NITROGEN-CONTAINING ANTI-AGGLOMERANTS FOR PRESERVING THE FLUIDITY OF FLUIDS CONTAINING GAS HYDRATES

Abstract

The present invention relates to the use of a specific group of acylated nitrogen-containing compounds as anti-agglomerants for gas hydrates. The anti-agglomerants are surface active nitrogen-containing compounds with 1-7 nitrogen atoms, which compounds have at least two hydrophobic groups with 6-24 carbon atoms, and where the hydrophobic groups are connected to the remainder of the molecule by an amine moiety or an amide moiety, and which compounds have at least one C2-C5 acyl group; or a salt thereof. The invention also relates to a method for inhibiting the agglomeration of gas hydrates in a conduit, and compositions comprising the gas hydrate anti-agglomerant, a corrosion inhibitor and/or a paraffin deposition inhibitor.

Claims

1. A method for inhibiting agglomeration of gas hydrates, the method comprising: preparing a surface-active nitrogen-containing compound selected from the group of compounds having the following general formulae I and II ##STR00004## wherein R is H or a hydrocarbyl group having 2-24, preferably 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, G is a hydrocarbyl group having 6-24 carbon atoms or the group E, whereby R and G are selected such that the compound has at least one hydrocarbyl group with 6-24 carbon atoms connected to a nitrogen atom; each E is independently H, CH.sub.3, CH.sub.2CH.sub.3 or an acyl group C(O)R.sub.i, wherein each C(O)R.sub.1 is independently an acyl group having 2-24 carbon atoms; provided that at least one, preferably at least 2, of the C(O)R.sub.1 groups is an acyl group having 2-5 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 6-24 carbon atoms; and provided that when both R is H, then there are at least two of C(O)R.sub.1 that are an acyl group having 6-24 carbon atoms; m is 2 or 3, preferably 3, a=1-5, preferably 1-4, more preferably 1-3, and most preferably 1-2; and ##STR00005## wherein R is a hydrocarbyl group having 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, R is H, CH.sub.3 or CH.sub.2CH.sub.3; m and E have the same meaning as in formula (I); provided that at least one of the C(O)R.sub.1 groups is an acyl group having 6-24 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 2-5 carbon atoms; and b and c, independently, is a number 0-2, whereby in formulae I and II the groups E are selected such that the compound contains 2-7 amide groups, as an anti-agglomerant for gas hydrates; and adding the surface-active nitrogen-containing compound to an aqueous mixture.

2. The method according to claim 1 wherein the anti-agglomerant has formula I, wherein a=2, m=2 and RH; wherein G is a group E, and wherein two of the groups E are acyl groups having 6-24 carbon atoms and two are acyl groups having 4 carbon atoms.

3. The method according to claim 1 wherein the anti-agglomerant has formula I, wherein a=3, m=2 and RH; wherein G is a group E, and wherein two of the groups E are acyl groups having 6-24 carbon atoms, two are acyl groups having 2 carbon atoms and one is an acyl group having 4 carbon atoms.

4. The method according to claim 1 wherein the anti-agglomerant has formula I, wherein a=1, m=3 and one R is a hydrocarbyl group having 8-24 carbon atoms; wherein G is a group E, and wherein one of the groups E is an acyl group having 6-24 carbon atoms, one of the groups E is an acyl group having 4 carbon atoms and one of the groups E is an acyl group having 2 carbon atoms.

5. The method according to claim 1 wherein the anti-agglomerant has formula I, wherein a=1, m=3 and one R is a hydrocarbyl group having 8-24 carbon atoms; wherein G is a group E, and wherein one of the groups E is an acyl group having 6-24 carbon atoms and two of the groups E are acyl groups having 4 carbon atoms.

6. The method according to claim 1 wherein the anti-agglomerant has formula I, wherein a=2, m=3 and one R is a hydrocarbyl group having 8-24 carbon atoms; wherein G is a hydrocarbyl group having 8-24 carbon atoms, and wherein the above-mentioned hydrocarbyl groups G and R are situated on the same carbon atom; and two of the groups E are acyl groups having 4 carbon atoms and one of the groups E is an acyl group having 2 carbon atoms.

7. The method according to claim 1 wherein the anti-agglomerant has formula II, wherein the non-terminal R is a hydrocarbyl group having 8-24 carbon atoms, m=3, one of the groups E is an acyl group having 8-24 carbon atoms, one of the groups E is an acyl group having 4 carbon atoms, and b and c are 0.

8. The method according to claim 1 wherein the anti-agglomerant has formula II, wherein the non-terminal R is a hydrocarbyl group having 8-24 carbon atoms, m=3, one of the groups E is an acyl group having 8-24 carbon atoms, one of the groups E is an acyl group having 4 carbon atoms, two of the groups E are acyl groups having 2 carbon atoms, and b and c are 1.

9. A method for inhibiting agglomeration of gas hydrates in a conduit, wherein the conduit contains a flowing mixture comprising hydrocarbons with 1-4 carbon atoms and water, and wherein hydrates are formed from the hydrocarbons and water; the method comprising the steps: a) adding to the mixture an anti-agglomerant in an amount that is effective to inhibit the agglomeration of hydrates at the prevailing temperature and pressure in the conduits, wherein the anti-agglomerant is selected from the group of compounds having the following general formulae I and II ##STR00006## wherein R is H or a hydrocarbyl group having 2-24, preferably 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, G is a hydrocarbyl group having 6-24 carbon atoms or the group E, whereby R and G are selected such that the compound has at least one hydrocarbyl group with 6-24 carbon atoms connected to a nitrogen atom; each E is independently H, CH.sub.3, CH.sub.2CH.sub.3 or an acyl group C(O)R.sub.1, wherein each C(O)R.sub.1 is independently an acyl group having 2-24 carbon atoms; provided that at least one, preferably at least 2, of the C(O)R.sub.1 groups is an acyl group having 2-5 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 6-24 carbon atoms; and provided that when both R is H, then there are at least two of C(O)R.sub.1 that are an acyl group having 6-24 carbon atoms; m is 2 or 3, preferably 3, a=1-5, preferably 1-4, more preferably 1-3, and most preferably 1-2; and ##STR00007## wherein R is a hydrocarbyl group having 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, R is H, CH.sub.3 or CH.sub.2CH.sub.3; m and E have the same meaning as in formula (I); provided that at least one of the C(O)R.sub.1 groups is an acyl group having 6-24 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 2-5 carbon atoms; and b and c, independently, is a number 0-2, whereby in formulae I and II the groups E are selected such that the compound contains 2-7 amide groups; and b) flowing the mixture containing the anti-agglomerant through the conduit.

10. The method according to claim 9 wherein the anti-agglomerant is added to the hydrocarbon/water mixture in an amount of 0.05-10%, preferably 0.5-5%, and most preferably 0.5-3%, by weight, based on the water content of the hydrocarbon/water mixture.

11. The method according to claim 9 wherein one or more corrosion inhibitors and/or one or more paraffin deposition inhibitors are added to the hydrocarbon/water mixture.

12. The method of claim 11 wherein the one or more corrosion inhibitors and/or one or more paraffin deposition inhibitors are present in an amount of from 0.01 to 10 wt %, based on the weight of the anti-agglomerant.

13. An anti-agglomerant for gas hydrates, the anti-agglomerant comprising: a) a surface-active nitrogen-containing compound selected from the group of compounds having the following general formulae I and II ##STR00008## wherein R is H or a hydrocarbyl group having 2-24, preferably 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, G is a hydrocarbyl group having 6-24 carbon atoms or the group E, whereby R and G are selected such that the compound has at least one hydrocarbyl group with 6-24 carbon atoms connected to a nitrogen atom; each E is independently H, CH.sub.3, CH.sub.2CH.sub.3 or an acyl group C(O)R.sub.1, wherein each C(O)R.sub.1 is independently an acyl group having 2-24 carbon atoms; provided that at least one, preferably at least 2, of the C(O)R.sub.1 groups is an acyl group having 2-5 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 6-24 carbon atoms; and provided that when both R is H, then there are at least two of C(O)R.sub.1 that are an acyl group having 6-24 carbon atoms; m is 2 or 3, preferably 3, a=1-5, preferably 1-4, more preferably 1-3, and most preferably 1-2; and ##STR00009## wherein R is a hydrocarbyl group having 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, R is H, CH.sub.3 or CH.sub.2CH.sub.3; m and E have the same meaning as in formula (I); provided that at least one of the C(O)R.sub.1 groups is an acyl group having 6-24 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 2-5 carbon atoms; and b and c, independently, is a number 0-2, whereby in formulae I and II the groups E are selected such that the compound contains 2-7 amide groups; and b) 0.01-10 wt %, based on the weight of said surface-active nitrogen-containing compound, of one or more corrosion inhibitor and/or one or more paraffin deposition inhibitors.

14. The anti-agglomerant of claim 13 further comprising one or more foam depressors, glycol and polyglycols, polymers or co-polymers of N-vinyl-2-pyrrolidone, biocides, metal-complexing agents, solubilizing agents, and additives for stabilizing dispersions, and dispersants.

Description

DESCRIPTION OF THE INVENTION

[0017] The aim of the present invention is to find new anti-agglomerants for gas hydrates that are efficient in seawater, brackish and/or in fresh water and are more economically attractive than previously known compounds.

[0018] It has now surprisingly been found that a surface-active nitrogen-containing compound with 2-7, preferably 2-5, more preferably 2-4, most preferably 2-3, amide groups, which compound has at least one hydrocarbyl group with 6-24, preferably 8-24, and most preferably 8-18 carbon atoms, connected to a nitrogen atom, and where the acyl groups of the amide bonds are having 2-24 carbon atoms, provided that at least one of the acyl groups is having 6-24 carbon atoms; is an efficient anti-agglomerant for gas hydrates in both salt and fresh water. A further advantage is that these compounds also have the ability to act as corrosion inhibitors. According to an unproven theory, it is believed that the essential acyl groups have an improved adhesion to the gas hydrate surface, and thereby facilitate dispersion and prevent agglomeration.

[0019] The compounds according to the invention is suitably described by the formula

##STR00002##

[0020] where R is H or a hydrocarbyl group having 2-24, preferably 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, G is a hydrocarbyl group having 6-24 carbon atoms or the group E; each E is independently H, CH.sub.3, CH.sub.2CH.sub.3 or an acyl group C(O)R.sub.1, wherein each C(O)R.sub.1 group, independently, is an acyl group having 2-24 carbon atoms; provided that at least one, preferably at least 2, of the C(O)R.sub.1 groups is an acyl group having 2-5 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 6-24 carbon atoms; and provided that when both R is H, then there are at least two of C(O)R.sub.1 that are an acyl group having 6-24 carbon atoms; m is 2 or 3, preferably 3, a=1-5, preferably 1-4, more preferably 1-3, and most preferably 1-2; or the formula

##STR00003##

[0021] wherein R is a hydrocarbyl group having 6-24, more preferably 8-24 and most preferably 8-18 carbon atoms, R is H, CH.sub.3 or CH.sub.2CH.sub.3; m, and the group E have the same meaning as in formula (I); provided that at least one of the C(O)R.sub.1 groups is an acyl group having 6-24 carbon atoms, and at least one C(O)R.sub.1 is an acyl group having 2-5 carbon atoms; and b and c independently is a number 0-2.

[0022] One embodiment of formula I are compounds where a=2, m=2 and RH; wherein G is a group E, and wherein two of the groups E is an acyl group having 6-24 carbon atoms and two is an acyl group having 4 carbon atoms.

[0023] Another embodiment of formula I are compounds where a=3, m=2 and RH; wherein G is a group E, and wherein two of the groups E is an acyl group having 6-24 carbon atoms, two is an acyl group having 2 carbon atoms and one is an acyl group having 4 carbon atoms.

[0024] Another embodiment of formula I are compounds where a=1, m=3 and one R is a hydrocarbyl group having 8-24 carbon atoms; wherein G is a group E, and wherein one of the groups E is an acyl group having 6-24 carbon atoms, one is an acyl group having 4 carbon atoms and one is an acyl group having 2 carbon atoms.

[0025] Another embodiment of formula I are compounds where a=1, m=3 and one R is a hydrocarbyl group having 8-24 carbon atoms; wherein G is a group E, and wherein one of the groups E is an acyl group having 6-24 carbon atoms and two is an acyl group having 4 carbon atoms.

[0026] Another embodiment of formula I are compounds where a=2, m=3 and one R is a hydrocarbyl group having 8-24 carbon atoms; wherein G is a hydrocarbyl group having 8-24 carbon atoms, and wherein the above-mentioned hydrocarbyl groups G and R are situated on the same carbon atom; and two of the groups E is an acyl group having 4 carbon atoms and one is an acyl group having 2 carbon atoms.

[0027] One embodiment of formula II is a compound wherein the non-terminal R is a hydrocarbyl group having 8-24 carbon atoms, m=3, one of the groups E is an acyl group having 8-24 carbon atoms, one of the groups E is an acyl group having 4 carbon atoms, and b and c are 0.

[0028] Another embodiment of formula II is a compound wherein the non-terminal R is a hydrocarbyl group having 8-24 carbon atoms, m=3, one of the groups E is an acyl group having 8-24 carbon atoms, one is an acyl group having 4 carbon atoms, two are an acyl group having 2 carbon atoms, and b and c are 1.

[0029] The compounds having these formulae or their salts were found to be very efficient anti-agglomerants for gas hydrates. Optionally, products of formula I or II may be derivatized. For example, the products having basic nitrogens available may be quaternized in a conventional way.

[0030] The above compounds are obtainable by methods well known in the art. Compounds of formula I where m is 3, are obtainable by reacting an alkyl polyamine or a dialkyl polyamine with a mixture of suitable anhydrides, fatty acids, or fatty acid chlorides. The products obtained will obviously consist of a mixture of molecules having the different acyl groups statistically distributed, and formula I will thus only show the average molecule.

[0031] Compounds of formula I where m is 2, are obtainable by reacting a polyethylene polyamine with a mixture of suitable anhydrides, fatty acids, or fatty acid chlorides.

[0032] Compounds of formula II are obtainable by acylating a suitable alkyl polyamine containing a tertiary mono(fatty alkyl)amino group with a mixture of suitable anhydrides, fatty acids, or fatty acid chlorides.

[0033] Suitable alkyl polyamines that can be used as starting materials for compounds of formula I where m is 3 are e.g. linear (fatty alkyl)dipropylenetriamines according to formula RNHCH.sub.2CH.sub.2CH.sub.2NHCH.sub.2CH.sub.2CH.sub.2NH.sub.2, wherein R is an aliphatic group having 6-24 carbon atoms. Other examples are N-alkyl tripropylenetetramines and N-alkyl tetrapropylenepentamines. Further examples are di(fatty alkyl)triamines according to formula R.sub.2NCH.sub.2CH.sub.2CH.sub.2NHCH.sub.2CH.sub.2CH.sub.2NH.sub.2 wherein R is an aliphatic group having 6-24 carbon atoms. Another example is N,N-dialkyl tripropylenetetramines. Suitable polyamines that may be used as starting materials for compounds of formula I where m is 2 are for example dietylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine and hexaethyleneheptamine. Suitable alkylpolyamines that can be used as starting materials for compounds of formula II are branched (fatty alkyl)triamines (Y-triamines) of formula RN(CH.sub.2CH.sub.2CH.sub.2NH.sub.2).sub.2, wherein R is an aliphatic group having 6-24, preferably 8-24, carbon atoms, or branched (fatty alkyl) pentaamines of formula RN(CH.sub.2CH.sub.2CH.sub.2NHCH.sub.2CH.sub.2CH.sub.2NH.sub.2).sub.2, wherein R is has the same meaning as above.

[0034] Examples of suitable fatty amines for use as starting materials for compounds of formula I are N-(n-decyl)-N-(3-aminopropyl)-1,3-propane diamine, N-(n-dodecyl)-N-(3-aminopropyl)-1,3-propane diamine, N-(coco alkyl)-N-(3-aminopropyl)-1,3-propane diamine, N-(rape seed alkyl)-N-(3-aminopropyl)-1,3-propane diamine, N-(soya alkyl)-N-(3-aminopropyl)-1,3-propane diamine, N-oleyl-N-(3-aminopropyl)-1,3-propane diamine, N-(tallow alkyl)-N-(3-aminopropyl)-1,3-propane diamine, N-erucyl-N-(3-aminopropyl)-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-decylamino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-dodecylamino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-(coco alkyl)amino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-(rape seed alkyl)amino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-(soya alkyl)amino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-octadecenylamino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-(tallow alkyl)amino)propyl]-1,3-propane diamine, N-(3-aminopropyl)-N-[3-(9-erucylamino)propyl]-1,3-propane diamine, and, N-{3-[(3-aminopropyl)amino]propyl}-N,N-di-C16-18 alkyltrimethylenediamine. Commercial examples (ex AkzoNobel) of these products are Triameen OV, Triameen C, Tetrameen T, and Tetrameen OV

[0035] Examples of fatty acids for use as starting materials for the amides of compounds of formula I and II are acetic acid, butanoic acid, hexanoic acid, 2-ethylhexanoic acid, n-octanoic acid, n-decanoic acid, 2-propylheptanoic acid, n-dodecanoic acid, coco fatty acid, myristic acid, palmitic acid, oleic acid, stearic acid, rape seed fatty acid, soya fatty acid, tallow fatty acid, tall oil fatty acid, and erucic acid.

[0036] Examples of (fatty alkyl)polyamines that can be used as starting materials for compounds of formula II are N,N-bis(3-aminopropyl)hexyl amine, N,N-bis(3-aminopropyl)(2-ethylhexyl)amine, N,N-bis(3-aminopropyl)n-octyl amine, N,N-bis(3-aminopropyl)decyl amine, N,N-bis(3-aminopropyl)(2-propylheptyl)amine, N,N-bis(3-aminopropyl)dodecyl amine, N,N-bis(3-aminopropyl)(coco alkyl)amine, N,N-bis(3-aminopropyl)tetradecyl amine, N,N-bis(3-aminopropyl)hexadecyl amine, N,N-bis(3-aminopropyl)stearyl amine, N,N-bis(3-aminopropyl)(rape seed alkyl)amine, N,N-bis(3-aminopropyl)(tallow alkyl)amine, N,N-bis(3-aminopropyl)(soya alkyl)amine, N,N-bis(3-aminopropyl)oleyl amine, and N,N-bis(3-aminopropyl)erucyl amine. Commercial examples of these products are Triameen Y-12 and Triameen YT (ex AkzoNobel).

[0037] The acylation reaction can be performed with an acid, an acid anhydride or an acyl chloride. The acetylation reaction is most conveniently performed with acetic anhydride, but also, e.g., acetic acid or acetyl chloride may be used.

[0038] The present invention also relates to a method for inhibiting the agglomeration of gas hydrates in a conduit, where the conduit contains a flowing mixture comprising hydrocarbons with 1-4 carbon atoms and water and where hydrates are formed from the hydrocarbons and water; the method comprising the steps:

[0039] a) adding to the mixture at least one anti-agglomerant selected from the group of compounds as defined in formulae I and II in an amount that is effective to inhibit the agglomeration of hydrates at the prevailing temperature and pressure in the conduits

[0040] b) flowing the mixture containing the anti-agglomerant through the conduit.

[0041] The concentrations of the anti-agglomerants are at least 0.05%, preferably at least 0.5%, by weight of the water phase, and at most 10%, preferably at most 5%, and most preferably at most 3%, by weight of the water phase. The exact amount of anti-agglomerant to be used depends, inter alia, on the structure of the anti-agglomerant, the water quality, the pressures applied, the temperatures involved, and the actual composition of the gas and/or oil. The anti-agglomerants of the invention in addition to their dispersing ability also have other useful properties, such as corrosion inhibiting ability. The anti-agglomerant is preferably added in the well head in a composition that may also contain other corrosion inhibitors and paraffin deposition inhibitors. Such a composition suitably contains

[0042] a) 1 part by weight of at least one gas hydrate anti-agglomerant selected from the group of compounds as defined in formulae I and II, and

[0043] b) 0.0001-0.1, preferably 0.001-0.05 parts by weight of a corrosion inhibitor and/or a paraffin deposition inhibitor per part by weight of gas hydrate anti-agglomerant.

[0044] Examples of suitable corrosion inhibitors are monomeric or polymeric nitrogen-containing compounds, such as a fatty amines, alkoxylated fatty amines, alkyl amidoamines alkyl imidazolines, and quartemary ammonium compounds. Suitable examples include tallow amines, N-(tallow alkyl)-trimethylene diamines, imidazolines, and quaternary amines.

[0045] Examples of suitable paraffin deposition inhibitors, also known as wax dispersants, are usually polymers with a polar moiety as well as hydrophobic side chains which are compatible with the oil and thus have dispersant properties in said oil. Suitable paraffin deposition inhibitors include alcohol esters of alpha-olefin maleic anhydride copolymers, ethylene vinyl acetate copolymers, and alcohol esters of polyacrylic acid.

[0046] Other additives that may be present in the compositions are foam depressors, such as silicone-containing compounds, glycol and polyglycols, polymers or co-polymers of N-vinyl-2-pyrrolidone as described in WO 1993/025798, biocides, metal complexants, such as citric acid, solubilizing agents, and additives for stabilizing the dispersion, as well as other dispersants.

[0047] It should be appreciated that the various aspects and embodiments of the detailed description as disclosed herein are illustrative of the specific ways to make and use the invention and do not limit the scope of invention when taken into consideration with the claims and the detailed description. It will also be appreciated that features from different aspects and embodiments of the invention may be combined with features from different aspects and embodiments of the invention. The term consisting wherever used herein also embraces consisting substantially, but may optionally be limited to its strict meaning of consisting entirely. Further, throughout the description and claims of this specification, the words comprise and contain and variations of the words, for example comprising and comprises, mean including but not limited to, and do not exclude other moieties, additives, components, integers or steps. Moreover the singular encompasses the plural unless the context otherwise requires: in particular, where the indefinite article is used, the specification is to be understood as contemplating plurality as well as singularity, unless the context requires otherwise. Where upper and lower limits are quoted for a property, for example for the concentration of the amide, then a range of values defined by a combination of any of the upper limits with any of the lower limits is also implied. Amounts, unless defined differently, are in weight percent (wt %). Substantially free of a certain component for the purpose of the present invention means that the content of such certain component in the composition is less than 10 wt %, more specifically less than 5 wt %, even more specifically less than 1 wt %, in particular less 0.5 wt %, and in one embodiment less than 0.1 wt %.

[0048] The following embodiments illustrate the invention and should not be construed as limiting the scope thereof.

EXAMPLES

[0049] Synthesis of Intermediate Fatty Amide

[0050] Triameen OV (ex AkzoNobel; 607.7 g, 1.489 mole) was melted and charged to a 2 liter flange flask equipped with mechanical stirrer, thermostat, Liebig condenser, vacuum and nitrogen flow control. At 70 C. oleic acid (405.60 g, 1.490 mole) was charged to the Triameen and temperature rose due to heat of neutralization. Temperature was set at 150 C. and nitrogen flow to 20%. At 150 C. water started to distill and temperature was then raised at a rate of about 10 C./30 min. After 4 hat 150-190 C. the amine value was analysed. Total amine value with potentiometric titration with 0.1 M HClO4 showed amine=2.40 meq/g. Although the amidation is a statistical process, most of the amide function will be on the nitrogen farthest from the nitrogen attached to the alkyl function of the Triameen OV.

[0051] Synthesis of Sample 12Condensate of Oligomeric Amide with Oleyl and Acetyl Groups

[0052] To the reaction flasks of parallel synthesis equipment Radley carousel equipped with 3 three-necked flasks (250 ml) with magnet-stirrers Triameen OV-oleyl amide (78.35 g, 0.118 mole) was charged. Reaction was started at 30 C. by addition of acetic acid anhydride (AAH, 29.6 g, 0.29 mole) to substitute remaining amine groups of the intermediate fatty amide. An exotherm increased the temperature to about 50 C. The reaction was left over night. Day 2 the temperature was increased to 90-100 C. for 4 h.

[0053] Water was added to quench the residual AAH.

[0054] There was no amine left according to NMR measurements.

[0055] Synthesis of Sample 13Condensate of Oligomeric Amide with Oleyl and Butyl Groups

[0056] To the reaction flasks of parallel synthesis equipment Radley carousel equipped with 3 three-necked flasks (250 ml) with magnet-stirrers Triameen OV-oleyl amide (75.28 g, 0.114 mole) was charged. Reaction was started at 30 C. by addition of butanoic acid anhydride (BAH, 45.5 g, 0.288 mole) to substitute remaining amine groups of the intermediate fatty amide. The exotherm increased the temperature to appr. 50 C. The reaction was left over night. Day 2 the temperature was increased to 90-100 C. for 4 h.

[0057] Water was added to quench the residual BAH.

[0058] There was no amine left according to NMR measurements.

[0059] Synthesis of Sample 14 Condensate of Oligomeric Amide with Oleyl, Butyl and Acetyl Groups

[0060] To the reaction flasks of parallel synthesis equipment Radley carousel equipped with 3 three-necked flasks (250 ml) with magnet-stirrers Triameen OV-oleyl amide (74.60 g, 0.113 mole) was charged. Reaction was started at 30 C. by addition of butanoic acid anhydride (22.97 g, 0.145 mole) and acetic anhydride (14.98 g, 0.147 mole) to substitute remaining amine groups (non-amide NH bonds) of the intermediate fatty amide. The AAH/BAH mixture was pre-mixed before addition to the amine/amide. The anhydrides reacted with the non-amide NH bonds. The exotherm increased the temperature to approximately 50 C. The reaction was left over night. Day 2 the temperature was increased to 90-100 C. for 4 h. Thereafter water was added to quench any residual AAH and BAH.

[0061] There was no amine function left according to NMR measurements.

[0062] General about Rocking Cell Technique

[0063] The Rocking Cell technique is disclosed in Production Chemicals for the oil and gas industry, Malcolm A. Kelland, 2009, CRC Press, p 247, as well as WO/2010/104727 and WO/2005/116399, and is based on a purely visual observation of a ball displacement from side to side of a cell that is being rocked at a steady rate in a mixture of oil, water and gas under pressure and declining temperature. The main advantages of this technique are that it allows for direct observation of the formation of gas hydrates. If there are gas hydrates formed, then those will be spotted through a glass window, usually constructed of sapphire glass. If the formation of the hydrates is such that it impedes the movement of the ball, then that will also be spotted and conclude formation of agglomerates which will totally block the cell. For the examples presented below a rocking cell instrumentation RCS20 from PSL Systemtechnik with up to 20 cells was used.

[0064] Experimental Sapphire Multi-Cell Anti-Agglomerant Test Method

[0065] To a water phase (5 ml) or 0.5-1.5 wt % NaCl water solution, European white spirit (7 ml) was added. The mixture was cooled by a cool bath which was set to 18 C., pressure was increased to 90 bar. The Multi-cell was rocked at 15 rocks/min and then gradually cooled to 2 C. during approximately 12 hours. Then the temperature and pressure were held at 2 C. for 1 hr. After the cooling procedure the multi-cell was gradually warmed to 20 C. during approximately 4 hours and held at 20 C. for 1 hour. Additional cooling was performed by gradually lowering the temperature to 6 C. without rocking, followed by rocking for 10 hours at 6 C. The cells were then gradually warmed again to 20 C. during 3 hours.

[0066] The ranking in the rocking cell test is as follows:

[0067] Afine dispersed hydrates, no deposits

[0068] BNo plugging is observed in video, but run time increased (No deposits but coarse hydrate particles)

[0069] CSignificant deposits, ball still moving slowly

[0070] Dplug of hydrate, run time decreases as the ball breaks up hydrate lumps after some hours

[0071] Eplug of hydrate, ball stops moving

Example 1

[0072] The comparison products X and Y, and the products 12, 13 and 14 according to the invention were investigated with the Rocking Cell technique, and the results are collected in the Table below.

TABLE-US-00001 Sea Sea Sea Fresh Fresh Fresh water water water water water water (1.5% (1% (0.5% (1.5% (1% (0.5% Shut Product a.s) a.s) a.s) a.s) a.s) a.s) in Compar- AA BB BB AA ison X * Compar- AB CD EE ison Y ** 12 AA Not Not AA Not Not tested tested tested tested 13 AA AA-BB AA-CC AA-CC 14 AA AA AA AA, CC AA * Diester of dibutyldiethanol ammonium bromide and coconut fatty acid. ** N-oleyl-trimethylene diamine diamidated with acetic anhydride

[0073] The products 12, 13 and 14 have been described in the synthesis examples above, and all of these products have one long alkyl group, one long amide group and two short amide groups. In the tests with the Rocking Cell technique very fine dispersed gas hydrate crystals in the oil is resulting when these products are used. From the results in the Table it is evident that the products according to the invention are more efficient than the comparison dialkyl quat X and the monoalkyl diamide Y in both sea water and in fresh water.