LAUNDRY PRODUCTS

Abstract

Combination of reservoirs (6a, 6b, 6c) providing segregated stocks of components for laundry products to enable a user to formulate multiple doses of laundry products on demand for supplying to a washing machine drum (11), the combination comprises a first reservoir (6a) containing a stock of a first composition containing a bleach component and a second reservoir (6b) containing a stock of a second composition containing a component capable of initiating and/or promoting action of the bleach component in a subsequent wash/rinse cycle and, optionally, a stock of detergent provided in the second reservoir (6b) or an optional third reservoir (6c).

Claims

1. A combination of reservoirs providing segregated multi-dose stocks of components for laundry products to enable a user to formulate doses of laundry products on demand for supplying to a washing machine drum, the combination comprising: a first reservoir containing a stock of a first composition containing a bleach component; and a second reservoir containing a stock of a second composition containing a source of alkalinity selected from alkali metal hydroxides, alkali metal carbonates, alkali metal bicarbonates, alkali metal silicates and alkanolamines wherein the first composition and/or second composition are in liquid form.

2. The combination of reservoirs according to claim 1 wherein the source of alkalinity is present in a total amount of 10 to 50 wt % based on the total weight of the second composition.

3. The combination of reservoirs according to claim 1 wherein the bleach component of the first composition comprises an oxygen bleach system.

4. (canceled)

5. The combination of reservoirs according to claim 1, wherein the first composition comprises 0.1 wt % to 20 wt %, preferably from 1 wt % to 20 wt % of bleach component, based on the total weight of the composition.

6. The combination of reservoirs according to claim 1, wherein the first composition contains bleach component and at least one selected from (ia) fluorescer and (ib) shading dye

7. The combination of reservoirs according to claim 1, wherein the combination optionally comprises a stock of detergent provided in the second reservoir or an optional third reservoir.

8. The combination of reservoirs according to claim 1, which includes a stock of a detergent composition containing at least 40 wt % of a non-soap surfactant system and which has an in-reservoir pH of less than 8 when measured on dilution to 1% using demineralised water.

9. The combination of reservoirs according to claim 7 wherein the detergent composition contains anionic and/or nonionic surfactant.

10. (canceled)

11. The combination of reservoirs according to claim 1 wherein the bleach component comprises a percarboxylic acid or a salt thereof.

12. The combination of reservoirs according to claim 1 wherein the bleach component comprises an organic percarboxylic acid or salt thereof.

13. The combination of reservoirs according to claim 1 wherein the bleach component comprises 6-(phthalimido) peroxyhexanoic acid (PAP) or salt thereof.

Description

Apparatus

[0072] Embodiments of the apparatus aspect of the invention will now be described with reference to the following diagrammatical drawings in which:

[0073] FIG. 1 shows a representative drawing of an apparatus according to an embodiment of the invention.

[0074] FIG. 2 shows a partially cut away representative drawing of the above apparatus showing part of the cartridge arrangement.

[0075] FIG. 3 shows a cross-section drawing of a device for formulating doses of the present compositions which is integral to a washing machine.

[0076] The apparatus as illustrated in FIG. 1 has a dispensing device 1 and a dosing unit 2. The apparatus is a standalone device, designed to be placed on a countertop or similar. For example, it may be placed on a countertop in a kitchen or utility room, or may be placed on top of a washing machine.

[0077] As illustrated, the dosing unit 2 is a conventional dosing ball, which is typically made of plastics material. In use, the dosing unit is placed in a dispensing area 3 located underneath a nozzle 4. As illustrated, the dispensing area 3 is a recess provided in the device housing, and the dosing unit 2 is placed on a surface provided in the housing. However, it will be appreciated that the housing may be shaped in different ways such that, for example, the dosing unit is placed directly on the countertop (or other surface on which the device is placed) in use.

[0078] Laundry product ingredients are dispensed into the dosing unit 2 via the nozzle 4. As shown, only one nozzle is used. However, it will be appreciated that more than one nozzle may be provided. For example, different reservoirs may be in fluid communication with different nozzles such that a first reservoir is in fluid communication with a first nozzle and a second reservoir is in fluid communication with a second nozzle.

[0079] The device has a control/information interface 5. As illustrated, the interface 5 is a touch screen provided in the housing that both displays information and allows selections and information to be inputted to a computer module (not shown).

[0080] However, in other embodiments the device may be provided with a panel having buttons, dials or similar for inputting information. In other embodiments, input may be conveyed via command or gesture. It will be appreciated that a display screen in the housing of the device is not essential. The device may be configured for use without a display screen, or an external display screen on for example a phone or tablet may be coupled to the device (for example, via Bluetooth or similar).

[0081] FIG. 2 shows a partially cutaway image of the apparatus of FIG. 1. In this embodiment the interior houses three reservoir cartridges 6a, 6b, and 6c. Each cartridge houses a stock of an ingredient composition.

[0082] For example, in this non-limiting illustrated embodiment, 6a houses a detergent base composition, 6b houses a bleach composition, and 6c houses a pH switch for promoting action of the bleach composition. Each cartridge 6a, 6b, 6c has a valve 7 and each cartridge is in fluid communication with a nozzle via a flow path 8. Flow from a cartridge to the nozzle 4 (where it is dispensed) is controlled by the valve. In this embodiment therefore each valve is a metering valve, with the volume metered controlled by the computer module. The valves may be located at any point along the flow path, and other types of valve may be used. Also metering of the ingredient compositions may be achieved in other ways, for example through generation of pressure in the reservoir to force the liquid out.

[0083] The diagram shows individual flows running from each reservoir to the nozzle 4. It will be appreciated that flow paths may meet before the nozzle is reached. For example, the device may have a pre-mixing chamber in which different ingredient compositions meet before they are dispensed into the dosing unit.

[0084] In use, the dosing unit is located under the nozzle 4 (such that product dispensed through the nozzle enters a chamber of the doing device). The user inputs information about the laundry load to the computer module. Typically, data may be entered in in two or more sets, each set requiring certain information from the user. For example, Set I may be used to input the load type: whites or colours. Set II may be used to input the presence or absence of staining and, optionally, the stain type. The user may therefore select whites, grass stains, mud stains. Other data requirements may include the fabric type (cotton/polycotton/polyester) as optimal fabric care benefit agents and amounts may be different in each case; fragrance selection (different members of the household may prefer different fragrances for their clothing, or it may be desirable to fragrance bedding and towels but not clothes); extent of staining (for example, lots of grass stains, only light mud stains); size of load (small loads require less product).

[0085] An optimised wash composition is then determined and the appropriate amount from relevant cartridges dispensed. The computer module (not shown) controls the amount dispensed.

[0086] The recipe used to determine the amounts may be obtained from an internal memory within the device, or may be obtained from an external memory accessed, for example, via the internet. Often, particularly where there is more than one stain type, an algorithm may be employed to determine the optimised formulation, balancing the cleaning needs of certain stains against others.

[0087] For example, in the case where reservoir cartridge 6a houses a detergent base composition which has a high pH, it may be appropriate to dispense 6a and 6b alone to provide the laundry product. In the case where reservoir cartridge 6a houses a detergent base composition having a low pH, it may be appropriate to dispense from 6a, 6b and 6c, in order to provide a sufficient pH switch to activate the bleach component. If it is desired to provide a bleach component for cleaning or disinfecting the machine without the need for detergent surfactant, it may be appropriate to dispense from 6b and 6c alone.

[0088] It will be appreciated that various further reservoir cartridges may be provided, each containing one or more ingredients for a laundry product to enhance versatility of the system.

[0089] The user may select various options, such as type of stain and type of fabric, and the computer module may then dose appropriate amounts of components from the relevant reservoir cartridge in to the dosing ball ready to be introduced in to the washing machine drum by the user.

[0090] The illustrated embodiment concerns a standalone apparatus in which the dispensing device and the dosing unit are located externally of the washing machine.

[0091] In other embodiments a dispensing device and/or a dosing unit may be accommodated within a washing machine. The dosing unit may be arranged in fluid communication with the washing machine drum so that the dose of laundry product is supplied without the need for the user to handle it.

[0092] FIG. 3 illustrates a device which is integral to a washing machine 10. The washing machine has a drum area 11 in which articles are laundered. During a wash program, water and wash liquor enter the drum via a sprayer 12. Water enters the machine via inlet 13 (schematically and only partially shown). Water and wash liquor drain from the drum area 11 into a sump 14 and may then recirculate via recirculating pump 15 (arrows indicate direction) to be resprayed into the drum area, or may be drained via waste outlet 16. Reservoirs 6a, 6b, and 6c contain stocks of components, as before. As shown, these are cartridges that engage with dispensing means 18, although it will be appreciated that the reservoirs may be provided simply as containers into which compositions are poured. The cartridges may be loaded and changed through access flap 19.

[0093] The device has a computer module 20. As described herein the computer module controls which and optionally how much of each cartridge is dispensed. As shown here, the washing machine has a control panel 21 via which input may be provided to the computer module. As illustrated, the control panel is a touch screen. In the present case, the control panel and computer module are also the used to determine the machine program, although it will be appreciated that they may be separate.

[0094] As previously described, in use the user inputs information about the laundry load to the computer module 20. The optimal wash composition is then determined and the appropriate amount from relevant cartridges dispensed by dispensing means 18 and may be combined before entering the water flow of the machine for example in a single pipe or chamber. This may be termed a pre-mixing area 27. As illustrated, three individual pipes combine to a single pipe, via which the product is dosed. In other words, the ingredient compositions dispensed may be at least partially premixed before being diluted to provide a wash liquor. The computer module controls the amount dispensed. Embodiments of components for the laundry product are described below.

Laundry Product Components

First CompositionBleach Component

[0095] The bleach component is a component suitable for use in a laundry process. Preferably the bleach component comprises an oxygen bleach system. Such bleach systems may be, for example, a peroxygen bleach or a peroxybased or peroxygenerating system.

[0096] Mixtures of bleaches can also be used.

[0097] Preferably the bleach component is selected so as to be easy to handle and storable according to the requirements for the least hazardous class of organic peroxides. This allows the first composition to be safely transported to and stored in a domestic setting.

[0098] A preferred category of bleaches includes percarboxylic acid bleaching agents, salts and precursors thereof, especially organic percarboxylic acids, salts and precursors thereof, particularly aromatic percarboxylic acids and salts thereof and especially heteroaromatic peroxycarboxylic acids and salts thereof. Particularly preferred embodiments employ 6-(phthalimido) peroxyhexanoic acid (PAP) and salts thereof.

##STR00002##

[0099] Suitable grades of PAP are commercially available under the trade name Eureco. Example liquid grades include Eureco LX5, LX10 and LX17 which are stabilized aqueous suspensions of PAP crystals.

[0100] Further examples of oxygenbased bleach are available under the trade name Suprox.

[0101] Typically a first composition may comprise up to 20 wt % of bleach component, especially up to 19 wt % and preferably up to 18 wt %. Suitably a first composition may comprise at least 1 wt % especially at least 2 wt %, preferably at least 3 wt %, more preferably at least 4 wt % of bleach component.

[0102] Peroxygen bleaches, perborates and percarbonates may also be combined with bleach activators which lead to the in situ production during the washing process of a peroxy acid corresponding to the bleach activator. Examples of preferred peroxy acid bleach precursors or activators are TAED (N, N, N Ntetraacetyl ethylene diamine) and SNOBS (sodium nonanoyloxybenzene sulphonate).

[0103] The first composition may be in the form of a liquid, gel or powder, for example. In preferred embodiments the first composition is in the form of a liquid, which may comprise a suspension of bleach component. If the first composition and/or bleach component are in liquid form a bleach activator may preferably be provided in a different reservoir to the bleach component.

First CompositionSolvents/Carriers

[0104] Various solvents and carriers typically employed in laundry detergent formulations may be included in the first composition, provided that they are compatible with the bleach component.

[0105] The first composition containing a bleach component may optionally comprise water and/or non-aqueous carrier solvents in an amount of up to 85 wt %, preferably up to 80 wt %, more preferably up to 75 wt % or up to 70 wt %. Preferably, the first composition may contain non-aqueous carrier solvents in an amount of up to 85 wt %, preferably up to 80 wt %, more preferably up to 75 wt % or up to 70 wt %. Example solvents include glycols and other alcohols. Aqueous and non-aqueous mixtures may be employed.

Sequestrants

[0106] Especially in the case where the first composition is in liquid form, it may contain sequestrant in order to stabilise a bleach component.

[0107] Example sequestrants include HEDP (1-Hydroxyethylidene -1,1,-diphosphonic acid), for example sold as Dequest 2010, and (Diethylenetriamine penta(methylene phosphonic acid or Heptasodium DTPMP), Dequest 2066. Conveniently the compositions may contain up to 2 wt % sequestrant.

[0108] A particularly preferred first composition may comprise a suspension of 6-(phthalimido) peroxyhexanoic acid (PAP) in water with sequestrant. PAP is commercially available in various liquid forms as Eureco LX5 (stabilized water suspension with 5% PAP crystals), Eureco LX10 and LX17 (stabilized water suspensions with 10 and 17% PAP crystals, respectively.

[0109] Excellent PAP stability is achieved at pH 3.70.2.

Fluorescent Agents

[0110] It may be advantageous to include fluorescer in a composition and especially in a first composition which contains a bleach component. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts. The total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 5 wt %, preferably from 0.005 to 2 wt %, more preferably 0.01 to 0.5 wt %.

[0111] Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X and Tinopal CBS-CL, Di-amine stilbene di-sulphonic acid compounds, e.g. Tinopal DMS pure Xtra, Tinopal SBMGX, and Blankophor (Trade Mark) HRH, and Pyrazoline compounds, e.g. Blankophor SN.

[0112] Preferred fluorescers are: salts of: 2 (4-styryl-3-sulfophenyl)-2H-napthol[1,2-d]triazole,; 4,4-bis{[(4-anilino-6-(N methyl-N-2 hydroxyethyl) amino 1,3,5-triazin-2-yl)]amino}stilbene-2-2 disulfonate; 4,4-bis{[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino}stilbene-2-2 disulfonate; and 4,4-bis(2-sulfostyryl)biphenyl.

Shading Dyes

[0113] Shading dye can be used to improve the performance of the detergent compositions and may optionally be included in a first composition. Preferred dyes are violet or blue. It is believed that the deposition on fabrics of a low level of a dye of these shades, masks yellowing of fabrics. A further advantage of shading dyes is that they can be used to mask any yellow tint in the composition itself. Suitable and preferred classes of dyes are discussed below.

Direct Dyes

[0114] Direct dyes (otherwise known as substantive dyes) are the class of water soluble dyes which have an affinity for fibres and are taken up directly. Direct violet and direct blue dyes are preferred.

[0115] Preferably bis-azo or tris-azo dyes are used.

[0116] Most preferably, the direct dye is a direct violet of the following structures:

##STR00003##

wherein:
ring D and E may be independently naphthyl or phenyl as shown; R.sub.1 is selected from: hydrogen and C.sub.1-C.sub.4-alkyl, preferably hydrogen;
R.sub.2 is selected from: hydrogen, C.sub.1-C.sub.4-alkyl, substituted or unsubstituted phenyl and substituted or unsubstituted naphthyl, preferably phenyl;
R.sub.4 and R.sub.5 are independently selected from: hydrogen and C.sub.1-C.sub.4-alkyl, preferably hydrogen or methyl;
X and Y are independently selected from: hydrogen, C.sub.1-C.sub.4-alkyl and C.sub.1-C.sub.4-alkoxy; preferably the dye has X=methyl; and, Y=methoxy and n is 0, 1 or 2, preferably 1 or 2.

[0117] Preferred dyes are direct violet 7, direct violet 9, direct violet 11, direct violet 26, direct violet 31, direct violet 35, direct violet 40, direct violet 41, direct violet 51, and direct violet 99. Bis-azo copper containing dyes for example direct violet 66 may be used. The benzidene based dyes are less preferred.

[0118] Preferably the direct dye is present at 0.000001 to 1 wt % more preferably 0.00001 wt % to 0.0010 wt % of the composition.

[0119] In another embodiment the direct dye may be covalently linked to the photo-bleach, for example as described in WO2006/024612.

Acid Dyes

[0120] Cotton substantive acid dyes give benefits to cotton containing garments. Preferred dyes and mixes of dyes are blue or violet. Preferred acid dyes are:

(i) azine dyes, wherein the dye is of the following core structure:

##STR00004##

wherein R.sub.a, R.sub.b, R.sub.c and R.sub.d are selected from: H, a branched or linear C1 to C7-alkyl chain, benzyl a phenyl, and a naphthyl;
the dye is substituted with at least one SO.sub.3.sup. or COO.sup. group;
the B ring does not carry a negatively charged group or salt thereof; and
the A ring may further substituted to form a naphthyl; the dye is optionally substituted by groups selected from: amine, methyl, ethyl, hydroxyl, methoxy, ethoxy, phenoxy, Cl, Br, I, F, and NO.sub.2.

[0121] Preferred azine dyes are: acid blue 98, acid violet 50, and acid blue 59, more preferably acid violet 50 and acid blue 98.

[0122] Other preferred non-azine acid dyes are acid violet 17, acid black 1 and acid blue 29.

[0123] Preferably the acid dye is present at 0.0005 wt % to 0.01 wt % of the formulation.

Hydrophobic Dyes

[0124] The composition may comprise one or more hydrophobic dyes selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone, anthraquinone and mono-azo or di-azo dye chromophores. Hydrophobic dyes are dyes which do not contain any charged water solubilising group. Hydrophobic dyes may be selected from the groups of disperse and solvent dyes. Blue and violet anthraquinone and mono-azo dye are preferred.

[0125] Preferred dyes include solvent violet 13, disperse violet 27 disperse violet 26, disperse violet 28, disperse violet 63 and disperse violet 77.

[0126] Preferably the hydrophobic dye is present at 0.0001 wt % to 0.005 wt % of the formulation.

Basic Dyes

[0127] Basic dyes are organic dyes which carry a net positive charge. They deposit onto cotton. They are of particular utility for used in composition that contain predominantly cationic surfactants. Dyes may be selected from the basic violet and basic blue dyes listed in the Colour Index International.

[0128] Preferred examples include triarylmethane basic dyes, methane basic dye, anthraquinone basic dyes, basic blue 16, basic blue 65, basic blue 66, basic blue 67, basic blue 71, basic blue 159, basic violet 19, basic violet 35, basic violet 38, basic violet 48; basic blue 3, basic blue 75, basic blue 95, basic blue 122, basic blue 124, basic blue 141.

Reactive Dyes

[0129] Reactive dyes are dyes which contain an organic group capable of reacting with cellulose and linking the dye to cellulose with a covalent bond. They deposit onto cotton.

[0130] Preferably the reactive group is hydrolysed or reactive group of the dyes has been reacted with an organic species for example a polymer, so as to the link the dye to this species. Dyes may be selected from the reactive violet and reactive blue dyes listed in the Colour Index International.

[0131] Preferred examples include reactive blue 19, reactive blue 163, reactive blue 182 and reactive blue, reactive blue 96.

Dye Conjugates

[0132] Dye conjugates are formed by binding direct, acid or basic dyes to polymers or particles via physical forces. Dependent on the choice of polymer or particle they deposit on cotton or synthetics. A description is given in WO2006/055787.

[0133] Particularly preferred dyes are: direct violet 7, direct violet 9, direct violet 11, direct violet 26, direct violet 31, direct violet 35, direct violet 40, direct violet 41, direct violet 51, direct violet 99, acid blue 98, acid violet 50, acid blue 59, acid violet 17, acid black 1, acid blue 29, solvent violet 13, disperse violet 27 disperse violet 26, disperse violet 28, disperse violet 63, disperse violet 77 and mixtures thereof.

[0134] Shading dye can be used in the absence of fluorescer, but it is especially preferred to use a shading dye in combination with a fluorescer, for example in order to reduce yellowing due to chemical changes in adsorbed fluorescer.

[0135] Particularly preferred embodiments of the first composition comprise bleach component in combination with at least one of (ia) fluorescer and/or (ib) shading dye.

Second Composition

[0136] The second composition may preferably function as a pH switch to enhance performance of the bleach component during the wash cycle.

pH Adjustment Agents

[0137] Example pH adjustment may be effected with an alkanolamine, such as monoethanolamine MEA, diethanolamine and triethanolamine TEA; alkali metal hydroxides, such as NaOH and KOH; alkali metal carbonates and bicarbonates such as sodium carbonate/bicarbonate and alkali metal silicates such as sodium silicate. Mixtures of bases may be employed.

[0138] Preferably the second composition for providing a pH switch has an in-reservoir pH of at least 8, preferably at least 9, more preferably at least 10, especially at least 11, most preferably at least 12 and optionally at least 13. The concentration of base is selected in order to provide an in wash pH of 8 to 11, preferably 8 to 10, optionally 8 to 9.5, particularly 8 to 9.

Builders and Sequestrants

[0139] The second composition also preferably includes builder and/or sequestrant. Examples include the alkali metal carbonates, citrates, succinates, malonates, carboxymethyl succinates, carboxylates, polycarboxylates and polyacetyl carboxylates. Specific examples include sodium, potassium and lithium salts of oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, and citric acid. Other examples are DEQUEST, organic phosphonate type sequestering agents sold by Monsanto and alkanehydroxy phosphonates. Salts of carbonic acid and citric acid are preferred, especially sodium carbonate and sodium citrate.

[0140] Other suitable organic builders include the higher molecular weight polymers and copolymers known to have builder properties. For example, such materials include appropriate polyacrylic acid, polymaleic acid, and polyacrylic/polymaleic acid copolymers and their salts, for example those sold by BASF under the name SOKALAN.

[0141] An appropriate amount of builder will depend upon the product form of the composition in particular whether it is a powder or a liquid. In preferred embodiments of the invention the second composition is in liquid form. Preferably the second composition contains from 5 to 40 wt % of builder component, especially up to 30 wt %, more preferably up to 25 wt % and most preferably up to 20 wt %.

[0142] Example sequestrants are HEDP (1-Hydroxyethylidene-1,1,-diphosphonic acid), for example sold as Dequest 2010, and (Diethylenetriamine penta(methylene phosphonic acid or Heptasodium DTPMP), Dequest 2066. Preferably the compositions contain up to 5 wt % sequestrant, especially from 0.1 wt % to 3 wt %.

[0143] The second composition may additionally contain detergent components such as surfactants which are stable at the in-reservoir pH of the composition. In addition, or alternatively detergent may be provided in a third composition.

Third CompositionConcentrated Detergent Base

[0144] A third composition containing a concentrated detergent base is preferably used together with the first and second compositions in order to provide a laundry detergent formulation. Preferably such a third composition does not contain a bleach component.

[0145] Example components for a concentrated detergent base composition include the following:

Surfactants

[0146] A detergent base composition may contain a surfactant system which comprises one or more non-soap surfactant components. Preferred surfactant systems comprise at least anionic or nonionic surfactant. Preferably a detergent base is a concentrated composition which contains high levels of a surfactant system. Preferred embodiments contain at least 40 wt %, preferably at least 45 wt % and most preferably at least 50 wt % of a non-soap surfactant system. Suitably the detergent base composition contains up to 80 wt % non-soap surfactant, preferably up to 70 wt %. Soaps may also be included in the compositions, as described later.

Anionic Surfactants

[0147] Preferred anionic surfactants have an anion selected from linear alkyl benzene sulfonate (LAS), primary alkyl sulfate (PAS), alkyl ether sulfate (AES) and mixtures thereof.

[0148] Preferred alkyl sulphonates are alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates (LAS) having an alkyl chain length of C.sub.8-C.sub.15. The counter ion for anionic surfactants is generally an alkali metal (such sodium) or an ammoniacal counterion (such as MEA, TEA). Suitable anionic surfactant materials are available in the marketplace as the Genapor range from Clariant. Preferred linear alkyl benzene sulphonate surfactants are Detal LAS with an alkyl chain length of from 8 to 15, more preferably 12 to 14. LAS is normally formulated into compositions in acid, i.e., HLAS form and then at least partially neutralized in-situ. Other common anionic surfactants are generally provided in pre-neutralised form.

[0149] The compositions may also contain base to provide a counterion for any anionic surfactant, together with performing pH adjustment. Typically a base provides a counterion selected from Na+, K+and ammoniacal ions. Suitable bases include potassium hydroxide, sodium hydroxide, monoethanolamine, diethanolamine and triethanolammine. Most preferred bases include potassium hydroxide and monoethanolamine. Mixtures of bases may be employed. The composition may optionally contain from 0.1 wt % to 20 wt %, preferably from 0.2 wt % to 15 wt %, more preferably 1 to 10 wt % of base.

[0150] A detergent base composition may optionally include an alkyl polyethoxylate sulphate anionic surfactant of the formula (I):

RO(C.sub.2H.sub.4O).sub.xSO.sub.3M.sup.+(I)

where R is an alkyl chain having from 10 to 22 carbon atoms, especially 12 to 16 carbon atoms and is saturated or unsaturated, M is a cation which makes the compound water-soluble, especially an alkali metal, ammonium or substituted ammonium cation, and x averages from 1 to 15, especially 1 to 3. An example is the anionic surfactant sodium lauryl ether sulphate (SLES) which is the sodium salt of lauryl ether sulphonic acid in which the predominantly C12 lauryl alkyl group has been ethoxylated with an average of 3 moles of ethylene oxide per mole.

[0151] Typically a non-soap surfactant system will contain less than 20 wt % of alkyl polyethoxylate sulfate anionic surfactant.

[0152] Some alkyl sulphate surfactant (PAS) may be used, especially the non-ethoxylated C.sub.12-15 primary and secondary alkyl sulphates. An example material, commercially available from Cognis, is Sulphopon 1214G.

[0153] When included therein the composition may contain from 0.1 wt % to 50 wt %, preferably 0.2 wt % to 50 wt %, more preferably 1 wt % to 45 wt %, and especially 5 to 40 wt % of a anionic surfactant.

Nonionic Surfactants

[0154] Nonionic surfactants include primary and secondary alcohol ethoxylates, especially C.sub.8-C.sub.20 aliphatic alcohol ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C.sub.10-C.sub.15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol. Non-ethoxylated nonionic surfactants include alkyl polyglycosides, glycerol monoethers and polyhydroxy amides (glucamide). Mixtures of nonionic surfactant may be used.

[0155] When included therein the composition may contain from 0.1 wt % to 50 wt %, preferably 0.2 wt % to 50 wt %, more preferably 1 wt % to 45 wt %, and especially 5 to 40 wt % of a nonionic surfactant, such as alcohol ethoxylate, nonylphenol ethoxylate, alkylpolyglycoside, alkyldimethylamineoxide, ethoxylated fatty acid monoethanolamide, fatty acid monoethanolamide, polyhydroxy alkyl fatty acid amide, or N-acyl N-alkyl derivatives of glucosamine (glucamides).

[0156] Nonionic surfactants that may preferably be used include the primary and secondary alcohol ethoxylates, especially the C.sub.8-C.sub.20 aliphatic alcohols ethoxylated with an average of from 1 to 35 moles of ethylene oxide per mole of alcohol, and more especially the C.sub.10-C.sub.15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.

[0157] Preferred surfactant systems comprise nonionic and anionic surfactant in a ratio in the range of 20:80 to 80:20, preferably in the range of 40:60 to 80:20 and more preferably in a range of 40:60 to 70:30.

[0158] A particularly preferred surfactant system is provided by anionic surfactant comprising linear alkyl benzene sulfonate (LAS) and nonionic surfactant comprising C.sub.10-C.sub.15 alcohol ethoxylate with 2 to 7 EO.

Amine Oxide Surfactants

[0159] The surfactant system of the composition may contain an amine oxide of the formula (2):

R.sup.1N(O)(CH.sub.2R.sup.2).sub.2 (2)

[0160] In which R.sup.1 is a long chain moiety and each CH.sub.2R.sup.2 is a short chain moiety. R.sup.2 is preferably selected from hydrogen, methyl and CH.sub.2OH. In general R.sup.1 is a primary or branched hydrocarbyl moiety which can be saturated or unsaturated, preferably, R.sup.1 is a primary alkyl moiety having chain length of from about 8 to about 18 and R.sup.2 is H. These amine oxides are illustrated by C.sub.12-14alkyldimethyl amine oxide, hexadecyl dimethylamine oxide, octadecylamine oxide.

[0161] Example amine oxide materials are Lauryl dimethylamine oxide, also known as dodecyldimethylamine oxide or DDAO, commercially available from Hunstman under the trade name Empigen OB.

[0162] Amine oxides suitable for use herein are also available from Akzo Chemie and Ethyl Corp. See McCutcheon's compilation and Kirk-Othmer review article for alternate amine oxide manufacturers.

[0163] Preferably the detergent compositions contain less than 10 wt %, more preferably less than 5 wt % and especially less than 2 wt % amine oxide surfactant.

Zwitterionic Surfactants

[0164] Some zwitterionic surfactant, such as sulphobetaine, may be present. A preferred zwitterionic material is a betaine available from Huntsman under the name Empigen BB.

[0165] Preferably the detergent compositions contain less than 10 wt %, more preferably less than 5 wt % and especially less than 2 wt % zwitterionic surfactant.

Cationic Surfactants

[0166] Cationic surfactants are preferably substantially absent from the third composition which provides a detergent base composition.

A polymer system

[0167] A detergent base composition may preferably contain a polymer system which comprises at least one of the following (bi) to (biii): [0168] (bi) one or more particulate soil removal polymer(s) and/or [0169] (bii) one or more anti-redeposition polymer(s) and/or [0170] (biii) one or more soil release polymer(s).

[0171] The inclusion of such a polymer system results in enhanced weight efficiency for the compositions. In particular it has been found that such a polymer system contributes to the good dissolution characteristics of the compositions and allows for a reduction in the amount of other non-functional components and solvents required in order to achieve acceptable dissolution.

[0172] Example compositions may preferably contain up to 25 wt %, more preferably up to 20 wt % and especially up to 18 wt % of the polymer system. Preferably the compositions contain at least 5 wt %, preferably at least 6 wt % and more preferably at least 7 wt % of the polymer system.

[0173] Embodiments may employ an ethoxylated polyethylene imine polymer (EPEI) which may assist with particulate soil removal and/or perform an anti-redeposition function. Preferably the EPEI is nonionic. That means it does not have any quaternary nitrogens, or nitrogen oxides or any ionic species other than possible pH affected protonation of nitrogens.

[0174] Polyethylene imines (PEIs, especially modified PEIs) are materials composed of ethylene imine units CH2CH2NH and, where branched, the hydrogen on the nitrogen is replaced by another chain of ethylene imine units. These polyethyleneimines can be prepared, for example, by polymerizing ethyleneimine in the presence of a catalyst such as carbon dioxide, sodium bisulphite, sulphuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, and the like. Specific methods for preparing these polyamine backbones are disclosed in U.S. Pat. No. 2,182,306, Ulrich et al., issued Dec. 5, 1939; U.S. Pat. No. 3,033,746, Mayle et al., issued May 8, 1962; U.S. Pat. No. 2,208,095, Esselmann et al., issued Jul. 16, 1940; U.S. Pat. No. 2,806,839, Crowther, issued Sep. 17, 1957; U.S. Pat. No. 2,553,696, Wilson, issued May 21, 1951 and WO2006/086492 (BASF).

[0175] Preferably, the EPEI comprises a polyethyleneimine backbone wherein the modification of the polyethyleneimine backbone is intended to leave the polymer without quaternisation. Such nonionic EPEI may be represented as PEI(X)YEO where X represents the molecular weight of the unmodified PEI and Y represents the average moles of ethoxylation per nitrogen atom in the polyethyleneimine backbone. The ethoxylation number Y may range from 9 to 40 ethoxy moieties per modification, preferably it is in the range of 16 to 26, most preferably 18 to 22. X is selected to be from about 300 to about 10000 weight average molecular weight and is preferably about 600.

[0176] A preferred example EPEI is PEI (600) 20EO.

[0177] If present, the polymer (bi) and/or (bii), such as ethoxylated polyethyleneimine polymer (EPEI), may typically be included in the composition at a level of between 0.01 and 20 wt %, and preferably at a level of at least 1 wt % and/or less than 18 wt %, more preferably at a level of from 2 wt % and/or up to 15 wt %. Particularly preferred compositions contain 3 wt % to 10 wt % and especially 5 to 10 wt % or 4 to 10 wt % EPEI. A ratio of non-soap surfactant to EPEI may preferably be from 2:1 to 9:1, preferably from 3:1 to 8:1, or even to 3:1 to 7:1.

[0178] In other embodiments a polymer (bi) and/or (bii) may be omitted.

Soil Release Polymer

[0179] A polymer system of the composition preferably comprises at least some soil release polymer for oily soil removal, especially from polyester.

[0180] Soil release polymers improve the main wash performance of the compositions when used in the low in wash surfactant process of the present invention.

[0181] One preferred class of polymer is the fabric-substantive polymers comprising at least one of (i) saccharide or (ii) dicarboxylic acid and polyol monomer units. Typically these have soil release properties and while they can have a primary detergency effect they generally assist in subsequent cleaning. Preferably these should be present at a level of at least 2% wt preferably at least 3 wt % of the composition.

[0182] If present, the soil release polymer(s) (biii) will generally comprise up to 12.0 wt %, of the detergent composition, preferably up to 9 or 10 wt %. Preferably they are used in an amount of at least 1 or perhaps 2 wt %. Most preferably they are used in an amount of 1 to 9 wt %, more preferably 2 wt % to 9 wt %, especially 2 wt % to 8 wt %.

[0183] Generally the soil release polymers for polyester will comprise polymers of aromatic dicarboxylic acids and alkylene glycols (including polymers containing polyalkylene glycols).

[0184] The polymeric soil release agents useful herein especially include those soil release agents having: [0185] (a) one or more nonionic hydrophilic components consisting essentially of: [0186] (i) polyoxyethylene segments with a degree of polymerization of at least 2, or [0187] (ii) oxypropylene or polyoxypropylene segments with a degree of polymerization of from 2 to 10, wherein said hydrophilic segment does not encompass any oxypropylene unit unless it is bonded to adjacent moieties at each end by ether linkages, or [0188] (iii) a mixture of oxyalkylene units comprising oxyethylene and from 1 to about 30 oxypropylene units wherein said mixture contains a sufficient amount of oxyethylene units such that the hydrophilic component has hydrophilicity great enough to increase the hydrophilicity of conventional polyester synthetic fibre surfaces upon deposit of the soil release agent on such surface, said hydrophilic segments preferably comprising at least about 25% oxyethylene units and more preferably, especially for such components having about 20 to 30 oxypropylene units, at least about 50% oxyethylene units; or [0189] (b) one or more hydrophobic components comprising: [0190] (i) C.sub.3 oxyalkylene terephthalate segments, wherein, if said hydrophobic components also comprise oxyethylene terephthalate, the ratio of oxyethylene terephthalate: C.sub.3 oxyalkylene terephthalate units is about 2:1 or lower, [0191] (ii) C.sub.4-C.sub.6 alkylene or oxy C.sub.4-C.sub.6 alkylene segments, or mixtures therein, [0192] (iii) poly (vinyl ester) segments, preferably polyvinyl acetate), having a degree of polymerization of at least 2, or (iv) C.sub.1-C.sub.4 alkyl ether or C.sub.4 hydroxyalkyl ether substituents, or mixtures therein, wherein said substituents are present in the form of C.sub.1-C.sub.4 alkyl ether or C.sub.4 hydroxyalkyl ether cellulose derivatives, or mixtures therein, and such cellulose derivatives are amphiphilic, whereby they have a sufficient level of C.sub.1-C.sub.4 alkyl ether and/or C.sub.4 hydroxyalkyl ether units to deposit upon conventional polyester synthetic fibre surfaces and retain a sufficient level of hydroxyls, once adhered to such conventional synthetic fibre surface, to increase fibre surface hydrophilicity, or a combination of (a) and (b).

[0193] Typically, the polyoxyethylene segments of (a)(i) will have a degree of polymerization of from about 200, although higher levels can be used, preferably from 3 to about 150, more preferably from 6 to about 100. Suitable oxy C.sub.4-C.sub.6 alkylene hydrophobic segments include, but are not limited to, end-caps of polymeric soil release agents such as MO.sub.3 S(CH.sub.2).sub.nOCH.sub.2 CH.sub.2 O, where M is sodium and n is an integer from 4-6, as disclosed in U.S. Pat. No. 4,721,580, issued Jan. 26, 1988 to Gosselink.

[0194] Soil release agents characterized by poly(vinyl ester) hydrophobic segments include graft copolymers of poly(vinyl ester), e.g., C.sub.1-C.sub.6 vinyl esters, preferably poly(vinyl acetate) grafted onto polyalkylene oxide backbones, such as polyethylene oxide backbones. See European Patent Application 0 219 048, published Apr. 22, 1987 by Kud, et al. Commercially available soil release agents of this kind include the SOKALAN type of material, e.g., SOKALAN HP-22, available from BASF (West Germany).

[0195] One type of preferred soil release agent is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymeric soil release agent is in the range of from about 25,000 to about 55,000. See U.S. Pat. No. 3,959,230 to Hays, issued May 25, 1976 and U.S. Pat. No. 3,893,929 to Basadur issued Jul. 8, 1975.

[0196] Another preferred polymeric soil release agent is a polyester with repeat units of ethylene terephthalate units contains 10 to 15 wt % of ethylene terephthalate units together with 90 to 80 wt % weight of polyoxyethylene terephthalate units, derived from a polyoxyethylene glycol of average molecular weight 300-5,000. Examples of this polymer include the commercially available material ZELCON 5126 (from DuPont) and MILEASE T (from ICI). See also U.S. Pat. No. 4,702,857, issued Oct. 27, 1987 to Gosselink.

[0197] Another preferred polymeric soil release agent is a sulphonated product of a substantially linear ester oligomer comprised of an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeat units and terminal moieties covalently attached to the backbone. These soil release agents are described fully in U.S. Pat. No. 4,968,451, issued Nov. 6, 1990 to J. J. Scheibel and E. P. Gosselink. Other suitable polymeric soil release agents include the terephthalate polyesters of U.S. Pat. No. 4,711,730, issued Dec. 8, 1987 to Gosselink et al, the anionic end-capped oligomeric esters of U.S. Pat. No. 4,721,580, issued Jan. 26, 1988 to Gosselink, and the block polyester oligomeric compounds of U.S. Pat. No. 4,702,857, issued Oct. 27, 1987 to Gosselink.

[0198] Preferred polymeric soil release agents also include the soil release agents of U.S. Pat. No. 4,877,896, issued Oct. 31, 1989 to Maldonado et al, which discloses anionic, especially sulfoarolyl, end-capped terephthalate esters.

[0199] Still another preferred soil release agent is an oligomer with repeat units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy and oxy-1,2-propylene units. The repeat units form the backbone of the oligomer and are preferably terminated with modified isethionate end-caps. A particularly preferred soil release agent of this type comprises about one sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethyleneoxy and oxy-1,2-propyleneoxy units in a ratio of from about 1.7 to about 1.8, and two end-cap units of sodium 2-(2-hydroxyethoxy)-ethanesulphonate. Said soil release agent also comprises from about 0.5% to about 20%, by weight of the oligomer, of a crystalline-reducing stabilizer, preferably selected from the group consisting of xylene sulfonate, cumene sulfonate, toluene sulfonate, and mixtures thereof.

[0200] Suitable soil release polymers are described in WO 2008095626 (Clariant); WO 2006133867 (Clariant); WO 2006133868 (Clariant); WO 2005097959 (Clariant); WO 9858044 (Clariant); WO 2000004120 (Rhodia Chimie); U.S. Pat. No. 6,242,404 (Rhodia Inc); WO 2001023515 (Rhodia Inc); WO 9941346 (Rhodia Chim); WO 9815346 (Rhodia Inc); WO 9741197 (BASF); EP 728795 (BASF); U.S. Pat. No. 5,008,032 (BASF); WO 2002077063 (BASF); EP 483606 (BASF); EP 442101 (BASF); WO 9820092 (Proctor & Gamble); EP 201124 (Proctor & Gamble); EP 199403 (Proctor & Gamble); DE 2527793 (Proctor & Gamble); WO 9919429 (Proctor & Gamble); WO 9859030 (Proctor & Gamble); U.S. Pat. No. 5,834,412 (Proctor & Gamble); WO 9742285 (Proctor & Gamble); WO 9703162 (Proctor & Gamble); WO 9502030 (Proctor & Gamble); WO 9502028 (Proctor & Gamble); EP 357280 (Proctor & Gamble); U.S. Pat. No. 4,116,885 (Proctor & Gamble); WO 9532232 (Henkel); WO 9532232 (Henkel); WO 9616150 (Henkel); WO 9518207 (Henkel); EP 1099748 (Henkel); FR 2619393 (Colgate Palmolive); DE 3411941 (Colgate Palmolive); DE 3410810 (Colgate Palmolive); WO 2002018474 (RWE-DEA MINERALOEL & CHEM AG; SASOL GERMANY GMBH); EP 743358 (Textil Color AG); PL 148326 (Instytut Ciezkiej Syntezy Organicznej Blachownia, Pol.); JP 2001181692 (Lion Corp); JP 11193397 A (Lion Corp); RO 114357 (S.C. Prod Cresus S. A., Bacau, Rom.); and U.S. Pat. No. 7,119,056 (Sasol).

[0201] The most preferred soil release polymers are the water soluble/miscible or dispersible polyesters such as: linear polyesters sold under the Repel-O-Tex brand by Rhodia (Gerol), or the Texcare brand by Clariant, especially Texcare SRN100 and SRN170, and heavily branched polyesters such as those available from Sasol and described in U.S. Pat. No. 7,119,056. The polyesters are preferably nonionic and comprise a mid block of spaced apart terephthalate repeat units and at least one end block based on polyethylene glycol with a lower alkyl or hydrogen termination.

[0202] Example soil release polymers may also be of the type E-M-L-E, where the ester midblock M is connected to generally hydrophilic end blocks E, each comprising capped oligomers of polyethylene glycol, the linking moiety L is of the form B-Ar-B, where B is a urethane, amide or ester moiety. Such soil release polymers are described in WO2012/104159.

[0203] Particularly preferred polymer systems (bi), (bii) and (biii) are combinations of relatively high levels of EPEI, particularly greater than 2.5 wt % based on the composition, with soil release polymers.

[0204] The polymer system (b) may typically be present in an amount such that the ratio of polymer system (b) to surfactant system is in a range of 0.15:1 to 0.4:1, preferably 0.2:1 to 0.4:1 and more preferably 0.2:1 to 0.3:1.

Water

[0205] The detergent base compositions are intended to be highly weight efficient and as such may contain relatively low levels of water, preferably up to 15 wt % added water. Preferred embodiments contain up to 12 wt % and more preferably up to 10 wt % added water. The amount of water will vary in dependence upon the dose volume required.

[0206] The compositions may also contain water provided as a component of a raw material. Preferably the total water content of the composition (as provided by the raw materials and as added water) is less than 20 wt %, preferably less than 15 wt % and more preferably less than 12 wt %.

Fatty acid/Soap

[0207] The detergent base compositions may comprise fatty acid and/or soap, preferably in an amount up to 10 wt %, especially up to 8 wt % and most preferably up to 5 or 6 wt % fatty acid. Typically a composition may contain at least 0.1 wt % fatty acid and preferably at least 1 wt %.

[0208] Preferred example fatty acids contain 8 to 24 carbon atoms, preferably in a straight chain configuration, saturated or unsaturated. Particularly preferred fatty acids include those where the weighted average number of carbons in the alkyl/alkenyl chains is from 8 to 24, more preferably 10 to 22, most preferably from 12 to 18. Suitably fatty acids include linear and branched stearic, oleic, lauric, linoleic and tallow acids and mixtures thereof.

[0209] Particularly preferred blends of fatty acids that are commercially available include: hydrogenated topped palm kernel fatty acid, and coconut fatty acid saturated fatty acids are preferred. The fatty acid can act as a buffer in addition to preforming a builder and/or as an antifoam. Fatty acids may form part of a buffer system that provides buffering in a pH range of 5 to 9. Preferably the present detergent compositions have a pH in those ranges when measured on dilution of the liquid composition to 1% using demineralised water. The most preferred pH range all vary in dependence upon the polymer system; soil release polymers in particular can have reduced stability under certain conditions of pH.

Base

[0210] As described above in relation to the anionic surfactant, a detergent base composition may preferably contain from 1 to 15 wt %, more preferably from 1 to 10 wt % in total of base which may provide a counterion for any anionic surfactant and perform a pH adjustment function. Suitable bases include potassium hydroxide, sodium hydroxide, monoethanolamine, diethanolamine and triethanolammine. A most preferred base is monoethanolamine. Mixtures of bases may be employed.

Solvent and Hydrotropes

[0211] As the present detergent base compositions are intended to be highly weight efficient it is proposed that a base composition contains less than 40 wt %, preferably less than 35 wt %, more preferably less than 30 wt % and especially less than 20 wt % of any solvents and hydrotropes. Generally the solvents are non-amino functional.

[0212] In this context, non-amino functional solvent refers to any solvent that does not contain amino functional groups. It includes non-surfactant solvents such as C.sub.1-C.sub.5 alcohols (such as ethanol), C.sub.2-C.sub.6 diols (such as monopropylene glycol and dipropylene glycol) and C.sub.3-C.sub.9 triols (such as glycerol). In preferred embodiments the solvents are optionally selected from one or more of glycerol, monopropylene glycol (MPG) and ethanol.

[0213] The level of such solvents including non-amino functional solvents will vary in dependence upon the dose volumes required. Amino-functional materials are not included in the category of solvents as they would be classified by the skilled reader as a base.

[0214] In the present detergent base compositions the combined total amount of added water and solvents is preferably less than 45 wt % and more preferably less than 40 wt %.

Additional ingredients up to 100%

[0215] The compositions may contain additional ingredients such a fragrance, colorants, pearlisers and/or opacifiers. Typically such additional ingredients will be present in a total amount of less than 10 wt %, more preferably less than 9 wt % and especially less than 8 wt %.

[0216] Additionally or alternatively, such additional ingredients may be provided in one or more additional reservoirs.

External Structurants

[0217] The compositions may have their rheology further modified by use of a material or materials that form a structuring network within the composition. Suitable structurants include hydrogenated castor oil, microfibrous cellulose and natural based structurants for example citrus pulp fibre. Citrus pulp fibre is particularly preferred especially if lipase enzyme is included in the composition. Preferably, if utilised, such external structurants are present in an amount of less than 2 wt %, preferably less than 1 wt %.

Visual Cues

[0218] The compositions may comprise visual cues of solid material that is not dissolved in the composition. Preferred visual cues are lamellar cues formed from polymer film and possibly comprising functional ingredients that may not be as stable if exposed to the alkaline liquid. Enzymes and bleach catalysts are examples of such ingredients. Also perfume, particularly microencapsulated perfume.

Packages and Dosing

[0219] The compositions are preferably in liquid form. Each composition is preferably provided in a reservoir cartridge adapted for use with a dosing device which is operable to selectively dispense portions of a composition from a reservoir into a dosing unit upon command by a user, such as in a manner as described herein.

[0220] A reservoir cartridge may contain a stock of a composition in an amount sufficient for two or more doses, preferably for three or more and more preferably for five or more doses of laundry product. A cartridge may be disposable or be designed to be refillable.

[0221] A combination of cartridges can provide segregated stocks of components in amounts sufficient to provide multiple doses of laundry products. Directions may be provided to guide the user to make certain selections in dependence upon factors such as fabric type and nature of staining. A dosing unit (such as a ball) may also be provided as part of a kit for formulating multiple doses of laundry products.

EXAMPLES

[0222] The following concentrated liquid stock compositions were prepared:

First CompositionContaining Bleach Component

[0223] The first liquid stock composition (1.1) contained the following components: [0224] 1.1. 17% 6-(phthalimido) peroxyhexanoic acid (PAP), 2% HEDP stabilizer and 81% carrier fluid (water and glycerol). This is available as Eureco LX17 ex Solvay [0225] 1.2. 17% 6-(phthalimido) peroxyhexanoic acid (PAP), 0.035% Tinopal CBS-CL, 2% HEDP stabilizer and 81% carrier fluid (water and glycerol). [0226] 1.3. 17% 6-(phthalimido) peroxyhexanoic acid (PAP), 0.035% Tinopal CBS-CL, 0.05% acid violet 50, 2% HEDP stabilizer and 81% carrier fluid (water and glycerol).

[0227] The volume of the stock solution was 125 ml. The volume designated for a single wash was 9 ml or 10 ml with the aim of delivering between 75-200 ppm PAP in the wash.

Second CompositionpH Switch

[0228] The following second liquid stock compositions (2.1 to 2.4) were prepared: [0229] 2.1. 50 wt % NaOH and 50 wt % water. [0230] 2.2. 25 wt % NaOH, 25 wt % sodium citrate and 50 wt % water. [0231] 2.3. 50 wt % KOH and 50 wt % water. [0232] 2.4 25 wt % MEA, 25 wt % sodium citrate and 50 wt % water. The volume of each stock solution was 500 ml. The volume designated for a single wash was 20 ml.

Third CompositionDetergent Base

[0233] The following liquid stock compositions (3.1) and (3.2) were prepared: [0234] 3.1 3.3 wt % water [0235] 6.8 wt % MEA [0236] 32.6 wt % Nonionic surfactant (C12-C15 alcohol ethoxylate 7EO) [0237] 32.6 wt % LAS acid (C12-C14 alkylbenzene sulphonic acid) [0238] 5.9 wt % Fatty acid (saturated lauric fatty acid) [0239] 9.4 wt % EPEI (ethoxylated polyethylene imine polymer PEI (600) 20EO) [0240] 6 wt % Soil release polymer (Texcare SRN100) [0241] 0.035 wt % Fluorescent agent (Tinopal CBS-CL) [0242] 3.4 wt % fragrance [0243] 3.2 1.3 wt % water [0244] 2.0 wt % MPG [0245] 6.8 wt % MEA [0246] 32.6 wt % Nonionic surfactant (C12-C15 alcohol ethoxylate 7EO) [0247] 32.6 wt % LAS acid (C12-C14 alkylbenzene sulphonic acid) [0248] 5.9 wt % Fatty acid (saturated lauric fatty acid) [0249] 9.4 wt % EPEI (ethoxylated polyethylene imine polymer PEI (600) 20EO) [0250] 6 wt % Soil release polymer (Texcare SRN100) [0251] 0.035 wt % Fluorescent agent (Tinopal CBS-CL) [0252] 3.4 wt % fragrance

[0253] The volume of each stock solution was 300 ml. The volume designated for a single wash was 12-20 ml.

[0254] The stock compositions were loaded in an apparatus as illustrated in the accompanying drawings. Portions of the stock compositions were combined in a variety of ways so as to provide a range of laundry products in a dosing unit.

[0255] Combinations of 1.1 (9 ml) and one selected from each of 2.1 to 2.4 (20 ml) each provided a 29 ml dose of a laundry product for cleaning or disinfecting an empty washing machine, in the absence of a wash load.

[0256] Combinations of 1.1 (9 ml), one selected from 2.1 to 2.4 (20 ml) and one selected from 3.1 and 3.2 (12 ml) each provided a 41 ml dose of a laundry detergent composition suitable for cleaning white fabric loads stained with bleachable stains.

[0257] The provision of the compact, concentrated stock compositions provides enhanced versatility as it makes multiple laundry products available the domestic user without requiring significant storage space. These example stock compositions provide sufficient amounts for at least 25 detergent compositions.

[0258] The relative volumes of each stock composition may be adjusted in dependence upon the level of bleach required in the wash liquor (in accordance with the level of staining). Also, the detergent may be omitted altogether to provide a bleach formulation for cleaning a washing machine.