Aluminium based alloys for high temperature applications and method of producing such alloys

Abstract

The present disclosure relates to aluminum based alloys and a method for producing the aluminum based alloys. The method comprises acts of, casting of the aluminum based alloy in a chilled casting mold. Then, aging the cast aluminum based alloy at a first predetermined temperature for a first predetermined time. The aging results in the formation of a first precipitate. Followed by this, solutionizing the aluminum based alloy at a second predetermined temperature for a second predetermined time such that the major alloying element is dissolved in aluminum matrix without much affecting the first precipitate. Then, aging the aluminum based alloy at a third predetermined temperature for a third predetermined time. The aging results in the formation of a second precipitate.

Claims

1. A method for producing an aluminium based alloy comprising: a. casting of the aluminium based alloy in a chilled casting mould, the aluminium based alloy including a composition in weight percentage of: copper (Cu) at 4 wt % to 6.5 wt %; Zirconium (Zr) at 0.3 wt % to 0.5 wt %; and at least one transition metal selected from a group including: (a) Niobium (Nb) at 0.3 wt % to 0.5 wt %; (b) Hafnium (Hf) at 0.3 wt % to 0.6 wt %; and (c) Vanadium (V) at 0.18 wt % to 0.36 wt %; wherein the balance being aluminium (Al) and optionally along with incidental elements of the alloy; b. aging the cast aluminium based alloy at a first predetermined temperature for a first predetermined time, wherein the aging results in the formation of first precipitate; c. solutionising the aluminium based alloy at a second predetermined temperature for a second predetermined time; and d. aging the aluminium based alloy at a third predetermined temperature for a third predetermined time, wherein the aging results in the formation of second precipitate; wherein, the first predetermined temperature is higher than the third predetermined temperature.

2. The method as claimed in claim 1 optionally comprise an act of cold working of the aluminium based alloy between acts a and b.

3. The method as claimed in claim 1 comprises an act of fast cooling of the aluminium based alloy by quenching in water bath after acts b, c and d.

4. The method as claimed in claim 1, wherein the casting mould is chilled copper mould.

5. The method as claimed in claim 1, wherein the first predetermined temperature ranges from 350 C. to 450 C., and the first predetermined time ranges from 5 hours to 40 hours.

6. The method as claimed in claim 1, wherein the second predetermined temperature ranges from 525 C. to 545 C., and the second predetermined time ranges from 15 minutes to 60 minutes.

7. The method as claimed in claim 1, wherein the third predetermined temperature ranges from 150 C. to 250 C., and the third predetermined time ranges from 2 hours to 30 hours.

8. The method as claimed in claim 1, wherein alloying elements are melted by arc melting for casting the ingot of the aluminium based alloy.

9. The method as claimed in claim 1, wherein the incidental elements are selected from a group comprising Titanium, Chromium, Manganese, Iron, Silicon, and combination thereof.

Description

BRIEF DESCRIPTION OF THE ACCOMPANYING FIGURES

(1) The novel features and characteristics of the disclosure are explained herein. The embodiments of the disclosure itself, however, as well as a preferred mode of use, further objectives and advantages thereof, will best be understood by reference to the following detailed description of an illustrative embodiment when read in conjunction with the accompanying drawings. One or more embodiments are now described, by way of example only, with reference to the accompanying drawing in which:

(2) FIG. 1 illustrates a flow chart of a method of producing an aluminum based alloy of the present disclosure.

(3) FIG. 2 illustrates Transmission Electron Microscope (TEM) Dark Field image of the quaternary Al-4.6Cu-0.33Nb-0.49Zr (wt % everywhere) alloy showing plate shaped (Al.sub.2Cu) precipitates with spherical Al.sub.3(Zr,Nb) precipitates in the final microstructure.

(4) FIG. 3 illustrates aging curve at third predetermined temperature 190 C. for quaternary Al-4.6Cu-0.33Nb-0.49Zr alloy, which is produced by the method of present disclosure, and binary Al-4.6Cu alloy produced by conventional heat treatment.

(5) FIG. 4 illustrates Scanning Transmission Electron Microscope (STEM) HAADF micrographs of binary Al-4.6Cu and quaternary Al-4.6Cu-0.33Nb-0.49Zr alloys peak aged at 190 C.

(6) FIG. 5 illustrates stability curves of peak aged (at 190 C.) binary Al-4.6Cu and quaternary Al-4.6Cu-0.33Nb-0.49Zr alloys at 250 C.

(7) FIG. 6 illustrates stability curves of peak aged (at 190 C.) binary Al-4.6Cu and quaternary Al-4.6Cu-0.33Nb-0.49Zr alloys at 300 C.

(8) FIG. 7 illustrates Scanning Transmission Electron Microscope (STEM) HAADF micrographs of peak aged (at 190 C.) binary Al-4.6Cu and quaternary Al-4.6Cu-0.33Nb-0.49Zr alloys after 50 hours exposure at 250 C.

(9) FIG. 8 illustrates tensile test curves of binary Al-4.6Cu and quaternary Al-4.6Cu-0.33Nb-0.49Zr alloy (peak aged at 190 C.) at room temperature and at 250 C.

(10) The figures depict embodiments of the disclosure for purposes of illustration only. One skilled in the art will readily recognize from the following description that alternative embodiments of the structures and methods illustrated herein may be employed without departing from the principles of the disclosure described herein.

DETAILED DESCRIPTION

(11) The foregoing has broadly outlined the features and technical advantages of the present disclosure in order that the detailed description of the disclosure that follows may be better understood. Additional features and advantages of the disclosure will be described hereinafter which form the subject of the claims of the disclosure. It should be appreciated by those skilled in the art that the conception and specific embodiment disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present disclosure. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the disclosure as set forth in the appended claims. The novel features which are believed to be characteristic of the disclosure, both as to its organization and method of operation, together with further objects and advantages will be better understood from the following description when considered in connection with the accompanying figures. It is to be expressly understood, however, that each of the figures is provided for the purpose of illustration and description only and is not intended as a definition of the limits of the present disclosure.

(12) To overcome the drawbacks mentioned in the background, the present disclosure provides a new class of aluminium alloys together with a method of producing such aluminium alloys. The aluminum alloy of the present disclosure, gives high strength at room temperature as well at high temperature ranging from 200 C. to 300 C. The class of aluminium alloys developed contains alloying additions like Zirconium (Zr), Niobium (Nb), Vanadium (V), Hafnium (Hf) or similar elements singly or in combination together with alloying additions that give high strength due to precipitation hardening like Aluminium (Al)-Copper (Cu) alloys of 2XXX series or other aluminium based alloys having similar alloying for precipitation strengthening. The alloy optionally contains incidental elements selected from a group comprising but not limiting to Titanium, Chromium, Manganese, Iron, Silicon, and combination thereof.

(13) The aluminum alloys are produced by casting in chill mould or similar processes that yield similar cooling rates. Then, the cast alloys are subjected to three stage heat treatment process, which results in both the low temperature precipitation and high temperature precipitation. The high temperature precipitates are stable at elevated temperatures and also reduce the coarsening of low temperature strengthening precipitates on exposure at elevated temperatures up to 300 C.

(14) FIG. 1 is an exemplary embodiment of the present disclosure which illustrates a flow chart of method of producing aluminium based alloy. The method comprises following acts, firstly preparing the molten metal of alloying elements optionally along with incidental elements of the aluminium based alloy. In an embodiment of the present disclosure, the alloying elements are melted by arc melting, however any similar melting process can be adapted to melt the alloying elements. In an embodiment, the alloying elements are selected from a group comprising Aluminium (Al), Copper (Cu), Zirconium (Zr), Niobium (Nb), Hafnium (Hf), Vanadium (V) and combination thereof. Further, the incidental elements are selected from a group comprising Titanium, Chromium, Manganese, Iron, Silicon, and combination thereof. The molten metal is then poured into the chilled cast mould for casting the aluminium based alloy. In an embodiment of the present disclosure, the chilled cast mould is water cooled copper mould, or any similar processes that yield similar cooling rates can be used for casting the aluminium based alloy. Further, a cold working may optionally be introduced onto the aluminium based alloy after casting the alloy, and before subjecting it to heat treatment process. In an embodiment of the present disclosure, the cold working process is selected from a group comprising but not limiting to rolling, extrusion, drawing and forging.

(15) The cast aluminium alloy is subjected to three stage heat treatment process to get a fine distribution of two precipitates, the first one at high temperature and the second one at low temperature. The three stage heat treatment process comprises of the following steps. Firstly, aging directly at first predetermined temperature ranging from 350 C. to 450 C. for a first predetermined time ranging from 5 hours to 40 hours. This first stage of heat treatment process, results in the formation of the first precipitate in the matrix, i.e., L1.sub.2 type Al.sub.3X (where X is transition metal). Then, the aluminium alloy is subjected to a fast cooling. Further, the aluminium alloy is subjected to second stage of heat treatment process, i.e., solutionizing treatment at second predetermined temperature ranging from 525 C. to 545 C. for a second predetermined time ranging from 15 minutes to 60 minutes. The solutionizing treatment on the aluminium alloy completely dissolves the elements which are responsible for low temperature precipitation like copper without affecting the high temperature precipitates. This is achieved by controlling the time and temperature for solutionizing. After solutionizing treatment, the aluminium alloy is subjected to a fast cooling. The third step of heat treatment is aging at the third predetermined temperature ranging from 150 C. to 250 C. for third predetermined time ranging from 2 hours to 30 hours. This third stage of heat treatment process results in the formation of the second precipitate in the matrix, i.e., low temperature strengthening precipitates. The high temperature Al.sub.3X precipitates reduce the coarsening of low temperature strengthening precipitates. Then, the aluminium alloy is subjected to a fast cooling. In an embodiment of the present disclosure, the fast cooling of the aluminium based alloy after each stage of the heat treatment process is done by at least one of quenching in water bath or any fast cooling technique which is known in the art.

(16) In an embodiment of the present disclosure, a new class of aluminium alloy is disclosed. The aluminium alloy of the present disclosure, gives high strength at room temperature as well at high temperature ranging from 200 C. to 300 C. The class of aluminium alloy being developed contains alloying elements such as Copper (Cu) at 4 wt % to 6.5 wt %, Zirconium (Zr) at 0.3 wt % to 0.5 wt %. At least one or combination of transition metals is added to the alloy to increase the strength. The transition metals are selected from a group comprising, Niobium (Nb) at 0.3 wt % to 0.5 wt %, Hafnium (Hf) at 0.3 wt % to 0.6 wt %, Vanadium (V) at 0.18 wt % to 0.36 wt %. The balance being aluminium (Al) optionally along with incidental elements. In an embodiment of the present disclosure, the incidental elements are selected from a group comprising but not limiting to Titanium, Chromium, Manganese, Iron, Silicon, and combination thereof.

(17) The aluminium based alloy as disclosed above would have tensile properties as following: 0.2% proof stress of 460 MPa, ultimate tensile strength of 540 MPa, and elongation to fracture of 6%, at room temperature; and 0.2% proof stress of 250 MPa, ultimate tensile strength of 260 MPa and elongation to fracture of 8.5%, at high temperature 250 C. Further, the Vickers hardness of aluminium based alloy as disclosed above would range about 1400 MPa-1520 MPa at room temperature.

Example

(18) The aluminium alloy is produced by using the method as disclosed in the present disclosure. The quaternary aluminium alloy containing copper, niobium, zirconium is made with composition Al-4.6Cu-0.33Nb-0.49Zr (wt % everywhere). The mechanical properties of this alloy are compared with a binary Al-4.6Cu alloy in peak aged condition. The quaternary alloy is prepared by arc melting process followed by remelting and casting into 3 mm rods using water cooled copper mould. After casting, this alloy is heat treated, i.e., subjected to aging at 400 C. for 10 hours, then quenched in water. This process results in the formation of L1.sub.2 type Al.sub.3(Zr,Nb) precipitates (first precipitates) with no effect on copper. Then it is subjected to solution heat treatment at 535 C. for 30 minutes so that copper dissolves into the aluminium matrix and is quenched in water to retain copper in solid solution. This treatment does not have significant effect on Al.sub.3(Zr,Nb) precipitates. Finally, an aging treatment is carried out at 190 C. for 5 hours till the peak hardness is reached. The final microstructure contains nanometric (second precipitates) and Al.sub.3(Zr,Nb) precipitates.

(19) The final TEM microstructure shows the presence of plate shaped precipitates along with spherical Al.sub.3(Zr,Nb) precipitates in FIG. 2. FIG. 3 shows aging curve at 190 C. for Al-4.6Cu alloy after conventional heat treatment and for Al-4.6Cu-0.33Nb-0.49Zr alloy after the three stage heat treatment described in the present disclosure. The peak aged hardness value for the quaternary alloy is obtained as 1475 MPa after 5 hours of aging, which is much higher than the peak hardness value of 1261 MPa obtained for the binary alloy after 10 hours of aging. FIG. 4 shows comparison of microstructure for both Al-4.6Cu and Al-4.6Cu-0.33Nb-0.49Zr alloys peak aged at 190 C., and it is clear that the size and distribution of precipitates in quaternary alloy is much finer than precipitates in the binary alloy. From FIGS. 5 and 6, it is observed that the room temperature hardness values after exposure at 250 C. and 300 C. up to 100 hours are much higher for the Al-4.6Cu-0.33Nb-0.49Zr alloy (peak aged at 190 C.) than the Al-4.6Cu alloy (peak aged at 190 C.). FIG. 7 shows microstructure of Al-4.6Cu and Al-4.6Cu-0.33Nb-0.49Zr alloys (peak aged at 190 C.) after exposure of 50 hours at 250 C. It is clear that the coarsening of precipitates is markedly less in the quaternary alloy as compared to the coarsening of precipitates in binary alloy.

(20) The tensile specimens were tested using Zwick screw driven tensile testing machine at a strain rate of 10.sup.3/sec. For high temperature testing, the samples were kept in electric furnace attached to machine and temperature was raised to 250 C. at a rate of 10 C./min. After reaching the temperature, it was held for 30 minutes in order to stabilize the temperature. FIG. 8 shows tensile test curves for both Al-4.6Cu and Al-4.6Cu-0.33Nb-0.49Zr alloys (peak aged at 190 C.) at room temperature and at 250 C. In peak aged condition, the quaternary alloy shows 0.2% proof stress of 460 MPa, ultimate tensile strength of 540 MPa and 6% elongation at room temperature. The binary alloy shows 0.2% proof stress of 250 MPa, ultimate tensile strength of 275 MPa and 12.5% elongation at room temperature. At 250 C., the quaternary alloy shows 0.2% proof stress of 250 MPa, ultimate tensile strength of 260 MPa and 8.5% elongation. On the other hand, the binary alloy shows 0.2% proof stress of 125 MPa, ultimate tensile strength of 135 MPa and 5.5% elongation at 250 C. Thus, the strength values of the quaternary alloy are much higher than the binary alloy at room temperature and at 250 C.

(21) As another example, the aluminium based alloy containing Copper, Hafnium, Zirconium is made with composition of Al-4.6Cu-0.63Hf-0.49Zr by the method of the present disclosure. The aluminium based alloy of this composition, after final aging at 190 C. for 5 hours (peak aged), has hardness value of 1496 MPa at room temperature.

(22) As yet another example, the aluminium based alloy containing Copper, Vanadium, Zirconium is made with composition of Al-4.6Cu-0.27V-0.49Zr by the method of the present disclosure. The aluminium based alloy of this composition, after final aging at 190 C. for 20 hours (peak aged), has hardness value of 1426 MPa at room temperature.

(23) Further, the aluminium based alloy containing Copper, Niobium, and Zirconium and other incidental elements in which 0.33 wt % Nb and 0.34 wt % Zr are added to 2219 Al alloy (Al-6.5Cu-0.32Mn-0.13Zr-0.06V-0.03Ti-0.05Si-0.13Fe) is produced by the method of the present disclosure. The aluminium based alloy of this composition, after final aging at 190 C. for 5 hours (peak aged), has hardness of 1515 MPa.

(24) Table 1 summarizes the peak aged hardness values at 190 C. for Al-4.6Cu and commercial 2219 aluminium alloys after conventional heat treatment, and the peak aged hardness values at 190 C. for Al-4.6Cu-0.33Nb-0.49Zr, 2219-0.33Nb-0.34Zr, Al-4.6Cu-0.63Hf-0.49Z, and Al-4.6Cu-0.27V-0.49Zr alloys after the three stage heat treatment described in the present disclosure.

(25) TABLE-US-00001 TABLE 1 Peak Aged hardness (MPa) at Heat Treatment Alloys 190 C. Conventional Al4.6Cu 1261 2219 1425 Three Stage Al4.6Cu0.33Nb0.49Zr 1475 Heat Treatment 2219-0.33Nb0.34Zr 1515 Schedule Al4.6Cu0.63Hf0.49Zr 1496 Al4.6Cu0.27V0.49Zr 1426

(26) It is to be noted that 0.2% proof stress value is expected to be about one-third of the hardness value reported in MPa.

(27) With respect to the use of substantially any plural and/or singular terms herein, those having skill in the art can translate from the plural to the singular and/or from the singular to the plural as is appropriate to the context and/or application. The various singular/plural permutations may be expressly set forth herein for the sake of clarity.

(28) While various aspects and embodiments have been disclosed herein, other aspects and embodiments will be apparent to those skilled in the art. The various aspects and embodiments disclosed herein are for purposes of illustration and are not intended to be limiting, with the true scope and spirit being indicated by the following claims.