected as 0.1 mm/sec. The final resolution of the inkjet-printed lines may be 400 m. The ink is cured at 120 C. to reduce the resistance of the inkjet-printed film and allow reliable interconnections between the fabricated electronic decals. Then, the decals are placed upside down on top of a low adhesion tape as a temporary substrate. Then, the decal system is printed on top of the inkjet-printed substrate using a manual roll printer with a speed of 1 mm/sec and a printing force of 50 N in order to allow complete adhesion between the decals and the final host substrate. Finally, the temporary low adhesion tape is removed from the final substrate by simply peeling it at an angle of 45 with respect of the horizontal axis of the substrate.

[0063] In one embodiment, flexible TFTs may be tested using a semiconductor analyzer and a probe station. First, the transfer characteristics of the transistors are measured by sweeping the gate voltage from 10 to 10 V while keeping the drain voltage at 10 V and measuring the drain current (I.sub.d). Then, the output transfer curves are obtained by sweeping the drain voltage from 0 to 10 V for each gate voltage step (5 to 10 V with step size of 5 V).

[0064] In one embodiment, the fabricated devices were tested in three different configurations. First, the devices are tested in bulk (before flexing) using a semiconductor analyzer and a probe station. Then, the devices are tested after BOSCH processing (flexible) and finally after embedding the devices in the 3D printed package. In the case of the inverter, the VTC was obtained by setting the V.sub.dd voltage to 10 V, the bias voltage (V.sub.B) to 10 V, and the input voltage is swept from 10 to 10 V while measuring the output voltage. Then, the inverters are connected to an AC signal generator with a frequency of 1 kHz and a peak-to-peak voltage (V.sub.pp) of 10 V and the output waveform is measured with an oscilloscope. In the case of the NAND and the NOR gates, the output curves are obtained by using a dual output waveform generator with a V.sub.pp of 10 V and two different frequencies (100 Hz and 200 Hz) while measuring the output voltage of the fabricated circuits using an oscilloscope. Performance measurements of the flexible circuits were measured for different bending radii (e.g., 1, 1.5, 2, 2.5, 5, and 10 cm) before and after embedding in the 3D printed packages.

[0065] In one embodiment, the decals containing the embedded strain sensors are subject to bending tests while measuring the end-to-end resistance of the sensor. The measurements are carried out using a semiconductor analyzer to obtain the resistance with respect of time while the sensor is bent from flat to the different bending radii (0.5, 1, 2.5, and 10 cm). In the case of the humidity sensors, the capacitance of the embedded sensors is first measured in a controlled environment (22 C. and 10% RH) in order to obtain the initial value. The humidity characterization setup contains paths for water vapor, for which the concentration can be accurately regulated by adjusting the flow rate through mass flow controllers (MFCs). The test cell, e.g., the humidity chamber, is connected to an LCR meter and a multimeter through BNC electrical connectors. Paths for vacuum pump and a humidifier (bubbler) are connected to the test cell through controlling valves and MFCs, with flow rates up to 200 mL/min for the bubbler path. A path of dry N.sub.2 is also used for purging the chamber. The vapor is generated through the flow of nitrogen inside the bubbler creating an air-water mixture. The ratio of the partial pressure of water vapor in the mixture to the saturated vapor pressure of water at ambient temperature is the relative humidity (RH %). The water vapor mixture reaches the testing chamber through a mass flow meter. The chamber contains two sensors: a commercial humidity sensor and our fabricated sensor. The commercial sensor is used as a reference to measure the humidity levels inside the chamber. Then, the output voltage of the commercial sensor is measured through the multimeter, while capacitance changes in our fabricated sensor are measured using the connected LCR meter. Then, both the Multimeter and LCR meter are interfaced to software through a GPIB to USB cable. Thus, data acquisition and collection is automated through software. For the humidity testing of the sensor, we perform data acquisition using purging cycles, which means in between every step of changing RH levels, we purge the chamber. In this case, the % RH was varied by changing the carrier flow of the bubbler's inlet and dilution of dry N.sub.2. This purge experiment was repeated three times to prove the reproducibility of the results.

[0066] In one embodiment, fabrication of flexible circuit boards with bonded flexible silicon chips may include, first, fabricating a silicon chip using mask-less lithography (e.g., laser patterning) with a positive photoresist. Next, 10 nm/150 nm Cr/Au are sputtered on top of the wafer and patterned using lift-off technique. Then, 10 nm/150 nm Cr/Au are sputtered on top of O.sub.2 plasma treated polyimide sheet (100 m thick) to enhance adhesion between the sputtered metal and the polyimide surface. Then, the substrate is spin coated with photoresist (PR) and patterned using standard wet Au etching (for 1 min) and wet Cr etching (for 20 sec). Next, the PR is removed using acetone and IPA. Then, the silicon chip is flexed using the same procedure described in the circuit flexing section. Next, the flexible PCB and the flexible chip are mounted on a flip-chip bonding machine (in order to allow correct alignment of the pads in the silicon sample and the contacts in the flexible PCB. Next, Ag-based epoxy is dispensed on top of the contact pads of the circuit board using the automated feature of the bonding tool to prevent circuit shorting. Finally, the chip is flip-chip bonded to the board pads using a dual camera system which allows correct alignment of the bonding pads.

[0067] The schematic flow chart diagrams of FIG. 2, FIG. 4, FIG. 6 and FIG. 8 and the other methods described above are generally set forth as a logical flow chart diagram. As such, the depicted order and labeled steps are indicative of aspects of the disclosed method. Other steps and methods may be conceived that are equivalent in function, logic, or effect to one or more steps, or portions thereof, of the illustrated method. Additionally, the format and symbols employed are provided to explain the logical steps of the method and are understood not to limit the scope of the method. Although various arrow types and line types may be employed in the flow chart diagram, they are understood not to limit the scope of the corresponding method. Indeed, some arrows or other connectors may be used to indicate only the logical flow of the method. For instance, an arrow may indicate a waiting or monitoring period of unspecified duration between enumerated steps of the depicted method. Additionally, the order in which a particular method occurs may or may not strictly adhere to the order of the corresponding steps shown. Similarly, references to a first part and a second part are for understanding. For instance, references to a first part and a second part may be, e.g, reversed.

[0068] Although the present disclosure and certain representative advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the disclosure as defined by the appended claims. For example, although 3D printing is described throughout the application, manufacturing methods described herein and resulting apparatuses may be produced through any additive manufacturing technique. Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, composition of matter, means, methods and steps described in the specification. As one of ordinary skill in the art will readily appreciate from the present disclosure, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized. Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, compositions of matter, means, methods, or steps.