Magnesium material and method of manufacturing the same

Abstract

There is provided a MgN-A based magnesium material (A is a metal or non-metal element configuring a nitride, N: nitrogen originating from the nitride). The magnesium material includes a spherical MgN-A eutectic phase and nitrogen atoms are dispersed in a magnesium matrix, whereby mechanical and ignition properties of the magnesium material are improved, as compared to a magnesium material or pure magnesium material in which the nitrogen atoms are not included and only the metal or non-metal element is included.

Claims

1. A magnesium alloy having a composition of MgN-A (A: a metal or non-metal element decomposed from a nitride particle including the metal or non-metal element, and N: nitrogen atoms decomposed from the nitride particle), wherein the magnesium alloy comprising: a magnesium matrix; some of the nitrogen atoms solid-solutioned in the magnesium matrix; and eutectic phases formed by Mg of the magnesium alloy, the metal or non-metal element, and a rest of the nitrogen atoms, thereby improving mechanical and ignition properties of the magnesium alloy as compared to a magnesium material or pure magnesium material in which the nitrogen atoms are not included and only the metal or non-metal element is included, wherein the metal or non-metal element and the nitrogen atoms have 20 wt % or less, respectively in the magnesium alloy.

2. The magnesium alloy according to claim 1, wherein the nitride particle is one or more nitrides selected from a group consisting of SiNx, CuNx, ZnNx, YNx, ZrNx, CNx, MgNx, AlNx, TiNx and CuNx.

3. The magnesium alloy according to claim 2, wherein the magnesium material further comprises one or more elements selected from a group consisting of calcium (Ca), beryllium (Be), aluminum (Al), silicon (Si), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), gallium (Ga), yttrium (Y), germanium (Ge), palladium (Pd), silver (Ag), cadmium (cd), indium (In), tin (Sn), lead (Pb), bismuth (Bi), manganese (Mn), molybdenum (Mo), phosphorous (P), boron (B) and strontium (Sr).

4. A magnesium alloy having a composition of MgN-A (A: a metal or non-metal element decomposed from a nitride particle including the metal or non-metal element, and N: nitrogen atoms decomposed from the nitride particle), wherein the magnesium alloy comprising: a magnesium matrix; some of the nitrogen atoms solid-solutioned in the magnesium matrix; and eutectic phases formed by Mg of the magnesium alloy, the metal or non-metal element, and a rest of the nitrogen atoms, thereby improving mechanical and ignition properties of the magnesium alloy as compared to a magnesium material or pure magnesium material in which the nitrogen atoms are not included and only the metal or non-metal element is included, wherein the metal or non-metal element and the nitrogen atoms have 20 wt % or less, respectively in the magnesium alloy, wherein the nitride particle comprises a bulk material pressed within a pressure range in which the nitride particle is not damaged, wherein a size of the nitride particle is less than 100 nm.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a flowchart showing schematic processes of manufacturing a magnesium material having nitrogen atoms included therein according to an illustrative embodiment of the present invention.

(2) FIG. 2 is a graph showing a test result in terms of an ignition property of the magnesium material manufactured according to the illustrative embodiment.

(3) FIG. 3 is photographs of a molten magnesium material taken at an interval of 50 C.

(4) FIG. 4 is microscope photographs showing micro structures of a magnesium material (a comparative example) having only Si added thereto and a magnesium material (an illustrative embodiment) manufactured by adding silicon nitride particles.

(5) FIG. 5 is a graph showing mechanical properties of the magnesium material (a comparative example) having only Si added thereto and the magnesium material (an illustrative embodiment) manufactured by adding silicon nitride particles.

(6) FIG. 6 is a photograph of a molten material in which calcium is added to the magnesium material of the illustrative embodiment.

DETAILED DESCRIPTION OF THE INVENTION

(7) Reference will now be made in detail to exemplary embodiments of the present invention in conjunction with the accompanying drawings. Herein, detailed descriptions of some technical constructions or terms well known in the art will be omitted. Even if such descriptions are omitted, the features of the present invention will be apparent to a person skilled in the art from the following description.

(8) FIG. 1 schematically shows processes of manufacturing a magnesium material according to an illustrative embodiment of the present invention.

(9) As shown in FIG. 1, the inventors selected magnesium (metal material) and silicon nitride particles (Si.sub.3N.sub.4, 50 nm) as a matrix material and nitride nano-particles, respectively, manufactured a magnesium material in accordance with following processes and evaluated properties thereof.

(10) First, the inventors added the nitride nano-particles to a molten matrix material by using a general casting method, and could obtain unexpected results. Specifically, pure magnesium was melted using an electric melting furnace and then nitride (silicon nitride) nano-particle powders (Si.sub.3N.sub.4, 50 nm) were input to the molten material by 1 vol %. At this time, the silicon nitride nano-particle powders were not directly input to the molten material. That is, in order to prevent the silicon nitride nano-particle powders from floating, a bulk material was first manufactured by applying a pressure to the powders within a pressure range in which the powders are not damaged. Then, the bulk material was input to the molten material. The temperature of the molten material was increased to about 700 C. and was kept for 60 minutes so that the powders could be decomposed. Then, the molten material was cast to manufacture a cast material. Also, a protective gas (SF.sub.6+CO.sub.2) was used throughout the manufacturing process so as to prevent oxidation and ignition of the magnesium material.

(11) FIG. 2 shows a test result in terms of the ignition property of the material by remelting the manufactured magnesium material (i.e., the manufactured cast material was solidified to be a solid phase, which was then again melted). Specifically, it can be seen from FIG. 2 that the manufactured magnesium material was melted at about 678 C., the molten material exhibited the thermal stability up to about 850 C. and the ignition started at temperatures of 850 C. or higher. The ignition temperature is significantly increased, as compared to a conventional magnesium material.

(12) FIG. 3 is photographs of a molten material of the above manufactured magnesium material, which are taken at an interval of 50 C. from 680 C. to 850 C.

(13) As described above, in order to analyze the reason to improve the ignition property, the inventors analyzed a micro structure of the manufactured magnesium material. Specifically, the magnesium material (the material manufactured by adding the silicon nitride nano-particle powders) and a material manufactured by adding only silicon (Si) to magnesium by the same mass ratio as the silicon nitride nano-particle powders were observed with a scanning electron microscope. The results are shown in FIG. 4.

(14) As shown in FIG. 4, the magnesium material manufactured by adding only Si and the magnesium material manufactured according to the above illustrative embodiment have totally different structures. That is, in the magnesium material manufactured by adding only Si (refer to a left photograph of FIG. 4), only a eutectic phase (Mg.sub.2Si) having a lamella structure of magnesium and silicon is observed. In contrast, in the magnesium material manufactured by adding silicon nitride according to the above illustrative embodiment (refer to a right photograph of FIG. 4), eutectic phases are agglomerated to form a substantially spherical eutectic phase. Also, the eutectic phase consists of MgSiN (refer to an inset in FIG. 4), and nitrogen atoms originating from the silicon nitride are dispersed in the magnesium matrix. That is, it seems that the nitride is decomposed and the nitrogen atoms configuring the nitride are diffused and dispersed in the magnesium matrix. It also seems that the ignition property of the magnesium material of the illustrative embodiment has been improved by the micro structure. That is, when the nitride nano-particles are input to the molten material, the metal or non-metal element (Si, in the illustrative embodiment) configuring the nitride and nitrogen atoms form the spherical eutectic phase with magnesium, and some nitrogen atoms are dispersed in the magnesium matrix, so that the exceptional ignition property improvement effect is exhibited. In the meantime, when a size of the nitride nano-particle is greater than 100 nm, an energy barrier for diffusion is not sufficiently lowered, so that the diffusion is not made well even though the thermal energy is applied. Therefore, according to the manufacturing method of the present invention, it is preferably to use the nitride nano-particles having a size of about 100 nm or less, from a standpoint of the energy barrier.

(15) Like this, the magnesium material of the present invention can be expressed by a formula of Mg.sub.100-x-yN.sub.xA.sub.y in which A is a metal or non-metal element configuring a nitride, N is nitrogen originating from the nitride, and x and y are respectively 20 wt % or less in a total weight of the magnesium material. That is, when an amount of an addition element is added by 20% or greater of a magnesium material, it is difficult to consider it as a magnesium material.

(16) Further, the inventors performed a tensile test so as to analyze the mechanical properties of the manufactured magnesium materials. The results are shown in a graph of FIG. 5.

(17) As shown in FIG. 5, a yield strength of the magnesium material of the above illustrative embodiment was increased by about 30 MPa, as compared to a yield strength of the magnesium material in which only silicon was added. It seems that the increase in the yield strength results from the influence of the nitrogen atoms, which are entered into solid solution and are dispersed in the magnesium matrix.

(18) Also, in order to check whether the thermal stability between the above-manufactured magnesium material and an additive element is kept, the inventors added calcium (Ca) of 0.5% (mass ratio) to manufacture a magnesium material having a composition of MgNSiCa in accordance with the above-described processes, performed ignition and tensile tests and confirmed that the substantially same tendency as the above-manufactured magnesium material is exhibited. FIG. 6 is a photograph of a molten material for which the ignition property of the magnesium material having calcium added thereto was tested, in which a photograph of a molten magnesium material melted without the protective gas is presented. As shown, even though the specific element (Ca) was added for a predetermined purpose, it can be seen that the ignition was not caused.

(19) Although the present invention has been described in relation to the certain exemplary embodiments, it should be understood that the present invention is not limited thereto. The foregoing embodiments can be made into various alterations and modifications without departing from the scope of the appended Claims, and all such alterations and modifications fall within the scope of the present invention. For example, the ceramic particles, i.e., silicon nitride (Si.sub.3N.sub.4) particles have been exemplified in the illustrative embodiment. However, it should be noted that one or more nitride nano-particles selected from a nitride group having metal or non-metal element and nitrogen, such as CuNx, ZnNx, YNx, ZrNx, CNx, MgNx, AlNx, TiNx and CuNx, can be applied to the present invention and the corresponding particles can be decomposed and dispersed in a magnesium matrix and can improve the mechanical and ignition properties and the thermal stability of the molten material.

(20) In the meantime, calcium (Ca) has been exemplified as an element that is added for a predetermined purpose. However, the present invention is not limited thereto. For example, in order to provide a magnesium alloy with a predetermined property, one or more elements of beryllium (Be), aluminum (Al), silicon (Si), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), gallium (Ga), yttrium (Y), germanium (Ge), palladium (Pd), silver (Ag), cadmium (Cd), indium (In), tin (Sn), antimony (Sb), lead (Pb), bismuth (Bi), manganese (Mn), molybdenum (Mo), phosphorous (P), boron (B) and strontium (Sr) can be selected and added, in addition to the calcium (Ca).

(21) Like this, the present invention can be diversely modified and changed, which are all included within the scope of the present invention. Therefore, the present invention shall be defined by only the claims and their equivalents.