Heat shrink laminated composite patch for repairing composite components
10272652 ยท 2019-04-30
Assignee
Inventors
- Laurel Lindsey Skaggs (Orlando, FL, US)
- Mark E. Tripp (Clermont, FL, US)
- Mark Alan Naylor (Minneola, FL, US)
Cpc classification
B32B2305/72
PERFORMING OPERATIONS; TRANSPORTING
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B32B27/06
PERFORMING OPERATIONS; TRANSPORTING
B32B5/02
PERFORMING OPERATIONS; TRANSPORTING
B29C73/10
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/106
PERFORMING OPERATIONS; TRANSPORTING
B32B2556/00
PERFORMING OPERATIONS; TRANSPORTING
B32B2260/021
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B5/02
PERFORMING OPERATIONS; TRANSPORTING
B32B27/06
PERFORMING OPERATIONS; TRANSPORTING
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A sheet of heat shrink laminated composite for use creating repair patches for repairing or building up a surface formed of a composite material such as fiberglass-reinforced plastic. The sheet includes first and second layers of a heat-curable adhesive. The sheet includes a reinforcement layer sandwiched between the first and second layers of the adhesive. The sheet further includes a pressure application layer, which is formed of a heat-activated shrink wrap film, abutting an outer surface of the first layer of the adhesive. The reinforcement layer may include a sheet of a porous fabric or cloth, which may be fibers of carbon or glass such as unidirectional e-glass fibers. The adhesive is cured when heated to a temperature in a curing temperature range, and the shrink wrap film is activated when heated to a temperature in an activation temperature range that overlaps the curing temperature range of the adhesive.
Claims
1. A multi-layer sheet for use in repairing and building up a surface formed of a composite material, comprising: a first layer comprising a resin; a second layer comprising the resin, wherein the resin comprises a heat activated adhesive; a reinforcement layer sandwiched between the first and second layers of the resin; and a pressure application layer comprising a heat-activated shrink wrap film abutting a surface of the first layer of the resin opposite the reinforcement layer, wherein the adhesive is cured when heated to temperatures in a curing temperature range and wherein the heat-activated shrink wrap film has an activation temperature range at least partially overlapping the curing temperature range of the adhesive.
2. The multi-layer sheet of claim 1, wherein the reinforcement layer comprises a sheet of a porous fabric or cloth.
3. The multi-layer sheet of claim 2, wherein the fabric or cloth comprises fibers of glass or carbon.
4. The multi-layer sheet of claim 3, wherein the fibers are glass fibers including unidirectional e-glass fibers.
5. The multi-layer sheet of claim 2, wherein the curing temperature range has a minimum temperature greater than 150 F.
6. The multi-layer sheet of claim 5, wherein the adhesive comprises an epoxy adhesive.
7. The multi-layer sheet of claim 5, wherein the minimum temperature is greater than about 200 F. and wherein the activation temperature range overlaps the curing temperature range for at least 20 degrees.
8. The multi-layer sheet of claim 5, wherein the adhesive has a curing time period and wherein the heat-activated shrink wrap film has a shrink time that is in the curing time period.
9. The multi-layer sheet of claim 1, wherein the first and second layers of the resin each has a thickness that is at least one half of a thickness of the reinforcement layer.
10. The multi-layer sheet of claim 1, wherein the thicknesses of the first and second layers of the resin are both equal to one half of the thickness of the reinforcement layer.
11. The multi-layer sheet of claim 1, wherein the heat-activated shrink wrap film comprises a polyolefin shrink wrap film.
12. A laminate for field repair of damaged surfaces, comprising: first and second films of an adhesive reacting when heated to a temperature in a first temperature range; a porous fabric layer between the first and second films of heat activated adhesive; and a heat shrink film, wherein the first film of the heat activated adhesive is sandwiched between the heat shrink film and the porous fabric layer, wherein the heat shrink film is activated to shrink and apply pressure on the first film of the heat activated adhesive when heated to a temperature in a second temperature range that overlaps with the first temperature range, and wherein the first and second films, the porous fabric layer, and the heat shrink film are laminated into a unitary sheet.
13. The laminate of claim 12, wherein, when the adhesive is heated to the temperature in the first temperature range for a curing time period, the first and second films infuse the porous fabric layer to form a layer of composite material.
14. The laminate of claim 13, wherein the porous fabric layer comprises a fabric including glass, carbon, or Kevlar fibers.
15. The laminate of claim 13, wherein the adhesive comprises an epoxy film and wherein the first and second films each have a thickness of at least about 50 percent of a thickness of the porous fabric layer.
16. A multi-layer sheet for use in repairing and building up a surface formed of a composite material, comprising: a first layer comprising a resin; a second layer comprising the resin, wherein the resin comprises an adhesive; a reinforcement layer, comprising a fabric sheet, sandwiched between the first and second layers of the resin; and a pressure application layer comprising a heat-activated shrink wrap film abutting a surface of the first layer of the resin opposite the reinforcement layer, wherein the adhesive is cured with temperatures in a curing temperature range having a minimum temperature greater than 150 F. and wherein the first and second layers of the resin have a thickness that is at least one half of a thickness of the reinforcement layer.
17. The multi-layer sheet of claim 16, wherein the heat-activated shrink wrap film has an activation temperature range at least partially overlapping the curing temperature range of the adhesive.
18. The multi-layer sheet of claim 16, wherein the fabric sheet comprises fibers of glass or carbon.
19. The multi-layer sheet of claim 16, wherein the minimum temperature is greater than about 200 F., wherein the activation temperature range overlaps the curing temperature range for at least 20 degrees, and wherein the adhesive has a curing time period and wherein the heat-activated shrink wrap film has a shrink time that is in the curing time period.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(7) Briefly, a heat shrink laminated composite is taught herein that can be sized, shaped, and applied in the field to repair or buildup surfaces of a structure or component formed of a composite material such as, but not limited to, fiber glass-reinforced plastic (FRP). The heat shrink laminated composite is made up of a fabric reinforcement layer sandwiched between a pair of adhesive layers formed of a heat activated adhesive material chosen to be compatible with the material of the fabric reinforcement layer. The heat shrink laminated composite further includes a heat shrink film adjacent or covering an exposed surface of one of the adhesive layers (e.g., covering the outer adhesive layer which will face outward from the surface being repaired when installed on a composite material structure/component). These material layers are laminated together to provide a unitary or one-piece sheet that can then be cut to fit an area and shape of a surface needing repair. The heat shrink film and the adhesive are chosen to cure/react at a range of common temperature (e.g., to have reaction/curing/activation temperature ranges that at least partially overlap such as with a 20-degree temperature overlap to facilitate field repairs with a heat gun or other heat source).
(8) It is believed that the heat shrink laminated composite provides at least the following advantages and/or benefits: (1) fits all structural shapes and sizes and not just flat surfaces; (2) only requires a small heat source (e.g., a handheld heat gun or the like) to cure and bond to surface of a structure/component being repaired; (3) short application and cure times (e.g., measured in minutes depending on size such as several minutes up 10 to 20 or more minutes); (4) customizable to a particular repair application such as by selecting a shrink pressure provided by the heat shrink film, selecting material properties of the layers of the laminated composite, choosing aesthetics of the cured product/installed repair patch, and sizing the patch to suit a repair need; and (5) there typically are no inconvenient storage requirements as the adhesive used for the adhesive film is generally chosen to be stable at room temperature (e.g., an epoxy adhesive with such room temperature-stable qualities that is cured with heat).
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(10) The sheet 100 also includes a pair of layers 120, 122 of adhesive material (e.g., a film of epoxy adhesive or the like) that is chosen so as to be compatible with the fabric of the reinforcement layer. Particularly, the adhesive material is selected to be stable at room temperature in most applications (but some applications may utilize an adhesive that needs to be refrigerated as it may react at room temperatures). Further, the adhesive material is chosen such that when it is activated or reacts, e.g., at raised temperature falling within a reaction/curing temperature range for the adhesive material, it melts and flows through the gaps and holes/pores of the porous fabric of the reinforcement layer 110. When cured, a new composite layer is formed made up of the cured adhesive (e.g., cured and hardened epoxy when the adhesive is an epoxy adhesive) bonded with the fabric provided by the reinforcement layer 110. As shown, the fabric reinforcement layer 110 is sandwiched between the two (outer and inner) adhesive layers 120, 122 so as to fully wet the reinforcement layer during the adhesive curing process (or to at least wet the outer portions of the fabric of layer 110) and also to effectively bond (e.g., through an adhesion zone) the fabric-adhesive composite to the surface of the component or structure being repaired (not shown in
(11) To provide a uniform and constant pressure upon the adhesive layers 120, 122 and reinforcement layer 110 once it has been applied to a damaged surface, the sheet 100 includes a heat shrink film 130 covering the outer adhesive layer 120. The heat shrink (or heat-activated shrink wrap) film 130 may take a wide variety of forms to practice the present invention such as a polyolefin shrink wrap while other embodiments may use a shrink film of a polymer plastic such as polyethylene, polypropylene, polyvinyl chloride (PVC), or the like. It may be chosen to provide a desired amount of pressure (amount of shrinkage) when activated. More significantly, though, the heat shrink film 130 may be selected to have an activation temperature that matches or is about the same as the curing temperature of the adhesive of layers 120, 122. To this end, the activation temperature range for the heat shrink film 130 may be chosen to overlap (such as with an overlap of about 15 to 25 F. (or 20 F. overlap in some cases)) so that the film 130 shrinks and applies pressure while the adhesive layers react and/or cure. For example, the adhesive of layers 120, 122 may have a curing temperature range of 250 to 350 F., and the heat shrink film 130 may be chosen to have an activation temperature range that overlaps with this temperature range (e.g., may have an activation temperature range of 200 to 270 F., 280 to 300 F., or the like).
(12) Although not required in all embodiments, the sheet 100 of
(13) This design for a heat shrink laminated composite combines the strength and cleanliness of pre-cured resin with the utility of heat shrink films. The sheet 100 and other embodiments taught herein are laminated products, and each laminated product or sheet includes a film adhesive, dry fiber fabric, and a heat shrink outer casing/layer. The reinforcement layer may be formed with a wide variety of type, construction, and/or direction of fibers making up the fabric or cloth. The film adhesive is selected to be compatible with the fabric or cloth and to have a cure time and temperature similar to the heat shrink film's shrink time (e.g., the film's shrink time should exceed the lower end of the cure time for the film adhesive) and temperature (overlap of ranges as discussed above). The laminated sheet (e.g., sheet 100 of
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(16) The sheet 200 also includes first and second layers (or inner and outer layers) 360 and 370 of adhesive (such as an epoxy film or the like). The reinforcement layer 350 is sandwiched between these two adhesive layers 360 and 370 with an inner surface 364 of the outer adhesive layer 360 abutting the outer surface 352 of the adhesive layer 350 and with an outer surface 372 of the inner adhesive layer 370 abutting the inner surface 354 of the adhesive layer 350. The adhesive of layers 360 and 370 typically is the same for both layers 360 and 370 and is chosen to be compatible with the fabric of reinforcement layer 350 and with bonding with material of surfaces to be repaired (e.g., composite material being replaced, filled, or repaired with the sheet 200). Further, the adhesive material is chosen to provide desired material properties such as strength and resistance to wear that may match the repaired composite surfaces. For example, an epoxy film may be used for the layers 360, 370 when the reinforcement layer 350 includes a glass fabric such as a unidirectional e-glass fabric or fiberglass cloth.
(17) Further, the thicknesses, tA1 and t.sub.A2, of the two adhesive layers 360, 370 typically are equal to each other and, more significantly, are chosen to wet a particular depth of the fabric in layer 350. For example, the fabric of reinforcement layer 350 may be chosen to be porous to facilitate movement of melted material from layers 360, 370 (during curing processes), and it may be desirable for the adhesive to fully wet and mix with (or infuse into) the fibers of the fabric in layer 350. To this end, the adhesive layers 360, 370 may each have a thickness, t.sub.A1 and t.sub.A2, that is at least one half of that of the thickness, t.sub.Fabric, to fully wet the layer 350. In some cases, the thicknesses may be exactly one half (plus or minus some tolerance) to avoid having excess adhesive material in the cured product (or applied composite patch). In other cases, a less than full wetting may be acceptable and the thicknesses, t.sub.A1 and t.sub.A2 may be some amount less than one half of the thickness, t.sub.Fabric, of layer 350 (e.g., each in the range of 40 to 50 percent of the thickness, t.sub.Fabric).
(18) As shown in the off-the-shelf (or pre-application) sheet 200, a heat-activated shrink film 210 is provided over the outer adhesive layer 360. Specifically, the shrink film 210 has an inner surface 314 that contacts and mates with the outer surface 362 of the outer adhesive layer 360, and the film 210 also has an outer surface 312 facing away from the reinforcement fabric 350 as well as surfaces of a composite structure or component to which sheet 200 is later applied. The shrink film 210 is activated by application of heat to raise its temperature into an activation temperature range, and this causes the film 210 to attempt to shrink in size (e.g., shrink the outer diameter of a patch formed from sheet 200 when wrapped about the circumference of a composite rod or tube), which applies a uniform and constant pressure upon the lower layers of 360, 350, 370 and surface being repaired (not shown in
(19) The sheet 200 further includes a protective film 380 applied over the inner (or repair surface-matching) surface 374 of the inner adhesive layer 370. The film 380 is chosen to protect the surface 374 from becoming contaminated or dirty as well as allowing the sheet 200 to easily be rolled upon itself for delivery/storage but to allow it to be easily unrolled with sticking to other surfaces. The protective film 380 typically will include a relative weak adhesive layer (not shown) that mates with and temporarily attaches the film 380 to the surface 374 of the adhesive layer 370. In this way, the protective film 380 can easily be removed from the sheet 200 or a composite repair patch formed by cutting the sheet 200 into a desired size and shape immediately prior to its application to a surface of a composite structure or component (e.g., an FRP rod or the like), e.g., removed in the field in most cases.
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(21) Particularly, the application of heat is used to raise the temperature of the sheet 200 to a temperature that is both in the activation temperature range of the heat shrink 210 and also in the reaction/cure temperature range of the adhesive provided in the two adhesive layers 360 and 370. Further, the application of heat is continued for a time period that falls within a curing time range for the adhesive of layers 360, 370 (and also suits the shrink time of the heat-activated shrink film 210). As shown in
(22) Instead, a new layer 450 is formed that is the fabric infused with cured adhesive (e.g., a fabric of glass fiber or other fibers infused with epoxy or the like). This new layer is formed under constant pressure as the shrink film 210 shrinks in size causing its inner or inward facing surface 314 to apply pressure or compression forces against an outer surface 452 of layer 450 (which during initial curing processes is outer surface 362 of the outer adhesive layer 360). The adhesive material of layers 360, 370 melts and flows through the pores of the porous material of the fabric reinforcement layer 350 as the new composite layer 450 is formed, and, as the adhesive cures, the two materials integrally bond together to form a new composite material.
(23) Additionally, the adhesive material of the two layers 360, 370 acts to bond the material of new layer 450 to adjacent surfaces, such as surfaces of a structure/component formed of a composite material compatible with the fabric and adhesive materials of layers 350, 360, and 370. Hence, the inner surface 454 of layer 450 bonds (in an adhesion zone) the patch/cured product 400 to the surface being repaired (now a repaired surface) as do sides/edges 456, 457 when the patch/sheet 400 is applied to a recessed surface (rather than simply on top of a surface to be repaired as may be useful in some repair/maintenance applications).
(24) The new composite layer 450 (or repair layer) has a thickness, t.sub.Repair Layer, as measured between the outer and inner surfaces 452, 454. This thickness, t.sub.Repair Layer, may be greater than the thickness, t.sub.Fabric, of the original fabric reinforcement layer 350, but, in some preferred embodiments where additional adhesive is not desired, the new layer 450 has a thickness, t.sub.Repair Layer, that is equal to the thickness, t.sub.Fabric, of the original fabric reinforcement layer 350 (or some relatively small amount less due to compression by the shrink wrap film 210) as may be the case when the two adhesive layers 360, 370 are provided at about 50 percent the thickness, t.sub.Fabric, of the reinforcement layer 350. After the curing process for the adhesive materials is complete, the heat shrink film 210 may be left on the patch 400 such as when it has been decorated or themed to fit the repaired surface and surrounding environment or the film 210 may be removed (and the surface 452 of the new composite or repair layer 450 may be themed or decorated to suit the repaired surface, structure, or surrounding environment).
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(26) The method 500 then continues at 510 with preparing the damaged surface (i.e., the surface identified as needing repair in step 505) to receive a repair or composite patch (e.g., a wrap sized and cut from one of the sheets of heat shrink laminated composite taught herein). Preparation is generally performed to facilitate good bonding of the new material from the patch with the existing materials and to remove damaged portions of the composite material of the surface to be repaired. For example, an FRP rod may need repair at or near a joint, and prepping in step 210 may involve sanding the damaged surface (e.g., to remove damaged material and create a recessed surface for receiving the patch (e.g., to a depth of about the expected final thickness of the cured product/applied composite patch)). Once sanding is complete, prepping 510 may also include cleaning the surface to be repaired such as by wiping the FRP rod's surface at and around the joint with a solvent (suited to the particular composite material forming the surface).
(27) The method 500 continues at 520 with providing a sheet of heat shrink laminated composite that is chosen to be compatible with the composite material of the surface to be repaired. For example, the surface that is damaged may be formed of FRP or other composite, and the sheet provided in step 520 is chosen to provide a reinforcement material such as one with a glass fabric (e.g., a unidirectional e-glass fabric or the like) as well as to provide adhesive materials in its two adhesive films that are suited for bonding with FRP (such as an epoxy adhesive (i.e., the two adhesive layers may be formed using films of epoxy adhesive)). Typically, the adhesive is chosen so as to be stable at room temperature, but some embodiments may use adhesive that requires refrigeration to remain stable until used for a repair.
(28) The inventors believe that with the teaching provided herein that in the near future maintenance sheets of composite for the patch may be available in rolls of laminate with the layers of material discussed in
(29) In step 530, the sheet provided in step 520 is cut, if and as needed, to form a repair patch that has the size and shape desired to repair the surface prepped in step 510. In the present working example, the surface to be repaired is an exterior surface of a rod (or joint in a rod). In this case, step 520 may involve cutting a square or rectangular section of the sheet from step 520 that has a width that is the same or some amount larger than the prepared surface of step 510 and with a length that allows the patch to be wrapped fully (or more than fully) about the rod (e.g., a length equal to or greater than the circumference of the rod being repaired).
(30) The method 500 continues at step 540 with applying or attaching the repair patch from step 530 to the prepped surface of the component/structure. In the rod example, this step may involve wrapping the laminate sized to the surface to be repaired tightly around the FRP (or other composite material) rod so as to cover or fill the surface being repaired. The method 500 may continue (optionally in some cases) with sealing at 550 exposed edges of the repair patch so as to better retain the patch over the surface being repaired during the later curing/activation steps, and step 550 may involve using a low-temperature soldering gun (or a soldering gun on a low setting) or other heat source to heat and seal the edges which may be at the sides of the patch or where the patch has been wrapped over upon itself (e.g., if the patch has a length exceeding that of the circumference of the rod or curved surface).
(31) The method 500 then continues at 560 with applying heat to the patch applied in step 540 so as to activate and/or cure the adhesive material in the two adhesive layers and to activate the shrink wrap to apply uniform and constant pressure to the inner layers of the patch. The activating of the shrink wrap is used to apply force over the entire surface area of the outer adhesive layer during the curing of the adhesive so as to better infuse the fabric of the reinforcement layer and to assist in bonding of the newly formed composite or repair layer with the composite material of the surface being repaired. Step 560 may be performed using a variety of heat sources such as a portable heat gun for a period of time falling within both the activation time period for the shrink wrap and the curing time period for the adhesive (e.g., 1 to 10 minutes or more in some cases).
(32) At step 564, the method 500 may involve determining whether or not the curing temperature for the adhesive has been reached (and the activation temperature for the shrink wrap as this material is chosen to have an activation temperature range overlapping that of the adhesive material's curing temperature range). The heat gun may be selected to provide heat that can raise a patch's temperature to some predefined minimum temperature falling in the curing temperature range. For example, the adhesive may be an epoxy adhesive and the shrink wrap may be a polyolefin shrink wrap, and, in this non-limiting example, a heat gun can be used to apply heat relatively uniformly at a minimum temperature of about 200 F. If not a high enough temperature (or not enough heat from source), the method 500 continues at 560. If heat is provided to raise the patch material temperature over the curing temperature, the method 500 continues at 568 with determining if the heat has been applied for more than the minimum curing time (e.g., for a length of time falling within a curing temperature range of the adhesive in the adhesive layers of the repair patch). If not, steps 560, 564, and 568 are repeated until the minimum curing time is met or exceeded. The curing time will vary with the particular adhesive, but many epoxy adhesives have a curing time that is quite short such as a range of 1.5 to 5 minutes or the like.
(33) Once the curing time is satisfied, the method 500 continues at 570 with ending the application of heat with the heat source (e.g., by moving the heat gun away from the repair patch or turning the heat gun off). At this point, the adhesive material has melted and fully wetted (or wetted to a desired or designed amount) the fabric of the reinforcement layer to form a new composite layer (or repair layer), and this layer has been bonded to the surface being repaired (e.g., a cured product, which is permanently attached to or over the repaired surface, has been created through performance of steps 550-568). The method 500 may then continue at step 580 with removing the heat shrink film to expose the newly installed/applied composite layer provided by the repair patch. This is an optional step as it may be useful or acceptable to leave the shrink wrap over the repaired surface of the structure/component. The method 500 then can end at step 590 or be repeated beginning at step 510 to repair another composite material surface.
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(37) Due to the application of heat for a curing period (e.g., performance of steps 560 to 570 in method 500) on the assembly of
(38) Although the invention has been described and illustrated with a certain degree of particularity, it is understood that the present disclosure has been made only by way of example, and that numerous changes in the combination and arrangement of parts can be resorted to by those skilled in the art without departing from the spirit and scope of the invention, as hereinafter claimed.
(39) In proving their concepts and designs, the inventors fabricated a prototype sheet (e.g., like sheet 100 of
(40) The shrink wrap or heat-activated shrink film may be themed or decorated to suit the application and surrounding environment such as via printing during manufacturing of the repair sheet or laminate or, in other cases, this outer pressure-providing layer may be removed after cure of the adhesive layers so as to expose an outer surface of the applied repair patch (e.g., the fabric that is now infused with the adhesive), which can be themed or decorated to suit the application or surrounding environment.