Modified forward osmosis membrane module for flow regime improvement

Abstract

To provide a modified forward osmosis (FO) membrane module for flow regime improvement, the FO membrane module includes but not limited to: a water inlet; a water outlet; a forward osmosis (FO) membrane; a frame; and folded plates for improving flow regime in which draw solution is introduced into the water inlet of membrane module, then flowed through flow channels composed by three opposite folded plates vertically arranged on upper and bottom portions of the frame alternatively along horizontal direction with equal space; and drawn out from the water outlet. The flow regime improvement is achieved by increasing number of flow-guide folded plate, which results in the decrease of internal concentration polarization and membrane fouling. Structure of frame is modified to improve flow regime and to satisfy requirement of convenient and reliable connections between numbers of membrane modules in the FO membrane system.

Claims

1. A forward osmosis (FO) membrane module, comprising: a water inlet; a water outlet; two forward osmosis membranes; a frame; internal folded plates, wherein at least one of the internal folded plates is for improving a flow regime; an air vent; and an intercommunicating hole, wherein: said water inlet, said two forward osmosis membranes, said internal folded plates and said water outlet are set on the frame forming a modularized membrane module, a first forward osmosis membrane of said two forward osmosis membranes is set on a front side of the frame and a second forward osmosis membrane of said two forward osmosis membranes is set on a back side of the frame to make a fluid feed space, and said air vent is set on a connecting part of at least one of the internal folded plates and the frame, said air vent is configured to vent air built up within the modularized membrane module through the water outlet, wherein a draw solution is introduced into the modularized membrane module through said water inlet, then flown through flow channels composed by the internal folded plates vertically arranged on upper and bottom portions of said frame alternatively along a horizontal direction with equal space, and then drawn out from the water outlet.

2. The forward osmosis membrane module of claim 1, wherein each of said internal folded plates is an opposite folded plate with peaks and valleys, the modularized membrane module consists of three opposite folded plates configured to improve the flow regime and to generate a vortex.

3. The forward osmosis membrane module of claim 1, wherein two borders of said frame have folded plate components configured to promote the flow regime of an inlet flow channel and an outlet flow channel defined by said frame and said internal folded plates, said two borders named A border and B border, the A border and the B border matching each other for joining the FO membrane module with another FO membrane module.

4. The forward osmosis membrane module of claim 2, wherein said intercommunicating hole is set on a connecting part of at least one of the internal folded plates and the frame of the modularized membrane module at a bottom thereof.

5. The forward osmosis membrane module of claim 1, wherein a folding angle of each of said internal folded plates is 60-120, through which a vortex is formed in the flow channel defined by said internal folded plates for improving the flow regime to get better mixture of liquids.

6. The forward osmosis membrane module of claim 3, wherein said two borders of said frames with said folded plate components are symmetric with respect to each other for improving the flow regime.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 shows the scheme of a FO membrane module according to an embodiment of the present disclosure.

(2) FIG. 2 shows the scheme of the internal folded plates of FO membrane module according to an embodiment of the present disclosure.

(3) FIG. 3 shows the flow regime between membrane components such as internal folded plates of the FO membrane module according to an embodiment of the present disclosure.

(4) FIG. 4(a).(b) shows the structure and assembly of frame of the FO membrane module according to an embodiment of the present disclosure.

LIST OF REFERENCE NUMBERS

(5) 1water input, 2water outlet, 3FO membrane, 4A border of modularized membrane module, 5B border of modularized membrane module, 6internal folded plate for improving flow regime, 7air vent, 8intercommunicating hole.

DETAILED DESCRIPTION OF THE INVENTION

(6) The present disclosure relates to structure design of a forward osmosis (FO) membrane module for improving internal flow regime. Number of internal flow-guide folded plates is increased to get better flow regime by increasing the disturbance of flow and decreasing internal concentration polarization and membrane fouling. Described herein are improved designs of frame providing enhanced flow regime as well as reliable and convenient joint of numbers of membrane components.

(7) In the following content, aspects and features of the modified forward osmosis membrane module for flow regime improvement will be described in detail with reference numbers to the drawings:

(8) As shown in FIG. 1-4, a forward osmosis membrane module for improving flow regime includes but is not limited to: 1water input, 2water outlet, 3FO membrane, 4A border of modularized membrane module, 5B border of modularized membrane module, 6internal folded plate for improving flow regime, 7air vent, and 8intercommunicating hole. Said water input 1 and water outlet 2 are set on left and right end of top-border of modularized membrane module respectively. FO membrane 3 is adhered to front and back surface of said frame of modularized membrane module, folded plates for improving flow regime are alternately mounted on the top-border and bottom-border of said frame alternatively along horizontal direction with equal space.

(9) An air vent is set at on the very top connection part of frame and upper folded plates mounted on the top-border, to help exhaust air to discharge the air from inside the membrane modules from outlet and avoid air accumulation which may cause short stream of the liquid. The intercommunicating hole 8 is set on the connection part of said folded plate for improving flow regime mounted on the bottom-border of said frame and said frame of FO membrane module to reduce flow shocks on folded plates, improve flow regime at the bottom of FO membrane module and avoid dead angle of flows. A folding angle of folded plates is set to be 60-120; and flow rate is set to be 20 cm.Math.s.sup.1 and 5 cm.Math.s.sup.1 at peaks and valleys of the folded plates, respectively. Materials of said folded plates are ABS plastic or PMMA.

(10) Said structure of frame of modularized membrane module is same with the folded plate as shown in FIG. 4, to improve flow regime in inlet channels and outlet channels, respectively. A border is designed to be matched with B border of the frame to firmly connect different modules in the FO membrane module.

(11) As shown in FIG. 1, draw solution is introduced into said inlet of membrane module, passed through the channels composed by the opposite folded plates vertically arranged inside of frame of the modularized membrane module subsequently, and then drawn out through said water outlet. The peaks of two close folded plates are displaced to be face-to-face and so are valleys. Shrunken-enlarged flow is formed in turn to improve flow regimes in the channels of folded plates by generating vortex. The vortex promotes internal mixture of liquids and mitigates concentration polarization of membrane surfaces.

EMBODIMENTS

(12) The present invention will be further described below with reference to specific examples. However, these examples should not be construed to limiting the scope of the present invention.

Example 1

(13) Activated sludge collected from a water treatment plant is put into OMBR to be acclimated, and the FO membrane module prepared according to the present disclosure was used. Draw solution are introduced into membrane chamber through water inlet 1 by peristaltic pump; then orderly passed through three flow channels composed by A border of frame of modularized membrane module 4 and folded plate for improving flow regime 6, two close folded plates for improving flow regime 6, folded plate for improving flow regime 6 and B border of frame of modularized membrane module 5 respectively; and finally drawn out through water outlet 2. Wherein, water quality of input sludge mixed liquid are as follows: COD=52221 mg.Math.L.sup.1, TN=415 mg.Math.L.sup.1, NH.sub.4.sup.+N=374 mg.Math.L.sup.1, NO.sub.3N=41 mg.Math.L.sup.1, TP=41 mg.Math.L.sup.1.

(14) Parameters of the FO membrane module in Example 1 are: folding angle is 60, flow velocity of peaks is 20.2 cm.Math.s.sup.1, and flow velocity of valleys is 4.6 cm.Math.s.sup.1.

(15) Operating parameters of the FO membrane module in Example 1 are: water temperature is 16.2 C., pH=6.5; draw solution is 1M NaCl; and stable operating flux is 7.4 LMH.

(16) Treated water quality is: COD, TN, NH.sub.4.sup.+N, NO.sub.3N, and TP all are not detected.

Example 2

(17) Activated sludge collected from a water treatment plant is put into OMBR to be acclimated, and the FO membrane module prepared according to the present disclosure was used. Draw solution are introduced into membrane chamber through water inlet 1 by peristaltic pump; then orderly passed through three flow channels composed by A border of frame of modularized membrane module 4 and folded plate for improving flow regime 6, two close folded plates for improving flow regime 6, folded plate for improving flow regime 6 and B border of frame of modularized membrane module 5 respectively; and finally drawn out through water outlet 2. Wherein, water quality of input sludge mixed liquid are as follows: COD=52221 mg.Math.L.sup.1, TN=415 mg.Math.L.sup.1, NH.sub.4.sup.+N=374 mg.Math.L.sup.1, NO.sub.3N=41 mg.Math.L.sup.1, TP=41 mg.Math.L.sup.1

(18) Parameters of the FO membrane module in Example 2 are: folding angle is 90, flow velocity of peaks is 20.2 cm.Math.s.sup.1, and flow velocity of valleys is 5.4 cm.Math.s.sup.1.

(19) Operating parameters of the FO membrane module in Example 1 are: water temperature is 16.4 C., pH=6.4; draw solution is 1M NaCl; and stable operating flux is 8.0 LMH.

(20) Treated water quality is: COD, TN, NH.sub.4.sup.+N, NO.sub.3N, and TP all are not detected.

Example 3

(21) Activated sludge collected from a water treatment plant is put into OMBR to be acclimated, and the FO membrane module prepared according to the present disclosure was used. Draw solution are introduced into membrane chamber through water inlet 1 by peristaltic pump; then orderly passed through three flow channels composed by A border of frame of modularized membrane module 4 and folded plate for improving flow regime 6, two close folded plates for improving flow regime 6, folded plate for improving flow regime 6 and B border of frame of modularized membrane module 5 respectively; and finally drawn out through water outlet 2. Wherein, water quality of input sludge mixed liquid are as follows: COD=52221 mg.Math.L.sup.1, TN=415 mg.Math.L.sup.1, NH.sub.4.sup.+N=374 mg.Math.L.sup.1, NO.sub.3N=41 mg.Math.L.sup.1, TP=41 mg.Math.L.sup.1

(22) Parameters of the FO membrane module in Example 3 are: folding angle is 120, flow velocity of peaks is 20.2 cm.Math.s.sup.1, and flow velocity of valleys is 6.7 cm.Math.s.sup.1.

(23) Operating parameters of the FO membrane module in Example 3 are: water temperature is 16.7 C., pH=6.4; draw solution is 1M NaCl; and stable operating flux is 7.6 LMH.

(24) Treated water quality is: COD, TN, NH.sub.4.sup.+N, NO.sub.3N, and TP all are not detected.

(25) Although the above aspects and embodiments are described separately for convenience and clarity, it is contemplated that the above aspects and embodiments may be combined without departing from the scope of the present disclosure.

(26) It should be understood that the foregoing description is only illustrative of the present disclosure. Various alternatives and modifications can be devised by those skilled in the art without departing from the disclosure. Accordingly, the present disclosure is intended to embrace all such alternatives, modifications and variances. The embodiments described with reference to the attached drawing figures are presented only to demonstrate certain examples of the disclosure. Other elements, steps, methods and techniques that are insubstantially different from those described above and/or in the appended claims are also intended to be within the scope of the disclosure.