PROVISION OF LAUNDRY PRODUCT
20190136439 ยท 2019-05-09
Assignee
Inventors
- Deborah Jane Cooke (Chester, GB)
- David Moorfield (Buckley, GB)
- Katharine Jane SHAW (Bebington, Wirral, GB)
Cpc classification
D06F2101/20
TEXTILES; PAPER
C11D3/386
CHEMISTRY; METALLURGY
D06F2105/58
TEXTILES; PAPER
C11D3/30
CHEMISTRY; METALLURGY
C11D17/041
CHEMISTRY; METALLURGY
C11D17/00
CHEMISTRY; METALLURGY
G07F13/10
PHYSICS
International classification
C11D11/00
CHEMISTRY; METALLURGY
C11D3/30
CHEMISTRY; METALLURGY
C11D3/386
CHEMISTRY; METALLURGY
D06F39/00
TEXTILES; PAPER
Abstract
The invention relates to methods for providing laundry product and a device (1) for dispensing laundry product according to a recipe. The laundry product is dispensed as a result of input by the user. The device has reservoirs (17a, 17b, 17c) containing different laundry product components which are dispensed according to input from the user. The device (1) may be integral to a washing machine (10) or stand-alone.
Claims
1. A method for providing laundry product bespoke to a wash load using a device comprising a computer module which is configured to receive input concerning a laundry load based on one or more of the following criteria: (i) stain identity; (ii) fabric type and/or colour; (iii) user requirements; and (iv) user preferences; and reservoirs containing various compositions, the method comprising the steps of: (a) providing input about stains present in the wash load to the computer module and (b) providing input about the wash load fabric type and/or colour; and then causing the device to determine, based on said information, a recipe for laundry product which is optimised with respect to said input and composed of one or more compositions of the reservoirs, such that the device dispenses from one or more reservoirs to provide said laundry product wherein the computer module is configured to receive input concerning a laundry load based on at least two of said criteria and wherein the computer module receives input via a user interface which provides a list of stains from which the user is prompted to select one or more stains and wherein the user interface has a filter function which filters the stain list by one or more of: category, colour, and frequently and recently selected.
2. A device for supplying a dose of laundry product, the device having a first reservoir containing a detergent composition and at least one further reservoir containing an ingredient composition, and a computer module which is configured to receive input concerning a laundry load based on one or more of the following criteria: (i) stain identity; (ii) fabric type and/or colour; (iii) user requirements; and (iv) user preferences; wherein the computer module is programmed to determine, using the input criteria, a recipe for laundry product which is optimised with respect to said input and is composed of one or more compositions of the reservoirs, and then cause the device to dispense from one or more reservoirs to provide said laundry product wherein the computer module is configured to receive input concerning a laundry load based on at least two of said criteria and wherein the computer module receives input via a user interface which provides a list of stains from which the user is prompted to select one or more stains and wherein the user interface has a filter function which filters the stain list by one or more of: category, colour, and frequently and recently selected.
3. (canceled)
4. (canceled)
5. (canceled)
6. The method of claim 1 wherein the computer module is configured further to use load size data to determine the quantity of laundry product dispensed.
7. The method of claim 1 wherein each reservoir is a cartridge that cooperates with the housing of the device, such that the composition in the reservoir is in controllable fluid communication with a nozzle for dispensing the composition.
8. The method of claim 1 wherein the computer module is programmed with an algorithm to determine what is dispensed from each reservoir based on the input.
9. The method according to claim 1 wherein the computer module is programmed to communicate with an external source to access an algorithm and determine what is dispensed from each reservoir based on the input.
10. The method according to claim 1 wherein the device is a standalone device such that compositions are dispensed into a dosing unit.
11. The method according to claim 1 wherein the device is integral to a washing machine such that compositions are dispensed to form a wash liquor during a wash program.
12. A method of doing laundry, the method comprising: (i) providing input to the computer module of the device of claim 2; then (ii) dispensing laundry product into a dosing unit; then (iii) introducing said laundry product into a washing machine; then (iv) starting a washing machine program.
13. A method of doing laundry, the method comprising: (i) providing input to the computer module of a device according to claim 2; then (ii) starting a washing machine program.
14. The device of claim 2 wherein the computer module is configured further to use load size data to determine the quantity of laundry product dispensed.
15. The device of claim 2 wherein each reservoir is a cartridge that cooperates with the housing of the device, such that the composition in the reservoir is in controllable fluid communication with a nozzle for dispensing the composition.
16. The device of claim 2 wherein the computer module is programmed with an algorithm to determine what is dispensed from each reservoir based on the input.
17. The device of claim 2 wherein the computer module is programmed to communicate with an external source to access an algorithm and determine what is dispensed from each reservoir based on the input.
18. The device of claim 2 wherein the device is a standalone device such that compositions are dispensed into a dosing unit.
19. The device of claim 2 wherein the device is integral to a washing machine such that compositions are dispensed to form a wash liquor during a wash program.
Description
DESCRIPTION
[0073] The invention will now be described without limitation with reference to the following diagrammatical drawings in which:
[0074]
[0075]
[0076]
[0077] The apparatus as illustrated in
[0078] As illustrated, the dosing unit is a conventional dosing ball, which is typically made of plastics material. In use, the dosing unit is placed in a dispensing area 3 located underneath a nozzle 4. As illustrated, the dispensing area 3 is a recess provided in the device housing, and the dosing unit 2 is placed on a surface provided in the housing. However, it will be appreciated that the housing may be shaped in different ways such that, for example, the dosing unit is placed directly on the countertop (or other surface on which the device is placed) in use.
[0079] Laundry product ingredients are dispensed into the dosing unit 2 via the nozzle 4. As shown, only one nozzle is used. However, it will be appreciated that more than one nozzle may be provided. For example, different reservoirs may be in fluid communication with different nozzles such that a first reservoir is in fluid communication with a first nozzle and a second reservoir is in fluid communication with a second nozzle.
[0080] The device has a control/information interface 5. As illustrated, the interface 5 is a touch screen provided in the housing that both displays information and allows selections and information to be inputted to a computer module (not shown).
[0081] However, in other embodiments the device may be provided with a panel having buttons, dials or similar for inputting information. In other embodiments, input may be conveyed via command or gesture. It will be appreciated that a display screen in the housing of the device is not essential. The device may be configured for use without a display screen, or an external display screen on for example a phone or tablet may be coupled to the device (for example, via Bluetooth or similar).
[0082]
[0083] Each cartridge houses an ingredient composition as described herein. Each cartridge has a valve 7. Each cartridge is in fluid communication with the nozzle via a flow path 8. Flow from the cartridge to the nozzle (where it is dispensed) is controlled by the valve. In this embodiment therefore each valve is a metering valve, with the volume metered controlled by the computer module. It will be appreciated that the valves may be located at any point along the flow path, and other types of valve may be used. It will also be appreciated that metering of the ingredient compositions may be achieved in other ways, for example through generation of pressure in the reservoir to force the composition out.
[0084] The diagram shows individual flows running from each reservoir to the nozzle 4. It will be appreciated that flow paths may meet before the nozzle is reached. For example, the device may have a pre-mixing chamber in which different ingredient compositions meet before they are dispensed into the dosing unit.
[0085] In use, the dosing unit is located under the nozzle (such that product dispensed through the nozzle enters a chamber of the doing device). The user inputs information about the laundry load to the computer module. Typically, data may be entered in in two or more sets, each set requiring certain information from the user. For example, Set I may be used to input the load type: whites or colours. Set II may be used to input the presence or absence of staining and, optionally, the stain type. The user may therefore select whites, grass stains, mud stains. Other data requirements may include the fabric type (cotton/polycotton/polyester) as optimal fabric care benefit agents and amounts may be different in each case; fragrance selection (different members of the household may prefer different fragrances for their clothing, or it may be desirable to fragrance bedding and towels but not clothes); extent of staining (for example, lots of grass stains, only light mud stains).
[0086] The optimised wash composition is then determined and the appropriate amount from relevant cartridges dispensed. The computer module (not shown) controls the amounts dispensed.
[0087] The recipe used to determine the amounts may be obtained from an internal memory within the device, or may be obtained from an external memory accessed, for example, via the internet. Often, particularly where there is more than one stain type, an algorithm may be employed to determine the optimised formulation, balancing the cleaning needs of certain stains against others.
[0088] As described herein, the device may be separate to a washing machine, for example on a countertop or built into kitchen units (so called, standalone), or may be integral to a washing machine.
[0089] The device has a computer module 20. As described herein the computer module controls which and optionally how much of each cartridge is dispensed. As shown here, the washing machine has a control panel 21 via which input may be provided to the computer module. As illustrated, the control panel is a touch screen. In the present case, the control panel and computer module are also the used to determine the machine program, although it will be appreciated that they may be separate.
[0090] As previously described, in use the user inputs information about the laundry load to the computer module 20. The optimised wash composition is then determined and the appropriate amount from relevant cartridges dispensed by dispensing means 18 and may be combined before entering the water flow of the machine, for example in a single pipe or chamber. This may be termed a pre-mixing area 27. As illustrated, three individual pipes combine to a single pipe, via which the product is dosed. In other words, the ingredient compositions dispensed may be at least partially premixed before being diluted to provide a wash liquor. The computer module controls the amounts dispensed.
[0091] The following representative compositions may be used. It will be appreciated that it is not essential that all of the following compositions are present in the device. Further compositions may be present.
[0092] (i) Composition Comprising a Surfactant
[0093] Also referred to as a detergent formulation/composition, this composition comprises one or more surfactants. Preferably, the composition does not contain an enzyme. Preferably, the composition does not contain a bleach. Optionally, the composition does not contain a sequestrant.
[0094] Example components for the detergent composition include the following:
[0095] Anionic surfactants, for example having an anion selected from linear alkyl benzene sulfonate (LAS), primary alkyl sulfate (PAS), alkyl ether sulfate (AES) and mixtures thereof.
[0096] Nonionic surfactants, for example which may include primary and secondary alcohol ethoxylates, especially C.sub.8-C.sub.20 aliphatic alcohol ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C.sub.10-C.sub.15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol. Non-ethoxylated nonionic surfactants include alkyl polyglycosides, glycerol monoethers and polyhydroxy amides (glucamide). Mixtures of nonionic surfactant may be used.
[0097] Amine Oxide Surfactants of formula R.sup.1N(O)(CH.sub.2R.sup.2).sub.2 in which R.sup.1 is a long chain moiety and each CH.sub.2R.sup.2 is a short chain moiety. R.sup.2 is preferably selected from hydrogen, methyl and CH.sub.2OH. In general R.sup.1 is a primary or branched hydrocarbyl moiety which can be saturated or unsaturated, preferably, R.sup.1 is a primary alkyl moiety having chain length of from about 8 to about 18 and R.sup.2 is H. These amine oxides are illustrated by C.sub.12-14 alkyldimethyl amine oxide, hexadecyl dimethylamine oxide, octadecylamine oxide.
[0098] Some zwitterionic surfactant, such as sulphobetaine, may be present. A preferred zwitterionic material is a betaine available from Huntsman under the name Empigen BB.
[0099] Preferably the compositions contain less than 10 wt %, more preferably less than 5 wt % zwitterionic surfactant.
[0100] Cationic Surfactants may be included, but are preferably substantially absent from the detergent formulation.
[0101] A particularly preferred surfactant system is provided by linear alkyl benzene sulfonate (LAS) and C.sub.10-C.sub.15 alcohol ethoxylated nonionic surfactant with 2 to 7 EO.
[0102] (ii) and (iii) Compositions Comprising at Least One Enzyme
[0103] While enzymes are powerful stain removers, for many wash loads some or all enzymes may be omitted. For example, different families of enzymes are effective against different classes of stain, and a large number of laundry loads are not stained at all. Including enzymes in each and every wash may therefore be wasteful.
[0104] The inventors have observed that certain enzymes cannot be stored in combination. For example, protease and lipase cannot usually be combined in a single liquid composition because as the protease may digest the lipase on storage. Similarly, protease may digest cellulase on storage in a liquid. However, lipase gives excellent benefits on removal of fats, while cellulase gives improved fabric treatment with colour preservation and pill removal and/or background whiteness benefit (depending on the cellulase used). This means that conventional laundry projects often contain an enzyme mix.
[0105] The present invention permits, through use of more than one reservoir comprising an enzyme composition, the assorted benefits of these enzymes to be accessed in a single load.
[0106] For example, the device may comprise a reservoir (ii) containing a first composition comprising a protease and a further reservoir (iii) containing a second composition comprising a cellulase and/or a lipase. Neither, one or both of these compositions may then be supplied depending on, for example, the type of staining.
[0107] In some embodiments, the composition of reservoir (ii) comprises a protease. Suitably, the composition of reservoir (ii) does not contain a cellulase and/or a lipase. The composition of reservoir (ii) may optionally further comprise a pectate lyase.
[0108] The composition of reservoir (ii) may optionally further comprise a surfactant, for example, sodium laureth sulfate (SLES). This additional surfactant may be used to boost detergency over and about that of the detergent composition, which may be useful in the case of stained loads. Certain surfactants are also known to be more suited to enzymatic cleaning processes.
[0109] The device may dispense the composition of reservoir (ii) for stains such as grass and blood.
[0110] In some embodiments, the composition of reservoir (iii) comprises a cellulase and/or a lipase and/or an amylase. Preferably, the composition of reservoir (iii) comprises a lipase. Suitably, the composition of reservoir (iii) does not contain a protease.
[0111] In some cases, the composition of reservoir (iii) comprises a cellulase. In some cases, the composition of reservoir (iii) comprises a lipase.
[0112] In some cases, the composition of reservoir (iii) comprises an amylase.
[0113] Naturally, the composition of reservoir (iii) may comprise any combination of these enzymes.
[0114] The composition of reservoir (iii) may optionally further comprise a mannanase. The composition of reservoir (iii) may optionally further comprise a surfactant, for example SLES. As described for (ii), this additional surfactant may be used to boost detergency over and about that of the detergent composition, which may be useful in the case of stained loads.
[0115] The device may dispense the composition of reservoir (iii) for stains such as gravy, starch-based stains, chocolate and chocolate products, fatty cooking stains.
[0116] (iv) and (v) Compositions Comprising a Bleach Component and an Alkaline Component
[0117] Reservoirs of this type may be used in combination. In other words, the compositions may be dosed together, using the alkali to activate the bleach ready for, or during, a wash or a rinse process in order to provide an effective bleaching action.
[0118] These may be dispensed for tea, coffee, wine, and berry stains, as well as improving overall whiteness and providing hygiene benefits.
[0119] (iv) Composition Comprising a Bleach Component
[0120] Suitably, the composition comprising a bleach component (iv) has an in-reservoir pH equivalent to pH of 7 or less, while the composition comprising an alkali (v) is suitable for raising the pH wash liquor in order to initiate and/or promote action of the bleach component said wash liquor.
[0121] Preferably the composition containing the bleach component has an in-reservoir pH of 6 or less, and more preferably has a pH in a range of 3 to 5. If the composition is not aqueous based it may have a pH as described when measured on dilution of the liquid composition to 1% using demineralised water.
[0122] The composition comprising a bleach component may additionally contain detergent active components (e.g. surfactants) which are compatible with the bleach component, such as discussed below. The composition containing an alkali component (v) may also contain detergent active components.
[0123] The bleach component is a component suitable for use in a laundry process. Preferably the bleach component comprises an oxygen bleach system. Such bleach systems may be, for example, a peroxygen bleach or a peroxy-based or peroxy-generating system.
[0124] Mixtures of bleaches can also be used.
[0125] Preferably the bleach component is selected so as to be easy to handle and storable according to the requirements for the least hazardous class of organic peroxides. This allows the first composition to be safely transported to and stored in a domestic setting.
[0126] A preferred category of bleaches encompasses percarboxylic acid bleaching agents, salts thereof and precursors thereof, especially organic percarboxylic acids, salts thereof and precursors thereof, particularly aromatic percarboxylic acids and especially heteroaromatic peroxycarboxylic acids, salts and precursors thereof.
[0127] Particularly preferred embodiments employ 6-(phthalimido) peroxyhexanoic acid (PAP) and salts thereof. The peracid formula is shown below.
##STR00001##
[0128] Peroxygen bleaches, perborates and percarbonate bleach components may optionally be combined with bleach activators which lead to the in situ production during the washing process of a peroxy acid corresponding to the bleach activator. If such a bleach component is in liquid composition, then a bleach activator will generally be provided in a different reservoir to the bleach component.
[0129] Examples of preferred peroxy acid bleach precursors or activators are TAED (N,N,NN-tetraacetyl ethylene diamine) and SNOBS (sodium nonanoyloxybenzene sulphonate).
[0130] Typically the composition may comprise up to 20 wt % of bleach component, especially up to 19 wt % and more preferably up to 18 wt %. Suitably the composition may comprise at least 2 wt % of bleach component, preferably at least 3 wt %, more preferably at least 4 wt % and especially at least 5 wt %.
[0131] In preferred embodiments, the composition contains additional fluorescent and/or whitener components such as shading dyes. Such additional components may be present preferably in amounts of from 0.005wt % up to 5 wt %, especially up to 2 wt % and more preferably up to 1 wt %.
[0132] Fluorescent agents may be supplied and used in the form of their alkali metal salts. The total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 5 wt %, preferably from 0.005 to 2 wt %, more preferably 0.01 to 0.5 wt %.
[0133] Preferred classes of fluorescent agent are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X and Tinopal CBS-CL, Di-amine stilbene di-sulphonic acid compounds, e.g. Tinopal DMS pure Xtra, Tinopal SBMGX, and Blankophor (Trade Mark) HRH, and Pyrazoline compounds, e.g. Blankophor SN.
[0134] Preferred fluorescent agents are: salts of: 2(4-styryl-3-sulfophenyl)-2H-napthol[1,2-d]triazole,; 4,4-bis{[(4-anilino-6-(N methyl-N-2 hydroxyethyl)amino 1,3,5-triazin-2-yl)]amino}stilbene-2-2disulfonate; 4,4-bis{[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino} stilbene-2-2-disulfonate; and 4,4-bis(2-sulfostyryl)biphenyl.
[0135] Shading dyes may optionally be included. These may enhance the perception of whiteness. They may, for example, be violet or blue.
[0136] The composition of reservoir (iv) may optionally further comprise a surfactant, for example SLES. Once again, this may boost detergency over and above composition (i) alone in the presence of stains.
[0137] (v) Composition Comprising an Alkaline Component
[0138] pH adjustment may be effected with alkalinity sources such as, but not limited to: alkanolamines, such as monoethanolamine MEA, diethanolamine, and triethanolamine
[0139] TEA, and preferably MEA; alkali metal hydroxides, such as NaOH and KOH; alkali metal carbonates and bicarbonates such as sodium carbonate/bicarbonate and alkali metal silicates such as sodium silicate. Accordingly, the alkaline component may be one or more of these compounds.
[0140] The composition (v) may be up to 60 wt % in total of alkalinity components, more preferably up to 50 wt %, especially up to 40 wt %, even more preferably up to 30 wt %. For example, it may contain at least 15 wt % and preferably at least 20 wt %.
[0141] Optionally the composition has in-reservoir pH of at least 8, preferably at least 9, more preferably at least 10, especially at least 11, and most preferably at least 12. If the composition is not aqueous based it may have a pH in those ranges when measured on dilution of the liquid composition to 1% using demineralised water.
[0142] Preferably a dose of laundry product obtained from the combination of the compositions of reservoirs (iv) and (v), when diluted with 15 litres of water in a washing machine, is effective to provide a wash liquor having a pH of at least 6, preferably in a range of 7 to 11, more preferably in a range of 8 to 10, most preferably in a range of 8 to 9.5, and especially 8 to 9. Of course, different washing machine use different amount of water and dilution with greater amounts, for example 60 litres, is envisaged.
[0143] Preferably the composition contains components which function to buffer a wash liquor within a pH range of 7 to 11, more preferably 8 to 10 or to 9.5, especially 8 to 9.
[0144] The composition of reservoir (v) may include a builder. Suitable builders include inorganic materials (such as sodium citrate, sodium carbonate and sodium bicarbonate) and organic materials (such as polyacrylic acid, polymaleic acid and polyacrylic/polymaleic acid copolymers and salts thereof). The builder component(s) may be present in a total amount of from 5 wt % up to 50 wt % of the composition (v), more preferably up to 40 wt %, more preferably up to 30 wt %, especially up to 25 wt % and most preferably up to 20 wt %. The inventors believe that synergistic effects from a raised pH and lowered in-wash pCa or building enhance the detergency of both particulate and oily stains.
[0145] The composition of reservoir (v) may optionally further comprise a surfactant, for example SLES. Once again, this may boost detergency over and above composition (i) alone in the presence of stains.
[0146] (vi) Composition Comprising a Sequestrant;
[0147] The inventors have determined that the inclusion of a sixth reservoir comprising a sequestrant increases the flexibility of the device to deal with a variety of stains and garment types economically. Separating sequestrant from the composition of reservoir (i) may also permit greater flexibility of formulation of the composition of reservoir (i).
[0148] Sequestrant from reservoir (vi) may, for example, be dispensed to aid removal of bleachable stains on coloured garments, where use of a bleach may risk damage to the dye or fabric.
[0149] Suitably therefore, the composition of reservoir (vi) does not include a bleach.
[0150] Example sequestrants are HEDP (1-Hydroxyethylidene-1,1,-diphosphonic acid), for example sold as Dequest 2010, and (Diethylenetriamine penta(methylene phosphonic acid or Heptasodium DTPMP), Dequest 2066. Preferably the composition contains up to 40% w/w of a suitable sequestrant system, including mixtures of different commercial sequestrants.
[0151] The following advantages are noted:
[0152] 1. The recipe used is determined by input provided. In other words, it may be tailored to a particular wash. This means that active ingredients and benefit agents are dosed only as needed wanted, reducing waste and environmental impact. This may also improve the appearance and longevity of garments etc. Inefficient washes in which incorrect product is used leading to poor cleaning performance, necessitating additional washes, are avoided.
[0153] 2. The user does not need to understand laundry product recommendations. The device of the present invention means anyone in the household can confidently do the laundry without worrying they don't understand the products available.
[0154] 3. Each wash can be tailored to specific needs for different types and load and for different family members, including: [0155] selective non-biological washes [0156] hygiene washes for babies, pets and elderly family members [0157] garment care refresh washes for adult work wear which may be delicate [0158] tough stain removal for kids' clothes and sportswear [0159] fragrance free washes according to preference.
[0160] 4. In addition to general wash categories listed at point 2, each wash can be tailored to the specific type of stain(s), e.g. grass, beef fat, red wine.
[0161] 5. Where input would normally lead to contradictory guidance from conventional products, the device of the present invention may balance the needs of one selection against another to achieve optimal cleaning across the load, for example by dosing a not optimum but suitable component for one stain to improve fabric care, or moderating the amount of a component dispensed.
[0162] 6. Incompatible ingredients can be stored separately, and combined only in the wash liquor. Exemplary incompatible ingredient combinations are described herein.
[0163] 7. Combinations of, and relative ratios of, ingredients can be used that are outside the normal limits of liquid laundry composition stability.
[0164] It is to be understood that the examples and embodiments described herein are for illustrative purposes and that various modifications or changes in light thereof will be suggested to a person skilled in the art and are included in the spirit and scope of the invention and the appended claims.