Composition Comprising Oils, Free Fatty Acids And Squalene

Abstract

The present invention relates to a composition comprising a triglyceride-containing oil, jojoba oil, a free fatty acid or a salt thereof, and squalene. The present invention also relates to the use of such a composition as a skin conditioning agent.

Claims

1. A composition comprising: (A) 20 to 70% by weight of one or more oils comprising at least 75% by weight, referred to the total weight of the one or more oils, of one or more triglycerides as component A; (B) 10 to 50% by weight of jojoba oil as component B; (C) 5 to 30% by weight of one or more free fatty acids or salts thereof as component C; (D) 5 to 25% by weight of squalene as component D; and (E) 0 to 10% by weight of one or more antioxidants as component E.

2. The composition according to claim 1, wherein component A comprises at least 80% by weight, referred to the total weight of component A, of olive oil.

3. The composition according to claim 1, wherein component A comprises from 1 to 20% by weight, referred to the total weight of component A, of sunflower oil.

4. The composition according to claim 1, wherein the one or more free fatty acids or salts thereof of component C comprise at least 75% by weight, referred to the total weight of component C, of oleic acid or a salt thereof.

5. The composition according to claim 1, wherein component D is phytosqualene.

6. The composition according to claim 1, wherein the one or more antioxidants of component E comprises tocopherol.

7. The composition according to claim 1, wherein the composition comprises: (A) 35 to 50% by weight of component A; (B) 20 to 30% by weight of component B; (C) 10 to 20% by weight of component C; (D) 10 to 15% by weight of component D; and (E) 0 to 5% by weight, of component E.

8. The composition according to claim 1, wherein the composition comprises: (A) 40 to 50% by weight of one or more oils comprising at least 90% by weight, referred to the total weight of component A, of olive oil as component A; (B) 20 to 30% by weight of jojoba oil as component B; (C) 10 to 20% by weight of oleic acid as component C; (D) 10 to 15% by weight of squalene as component D; and (E) 1 to 4% by weight of tocopherol as component E.

9. The composition according to claim 1, wherein at least components A, B, C and D, and optionally component E, if present, are of plant origin.

10. A formulation comprising: (I) 0.1 to 50% by weight of a composition as defined in claim 1; and (II) 50 to 99.9% by weight of one or more cosmetically acceptable ingredients.

11. The formulation according to claim 10, wherein the formulation is a cosmetic formulation selected from the group consisting of skin care oil, skin care cream, skin care lotion, ointment, skin conditioner, face spray, body spray, hand oil, shower bath, hair conditioner, shaving gel, shampoo, body wash, facial cleanser, face mask, bubble bath, intimate wash, bath oil, cleansing milk, micellar water, make-up remover, cleansing wipes, hair mask, perfume, liquid soap, shaving soap, shaving stick, shaving foam, cleansing foam, day cream, anti-ageing cream, body milk, body lotion, body mousse, face serum, eye cream, sunscreen lotion, sun cream, face cream, after-shave lotion, pre-shaving cream, depilatory cream, skin-whitening gel, self-tanning cream, anti-acne gel, mascara, foundation, primer, concealer, blush, bronzer, blemish balm cream, eyeliner, night cream, eye brow gel, highlighter, lip stain, hand sanitizer, hair oil, nail varnish remover, conditioner, hair styling gel, hair styling cream, anti-frizz serum, scalp treatment, hair colorant, split end fluid, deodorant, antiperspirant, baby cream, insect repellent, hand cream, sunscreen gel, foot cream, exfoliator, body scrub, cellulite treatment, bar soap, cuticle cream, lip balm, hair treatment, eye shadow, bath additive, body mist, eau de toilette, mouthwash, toothpaste, lubricating gel, moisturizer, serum, toner, aqua sorbet, cream gel, styling mousse, dry shampoo, lip stick, lip gloss, body oil, shower milk, illuminator, lip crayon, hair spray, combing cream, sunblock and mixtures thereof.

12. A method for conditioning skin comprising the step of contacting skin with a composition comprising: (A) 20 to 70% by weight of one or more oils comprising at least 75% by weight, referred to the total weight of the one or more oils, of one or more triglycerides as component A; (B) 10 to 50% by weight of jojoba oil as component B; (C) 5 to 30% by weight of one or more free fatty acids or salts thereof as component C; (D) 5 to 25% by weight of squalene as component D; and (E) 0 to 10% by weight of one or more antioxidants as component E.

13. The method according to claim 12, wherein the composition is an emollient, lubricant, moisturizer, refatting agent, smoothing agent and/or soothing agent.

14. The composition according to claim 1, wherein the composition consists of: (A) 35 to 50% by weight of component A; (B) 20 to 30% by weight of component B; (C) 10 to 20% by weight of component C; (D) 10 to 15% by weight of component D; and (E) 1 to 5% by weight, of component E.

15. The composition according to claim 1, wherein the composition consists of: (A) 40 to 50% by weight of one or more oils comprising at least 90% by weight, referred to the total weight of component A, of olive oil as component A; (B) 20 to 30% by weight of jojoba oil as component B; (C) 10 to 20% by weight of oleic acid as component C; (D) 10 to 15% by weight of squalene as component D; and (E) 1 to 4% by weight of tocopherol as component E.

Description

EXAMPLES

Example 1—Example of a Composition of the Present Invention

[0233] The blend was prepared by mixing its ingredients at room temperature. The ingredients listed in Table 1 were added one by one and stirred until the blend was homogeneous. The blend was obtained as a clear oily liquid.

TABLE-US-00001 TABLE 1 Example of a composition of the present invention Ingredients INCI name Amount Plantasens ® Ref Olive Oil Olea europaea Olive oil 41% Golden Jojoba Oil Simmondsia chinensis seed oil 26% Oleic acid from Olive Oleic acid 16% Plantasens ® Olive Squalene Squalene 12% Plantasens ® Vitamin E Tocopherol, Helianthus annuus  5%* Natural 50 (Sunflower) Seed oil *2.5% Tocopherol + 2.5% Helianthus annuus (Sunflower) Seed oil

Example 2—Technical Parameters and Oxidative Stability

[0234] The following technical parameters were determined for the blend of Example 1: [0235] Surface tension [mN/m], determined according to EN 14370:2004 [25° C.]: 32.5 [0236] Spreadability [mm2/10 min]: 493 [0237] Cloud point, determined according to DIN ISO 3016 [° C.]: −3 [0238] Refractive index, determined according to DIN ISO 6320 [20° C.]: 1.4716

[0239] The spreadability was determined as follows: [0240] Vitro-Skin® hydration protocol: Vitro-Skin® pieces must be stored for a period of 16 to 24 hours on the shelf of a standardized hydration chamber with a 350 g mixture of glycerol (15%) and water (85%) at the bottom. [0241] The spreading value will be defined as the surface area covered by 10 μl of oil mixture after 10 minutes. [0242] The liquid will be dropped into the center of a hydrated Vitro-Skin® piece measuring 65×65 mm using a manual micropipette from Fa. Mettler-Toledo LLC, Ohio, USA. [0243] The Vitro-Skin® sample will be kept in the hydration chamber for 10 min according to the spreading phase. [0244] After 10 minutes, the outline of the spreading surface will be determined visually, and the spread will be determined using a ruler. [0245] The spreading area will be calculated using the circular area formula: A=πr.sup.2 [A: area; π: circle number (3.14159 . . . ); r: radius of the circle calculated]. [0246] Measurements will be performed in triplicate at room temperature. [0247] The spreading values are given in mm.sup.2 (the higher the value, the higher the spread).

[0248] The oxidative stability at 90° C. was determined according to DIN EN ISO 6886 for the blend of Example 1 and compared with the oxidative stability of squalene. The induction time for the blend of Example 1 (>50 hours) was significantly higher than the induction time for squalene (4.84 hours). Accordingly, the blend of Example 1 is significantly more stable to oxidation than squalene. The composition of the present invention shows high stability to oxidation.

Example 3—Sensory Evaluation

[0249] A sensory evaluation of the blend of Example 1 was conducted by a trained panel. The blend was applied to the skin. The panel found that the blend provides a pleasant feel during application as well as a pleasant after-feel. The composition of the present invention can be used as an emollient.

Example 4—Formulation Example

[0250] An anti-stress replenishing face spray was prepared using the following ingredients:

TABLE-US-00002 Phase Ingredient % A Aqua (water) 86.8 Propanediol 1.0 Aristoflex ® Silk (Sodium Polyacryloyldimethyl Taurate) 0.4 B Hostaphat ® KL340 D (Trilaureth-4 Phosphate) 2.0 Cetearyl Alcohol 1.5 Blend of Example 1 7.0 C Velsan ® CGE (Caprylyl Glyceryl Ether) 1.0 Parfum (Fragrance) 0.3

[0251] This formulation targets, for example, skin with imbalanced sebaceous lipids.

Example 5—Formulation Example

[0252] A regenerating booster hand oil was prepared using the following ingredients:

TABLE-US-00003 Phase Ingredient % A Blend of Example 1 19.5 Caprylic/capric triglycerides 10.0 Isopropyl Palmitate 50.0 Cetearyl Isononanoate 20.0 B Parfum (Fragrance) 0.5

[0253] This formulation targets, for example, skin deprived of sebaceous lipids.

Example 6—Formulation Example

[0254] A hydration shot face cream was prepared using the following ingredients:

TABLE-US-00004 Phase Ingredient % A Water (Aqua) 83.0 Glycerin 2.0 Trisodium Citrate 0.1 Aristoflex ® Silk (Sodium Polyacryloyldimethyl 1.0 Taurate) B Blend of Example 1 10.0 Plantasens ® Emulsifier HP 30 (Glyceryl Stearate 2.0 (and) Sodium Stearoyl Lactylate (and) Cetearyl Alcohol) Rainforest Bacuri Butter (Platonia Insignis Seed 0.5 Butter) C Nipaguard ® SCE (Benzoic Acid (and) Sorbitan 1.2 Caprylate) Fragrance (Golden Temptation) 0.2

[0255] This formulation targets, for example, healthy skin with balanced sebaceous lipids.

Example 7—Rinse-Off Formulations

Example 7a—Nourishing Repair Shampoo

[0256]

TABLE-US-00005 Phase Ingredient Function A Water Ad 100% Carbopol ® Ultrez 21 Rheology 0.40% (Acrylates/C10-30 Alkyl Acrylate Modifier Crosspolymer) B Genapol ® LRO liq (Clariant) Surfactant 37.00%  (Sodium Laureth Sulfate) C GlucoTain ® Care (Clariant) Co-Surfactant 5.00% (Cocoyl Methyl Glucamide) Blend of Example 1 Emollient 0.50% Fragrance AVOCADO (Cosnaderm) Fragrance 0.30% D Water 20.00%  Jaguar ® C-162 (Hydroxypropyl Conditioning 0.10% Guar Hydroxypropyltrimonium Agent Chloride) E NaOH/Citric acid Neutralizer q.s. pH 5.5 F Water 4.00% Sodium Benzoate Preservative 0.45% Trisodium Citrate Buffer 0.50% G Perlogen ®SF 117 (Clariant) Pearlizer 5.00% (Aqua (and) Glycol Distearate (and) Laureth-4) FD&C Violette 2 (Cosnaderm) (CI Colorant 0.002%  60730) H Sodium Chloride Rheology 2.00% Modifier

Example 7b—Clear SLES Free Shower Gel

[0257]

TABLE-US-00006 Phase Ingredient Function A Water Diluent 35.0%  Sodium Coco Sulfate, 90% Surfactant 4.0% B Genagen ® CAB 818 (Clariant) Surfactant 4.0% (Cocamidopropyl Betaine) Nipaguard ® SCE (Clariant) (Sorbitan Preservative 1.0% Caprylate (and) Propanediol (and) Benzoic Acid) C GlucoTain ® Care (Clariant) (Cocoyl Surfactant 5.0% Methyl Glucamide) D Blend of Example 1 Emollient 5.0% Emulsogen ® DTC 070 (Clariant) Solvent 10.0%  (Trideceth-7 Carboxylic Acid) E Genapol ® LT (Clariant) (PEG-150 Thickener 4.0% Polyglyceryl-2 Tristearate (and) Laureth-3 (and) Dipropylene Glycol) F Sodium Hydroxide, 10% Aqueous Solution pH Adjuster q.s. G Water Solubiliser q.s.

Example 7c—Sulfate Free Shower Cream for Atopic Skin

[0258]

TABLE-US-00007 Phase Ingredient Function A Blend of Example 1 Emollient 10.0%  Stearic Acid Stabilizer 5.0% Native Coco Oil Emollient 5.0% (Cocos Nucifera (Coconut) Oil) Velsan ® SC (Clariant) (Sorbitan Preservative 1.0% Caprylate) Booster Lanette ® O (Cetearyl Alcohol) Stabilizer 1.8% Lanette ® 18 (Stearyl Alcohol) Stabilizer 1.2% B GlucoTain ® Plus (Clariant) Co-Surfactant 3.4% (Capryloyl/Caproyl Methyl Glucamide (and) Lauroyl/Myristoyl Methyl Glucamide) Genagen ® 3SB (Clariant) Surfactant 37.7%  (Coco Betaine (and) Sodium Methyl Cocoyl Taurate (and) Sodium Cocoyl Isethionate) GlucoTain ® liquiFlex (Clariant) Co-Surfactant 5.7% (Lauroyl/Myristoyl Methyl Glucamide (and) Coco-Betaine) Genapol ® LA 030 (Clariant) Rheology 1.0% (Laureth-3) Modifier NaOH solution (25%) Neutralizer −0.3%   Water ad 100% C NaOH solution (10%) Neutralizer 1.0% Glycerin 85% Humectant 2.5% Velsan ® AS (Clariant) (p-Anisic Fragrance 0.3% Acid) D Carbopol ® Ultrez 21 (Acrylates/C10- Rheology 0.3% 30 Alkyl Acrylate Crosspolymer) Modifier E Niacinamide Active 2.0% Water Diluent 10.0%  F Citric Acid solution (50%) Neutralizing q.s. pH Agent 5.5

Example 7d—Nutritive Hair Mask

[0259]

TABLE-US-00008 Phase Ingredient Function A Plantasens ® Natural Emulsifier CP5 Emulsifier 1.0% (Clariant) (Glyceryl Oleate (and) Polyglyceryl-3-Polyricinoleate (and) Olea Europaea (Olive) Oil Unsaponifiables) Cetyl Alcohol Stabilizer 4.0% Stearic Acid Stabilizer 1.0% Plantasens ® Argan Butter (Clariant) Emollient 1.0% (Argania Spinosa Kernel Oil (and) Hydrogenated Vegetable Oil) Plantasens ® Apricot Butter (Clariant) Emollient 0.5% (Prunus Armeniaca (Apricot) Kernel Oil (and) Hydrogenated Vegetable Oil) Blend of Example 1 Emollient 1.4% B Water Diluent ad  100%  Allantoin (Clariant) Active 0.1% Tylose H100070 NP2 Rheology 0.5% (Hydroxyethylcellulose) Modifier Genamin ® CTAC (Clariant) (Cetrimonium Conditioning 0.5% Chloride) Agent Genamin ® KDMP (Clariant) Conditioning 1.5% (Behentrimonium Chloride) Agent Glycerol Humectant 5.0% C Beraclay Red (Beraca) Absorbant 2.0% (Magnesium Aluminum Silicate/Kaolin/Mica) Beraclay Dark Red (Beraca) Absorbant 4.0% (Magnesium Aluminum Silicate/Kaolin/ Montmorillonite/Mica) ImerCare ™ 04K (Kaolin) Absorbant 12.0%  D Plantasens ® Lime Serum (Clariant) Active 0.3% (Citrus Limon (Lemon) Seed Oil (and) Phytosterols (and) Olea Europaea (Olive) Oil Unsaponifiables (and) Beeswax) Plantasens ® Olive LD (Clariant) Emollient 0.5% (Hydrogenated Ethylhexyl Olivate (and) Hydrogenated Olive Oil Unsaponifiables) Fragrance ‘Orchidee’ (Cosnaderm) Fragrance 0.5% E EMortal ™ Pep (BioSpectrum) (Propanediol Active 0.8% (and) Water (and) Pisum Sativum (Pea) Peptide) COSI-PLANT Green Tea GW (Cosnaderm) Active 0.3% (Glycerin, Aqua, Camellia Sinensis Leaf Extract) Tocopheryl Acetate Active 0.5% F Nipaguard ® SCE (Clariant) (Sorbitan Preservative 1.2% Caprylate (and) Propanediol (and) Benzoic Acid) Sodium Hydroxide 10% Neutralizing q.s. to Agent pH approx. 4.3

Example 8—Sun Care Formulations

Example 8a—Protective Sun Care Oil SPF 30 (Calculated)

[0260]

TABLE-US-00009 Phase Ingredient Function A C12-15 Alkylbenzoate Emollient ad 100% Plantasens ® Carefeel Light (Clariant) Emollient 10.0%  (Ethylhexyl Olivate) Blend of Example 1 Emollient 5.0% Dow Corning ® 246 Emollient 13.0%  (Cyclohexasiloxane (and) Cyclopentasiloxane) Eclipsogen ® AVB (Clariant) UV Filter 5.0% (Butyl Methoxydibenzoylmethane) Eclipsogen ® OC (Clariant) UV Filter 7.0% (Octocrylene) Eclipsogen® Sorb S (Clariant) UV Filter 2.0% (Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) Eclipsogen ® EHMC (Clariant) UV Filter 7.0% (Ethylhexyl Methoxycinnamate) B Ethanol Solvent 15.0%  C Rainforest Annatto Oil (Beraca) Emollient 1.0% (Bixa Orellana Annatto Oil) Plantasens ® Abyssinian Oil (Clariant) Emollient 2.0% (Crambe Abyssinica Seed Oil) Tocopheryl Acetate Antioxidant 0.5% Fragrance “Frangipane Flower” Fragrance 0.3%

Example 8b—Sun Care Oil

[0261]

TABLE-US-00010 Phase Ingredient Function A Tegosoft ®TN (C12-15 Alkyl Benzoate) Emollient ad 100% Plantasens ® Carefeel Light (Clariant) Emollient 15.0%  (Ethylhexyl Olivate) Plantasens ® Flash 100 (Clariant) Emollient 13.0%  (Tridecane (and) Pentadecane) Eclipsogen ® AVB (Clariant) UV Filter 5.0% (Butyl Methoxydibenzoylmethane) Eclipsogen ® OCR (Clariant) UV Filter 7.0% (Octocrylene) Eclipsogen ® Sorb S (Clariant) UV Filter 2.0% (Bis-Ethylhexyloxylphenol Methoxyphenyl Triazine) Eclipsogen ® EHMC (Clariant) UV Filter 7.0% (Ethylhexylmethoxycinnamate) B Blend of Example 1 Emollient 2.0% Tocopheryl Acetate Antioxidant 0.5% Plantasens ® Olive Active HP (Clariant) Active 2.0% (Olea Europaea (Olive) Oil Unsaponifiables) Fragrance “Kirschblute” Fragrance 0.3%

Example 8c—after Sun Cream Gel

[0262]

TABLE-US-00011 Phase Ingredient Function A Mineral Oil, low viscosity Emollient 3.0% Isopropyl Palmitate Emollient 3.0% Cetiol ® SN (Cetearyl Isononanoate) Emollient 3.0% Blend of Example 1 Emollient 6.0% Tocopheryl Acetate Antioxidant 1.0% B Aristoflex ® AVC (Clariant) (Ammonium Rheology 1.0% Acryloyldimethyltaurate/VP Copolymer) Modifier C Water ad 100% Glycerin Humectant 3.0% Allantoin ® Active 0.2% Preservative Preservative q.s. Panthenol Humectant 1.0% D Collagen nativ 1% Active 3.0% Alcohol Solvent 1.5% Fragrance Fragrance 0.3%

Example 8d—Sun Cream SPF 50+, PA++++(Calculated)

[0263]

TABLE-US-00012 Phase Ingredient Function A Water Diluent ad 100% Glycerin Humectant 3.00% Eclipsogen ® PBSA (Clariant) UV Filter 2.00% (Phenylbenzimidazole Sulfonic Acid) Sodium Hydroxide pH Adjuster q.s. to pH 7 B Hostaphat ® KL 340 D (Clariant) Emulsifier 0.75% (Trilaureth-4 Phosphate) Cetearyl Alcohol Stabilizer 2.25% Plantasens ® Carefeel Light (Clariant) Emollient 4.00% (Ethylhexyl Olivate) Blend of Example 1 Emollient 2.00% Eclipsogen ® Sorb S (Clariant) UV Filter 5.00% (Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) Eclipsogen ® OC (Clariant) (Octocrylene) UV Filter 6.00% Eclipsogen ® EHT (Clariant) (Ethylhexyl UV Filter 3.00% Triazone) C Eclipsogen ® Sorb M (Clariant) UV Filter 10.00%  (Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (and) Water (and) Decyl Glucoside (and) Xanthan Gum (and) Propylene Glycol) D Aristoflex ® Silk (Clariant) Rheology 1.50% (Sodium Polyacryloyldimethyl Taurate) Modifier E Nipaguard ® PO5 (Clariant) Preservative 1.00% (Phenoxyethanol (and) Piroctone Olamine) Perfume Fragrance 0.30%

Example 9—Solid Bar Formulations

Example 9a—Facial Cleanser

[0264]

TABLE-US-00013 Ingredient INCI Function % Tapioca Starch Tapioca Starch Vehicle 63 Blend of Example 1 Sensory/Active 2 Hostapon ® TPHC Sodium Methyl Oleoyl Surfactant 8 Taurate Hostapon ® SCI 85P Sodium Cocoyl Isethionate Surfactant 23 Amazonian White Clay Kaolin Sensory 4

Example 9b—Solid Sun Care Cream

[0265]

TABLE-US-00014 Phase Ingredient INCI Function % A Plantasens ® Olive Hydrogenated Ethylhexyl Emollient 4 LD Olivate; Hydrogenated Olive Oil Unsaponifiables Plantasens ® Ethylhexyl Olivate Emollient 5.45 Carefeel Light Blend of Example 1 Emollient 3 Hostacerin ® DGI Polyglyceryl-2 Structure 3 Sesquiisostearate Former, Sensory B Plantasens ® Hydrogenated Vegetable Structure 15.75 Cosmetic Wax A4 Oil Former Microcrystalline Microcrystalline Wax Structure 6.5 Wax Former Stearic Acid Stearic Acid Structure 9 Former Myristic Acid Myristic Acid Structure 6 Former Plantasens ® Glyceryl Stearate (and) Structure 2.3 Emulsifier HP30 Cetearyl Alcohol (and) Former, Sodium Stearoyl Lactylate Sensory Tapioca Starch Tapioca Starch Sensory 19.5 C Jeescreen ® OS Octisalate UV Filter 5 Homosalate Homosalate UV Filter 10 Eclipsogen ® AVB Avobenzone UV Filter 3 Jeescreen ® OC Octocrylene UV Filter 7.5

Example 9c—Solid Cream

[0266]

TABLE-US-00015 Ingredient INCI Function % Behenyl Alcohol Behenyl Alcohol Structuring 6 agent Plantasens ® Cosmetic Hydrogenated Vegetable Oil Structuring 18 Wax A4 agent Plantasens ® Flash 100 Tridecane (and) Pentadecane Emollient/ 6 Conditioner Plantasens ® Olive LD Hydrogenated Ethylhexyl Emollient/ 15.5 Olivate (and) Hydrogenated Conditioner Olive Oil Unsaponifiables Plantasens ® Carefeel Ethylhexyl Olivate Emollient/ 15.5 Light Conditioner Blend of Example 1 Emollient/ 3 Conditioner Tapioca Starch Tapioca Starch Sensory 36

Example 9d—Solid Shampoo

[0267]

TABLE-US-00016 Ingredient INCI Function % Tapioca Starch Tapioca Starch Vehicle 60 Genagen ® KB Coco-Betaine Surfactant/ 5 Sensory Blend of Example 1 Emollient 3 Genadvance ® Hydra Lauryl/Myristyl Polyricinoleate; Emollient/ 2 Glycerin Humectant Hostapon ® TPHC Sodium Methyl Oleoyl Taurate Surfactant 4 Hostapon ® SCI 85P Sodium Cocoyl Isethionate Surfactant 20 Amazonian White Kaolin Sensory 4 Clay Natural Aromatic Aromatic Coconut Extract Aromatic 2 Extract Extract/ Fragrance

Example 9e—Solid Conditioner

[0268]

TABLE-US-00017 Ingredient INCI Function % Tapioca Starch Tapioca Starch Vehicle 70 Genadvance ® Repair Quaternium-98 Conditioner/Active 10 Natural Aromatic Grean Tea Mint Extract Aromatic Extract/ 2 Extract Fragrance Hostapon ® TPHC Sodium Methyl Oleoyl Surfactant 3 Blend of Example 1 Taurate Emollient 2 Plantasens ® Olive Hydrogenated Ethylhexyl Emollient 4 LD Olivate; Hydrogenated Olive Oil Unsaponifiables Beraca Green Clay Kaolin Sensory 5 DL-Panthenol 50L DL-Panthenol Emollient 4 (Liquid)

Example 9f—Solid Cleansing Body Bar

[0269]

TABLE-US-00018 Phase Ingredient INCI Function % A Plantasens ® Olea Europaea (Olive) Oil Consistency 9.5 Crystolive Wax Unsaponifiables agent Plantasens ® Hydrogenated Vegetable Oil Consistency 5.5 Cosmetic Wax agent A5 Cetyl Alcohol Cetyl Alcohol Structuring 21.5 agent Refined Astrocaryum Murumuru Seed Emollient/ 14.5 Murumuru Butter (and) Tocopherol Moisturizer Butter Blend of Emollient 6 Example 1 B Plantasens ® Sunflower Seed Oil Sorbitol Emulsifier 3 Emulsifier SFO Esters Plantasens ® Glyceryl Stearate (and) Emulsifier 3 Emulsifier HP Cetearyl Alcohol (and) 30 Sodium Stearoyl Lactylate C Amazonian Kaolin Light 6.5 White Clay Exfoliating agent + Colorant Tapioca Starch Tapioca Starch Sensory 9 agent D Hostapon ® Sodium Cocoyl Glutamate Surfactant 15 CCG E Quartz Crystal Silica Exfoliating 2 Facial agent F Multi Ex Butylene Glycol (and) Water Active 2 BSASM ™ (and) Centella Asiatica ingredient Extract (and) Polygonum Cuspidatum Root Extract (and) Scutellaria Baicalensis Root Extract (and) Camellia Sinensis Leaf Extract (and) Glycyrrhiza Glabra (Licorice) Root Extract (and) Chamomilla Recutita (Matricaria) Flower Extract (and) Rosmarinus Officinalis (Rosemary) Leaf Extract BioDTox ® Propanediol (and) Aloe Active 2 Barbadensis Leaf Extract ingredient (and) Bioflavonoids (and) Brassica Oleracea Italica (Broccoli) Extract Vanilla Extract Vanilla Extract Fragrance 0.5

Example 9g—Solid Hair Stick

[0270]

TABLE-US-00019 Ingredient INCI Function % Plantasens ® Olea Europaea (Olive) Oil Structuring 15 Crystolive Wax Unsaponifiables agent/ Viscosifier Plantasens ® Hydrogenated Vegetable Oil Structuring 20 Cosmetic Wax agent A5 Cetearyl Alcohol Cetearyl Alcohol Thickener/ 10 Stabilizer Genamin ® Behentrimonium Methosulfate Conditioning 11.5 BTMS agent Plantasens ® Hydrogenated Olive Oil 7 Olive LD Unsaponifiables Plantasens ® Dodecane Emollient 10 Flash 80 Blend of Emollient 5 Example 1 Plantasens ® VP Ricinus Communis (Castor) Seed Emollient 10 170 Oil (and) Hydrogenated Castor Oil (and) Copernicia Cerifera (Carnauba) Wax (and) Cera Alba (Beeswax) Plantasens ® VL Butyrospermum Parkii (Shea) Emollient 5 Butter (and) Glyceryl Rosinate (and) Olea Europaea (Olive) Oil Unsaponifiables Dongbaek Oil Camellia Japonica Seed Oil Active 4 ingredient Nipaguard ® Sorbitan Caprylate (and) Benzyl Preservative 1.5 SCA Alcohol Nipanox ™ BHT Butylated Hydroxy Toluene Antioxidant 0.3 Perfume Fragrance Fragrance 0.7

Example 9h—Solid Shampoo—Plastic Free

[0271]

TABLE-US-00020 Ingredient INCI Function % Medialan ® LD PF 10 Sodium Lauroyl Sarcosinate Surfactant 10 Hostapon ® SCI 85 G Sodium Cocoyl Isethionate Surfactant 37 Genagen ® KB Coco-Betaine Surfactant 20 Polyglykol 8000 PEG-180 Binder 27 Genadvance ® Repair Quaternium-98 Hair 3 Conditioning agent Blend of Example 1 Emollient 1.5 Nipaguard ® SCE Sorbitan Caprylate (and) Preservative 1 Propanediol (and) Benzoic Acid Perfume Fragrance Fragrance 0.5

Example 9i—Body Odour Deodorizing Soap Bar

[0272]

TABLE-US-00021 Ingredient INCI Function % Soap Base Opal Sodium Palmate, Sodium Surfactant base ad 100 508 Palm Kernelate, Water, Glycerin, Pentasodium Pentatate, EDTA Blend of Emollient 2 Example 1 Caremag ™ D Magnesium Hydroxide Deodorant agent, 2.5 (and) Magnesium Texturizer, Carbonate Hydroxide Antimicrobial agent Velsan ® CGE Caprylyl Glyceryl Ether Emollient 1 Perfume Fragrance 0.4 Color Dye 0.05

Example 9j—Conditioning Soap

[0273]

TABLE-US-00022 Ingredient INCI Function % Soap Base CremerSap Sodium Olivate, Water, Surfactant ad 100 BV 422 Sodium Chloride base Genadvance ® Hydra Lauryl/Myristyl Hair 5 Polyricinoleate (and) Conditioning Glycerin agent Blend of Example 1 Emollient 2 Perfume Fragrance 0.1

Example 9k—Caring Soap

[0274]

TABLE-US-00023 Ingredient INCI Function % Soap Base Opal Sodium Palmate, Sodium Palm Surfactant ad 100 508-SG Kernelate, Water, Glycerin, base Pentasodium Pentatate, EDTA Blend of Example 1 Emollient 3 Fragrance Flovea Fragrance 0.2 (Cosnaderm) Cosnacolor FD&C Dye 0.01 Red No4 CI 14700

Example 9l—Mineral Based Deodorant

[0275]

TABLE-US-00024 Phase Ingredient INCI Function % A Caremag ™ D Magnesium Hydroxide, Deodorant ad 100 Magnesium Carbonate agent, Hydroxide Texturizer, Antimicrobial agent Made White ™ Water (and) Pentylene Brightening 2 Glycol (and) agent Madecassoside Tocopheryl Tocopheryl Acetate 2 Acetate Tapioca Starch Tapioca Starch Texturizer 12 Jasmine Oil Fragrance 0.5 Fragrance Octopirox ® Piroctone Olamine Antimicrobial 0.1 B Plantasens ® Dodecane Emollient 20 Flash 80 Blend of Emollient 5 Example 1 Plantasens ® Orbygnya Oleifera Emollient 3.4 Refined (Babassu) Seed Oil Babassu Butter Plantasens ® Hydrogenated Emollient 5 Olive LD Ethylhexyl Olivate (and) Hydrogenated Olive Oil Unsaponifables Plantasens ® Hydrogenated Vegetable Structuring 15 Cosmetic Wax Oil agent A4 Candellila wax Candellila wax Structuring 15 agent

Example 10—Hand Hygiene Formulations

Example 10a—Hand Hygiene Cream Gel

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TABLE-US-00025 Phase Ingredient INCI Function w/w % A Water Aqua Solvent To 100 Ethanol Ethanol Solvent, Disinfectant 70 Genapol ® G260 Glycereth-26 Moisturization agent 3 B Aristoflex ® Velvet Polyacrylate Thickener, Sensory 1 crosspolymer-11 Enhancer C Blend of Emollient 1 Example 1 Fragrance Fragrance qs D JM Acticare ™ Silver Chloride, Titanium Antimicrobial, 0.1 Dioxide, Diethylhexyl Disinfectant sodium sulfosuccinate, Propylene glycol

Example 10b—Hand Hygiene Wipes

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TABLE-US-00026 Phase Ingredient INCI w/w % A Water Aqua To 100 Polyglykol 400 PEG-8 2 Genapol ® G260 Glycereth-26 2 B GlucoTain ® Sense Sunfloweroyl methyl glucamide 0.5 Emulsogen ® HCO PEG-40 Hydrogenated castor oil 1 040 Blend of Example 1 1 Fragrance 0.2 C Benzethonium Benzethonium Chloride 0.1 Chloride

Example 11—Facial Cleansing Wipes

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TABLE-US-00027 Phase Ingredient INCI % (w/w) A Water Water To 100 A Panthenol Panthenol 0.1 A Aristoflex ® TAC Ammonium Acrylyol Dimethyl Taurate/ 0.1 Carboxyethyl Acrylate Crosspolymer B Plantasens ® Caprylic/Capric Triglyceride, Aqua, Lauryl 2.5 Emulsifier CCT Glucoside, Glycerin, Sodium Lauroyl Lactylate, Glyceryl Stearate, Cetearyl Alcohol, Sodium Stearoyl Lactylate B Blend of 5 Example 1 B Tocopheryl Tocopheryl Acetate 0.05 Acetate B Nipaguard ® SCE Sorbitan Caprylate, Propanediol, Benzoic Acid 1.5 C Fragrance Fragrance 2

Example 12—Skin and Hair Leave-on Formulations

Example 12a—Hair and Skin Moisturizing Nectar

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TABLE-US-00028 Phase Ingredient Function % A Water Solvent ad 100 B Blend of Example 1 Skin Conditioning Agent 5.0 Dongbaek (Tsubaki) Oil Anti-Ageing Active 2.0 (Camellia Japonica Seed Oil) Genadvance ® Hydra (Lauryl/Myristyl Hair Moisturizer, Hair 1.5 Polyricinoleate (and) Glycerin) Conditioner C Aristoflex ® Silk Rheology Modifier 0.7 (Sodium Polyacryloyldimethyl Taurate) D Herbex ™ Yeast Beta Glucan Skin Well-Being 2.0 (Butylene Glycol, Yeast Beta Glucan) Enhancer, UV Protector Plantasens ® Berto™ Orthomoist Skin Moisturizer 1.0 (Orthosiphon Stamineus Leaf Extract (and) Chlorphenesin) E Nipaguard ® EHP Preservative 1.0 (Ethylhexylglycerin, Phenoxyethanol) Fragrance Fragrance 0.4 F Sodium Hydroxide 10% soln. (pH: 4.5-5.5) pH Adjuster q.s.

Example 12b—Skin and Hair Nourishing Cream

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TABLE-US-00029 Phase Ingredient Function % A Water Solvent ad 100 B Blend of Example 1 Skin Conditioning 3.0 Agent Plantasens ® Sunflower Butter Film Former 4.0 (Helianthus Annuus (Sunflower) Seed Oil (and) Hydrogenated Vegetable Oil) Plantasens ® Emulsifier HP 10 Emulsifier 3.0 (Sucrose Polystearate, Cetearyl Alcohol, Olea Europaea (Olive) Oil Unsaponifiables) Genadvance ® Hydra Hair Moisturizer, 1.5 (Lauryl/Myristyl Polyricinoleate (and) Glycerin) Hair Conditioner C Aristoflex ® BLV Rheology Modifier 0.7 (Ammonium Acryloyldimethyltaurate/Beheneth- 25 Methacrylate Crosspolymer) Aristoflex ® AVC (Ammonium Rheology Modifier 0.3 Acryloyldimethyltaurate/VP Copolymer) D Herbex ™ Yeast Beta Glucan Skin Well-Being 2.0 (Butylene Glycol, Yeast Beta Glucan) Enhancer, UV Protector RedSnow ® (Propanediol, Water, Camellia Anti-Ageing Active 2.0 Japonica Flower Extract) Plantasens ® Berto ™ Orthomoist (Orthosiphon Skin Moisturizer 1.0 Stamineus Leaf Extract (and) Chlorphenesin) E Nipaguard ® EHP Preservative 1.0 (Ethylhexylglycerin, Phenoxyethanol) Fragrance Fragrance 0.4 F Sodium Hydroxide 10% soln. (pH: 4.5-5.5) pH Adjuster q.s.

Example 13—Make Up

Example 13a—Blemish Base (BB) Cream Formulation

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TABLE-US-00030 Phase Ingredient % A Aqua to 100 Glycerin 3.00 B Hostaphat ® KL 340 D (Trilaureth-4-Phosphate) 2.2 Caprylic/Capric Triglyceride 2.0 Plantasens ® Olive Active HP 1.0 (Olea Europaea (Olive) Oil Unsaponifiables) Plantasens ® Carefeel Comfort 1.0 (Macadamia Integrifolia/Tetraphylla Seed Oil (and) Crambe Abyssinica Seed Oil (and) Orbignya Oleifera Seed Oil) Plantasens ® Abyssinian Oil (Crambe Abyssinica Seed Oil) 1.0 Blend of Example 1 1.0 Dicaprylyl Ether 1.0 Plantasens ® Olive LD (Hydrogenated Ethylhexyl Olivate (and) 2.0 Hydrogenated Olive Oil Unsaponifiables) Dodecane 3.0 Aristoflex ® Velvet (Polyacrylate Crosspolymer-11) 0.8 Aristoflex ® AVC (Ammonium Acryloyldimethyltaurate/VP Copolymer) 0.8 Caprylyl Methicone (and) PEG-12 Dimethicone/PPG-20 3.0 Crosspolymer Plantasens ® Vitamin E Natural 50 0.5 (Tocopherol and Helianthus annuus (Sunflower) Seed oil) C CI 77891 (and) aqua (and) glycerin (and) xanthan gum (and) sodium 11.0 citrate CI 77492 (and) aqua (and) glycerin (and) xanthan gum (and) sodium 1.6 citrate CI 77491 (and) aqua (and) glycerin (and) xanthan gum (and) sodium 0.7 citrate CI 77499 (and) aqua (and) glycerin (and) xanthan gum (and) sodium 0.2 citrate D Preservative 1.0 E Perfume 0.3

Example 13b—Volumising Mascara Emulsion Formula

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TABLE-US-00031 Phase Ingredient % A Aqua to 100 Disodium EDTA 0.1 Propylene Glycol 2.0 Triethanolamine 1.6 A1 Hydroxyethylcellulose 0.2 A2 Magnesium Aluminium Silicate 1.4 B Isostearic acid 1.0 Phenylpropyldimethylsiloxylicate 3.0 Stearic Acid 3.0 Glyceryl Stearate SE 1.2 Polyvinyl Stearyl Ether 5.0 Copernicia Prunifera (Carnauba) Wax 3.0 Candelilla Wax 4.0 Blend of Example 1 0.5 Synthetic Beeswax 4.0 C CI 77499, Methicone 10.0 D Phenoxetol ® (Phenoxyethanol) 0.6 O-Cymen-5-ol 0.1 E Hydrolyzed Corn Protein, Hydrolyzed Wheat Protein, 2.0 Hydrolyzed Soy Protein

Example 13c—Gelee Glow Multi Use Highlighter

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TABLE-US-00032 Phase Ingredient % A Aqua to 100 Glycerin 10.00 Carrageenan 0.75 Xanthan Gum 0.25 B Plantasens ® Emulsifier HP10 (Sucrose Polystearate 1.50 (and) Cetearyl Alcohol (and) Olea Europaea (Olive) Oil Unsaponifiables) Blend of Example 1 2.00 Plantasens ® Carefeel Light (Ethylhexyl Oleate) 2.00 Plantasens ® Olive LD SP ECO (Coco-Caprylate/ 1.00 Caprate (and) Hydrogenated Olive Oil Unsaponifiables) C Mica 6.50 Mica (and) Titanium Dioxide (and) Iron Oxides 3.00 Synthetic Fluorphlogopite (and) CI 77891 (and) Tin 3.00 Oxide Propanediol 20.00 D Nipaguard ® SCE 1.00 (Sorbitan Caprylate (and) Propanediol (and) Benzoic Acid) Eosidin ™ (Propanediol (and) Water (and) Citrus 1.00 Unshiu Peel Extract) Perfume 0.20

Example 14—Body and Face Leave-on Formulations

Example 14a—éBody Lotion for Dry Skin

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TABLE-US-00033 Phase Ingredient % A Decyl Oleate 2.0 Plantasens ® CP5 (Glyceryl Oleate (and) 5.0 Polyglyceryl-3 Polyricinoleate (and) Olea Europaea (Olive) Oil Unsaponifiables) Blend of Example 1 5.0 Plantasens ® Olive LD (Hydrogenated Ethylhexyl 2.0 Olivate (and) Hydrogenated Olive Oil Unsaponifiables) Caprylic/Capric Triglyceride 5.0 B Glycerin 3.0 Xanthan gum 0.2 C Water up to 100% D Hostapon ® CGN (Sodium Cocoyl Glutamate) 1.0 E Sodium Hydroxide (10%) qs pH 7.0 F Aristoflex ® Velvet (Polyacrylate Crosspolymer-11) 1.0 G Nipaguard ® SCE 1.4 (Sorbitan Caprylate and Propanediol and Benzoic Acid) H Fragrance 1   I Citric acid (10%) qs pH 5.0-5.2

Example 14b—Smooth Moisturiser for Body

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TABLE-US-00034 Phase Ingredient % A Water up to 100% Glycerin 3.5 B Aristoflex ® AVC 0.8 (Ammonium Acryloyl Dimethyltaurate/VP Copolymer) C Plantasens ® Olive LD (Hydrogenated Ethylhexyl 5.0 Olivate (and) Hydrogenated Olive Oil Unsaponifiables) Caprylic/Capric Triglyceride 5.0 Blend of Example 1 5.0 Cetearyl alcohol 1.0 Hostaphat ® KW340 D (Triceteareth-4 Phosphate) 4.0 D Tocopheryl Acetate 0.3 Nipaguard ® PO5 (Phenoxyethanol and Piroctone 1.0 Olamine) Fragrance 1.0 E Citric acid (10%) qs pH 4.5-5.0

Example 14c—Ultra Moisture Night Cream

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TABLE-US-00035 Phase Ingredient % A Caprylic/Capric Triglyceride 3.0 Plantasens ® Olive LD 5.0 (Hydrogenated Ethylhexyl Olivate (and) Hydrogenated Olive Oil Unsaponifiables) Plantasens ® Olive Squalane (Squalane) 3.0 Blend of Example 1 5.0 Isopropyl Palmitate 3.0 Plantasens ® Emulsifier CP40 5.0 (Polyglyceryl-3 Polyricinoleate and Sorbitan Oleate) B Water up to 100% Glycerin 3.0 Magnesium Sulfate 7 H2O 0.8 C Tocopheryl Acetate 0.2 Nipaguard ® SOP (Sorbitan Caprylate and 1.4 Phenoxyethanol) Fragrance 0.3

Example 14d—Proage Elixir—Face Oil

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TABLE-US-00036 Phase Ingredient % A Plantasens ® Abyssinian Oil (Crambe Abyssinica up to Seed Oil) 100% Plantasens ® Olive Oil (Olea Europaea (Olive) Oil) 23.25 Blend of Example 1 10.00 Plantasens ® Abyssinian Serum 0.10 (Crambe Abyssinica Seed Oil (and) Phytosterols (and) Olea Europaea (Olive) Oil Unsaponifiables (and) Cera Alba (Beeswax)) Plantasens ® Olive Active HP 1.00 (Olea Europaea (Olive) Oil Unsaponifiables) Rainforest Acai Oil (Euterpe Oleracea (Acai) Fruit Oil) 1.00 Tocopheryl Acetate 0.50 CI 42053 1.35

Example 14e—Daily Moisturiser for Men's Care

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TABLE-US-00037 Phase Ingredient % A Dicaprylyl Ether 2.50 Plantasens ® Olive LD (Hydrogenated Ethylhexyl 3.00 Olivate (and) Hydrogenated Olive Oil Unsaponifiables) Plantasens ® Olive Active HP 1.00 (Olea Europaea (Olive) Oil Unsaponifiables) Blend of Example 1 1.00 Cetearyl Ethylhexanoate 2.50 Plantasens ® Emulsifier HP10 3.00 (Sucrose Polystearate (and) Cetearyl Alcohol (and) Olea Europaea (Olive) Oil Unsaponifiables) B Water up to 100% Glycerin 5.00 C Aristoflex ® AVC 0.40 (Ammonium Acryloyldimethyltaurate/VP Copolymer) Aristoflex ® Velvet (Polyacrylate Crosspolymer-11) 0.40 D Tocopheryl Acetate 0.20 Nipaguard ® POB 0.80 (Phenoxyethanol (and) Benzoic Acid (and) Piroctone Olamine) Fragrance 0.20 CI 42090 0.01 E Sodium Hydroxide solution (10%) qs pH 5.0-5.3

Example 14f—Soothing Overnight Face Mask

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TABLE-US-00038 Phase Ingredient % A Water up to 100% Rose Water (Rose Damascena Flower Water) 5.0 Glycerin 4.0 Beraca Kaolin Clay Light Green (Kaolin) 0.5 B Plantasens ® Olive LD (Hydrogenated Ethylhexyl Olivate (and) 5.0 Hydrogenated Olive Oil Unsaponifiables) Plantasens ® Abyssinian Oil (Crambe Abyssinica Seed Oil) 5.0 Blend of Example 1 3.0 Plantasens ® Emulsifier HP30 (Glyceryl Stearate (and) Cetearyl 3.0 Alcohol (and) Sodium Stearoyl Lactylate) Plantasens ® Emulsifier DGDS (Polyglyceryl-2 Distearate) 5.0 Plantasens ® Babassu Butter Refined (Orbignya Oleifera Seed 3.0 Oil) Plantasens ® Cosmetic Wax A5 (Hydrogenated Vegetable Oil) 1.0 Plantasens ® Lemon Serum (Citrus Limon (Lemon) Seed Oil 2.0 (and) Phytosterols (and) Olea Europaea (Olive) Oil Unsaponifiables (and) Cera Alba (Beeswax)) Stearic Acid 1.0 C MultiEx BSASM ™ (Butylene Glycol (and) Aqua (and) Centella 3.0 Asiatica Extract (and) Polygonum Cuspidatum Root Extract (and) Scutellaria Baicalensis Root Extract (and) Camellia Sinensis Leaf Extract (and) Glycyrrhiza Glabra (Licorice) Root Extract (and) Chamomilla Recutita (Matricaria) Flower Extract (and) Rosmarinus Officinalis (Rosemary) Leaf Extract) HerbEx ™ Mulberry Extract 2.0 (Butylene Glycol (and) Aqua (and) Morus Alba Leaf Extract) HerbEx ™ Tomato Extract (Glycerin (and) Aqua (and) Solanum 2.0 Lycopersicum Fruit Extract) B-Circadin ® (Propanediol (and) Water (and) Lespedeza Capitata 2.0 Leaf/Stem Extract) D Beraca Passion Fruit Oil 2.0 (Passiflora Edulis Seed Oil (and) Tocopherol) Plantasens ® Olive Active HP 3.0 (Olea Europaea (Olive) Oil Unsaponifiables) Nipaguard ® EHP (Phenoxyethanol (and) Ethylhexylglycerin) 1.0 CI 75810 0.4 Tocopheryl Acetate 0.3 Perfume 0.2 E Citric acid (10%) qs pH 4.5-5.0

Example 15—Mild and Effective Deodorant Roll on

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TABLE-US-00039 Phase Ingredient % A Water up to 100% Xanthan gum 0.5 Aristoflex ® Silk (Sodium Polyacryloyldimethyl 0.3 Taurate) GlucoTain ® Sense (Sunfloweroyl Methylglucamide) 2.0 Blend of Example 1 0.5 Velsan ® CGE (Caprylyl Glyceryl Ether) 1.0 Fragrance 1.0 B Water 20.0 CareMag ™ D 7.5 (Magnesium Hydroxide (and) Magnesium Hydroxide Carbonate)