Apparatus, Methods, and Compositions for Producing Oriented Stretch Film In-Process

Abstract

Apparatus and methods for producing folded edges in a film in-process, and compositions of such film are provided. A method of folding edges includes: separating a first idler roll and a second idler roll by a first distance; positioning a plurality of folding guides between the first idler roll and the second idler roll; separating adjacent sections of film having a majority layer comprising a Ziegler Natta catalyzed linear low density polyethylene copolymer resin having molecules that inherently lack long chain branching, wherein a majority of said molecules are oriented in a substantially longitudinal direction due to an induced strain, and inducing two folds with each folding guide, thereby causing an edge of each section of film to turn under 180 and cling to a bottom surface of the section of film; and moving the adjacent sections of film from the folding guides to the second idler roll.

Claims

1. An apparatus for producing folded edges in a film in-process, the apparatus comprising: a first idler roll; a second idler roll separated from the first idler roll by a first distance; and a plurality of folding guides that are positioned between the first idler roll and the second idler roll, wherein each folding guide is configured to separates adjacent sections of film and induces two folds, thereby causing an edge of each section of film to turn under 180 and cling to a bottom surface of the section of the film as the film travels from the folding guides to the second idler roll, wherein each 180 turn under is completed in a single folding action without said film traversing any subsequent folding guides; wherein the film comprises a primary layer comprising a Ziegler Natta catalyzed linear low density polyethylene (LLDPE) copolymer resin having molecules that inherently lack long chain branching, wherein a majority of said molecules are oriented in a substantially longitudinal direction due to an induced strain.

2. The apparatus of claim 1, the film further comprising LLDPE copolymer resin blended with other resins chosen from the group consisting of Ziegler Natta catalyzed LLDPE, metallocene catalyzed linear low density polyethylene (m-LLDPE), polyethylenes, polyethylene copolymers, polyethylene terpolymers, polyethylene blends, polypropylenes, polypropylene copolymers, and blends thereof.

3. The apparatus of claim 1, the film further comprising a plurality of secondary layers and a total film thickness.

4. The apparatus of claim 3, further wherein the secondary layers comprise resins chosen from the group consisting of Ziegler Natta catalyzed LLDPE, metallocene catalyzed linear low density polyethylene (m-LLDPE), polyethylenes, polyethylene copolymers, polyethylene terpolymers, polyethylene blends, polypropylenes, polypropylene copolymers, and blends thereof.

5. The apparatus of claim 3, wherein the secondary layers have a thickness up to 49 percent of the total film thickness.

6. The apparatus of claim 5, wherein the secondary layers have a thickness of up to 16 percent of the total film thickness.

7. The apparatus of claim 4, further wherein the resins comprising the secondary layers have a melt index ranging from 0.5 g/10 min. @ 190 C./2.16 kg to 12 g/10 min. @ 190 C./2.16 kg.

8. The apparatus of claim 7, further wherein the resins comprising the secondary layers have a melt index ranging from 3 g/10 min. @ 190 C./2.16 kg to 5 g/10 min. @ 190 C./2.16 kg.

9. The apparatus of claim 4, further wherein the resins comprising the secondary layers have a density ranging from 0.850 g/cm.sup.3 to 0.969 g/cm.sup.3.

10. The apparatus of claim 9, further wherein the resins comprising the secondary layers have a density of 0.917 g/cm.sup.3.

11. The apparatus of claim 1, further wherein the resin comprising the primary layer has a melt index ranging from 0.5 g/10 min. @ 190 C.12.16 kg to 4 g/10 min. @ 190 C./2.16 kg.

12. The apparatus of claim 11, further wherein the resin comprising the primary layer has a melt index ranging from 0.8 g/10 min. @ 190 C./2.16 kg to 1.2 g/10 min. @ 190 C./2.16 kg.

13. The apparatus of claim 1, further wherein the resin comprising the primary layer has a density ranging from 0.900 g/cm.sup.3 to 0.960 g/cm.sup.3.

14. The apparatus of claim 13, further wherein the resin comprising the primary layer has a density of 0.920 g/cm.sup.3.

15. The apparatus of claim 1, further wherein the Ziegler Natta catalyzed LLDPE copolymer resin has a composition depth breadth index of less than 70 percent.

16. The apparatus of claim 15, further wherein the Ziegler Natta catalyzed LLDPE copolymer resin has a composition depth breadth index of 30 percent to 60 percent.

17. The apparatus of claim 1, further wherein at least 20 percent of the primary layer comprises the Ziegler Natta catalyzed LLDPE copolymer resin having molecules that inherently lack long chain branching.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0014] For a further understanding of the nature, objects and advantages of the present invention, reference should be had to the following descriptions read in conjunction with the following drawings:

[0015] FIG. 1 illustrates the steps for producing film in-process according to example embodiments disclosed herein; and

[0016] FIG. 2 illustrates an edge folding apparatus and folding assembly according to example embodiments disclosed herein.

DETAILED DESCRIPTION

[0017] The following description is not to be taken in a limiting sense, but is made merely for the purpose of illustrating example embodiments.

[0018] According to example embodiments, apparatus for producing film in-process for use in the stretch film market are provided. According to further example embodiments, apparatus and methods are described for folding the edges of film in-process. According to still further example embodiments, the apparatus and methods allow for edge folds to be created on each side of a single section of film simultaneously. In still further example embodiments, multiple film rolls are folded simultaneously using the disclosed apparatus and methods. In alternative example embodiments, edge folds increase the ease of use of the film and reduce waste by making the film less susceptible to failure due to tears, rough handling, or excessive stretching.

[0019] In further example embodiments, particular resins and an angled die are used to increase the level of orientation in the film as it is formed, thus eliminating the need to stretch the film in a separate step.

[0020] In still further example embodiments, a cling agent is incorporated into the film, thus eliminating the storage time traditionally needed to develop the film's cling properties.

[0021] Turning to FIG. 1, the steps 100 for producing pre-stretched stretch film in-process, according to example embodiments, are illustrated. Specifically, according to example embodiments, the steps comprise producing a film from molten resins 110, gauging the film 120, longitudinally slitting the film into multiple sections 130, folding the edges of the film 140, oscillating the film 150, and winding the film onto a film roll 160 in a manner that prevents stacking of the edge folds and entraps air between the layers of film. In still other example embodiments, all of the steps are performed in-process along a single production line. In still further example embodiments, the steps are performed in a different order, and in still other example embodiments, one or more steps are eliminated without departing from the scope of the present disclosure.

[0022] Slitting assemblies are well-known in the art, and according to example embodiments, any conventional slitting assembly is used to slit the film into multiple sections. According to further example embodiments, an interior slit is defined as a slit made somewhere within the original width of film, resulting in multiple sections of lesser width. According to still further example embodiments, each interior slit requires only one folding guide assembly to accommodate both adjacent film edges. In still further example embodiments, an exterior slit is defined as a slit made along one of the edges of the original width of film. In alternative example embodiments, each exterior edge requires a separate folding guide assembly.

[0023] As shown in FIG. 1, according to other example embodiments, the edges of the film are folded after the film is longitudinally slit into multiple sections. In other example embodiments, the edge folds make the film less susceptible to failure due to tears, rough handling, dropping, or excessive stretching. Thus, in still further example embodiments, the ability to introduce and maintain edge folds improves film performance.

[0024] Turning next to FIG. 2, according to example embodiments, a system for folding the edges of the film 210 comprises a first idler roll 220, a second idler roll 230, and a folding guide assembly 235, placed between the first idler roll 220 and the second idler roll 230. In alternative example embodiments, the folding guide assembly 235 is comprised of a plurality of folding guides 240-245, which are placed in the slits 270 between sections of film 210 to separate the sections of film 210. As shown in FIG. 2, the folding guides 240-245 are folding rods according to certain example embodiments, but other types of folding guides are also contemplated herein.

[0025] According to other example embodiments, after the sections of film 210 are separated, the cling agent and the tension of the film 210 cause the edge folds 250 to form spontaneously. In other example embodiments, each folding guide 240 separates adjacent sections of film 210 and induces two folds 250, thereby causing an edge of each section of film to turn under 180 and cling to a bottom surface of the section of film.

[0026] In other example embodiments, each interior folding rod 240 produces two edge folds 250, while each exterior folding rod 245 produces one edge fold 250.

[0027] According to further example embodiments, each folding guide 240-245 is comprised of steel, aluminum, nylon, or any other material of sufficient modulus to be able to maintain rigidity. According to still further example embodiments, each folding guide also has a coefficient of friction that allows the edge of the film to turn back on itself, thus introducing a fold. In still further example embodiments, the diameter and placement of the folding guides 240-245 assist in achieving and maintaining edge folds 250 without roping or wrinkling of the film 210.

[0028] In still other example embodiments, the folding guides 240-245 vary from about inch to about 1 inch in diameter, with a preferred diameter of approximately 11/16 inch. In still further example embodiments, the folding guides 240-245 have uniform diameter throughout their length. As an alternative, according to example embodiments, the portions of the folding guides 240-245 that contact the film 210 have a smaller diameter or narrow to a point to further aid in separating the sections of film 210.

[0029] According to example embodiments, the folding guides 240-245 are placed in the slits 270 between sections of the film 210 at a guide distance 280 and a guide angle 290. According to further example embodiments, the guide distance 280 is about of the distance between the first idler roll 220 and the second idler roll 230, as measured from the point where the film 210 leaves the first idler roll 220 to the point where the film 210 first contacts the folding guides 240-245. According to still further example embodiments, the guide angle 290 between the film 210 and the folding guides 240-245, measured with the folding guides 240-245 leaning toward the first idler roll 220, varies from 20 to 90, with a preferred angle of about 45.

[0030] As shown in FIG. 2, according to other example embodiments, the system for folding the edges of the film 210 also comprises a nip roll assembly 260. In other example embodiments, the nip roll assembly 260 comprises two rollers 265 pressed together, and are primarily intended to control the tension of the film 210 as it passes through the slitting assembly and the edge folding apparatus. In still other example embodiments, the nip roll assembly 260 also aids in pressing the folds 250 into the film 210, resulting in flat edge folds. In further example embodiments, if the nip roll assembly 260 is not employed, air entrapment occurs within the edge folds. In certain example embodiments, air entrapment within the edge folds results in a film roll with a different appearance and functionality, much like having bubble wrap on the ends of the roll.

[0031] Turning back to FIG. 1, according to example embodiments, the film is oscillated 150 and wound 160 onto film rolls once the film's edges are folded. According to further example embodiments, oscillation efficiently distributes the edge folds onto the film roll. In addition, according to still further example embodiments, air is entrapped between the layers of film as the film is wound onto a film roll, making the film easier to unwind and less susceptible to damage.

[0032] In producing a film from molten resins as shown in step 110 in FIG. 1, according to example embodiments, films comprised of resins having constituent elements with higher molecular weights than are conventionally used for stretch films are produced. In other embodiments, the resins with greater molecular weight constituent elements increase the level of orientation in the film as it is formed in step 110.

[0033] In still other embodiments, the resins are extruded onto the casting roll through an angled die, which further increases the level of orientation in the film. In certain embodiments, as a result of the increased level of orientation, the film does not have to be stretched in a separate operation. Eliminating the stretching step makes the film simpler, quicker, and less expensive to produce.

[0034] According to example embodiments, a cling agent is incorporated into the film to enable an oriented film to be produced without an extensive storage time between steps in the manufacturing process. In further example embodiments, the cling agent does not require an extended period of time to migrate to the surface of the film As a result, the cling properties of the film will be almost immediately apparent. Eliminating the storage time further reduces the time and cost associated with producing stretch film.

[0035] According to example embodiments, the film is comprised of one layer or multiple layers. In further embodiments, the composition of each layer varies.

[0036] In further example embodiments, resins used to produce the film layers include, but are not limited to, Ziegler Natta (ZN) catalyzed linear low density polyethylene (ZN-catalyzed LLDPE), metallocene catalyzed linear low density polyethylene (m-LLDPE), polyethylenes, polyethylene copolymers, polyethylene terpolymers, polyethylene blends, polypropylenes, polypropylene copolymers, and blends thereof.

[0037] According to certain embodiments, the majority of the ZN-catalyzed LLDPE and m-LLDPE molecules inherently lack long-chain branching.

[0038] In further embodiments, the ZN-catalyzed LLDPE resin has a composition breadth index (CDBI), which is defined as the weight percent of the copolymer molecules having a comonomer content within 50 percent of the median total molar comonomer content, of less than 70 percent. In example embodiments, the CDBI of ZN-catalyzed LLDPE resin may range from about 30 percent to about 60 percent.

[0039] According to example embodiments, the film is a three-layer film with a majority layer sandwiched between two minority layers. In still other example embodiments, the thickness of the minority layers ranges from about 0 to about 49 percent of the total film thickness. In further embodiments, the preferred thickness of the minority layers is about 16 percent of the total film thickness.

[0040] According to example embodiments, the majority layer comprises an LLDPE copolymer resin. In certain embodiments, the LLDPE copolymer resin is a higher alpha-olefin LLDPE resin.

[0041] In other example embodiments, the melt index of the LLDPE copolymer resin selected for the majority layer ranges from about 0.5 g/10 min. at 190 C. and 2.16 kg to about 4 g/10 min. at 190 C. and 2.16 kg, with a preferred melt index ranging from about 0.8 g/10 min. at 190 C. and 2.16 kg to about 1.2 g/10 min. at 190 C. and 2.16 kg.

[0042] According to further example embodiments, the density of the LLDPE copolymer resin used the majority layer ranges from about 0.900 g/cc to about 0.960 g/cc, with a preferred density of about 0.920 g/cc.

[0043] In other example embodiments, using a LLDPE copolymer resin with a higher molecular weight than is conventionally used in stretch films increases the level of orientation when the film is extruded through a die. In still other example embodiments, the LLPDE copolymer resin is also combined with other resins, including, but not limited to, other polyethylenes, polyethylene copolymers, and polypropylene copolymers.

[0044] According to certain example embodiments, the minority layers are resins comprised of polyethylene, polyethylene copolymers, polypropylene copolymers, or blends thereof. Depending upon the desired properties of the film, the minority layers have different compositions, according to example embodiments. In further example embodiments, the melt index of the resins selected for the minority layers range from about 0.5 g/10 min. at 190 C. and 2.16 kg to 12 g/10 min. at 190 C. and 2.16 kg, with a preferred melt index ranging from about 3 g/10 min. at 190 C. and 2.16 kg to 5 g/10 min. at 190 C. and 2.16 kg.

[0045] In still further example embodiments, the density of the resins selected for the minority layers range from about 0.850 g/cc to about 0.969 g/cc, with a preferred density of about 0.917 g/cc.

[0046] According to example embodiments, to impart cling to the film, a cling agent is incorporated into the film. In still further example embodiments, cling agents are used as discrete layers. In other example embodiments, cling agents are used as additives in blends of resins for layer(s) of the film.

[0047] Depending on the desire properties of the resultant film, embodiments are one-sided, differential, or two-sided cling structures.

[0048] In certain example embodiments, such cling agents are migratory. In other embodiments, the cling agents are non-migratory.

[0049] In certain example embodiments, a migratory cling agent is metered into a three-layer film through at least one extruder for the minority layers.

[0050] In other example embodiments wherein the film comprises a single layer, a migratory cling agent is metered into the film through the extruder for that layer.

[0051] In further example embodiments, the rate at which the migratory cling agent is metered into the film ranges from about 0 percent to about 25 percent of the total film structure on a weight-to-weight basis, with a preferred rate of about 0.6 percent of the total film structure on a weight-by-weight basis.

[0052] In alternative example embodiments, a non-migratory cling agent is added to the minority layers at a rate of about 0 percent to about 25 percent of the total film structure on a weight-to-weight basis, with a preferred rate of about 1 percent of the total film structure on a weight-to-weight basis.

[0053] According to example embodiments, a polybutene polymer with a Saybolt Universal Viscosity of 14,900 SUS at 99 C. with an average molecular weight of 2,060 is used as a cling agent. In further example embodiments, the molecular weight of this cling agent is higher than the molecular weight of a cling agent typically used in stretch films (which is polybutene with a Saybolt Universal Viscosity of 3,000 SUS at 99 C. with an average molecular weight of 1,290).

[0054] In still further example embodiments, unlike the typical cling agent, the higher molecular weight polybutene polymer will not require time to migrate to the film's surface.

[0055] In additional example embodiments, the higher molecular weight polybutene polymer is minimally affected over time or winding tension. In certain example embodiments, the oriented film is produced in-process, which is more cost-effective and efficient than the standard practice of producing master rolls of film, storing the master rolls for several days while the cling develops, and then converting the master rolls into pre-stretched film

[0056] The foregoing specification is provided only for illustrative purposes, and is not intended to describe all possible aspects of the present invention. While the invention has herein been shown and described in detail with respect to several exemplary embodiments, those of ordinary skill in the art will appreciate that minor changes to the description, and various other modifications, omissions and additions are also made without departing from the spirit or scope thereof.