RESISTIVE RANDOM ACCESS MEMORY (RRAM) CELLS AND METHODS OF CONSTRUCTION
20220393105 · 2022-12-08
Assignee
Inventors
Cpc classification
H10N70/826
ELECTRICITY
H10B63/30
ELECTRICITY
H10N70/245
ELECTRICITY
H10N70/24
ELECTRICITY
International classification
Abstract
Resistive random access memory (RRAM) cells, for example conductive bridging random access memory (CBRAM) cells and oxygen vacancy-based RRAM (OxRRAM) cells are provided. An RRAM cell may include a metal-insulator-metal (MIM) structure formed between adjacent metal interconnect layers or between a silicided active layer (e.g., including MOSFET devices) and a first metal interconnect layer. The MIM structure of the RRAM cell may be formed by a damascene process including forming a tub opening in a dielectric region, forming a cup-shaped bottom electrode in the tub opening, forming a cup-shaped insulator in an interior opening defined by the cup-shaped bottom electrode, and forming a top electrode in an interior opening defined by the cup-shaped insulator. The cup-shaped bottom electrode, or a component thereof (in the case of a multi-layer bottom electrode) may be formed concurrent with interconnect vias, e.g., by deposition of tungsten or other conformal metal.
Claims
1. A method of forming an integrated circuit structure including a resistive random access memory cell, the method comprising: forming a tub opening in a dielectric region; forming a cup-shaped bottom electrode in the tub opening; forming a cup-shaped insulator in an interior opening defined by the cup-shaped bottom electrode; forming a top electrode in an interior opening defined by the cup-shaped insulator; and forming an upper metal layer over the dielectric region, the upper metal layer including a top electrode contact in electrical contact with the top electrode, the cup-shaped bottom electrode, the cup-shaped insulator, and the top electrode defining the resistive random access memory cell.
2. The method of claim 1, wherein the resistive random access memory cell is formed by a damascene process.
3. The method of claim 1, wherein the resistive random access memory cell is formed without adding any photomask processes to a background integrated circuit fabrication process.
4. The method of claim 1, comprising, prior to forming the upper metal layer over the dielectric region: planarizing a top surface of the top electrode with a top surface of the dielectric region; and depositing a diffusion barrier layer to cover the planarized top surface of the top electrode, the diffusion barrier layer comprising a dielectric material.
5. The method of claim 4, wherein: forming the upper metal layer over the dielectric region comprises etching an upper dielectric layer to form a top electrode contact opening for forming the top electrode contact; and the diffusion barrier layer acts as an etch stop during the etch.
6. The method of claim 1, comprising: concurrently forming the tub opening and a via opening in the dielectric region; and depositing a conformal metal to concurrently form the cup-shaped bottom electrode in the tub opening and a via in the via opening.
7. The method of claim 6, wherein forming the upper metal layer over the dielectric region comprises concurrently forming the top electrode contact in electrical contact with the top electrode and an upper interconnect element in contact with the via.
8. The method of claim 1, wherein forming the cup-shaped bottom electrode in the tub opening comprises: depositing a conformal first metal to form a cup-shaped bottom electrode outer component in the tub opening concurrently with the via in the via opening; and depositing a conformal second metal over the cup-shaped bottom electrode outer component to form a cup-shaped bottom electrode inner component.
9. The method of claim 8, wherein: the conformal first metal comprises tungsten or cobalt; and the conformal second metal comprises platinum.
10. The method of claim 1, wherein the resistive random access memory cell comprises a conductive bridging random access memory cell.
11. The method of claim 1, wherein the resistive random access memory cell comprises an oxygen vacancy-based resistive random access memory cell.
12. The method of claim 1, wherein the cup-shaped bottom electrode comprises platinum.
13. An integrated circuit structure, comprising: a dielectric region including a tub opening; a resistive random access memory cell structure formed in the tub opening and including: a cup-shaped bottom electrode; a cup-shaped insulator; and a top electrode; and an upper metal layer over the dielectric region and including a top electrode contact in electrical contact with the top electrode.
14. The integrated circuit structure of claim 13, wherein the resistive random access memory cell comprises a damascene structure.
15. The integrated circuit structure of claim 13, wherein: the dielectric region is formed over a lower metal layer including a lower interconnect element; the resistive random access memory cell structure is conductively connected between the lower interconnect element in the lower metal layer and the top electrode contact in the upper metal layer.
16. The integrated circuit structure of claim 13, wherein: the dielectric region is formed over a transistor including a doped source region and a doped drain region; the cup-shaped bottom electrode of the resistive random access memory cell structure is conductively coupled to a silicide region formed on the source region or on the drain region of the transistor.
17. The integrated circuit structure of claim 13, comprising a via formed in a via opening in the dielectric region; and wherein the upper metal layer includes an interconnect element in contact with the via.
18. The integrated circuit structure of claim 13, wherein the cup-shaped bottom electrode comprises: a cup-shaped bottom electrode outer component formed in the tub opening; and a cup-shaped bottom electrode inner component formed on the cup-shaped bottom electrode outer component; wherein the cup-shaped bottom electrode inner component is formed from a different material than the cup-shaped bottom electrode outer component.
19. The integrated circuit structure of claim 18, wherein: the cup-shaped bottom electrode outer component comprises tungsten or cobalt; and the cup-shaped bottom electrode inner component comprises platinum.
20. The integrated circuit structure of claim 13, wherein the resistive random access memory cell comprises a conductive bridging random access memory cell.
21. The integrated circuit structure of claim 20, wherein the cup-shaped insulator comprises GeS.sub.2, Al.sub.3O.sub.3, or WO.sub.3.
22. The integrated circuit structure of claim 13, wherein the resistive random access memory cell comprises an oxygen vacancy-based resistive random access memory cell.
23. The integrated circuit structure of claim 22, wherein the cup-shaped insulator comprises Al.sub.3O.sub.3, Ta.sub.2O.sub.5, or HfO.sub.2.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0033] Example aspects of the present disclosure are described below in conjunction with the figures, in which:
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042] It should be understood that the reference number for any illustrated element that appears in multiple different figures has the same meaning across the multiple figures, and the mention or discussion herein of any illustrated element in the context of any particular figure also applies to each other figure, if any, in which that same illustrated element is shown.
DETAILED DESCRIPTION
[0043] The present disclosure provides Resistive Random Access Memory (RRAM) cells, for example, CBRAM and OxRRAM cells, including (a) a cup-shaped metal/insulator/metal (MIM) structure formed between adjacent metal interconnect layers or between a silicided active region and an interconnect layer, e.g., metal-1 layer and (b) a top contact. Such RRAM cells may be formed in accordance with the present disclosure without any added mask layers, as compared with a background CMOS fabrication process.
[0044] An RRAM cell can be perceived as a two-terminal device with a sandwiched metal/insulator/metal (MIM) structure, with an optional insulator cap layer to improve cell performance (improved program, erase, or reliability).
[0045] As used herein, a “metal layer,” for example in the context of the lower metal layer M.sub.x and upper metal layer M.sub.x+1, may comprise any metal or metalized layer or layers, including:
[0046] (a) a metal interconnect layer, e.g., comprising copper, aluminum or other metal formed by a damascene process or deposited by a subtractive patterning process (e.g., deposition, patterning, and etching of a metal layer), or
[0047] (b) a silicided active region including a number of silicided structures (structures having a metal silicide layer formed thereon), for example a silicided source region, drain region, or polysilicon gate of a MOSFET.
[0048] For example, an RRAM cell structure may be constructed between two adjacent metal interconnect layers M.sub.x and M.sub.x+1 at any depth in an integrated circuit structure. As another example, an RRAM cell structure may be constructed over a silicided active region, in particular on a silicon transistor having metal silicide layers formed on selected transistor components, and below a first metal interconnect layer (often referred to as Metal-1); in such an example, the silicided active region defines the lower metal layer M.sub.x where x=0 (i.e., M.sub.0) and the first metal interconnect layer (Metal-1) defines the upper metal layer M.sub.x+1 (i.e., M.sub.1).
[0049] In some examples, the RRAM cell, in particular the MIM structure of the RRAM cell, may be formed concurrent with certain interconnect structures, e.g., interconnect via, separate from the RRAM cell. For example, a cup-shaped bottom electrode (or a component thereof) of the RRAM cell may be formed concurrent with interconnect vias, by deposition of a conformal metal layer, e.g., tungsten, into respective openings for the cup-shaped bottom electrode and interconnect vias. For example,
[0050] In other examples, the RRAM cell, in particular the MIM structure of the RRAM cell, may be formed distinct (non-concurrent) from interconnect structures, e.g., interconnect vias. For example,
[0051] As discussed below with reference to
[0052]
[0053] As shown in
[0054] The CBRAM cell 202 includes a metal-insulator-metal (MIM) CBRAM structure 226 formed in a tub opening 229 in the via layer V.sub.x. The MIM CBRAM structure 226 includes a cup-shaped bottom electrode 220, a cup-shaped insulator 222 formed on the cup-shaped bottom electrode 220, and a top electrode 224 formed in an interior opening defined by the cup-shaped insulator 222. The cup-shaped bottom electrode 220 includes (a) a laterally-extending bottom electrode base 230 in contact with an underlying metal interconnect element 233 and (b) multiple vertically-extending bottom electrode sidewalls 232 extending upwardly from the laterally-extending bottom electrode base 230.
[0055] As discussed below with reference to
[0056] In one example, the bottom electrode base 230 may have a rectangular perimeter (e.g., having a square or non-square rectangular shape) defining four lateral sides when viewed from above, with four vertically-extending bottom electrode sidewalls 232 extending upwardly from the four lateral sides of the rectangular perimeter. The cup-shaped bottom electrode 220 may include any other number of vertically-extending bottom electrode sidewalls 232 extending upwardly from the bottom electrode base 230.
[0057] The laterally-extending bottom electrode base 230 and vertically-extending bottom electrode sidewalls 232 define an interior opening 236 of the cup-shaped bottom electrode 220. As shown, the cup-shaped insulator 222 is formed in the interior opening 236 defined by the cup-shaped bottom electrode 220 and includes a laterally-extending insulator base 240, formed over the bottom electrode base 230, and multiple vertically-extending insulator sidewalls 242 extending upwardly from the laterally-extending insulator base 240, with each vertically-extending insulator sidewall 242 formed on (laterally adjacent) a respective bottom electrode sidewall 232. The cup-shaped insulator 222 may comprise germanium disulfide (GeS.sub.2), WO.sub.3, Al.sub.3O.sub.3, a mixture of WO.sub.3 and Al.sub.3O.sub.3, or other suitable insulator material.
[0058] The laterally-extending insulator base 240 and vertically-extending insulator sidewalls 242 define an interior opening 244. The top electrode 224 is formed inside and fills the interior opening 244 defined by the cup-shaped insulator 222. The top electrode 224 may comprise silver (Ag), copper (Cu), platinum (Pt), or other suitable metal.
[0059] A diffusion barrier layer 282, which may comprise a dielectric material, such as SiN or SiC, without limitation, may be formed over the top electrode 224, insulator sidewalls 242, bottom electrode sidewalls 232, and interconnect via 214. The diffusion barrier layer 282 may be formed prior to formation of the upper metal layer M.sub.x+1 to provide an etch stop for a subsequent M.sub.x+1 trench metal etch (for forming upper interconnect element and a top electrode contact 260).
[0060] Diffusion barrier layer 282 may be formed over the MIM CBRAM structure 226 to provide a barrier against diffusion from the top electrode 224 (e.g., silver diffusion). In some examples, the diffusion barrier layer 282 may comprise silicon nitride (SiN), silicon carbide (SiC), or a high-k dielectric material (e.g., having a dielectric constant above 7). In addition to providing a diffusion barrier, the diffusion barrier layer 282 may act as an etch stop during construction of the upper metal layer M.sub.x+1, e.g., during a damascene etch for creating metal elements in upper metal layer M.sub.x+1. The diffusion barrier layer 282 may also provide an effective termination layer for the edge electric field of the CBRAM cell 202 to improve the breakdown voltage of the CBRAM cell 202.
[0061] The upper metal layer (M.sub.x+1) formed over the via layer V.sub.x (including interconnect via 214 and MIM CBRAM structure 226) includes a top electrode contact 258 in electrical contact with the CBRAM top electrode 224 and an upper interconnect element 260 in electrical contact with the interconnect via 214. In some embodiments, the top electrode contact 258 and upper interconnect element 260 comprise damascene elements formed by a damascene process, e.g., using copper, tungsten, or aluminum. For example, top electrode contact 258 and upper interconnect element 260 may comprise copper damascene elements formed over a barrier layer 259, e.g., a TaN/Ta bilayer.
[0062] Each of the top electrode contact 258 and upper interconnect element 260 may comprise a wire or other laterally elongated structure (e.g., elongated in the y-axis direction), or a discrete pad (e.g., having a square, circular, or substantially square or circular shape in the x-y plane), or any other suitable shape and structure.
[0063] Thus, according to the example process described above, the MIM CBRAM structure 226, in particular the cup-shaped bottom electrode 220, may be formed concurrent with the interconnect structure 204, in particular via 214. As noted above, in other examples the MIM CBRAM structure 226 may be formed distinct (non-concurrent) from interconnect structure 204 (e.g., distinct from via 214).
[0064]
[0065]
[0066] A photoresist layer 302 may be deposited and patterned to form photoresist openings, and the underlying IMD region 208 is etched through the photoresist openings to form a tub opening 229 for the formation of MIM CBRAM structure 226 and multiple via openings 215 in the IMD region 208. One via opening 215 is shown in
[0067] In contrast, the tub opening 229 may have a substantially greater width W.sub.tub_x in the x-direction and/or width W.sub.tub_y in the y-direction than via opening 215. The shape and dimensions of the tub opening 229 may be selected based on various parameters, e.g., for effective manufacturing of the MIM CBRAM structure 226 and/or for desired performance characteristics of the resulting CBRAM cell 202. In one example, the tub opening 229 may have a square or rectangular shape in the x-y plane. In other examples, tub opening 229 may have a circular or oval shape in the x-y plane.
[0068] As noted above, a width of tub opening 229 in the x-direction (W.sub.tub_x), y-direction (W.sub.tub_y), or both the x-direction and y-direction (W.sub.tub_x and W.sub.tub_y) may be substantially larger than both the width W.sub.via of via openings 215 in the x-direction and width W.sub.via of via openings 215 in the y-direction. For example, in some examples, each width of W.sub.tub_x and W.sub.tub_y of tub opening 229 is at least twice as large as the width W.sub.via of via openings 215. In particular examples, each width W.sub.tub_x and W.sub.tub_y of tub opening 229 is at least five time as large as the width W.sub.via of via opening 215. Each width of tub opening 229 (W.sub.tub_x and W.sub.tub_y) may be sufficient to allow a construction of the MIM CBRAM structure 226 within the tub opening 229 by a damascene process, for example allowing the construction of cup-shaped bottom electrode 220, cup-shaped insulator 222 formed in interior opening 236 of the cup-shaped bottom electrode 220, and top electrode 224 formed in interior opening 244 of the cup-shaped insulator 222. In some examples, W.sub.tub_x and W.sub.tub_y are each in the range of 0.5-100 μm, for example in the range of 0.5-10 μm.
[0069] Further, tub opening 229 may be formed with a height-to-width aspect ratio of less than or equal to 2.0 in both the x-direction and y-direction, e.g., to allow effective filling of the tub opening 229 by conformal materials. For example, tub opening 229 may be formed with aspect ratios H.sub.tub/W.sub.tub_x and H.sub.tub/W.sub.tub_y each in the range of 0.1-2.0, for example in the range of 0.5-2.0. In some examples, aspect ratios H.sub.tub/W.sub.tub_x and H.sub.tub/W.sub.tub_y are each less than or equal to 1.5, e.g., for effective filling of tub opening 229 by conformal materials, e.g., tungsten, cobalt, or aluminum. For example, tub opening 229 may be formed with aspect ratios H.sub.tub/W.sub.tub_x and H.sub.tub/W.sub.tub_y each in the range of 0.5-1.5, or more particularly in the range of 0.8-1.2.
[0070] Next, as shown in
[0071] A conformal metal layer 312 is then deposited over the glue layer 238 and extends down into the tub opening 229 and into the via opening 215. As shown, the deposited conformal metal layer 312 (a) fills interconnect via opening 215 to form the interconnect via 214 and (b) covers the interior surfaces of the tub opening 229 to form the cup-shaped bottom electrode 220 defining interior opening 236. As discussed above, the cup-shaped bottom electrode 220 includes multiple (in this example, four) vertically-extending bottom electrode sidewalls 232 extending upwardly from the laterally-extending bottom electrode cup base 230. In one example, the conformal metal layer 312 comprises tungsten deposited with a thickness of 1000 Å to 5000 Å. In other examples, the conformal metal layer 312 may comprise cobalt, aluminum, or other conformal metal. The conformal metal layer 312 may be deposited by a conformal chemical vapor deposition (CVD) process or other suitable deposition process. The glue layer 238 (e.g., comprising TiN) may increase or enhance an adhesion of the conformal metal layer 312 to the interior surfaces of the tub opening 229, including vertical sidewall surfaces of tub opening 229, to facilitate the formation of the cup-shaped bottom electrode 220.
[0072] Next, as shown in
[0073] Next, as shown in
[0074] Next, as shown in
[0075] The cup-shaped bottom electrode 220, the cup-shaped insulator 222, and the top electrode 224 collectively define the MIM CBRAM structure 226. According to the process described above, the MIM CBRAM structure 226 is thus formed by a damascene process including (a) depositing the conformal metal layer 312, insulator layer 320, and top electrode layer 330 over the IMD region 208 and extending down into the tub opening 229, and (b) a CMP process to remove the portions of the conformal metal layer 312, insulator layer 320, and top electrode layer 330 outside (above) the tub opening 229. The CMP process is suitable for a wide variety of electrode materials, including for example W, WO.sub.3, Al.sub.3O.sub.3, TiW, or Cu, without limitation.
[0076] Forming the MIM CBRAM structure 226 using such a damascene process—referred to herein as a “damascene integration”—allows the CBRAM cell 202 to be formed without a metal etch, which may be advantageous as compared with other processes for forming an MIM CBRAM structure that require one or more metal etch. For example, during a plasma etch (a common metal etch), certain exotic materials such as GeS.sub.2 and silver do not form a volatile by-product (i.e., a removable gas by-product) in the plasma etch chamber, resulting in a solid by-product remaining in the etch chamber, which can be problematic due to particle generation and degradation of etch chamber performance (e.g., etch rate, within wafer non-uniformity, and selectivity). The damascene integration disclosed above allows the use of exotic materials such as GeS.sub.2 and silver in the CBRAM cell 202 (e.g., a GeS.sub.2 for insulator layer 320 forming cup-shaped insulator 222 and silver for top electrode layer 330 forming top electrode 224) while avoiding the problems associated with etching such materials.
[0077] Next, as shown in
[0078] In addition, in some examples the diffusion barrier layer 282 also acts as an etch stop layer for a damascene trench etch (e.g., Cu trench etch) during formation of overlying metal structures, as discussed below.
[0079] Next, as shown in
[0080] To form the upper metal layer M.sub.x+1, a dielectric layer 262 is first deposited over the diffusion barrier layer 282. In some examples, the dielectric layer 262 may comprise silicon oxide, FSG (FluoroSilicate Glass), OSG (OrganoSilicate Glass), or porous OSG. The dielectric layer 262 may be patterned and etched to form a top electrode contact opening 350 above the top electrode 224, and an interconnect opening 352 (e.g., trench opening) above the via 214, with the etch proceeding through diffusion barrier layer 282 through top electrode contact opening 350 and interconnect opening 352. A barrier layer (e.g., a TaN/Ta bilayer) indicated at 259 and a copper seed layer may be deposited over the dielectric layer 262 and extending down into the etched top electrode contact opening 350 and interconnect opening 352. A copper plating process may then be performed, which fills the top electrode contact opening 350 and interconnect opening 352 with copper. A copper anneal may be performed, followed by a copper CMP process to remove portions of the copper above the dielectric layer openings 350 and 352, thereby defining the top electrode contact 258 in electrical contact with the CBRAM top electrode 224, and an upper interconnect element 260 in electrical contact with the via 214.
[0081] After forming the upper metal layer M.sub.x+1 as discussed above, the process may continue to construct additional interconnect structures, e.g., by constructing additional metal layers separated by respective dielectric layers.
[0082]
[0083] As shown in
[0084] In the example shown in
[0085] Other embodiments provide an OxRRAM cell formed by a process similar to the process for CBRAM cell 200a discussed above. For example, an OxRRAM cell may include a cup-shaped metal-insulator-metal (MIM) structure formed in a via layer between adjacent metal interconnect layers or between a silicided active region (e.g., including MOSFET transistors) and a metal-1 interconnect layer. The MIM structure of the OxRRAM cell may include a cup-shaped bottom electrode, an insulator/electrolyte layer, an optional insulator cap layer, and a top electrode, all formed in a tub opening in the via layer. In some examples, the cup-shaped bottom electrode may be formed simultaneously with vias in the via layer, e.g., by a conformal tungsten deposition, as shown in
[0086]
[0087] Turning first to
[0088] The interconnect structure 504 may include a lower interconnect element 510 formed in a lower metal layer M.sub.x (for example, where x=0 for a silicided active layer as discussed above) and an upper interconnect element 560, e.g., metal-1 layer, formed in an upper metal layer M.sub.x+1 and connected to the lower interconnect element 510 by at least one interconnect via 514 formed in via layer V.sub.x by depositing a conformal metal, e.g., tungsten, cobalt or aluminum, into respective via openings 515. Each of the lower interconnect element 510 and upper interconnect element 560 may comprise a wire or other laterally elongated structure (e.g., elongated in the y-axis direction), or a discrete pad (e.g., having a square, circular, or substantially square or circular shape in the x-y plane), or any other suitable shape and structure.
[0089] The MIM OxRRAM structure 526a is formed in a tub opening 529 in the via layer V.sub.x. The MIM OxRRAM structure 526a includes a cup-shaped bottom electrode 520, a cup-shaped insulator 522 formed on the cup-shaped bottom electrode 520, and a top electrode 524 formed in an interior opening defined by the cup-shaped insulator 522. The cup-shaped bottom electrode 520 includes (a) a laterally-extending bottom electrode base 530 in electrical contact with a metal interconnect element 533 underlying bottom electrode base 530, and (b) multiple vertically-extending bottom electrode sidewalls 532 extending upwardly from the laterally-extending bottom electrode base 530.
[0090] The cup-shaped bottom electrode 520 may be formed concurrently with the via 514 by depositing a conformal metal, e.g., tungsten, cobalt or aluminum, into the tub opening 529 and via opening 515 in via layer V.sub.x. In some example, a glue layer 538, e.g., comprising titanium nitride (TiN), is deposited in the tub opening 529 and via opening 515 prior to the conformal metal, to improve adhesion between the conformal metal and IMD region 508.
[0091] In one example, the bottom electrode base 530 may have a rectangular perimeter (e.g., having a square or non-square rectangular shape) defining four lateral sides when viewed from above, with four vertically-extending bottom electrode sidewalls 532 extending upwardly from the four lateral sides of the rectangular perimeter. The cup-shaped bottom electrode 520 may include any other number of vertically-extending bottom electrode sidewalls 532 extending upwardly from the bottom electrode base 530.
[0092] The laterally-extending bottom electrode base 530 and vertically-extending bottom electrode sidewalls 532 define an interior opening 536 of the cup-shaped bottom electrode 520. As shown, the cup-shaped insulator 522 is formed in the interior opening 536 defined by the cup-shaped bottom electrode 520 and includes a laterally-extending insulator base 540, formed over the bottom electrode base 530, and multiple vertically-extending insulator sidewalls 542 extending upwardly from the laterally-extending insulator base 540, with each vertically-extending insulator sidewall 542 formed on (laterally adjacent) a respective bottom electrode sidewall 532. In some examples, the cup-shaped insulator 522 may comprise an insulating material such as Al.sub.3O.sub.3, Ta.sub.2O.sub.5, ZrO.sub.2, HfO.sub.2, or other oxide, and may be deposited by chemical vapor deposition (CVD), atomic layer deposition (ALD) or other suitable process. In some examples, the cup-shaped insulator 522 may have a thickness in the range of 300-1000 Å, for example in the range of 400-600 Å.
[0093] The laterally-extending insulator base 540 and vertically-extending insulator sidewalls 542 define an interior opening 544. The top electrode 524 is formed inside and fills the interior opening 544 defined by the cup-shaped insulator 522. The top electrode 524 may comprise silver (Ag), copper (Cu), platinum (Pt), or other suitable metal.
[0094] In some examples, an optional insulator cap layer 550 comprising a dielectric or metallic layer may be formed between the cup-shaped insulator 522 and the top electrode 524. In some embodiments, the insulator cap layer 550 may comprise a layer of material such as Al.sub.3O.sub.3, Ta.sub.2O.sub.5, ZrO.sub.2, HfO.sub.2, Ti, or TiN, and may be deposited by CVD, PVD, or ALD methods with a layer thickness in the range of 50-200 Å, for example. The addition of the optional insulator cap layer 550 provides improved control over the performance of the resulting OxRRAM cell 502, such as reducing leakage current, which may improve the speed or reliability of resistive switching in the OxRRAM cell 502.
[0095] A diffusion barrier layer 582 may be formed over the MIM OxRRAM structure 526a to provide a barrier against diffusion from the top electrode 524 (e.g., silver diffusion). In some examples, the diffusion barrier layer 282 may comprise a dilectric material such as silicon nitride (SiN), silicon carbide (SiC), or a high-k dielectric material (e.g., having a dielectric constant above 7). In addition to providing a diffusion barrier, the diffusion barrier layer 582 may act as an etch stop during construction of the upper metal layer M.sub.x+1, e.g., during a damascene etch for creating damascene metal elements in upper metal layer M.sub.x+1. The diffusion barrier layer 582 may also provide an effective termination layer for the edge electric field of the OxRRAM cell 502 to improve the breakdown voltage of the OxRRAM cell 502.
[0096] The upper metal layer (M.sub.x+1) formed over the via layer V.sub.x (including interconnect via 514 and MIM OxRRAM structure 526a) includes a top electrode contact 558 in electrical contact with the OxRRAM top electrode 524 and an upper interconnect element 560 in electrical contact with the interconnect via 514. In some embodiments, the top electrode contact 558 and upper interconnect element 560 comprise damascene elements formed by a damascene process, e.g., using copper, tungsten, or aluminum. For example, top electrode contact 558 and upper interconnect element 560 may comprise copper damascene elements formed over a barrier layer 559, e.g., a TaN/Ta bilayer.
[0097] Each of the top electrode contact 558 and upper interconnect element 560 may comprise a wire or other laterally elongated structure (e.g., elongated in the y-axis direction), or a discrete pad (e.g., having a square, circular, or substantially square or circular shape in the x-y plane), or any other suitable shape and structure.
[0098] The example OxRRAM cell 502a may be formed by a process similar to the process for the example CBRAM cell 202 shown in
[0099] As discussed above, in other examples the cup-shaped bottom electrode has a multi-layer construction, e.g., including a cup-shaped bottom electrode outer component formed concurrently with interconnect vias, followed by a cup-shaped bottom electrode inner component formed on the cup-shaped bottom electrode outer component. As noted above, this allows the cup-shaped bottom electrode inner component (which is in contact with the insulation layer of the OxRRAM cell) to be formed from a different material (e.g., platinum) than the interconnect vias (e.g., tungsten).
[0100]
[0101] As with the CBRAM cell 202 and OxRRAM cell 502a discussed above, the OxRRAM cell 502b may be formed between two adjacent metal interconnect layers M.sub.x and an upper layer M.sub.x+1, or between a silicided active region M.sub.0 including silicided structures and a metal-1 interconnect layer M.sub.1.
[0102] First, as shown in
[0103] A photoresist layer 602 may be deposited and patterned to form photoresist openings, and the underlying IMD region 208 is etched through the photoresist openings to form tub opening 529 for the OxRRAM cell formation and via opening 515 in the IMD region 508. Via opening 515 may have a square, circular, or other suitable shape from a top view (x-y plane), with a width (or diameter or critical dimension (CD)) W.sub.via in both the x-direction and y-direction in the range of 0.1-0.35 μm, or for example. In contrast, the tub opening 529 may have a substantially greater width W.sub.tub in each of the x-direction W.sub.tub_x and y-direction W.sub.tub than width W.sub.via of via opening 515. The shape and dimensions of the tub opening 529 may be selected based on various parameters, e.g., for effective manufacturing of the MIM OxRRAM structure 526b and/or for desired performance characteristics of the resulting OxRRAM cell 502b. In one example, the tub opening 529 may have a square or rectangular shape in the x-y plane. In other examples, tub opening 529 may have a circular or oval shape in the x-y plane.
[0104] The details of the tub opening 529, including the shape in the x-y plane, the dimensions (e.g., W.sub.tub_x and/or W.sub.tub_y), and the height-to-width aspect ratio (H.sub.tub/W.sub.tub_x and/or H.sub.tub/W.sub.tub_y) may be the same or similar to the corresponding details of the tub opening 229 discussed above.
[0105] Next, as shown in
[0106] A first conformal metal layer 612 is then deposited over the glue layer 538 and extends down into the tub opening 529 and via opening 515. As shown, the deposited first conformal metal layer 612 (a) fills interconnect via opening 515 to form the interconnect via 514 and (b) covers the interior surfaces of the tub opening 529 to form the cup-shaped bottom electrode outer component 572 defining the interior opening 576 defined by the cup-shaped bottom electrode outer component 572. In one example, the first conformal metal layer 612 comprises tungsten deposited with a thickness in the range of 1000-5000 Å. In other examples, the first conformal metal layer 612 comprises cobalt, aluminum, or other conformal metal. The first conformal metal layer 612 may be deposited by a conformal CVD process or other suitable deposition process. The glue layer 538 may increase or enhance an adhesion of the first conformal metal layer 612 to the interior surfaces of the tub opening 529 to facilitate the formation of the cup-shaped bottom electrode outer component 572.
[0107] After depositing the first conformal metal layer 612, a second conformal metal layer 614 is then deposited over the first conformal metal layer 612 and extends down into the tub opening 529 to form the cup-shaped bottom electrode inner component 574 defining an interior opening 536. As noted above, the second conformal metal layer 614 may comprise a different metal than the first conformal metal layer 612. For example, the second conformal metal layer 614 may comprise platinum deposited by sputtering to a thickness in the range of 1000 Å-3000 Å.
[0108] Next, as shown in
[0109] As discussed above, in some examples an optional insulator cap layer 625 may be formed over the insulator layer 620 and extending down into the tub opening 529 to define an insulator cap 550. In some embodiments, the insulator cap layer 550 may comprise materials such as Al.sub.3O.sub.3, Ta.sub.2O.sub.5, ZrO.sub.2, HfO.sub.2, Ti, or TiN, and may be deposited by CVD, PVD, or ALD methods with a layer thickness in the range of 50-200 Å, for example.
[0110] Next, as shown in
[0111] Next, as shown in
[0112] The cup-shaped bottom electrode components 572 and 574, the cup-shaped insulator 522, the optional insulator cap 550, and the top electrode 524 collectively define the MIM OxRRAIV1 structure 526b. According to the process described above, the MIM OxRRAM structure 526b is thus formed by a damascene process including (a) depositing the first conformal metal layer 612, second conformal metal layer 614, insulator layer 620, optional insulator cap layer 625, and top electrode layer 630 over the IMD region 508 and extending down into the tub opening 529, and (b) a CMP process to remove the portions of the first conformal metal layer 612, second conformal metal layer 614, insulator layer 620, optional insulator cap layer 625, and top electrode layer 630 outside (above) the tub opening 529. The CMP process is suitable for a wide variety of electrode materials, including for example W, WO.sub.3, Al.sub.3O.sub.3, TiW, or Cu, without limitation.
[0113] Forming the MIM OxRRAM structure 526b using such damascene integration process allows the OxRRAM cell 502b to be formed without a metal etch, which may be advantageous as compared with other processes for forming an MIM OxRRAM structure that require one or more metal etch, as explained above with respect to the MIM CBRAM structure 226.
[0114] Next, as shown in
[0115] In addition, in some examples the diffusion barrier layer 582 also acts as an etch stop layer for a damascene trench etch (e.g., Cu trench etch) during formation of overlying metal structures, as discussed below.
[0116] Next, as shown in
[0117] The upper metal layer M.sub.x+1, may be formed similar to the upper metal layer M.sub.x+1 formed over the CBRAM cell 202 as discussed above regarding