LOW CARBON BIO-OIL AND ITS MANUFACTURING METHOD

Abstract

In order to develop a high combustion heat and stable bio-oil for safer transportation. The present invention discloses a low carbon bio-oil, selected from the group consisting of a thermo-chemical oil product, a fatty acid containing bio-oil and a bio-alcohol. The invention also discloses a preparation method of preparing the low carbon bio-oil.

Claims

1. A low-carbon bio-oil selected from the group consisting of a biomass thermo-chemical oil, a fatty acid-rich bio-oil, and bio-alcohol, wherein a range of high heat combustion for the low-carbon bio-oil is 3000-7000 cal/g.

2. The low-carbon bio-oil of claim 1, wherein the weight percentage of the fatty acid-rich bio-oil of the low-carbon bio-oil is less than 20%.

3. The low-carbon bio-oil of claim 1, wherein the weight percentage of the bio-alcohol of the low-carbon bio-oil is 0.1-10%.

4. The low-carbon bio-oil of claim 1, wherein the biomass thermo-chemical oil is a biomass pyrolysis oil, a carbonized tar, a liquid product after carbonization, pyrolysis or gasification.

5. The low-carbon bio-oil of claim 4, wherein the fatty acid-rich bio-oil is a black high acid value oils, a white high acid value oil or a palm fatty acid distillate (PFAD).

6. The low-carbon bio-oil of claim 5, wherein the weight ratio of the biomass pyrolysis oil to the black high acid value oil is 1:1.

7. The low-carbon bio-oil of claim 5, wherein the weight ratio of the biomass pyrolysis oil to the white high acid value oil is 3:1.

8. The low-carbon bio-oil of claim 5, wherein the weight ratio of the carbonized tar to the black high acid value oil is 3:1.

9. The low-carbon bio-oil of claim 5, wherein the weight ratio of the carbonized tar to the white high acid value oil is 3:1.

10. The low-carbon bio-oil of claim 4, wherein the fatty acid-rich bio-oil is obtained from a waste oil after manufacture process.

11. The low-carbon bio-oil of claim 5, wherein the alcohol is ethanol, butanol or a higher alcohol.

12. The low-carbon bio-oil of claim 11, wherein the weight ratio of the biomass pyrolysis oil, the black high acid value oil and the bio-alcohol is 15:5:1.

13. The low-carbon bio-oil of claim 11, wherein the weight ratio of the biomass pyrolysis oil, the white high acid value oil and the bio-alcohol is 15:5:2.

14. A method for producing a low-carbon bio-oil of claim 1, which comprises the steps of: a) obtaining an oil mixture selected from the group consisting of a biomass thermo-chemical oil, a fatty acid-rich bio-oil, and bio-alcohol; b) heating the oil mixture to 40-90 C.; and c) settling the mixture at room temperature to obtain a low-carbon bio-oil.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0022] The Sole FIGURE shows the method for producing a low-carbon bio-oil of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0023] By way of illustration, the specific embodiments will be disclosed in detail below, however, the features of the invention are not limited to these embodiments.

[0024] The present invention provides a low-carbon bio-oil which is selected from the group consisting of biomass thermo-chemical oil, a fatty acid-rich bio-oil, and bio-alcohol, wherein the characteristics of the raw material used in the examples herein are as shown in Table 1.

TABLE-US-00001 TABLE 1 characteristics of the raw material used in the examples biomass black high white high pyrolysis acid value acid value carbonized item oil oil oil tar Weight percentage 1.137 0.9024 0.9806 1.19 g/cm.sup.3 Ash content wt % 0.1734 0.0751 0.6986 0.113 higher heating value 3791 9213 7390 4167 (HHV) cal/g Viscosity 5.98 9.32 150.4 9.53 50 C., cSt Flash point C. 39 99 87 145

[0025] The present invention provides a method for producing a low-carbon bio-oil. Please refer to the Sole FIGURE, which comprises the steps of: mixing a biomass thermo-chemical oil, a fatty acid-rich bio-oil and bio-alcohol in a specific ratio in a pre-heating chamber, then heating the oil mixture to 40-90 C.; and transporting the oil mixture into the pre-heating chamber, keep the temperature same as the pre-heating chamber, then mixing the oil mixture for 2 hours: settling the oil mixture at room temperature to obtain a low-carbon bio-oil.

Example 1

[0026] 15 kg biomass pyrolysis oil and 15 kg black high acid value oil is mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. The first analysis sample is shaken before sampling and is analyzed again due to the large difference. According to the data, 15 kg of biomass pyrolysis oil and 15 kg black high acid value oil are mixed and the phase separation is more serious (as shown in Table 2).

TABLE-US-00002 TABLE 2 Analysis result of example 1 item 1-1 1-2 Upper Middle Lower Upper Middle Lower section section section section section section Weight percentage g/cm.sup.3 1.149 0.9170 1.162 0.9182 0.9182 1.12 Ash content wt % 0.2206 0.028 0.4043 0.0109 0.293 0.2822 higher heating value 3614 9068 2534 8899 8858 Cannot (HHV) cal/g be lit Viscosity 50 C., cSt 6.91 8.4 7.05 8.5 8.47 7.95

Example 2

[0027] 1125 g biomass pyrolysis oil and 375 g white high acid value oil is heated to 60 C., and then mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. From the test result of weight percentage and ash content, the properties of upper section is close to white high acid value oil, and the properties of lower section is close to biomass pyrolysis oil. Higher heating value (HHV) shows large difference of different section. (as shown in Table 3).

TABLE-US-00003 TABLE 3 Analysis result of example 2 2 Upper Middle Lower item section section section Weight percentage 0.939 1.111 1.125 g/cm.sup.3 Ash content wt % 0.0109 0.1543 0.2699 higher heating value 3754 3313 3338 (HHV) cal/g Viscosity 4.93 4.8 4.98 50 C., cSt

Example 3

[0028] 1125 g carbonized tar and 375 g white high acid value oil is heated to 60 C., and then mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. From the test result of weight percentage and ash content, the properties of upper section are close to white high acid value oil, and the properties of lower section is close to biomass pyrolysis oil. Higher heating value (HHV) shows large difference of different section. (as shown in Table 4).

TABLE-US-00004 TABLE 4 Analysis result of example 3 3 Upper Middle Lower item section section section Weight percentage 0.9745 1.142 1.161 g/cm.sup.3 Ash content wt % 0.4644 0.4528 0.2327 higher heating value 3370 3413 3838 (HHV) cal/g Viscosity 8.93 7.05 7.14 50 C., cSt

Example 4

[0029] 375 g carbonized tar and 125 g white high acid value oil is heated to 60 C., and then mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. From the test result of data, the properties are close to original oil, which means the carbonized tar mixed well with white high acid value oil. (as shown in Table 5).

TABLE-US-00005 TABLE 5 Analysis result of example 4 Item 4 Weight percentage 1.109 g/cm.sup.3 Ash content wt % 0.3341 higher heating value 3838 (HHV) cal/g Viscosity 7.51 50 C., cSt

Example 5

[0030] 375 g carbonized tar and 125 g black high acid value oil is heated to 60 C., and then mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. From the test result of higher heating value (HHV), the properties are different from original oil, which means the carbonized tar cannot mixed well with black high acid value oil. (as shown in Table 6).

TABLE-US-00006 TABLE 6 Analysis result of example 5 Item 5 Weight percentage 1.142 g/cm.sup.3 Ash content wt % 0.4528 higher heating value 8982 (HHV) cal/g Viscosity 9.6 50 C., cSt

Example 6

[0031] 1125 g biomass pyrolysis oil, 375 g black high acid value oil and 75 g alcohol are heated to 60 C., and then mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. From the test result of higher heating value (HHV), the alcohol can enhance the uniformity of overall oil. (as shown in Table 7).

TABLE-US-00007 TABLE 7 Analysis result of example 6 6 Upper Middle Lower item section section section Weight percentage 0.9779 1.049 1.057 g/cm3 Ash content wt % 0.1153 0.085 0.0898 higher heating value 4050 4084 4288 (HHV) cal/g Viscosity 6.8 3.57 3.48 50 C., cSt

Example 7

[0032] 1125 g biomass pyrolysis oil, 375 g black high acid value oil and 75 g alcohol are heated to 60 C., and then mixed and settling in room temperature, then take out as upper, middle and lower three sections. Then take out 500 g for each section to carry out specific gravity, ash content, higher heating value and viscosity analysis. From the test result of higher heating value (HHV), the alcohol can enhance the uniformity of overall oil. (as shown in Table 8).

TABLE-US-00008 TABLE 8 Analysis result of example 7 7 Upper Middle Lower item section section section Weight percentage 0.9779 1.077 1.078 g/cm.sup.3 Ash content wt % 0.4417 0.4241 0.4230 higher heating value 3930 4049 4115 (HHV) cal/g Viscosity 6.67 4.2 4.24 50 C., cSt

[0033] Although the present invention has been described in terms of specific exemplary embodiments and examples, it will be appreciated that the embodiments disclosed herein are for illustrative purposes only and various modifications and alterations might be made by those skilled in the art without departing from the spirit and scope of the invention as set forth in the following claims.