PROCESS FOR STRAIGHTENING KERATIN FIBRES WITH A HEATING MEANS AND DENATURING AGENTS

Abstract

The invention relates to a process for straightening keratin fibres, comprising: (i) a step in which a straightening composition containing at least two denaturing agents is applied to the keratin fibres, (ii) a step in which the temperature of the keratin fibres is raised, using a heating means, to a temperature of between 110 and 250 C.

Claims

1-33. (canceled)

34. A process for straightening the hair, comprising: (i) applying to the hair a composition comprising at least two denaturing agents, and (ii) raising the temperature of the hair, using a heating means at a temperature ranging from 110 C. to 250 C.

35. The process according to claim 34, wherein the pH of the composition is less than 9.

36. The process according to claim 34, wherein the composition comprises an overall concentration of denaturing agents ranging from 2 M to 8 M.

37. The process according to claim 34, wherein the temperature ranges from 140 C. to 220 C.

38. The process according to claim 34, wherein the molar mass of the denaturing agents ranges from 40 g/mol to 600 g/mol.

39. The process according to claim 34, wherein the denaturing agents are chosen from ureas, guanidines, -hydroxy acid, and -keto acid derivative, mono-, di-, tri- or polyhydroxylated aromatic derivatives, cyclic or linear amides, surfactants or detergents, amidines, thioureas, urethanes, alcohols, polyols, amine oxides, metal salts, sulfamides, carboxylic acids, amino acids, and nitrogenous heterocycles of the imidazole or triazole family.

40. The process according to claim 34, wherein at least one of the denaturing agents is chosen from ureas.

41. The process according to claim 40, wherein the ureas are chosen from ureas of formula (I): ##STR00014## wherein: R1, R2, R3 and R4 are independently chosen from: (a) hydrogen; and (b) linear or branched Cl -C4 lower alkyl and alkenyl radicals, optionally substituted with a radical chosen from hydroxyl, amino, dimethylamino, carboxyl, carboxamide, and N-methylcarboxamide radicals, when R1, R2 and R3 are hydrogen, R4 may also denote a radical chosen from carboxamide; methoxy; ethoxy; 1,2,4-triazolyl; cyclopentyl; methoxy-carbonyl; ethoxycarbonyl; CO-CH=CH-COOH; phenyl optionally substituted with a chlorine atom or a hydroxyl radical; benzyl; and 2,5-dioxo-4-im idazolidinyl radicals, when R1 and R2 are hydrogen, R3 and R4 may also form, together with the nitrogen atom that bears them, a ring chosen from piperidine, 3-methylpyrazole, 3,5-dimethylpyrazole, and maleimide rings, and R1 and R2 and R3 and R4 may also form, together with the nitrogen atom that bears them, an imidazole ring.

42. The process according to claim 40, wherein the ureas are chosen from ureas of formula (II): ##STR00015## wherein: R5 and R6 are independently chosen from: (a) hydrogen; and (b) linear or branched Cl -C4 lower alkyl radicals, optionally substituted with a radical chosen from hydroxyl, amino, dimethylamino, carboxyl, and carboxamide radicals, and A is chosen from CH2-CH2, CHCH, CH2-CO, CONH, CHN, COCO, CHOHCHOH, (HOOC)CHCH, CHOHCO, CH2-CH2-CH2, CH2-NHCO, CHC(CH3)-CO, NHCONH, CH2-CH2-CO, CH2-N(CH3)-CH2, NHCH2-NH, COCH(CH3)-CH2, COCH2-CO, CONHCO, COCH(COOH)CH2, COCHC(COOH), COCHC(CH3), COC(NH2)=CH, COC(CH3)=N, COCHCH, COCHN, and CONCH radicals.

43. The process according to claim 34, wherein at least one of the denaturing agents is a guanidine of formula (III): ##STR00016## wherein: R1, R2, R3, R4, and R5 are independently chosen from: (a) hydrogen; and (b) linear or branched C1-C4 lower alkyl and alkenyl radicals, optionally substituted with one or two radicals chosen from hydroxyl, amino, dimethylamino, methoxy, ethoxy, carboxyl, carboxamide, N-methylcarboxamide, and SO.sub.3H radicals, when R1, R2, R3, and R4 are hydrogen, R5 may also denote a radical chosen from acetyl; chloracetyl; carboxamide; methoxy; ethoxy; 1,2,4-triazolyl; cyclopentyl; methoxycarbonyl; ethoxycarbonyl; COCHCHCOOH; phenyl optionally substituted with a chlorine atom or a hydroxyl radical; benzyl; thiazolidone; benzimidazole; benzoxazole; benzothiazole; and C(NH)NR6R7 radicals, wherein R6 and R7 are independently chosen from hydrogen and linear or branched C1-C4 lower alkyl radicals, optionally substituted with one or two radicals chosen from hydroxyl, amino, dimethylamino, carboxyl, carboxamide, and N-methylcarboxamide radicals; or alternatively a phenyl radical, when R1, R2, and R3 are hydrogen, R4 and R5 may also form, together with the nitrogen atom that bears them, a ring chosen from pyrrolidine, piperidine, pyrazole, and 1,2,4-triazole rings optionally substituted with one or two radicals chosen from hydroxyl, amino, and carboxyl radicals, and when R1 and R2 are hydrogen and R4 is hydrogen or methyl, R3 and R5 may also together form a 5-membered ring optionally containing an oxo group and the organic or mineral salts thereof.

44. The process according to claim 34, wherein at least one of the denaturing agents is an a-hydroxy acid derivative of formula (IV): ##STR00017## wherein: R is chosen from OH and NR3R4, wherein R3 and R4 are independently chosen from hydrogen and linear or branched C1-C4 alkyl radicals optionally substituted with one or two OH radicals; R1 is chosen from H, OH, NH2, CH2-COOH, and linear or branched C1-C4 alkyl radicals; R2 is chosen from H, COOH, CHOH-COOH, CF3, CHCH2, NHCONH2; linear, branched, or cyclic C1-C8 alkyl radicals optionally substituted with a radical chosen from OH, Cl, NH.sub.2, COOH, CF.sub.3 and SCH.sub.3 radicals; phenyl and benzyl radicals optionally substituted with a radical chosen from OH and OCH.sub.3; or alternatively the following radical: ##STR00018## R1 and R2 may optionally form together an oxo radical (O) or a cyclopropyl, cyclobutyl, hydroxycyclobutyl, cyclopentyl, or cyclohexyl ring with the carbon atom that bears them, or alternatively a radical of the following formula: ##STR00019## and when R1 is H, R2 may also be chosen from (CHOH)2CH2OH and (CHOH)3CH2OH radicals, and the stereoisomers, organic and mineral salts, and solvates thereof.

45. The process according to claim 34, wherein at least one of the denaturing agents is an a-keto acid derivative of formula (V): ##STR00020## wherein R5 is chosen from H, COOH, linear or branched C1-C6 alkyl radicals optionally substituted with a radical chosen from OH, COOH, and Br; phenyl and benzyl radicals optionally substituted with a radical chosen from OH and COOH; indolyl radicals, and a radical of the following formula: ##STR00021## and the stereoisomers, organic and mineral salts and solvates thereof.

46. The process according to claim 45, wherein at least one of the denaturing agents is: pyruvic acid 2-ketobutyric acid -hydroxypyruvic acid 3-methyl-2-oxobutyric acid 2-oxovaleric acid ketomalonic acid 3-methyl-2-oxovaleric acid trimethylpyruvic acid oxoacetic acid 2-ketoglutaric acid benzylformic acid 2-oxooctanoic acid 2-oxoadipic acid phenylpyruvic acid bromopyruvic acid 2-ketopimelic acid 4-hydroxyphenylpyruvic acid 3-indoleglyoxalic acid imidazolopyruvic acid HCI 2-keto-L-gulonic acid 2-carboxy--oxobenzeneacetic acid 3-indolepyruvic acid 2-ketoglutaric acid dihydrate pyruvamide N-methylpyruvamide N-ethylpyruvamide N,N-dimethylpyruvamide N-2-hydroxyethylpyruvamide or a stereoisomer, organic or mineral salt, or solvate thereof.

Description

EXAMPLE 1

[1022] A simplified hair-relaxing composition is prepared, containing a mixture of guanidine hydrochloride at a concentration of 2 M and of pyruvic acid at a concentration of 2 M, in water, as hair-relaxing active agent. This composition is applied to naturally curly African hair for 15 minutes at a temperature of 40 C., and the hair is then rapidly towel-dried.

[1023] Lock-by-lock straightening of the head of hair is then performed using a flat iron heated to 180 C., for 10 to 15 seconds. The hair is efficiently relaxed and feels soft.

EXAMPLE 2

[1024] A simplified hair-relaxing composition is prepared, containing a mixture of guanidine hydrochloride at a concentration of 4 M and of urea at a concentration of 4 M, in water, as hair-relaxing active agent. This composition is applied to naturally curly African hair for 15 minutes at a temperature of 40 C., and the hair is then rapidly towel-dried.

[1025] Lock-by-lock straightening of the head of hair is then performed using a flat iron heated to 180 C., for 10 to 15 seconds. The hair is efficiently relaxed and feels soft.

EXAMPLE 3

[1026] A simplified hair-relaxing composition is prepared, containing urea at a concentration of 2 M in water, as hair-relaxing active agent. This composition is applied to naturally curly African hair for 15 minutes at a temperature of 40 C., and the hair is then rapidly towel-dried. A second simplified hair-relaxing composition is prepared, containing pyruvic acid at a concentration of 2 M, in water, as hair-relaxing active agent. This composition is applied to the same hair for 15 minutes at a temperature of 40 C., and the hair is then rapidly towel-dried. Lock-by-lock straightening of the head of hair is then performed using a flat iron heated to 180 C., for 10 to 15 seconds. The hair is efficiently relaxed and feels soft.