Method for preparing noble metal hydrogenation catalyst, noble metal hydrogenation catalyst and use thereof

Abstract

Disclosed are a method for preparing a noble metal hydrogenation catalyst comprising preparing a carrier from a molecular sieve having a 10-member ring structure and/or an amorphous porous material; preparing a noble metal impregnation solution; and preparing noble metal impregnation solutions in a concentration gradient ranging from 0.05 to 5.0 wt % with deionized water, and sequentially impregnating the carrier with the impregnation solutions from low to high concentrations during the carrier impregnation process, or preparing a noble metal impregnation solution at a low concentration ranging from 0.05 to 0.5 wt % and impregnating the carrier by gradually increasing the concentration of the noble metal impregnation solution to 2.0 to 5.0 wt % in the impregnation process, followed by homogenization, drying, and calcination, as well as a noble metal hydrogenation catalyst, use thereof, and a method for preparing lubricant base oil.

Claims

1. A method for preparing a noble metal hydrogenation catalyst, characterized in that said method comprises: step 1: preparing a carrier from a molecular sieve having a 10-member ring structure and an amorphous porous material, wherein the molecular sieve having a 10-member ring structure is selected from one or more of ZSM-5, SAPO-11, EU-1, ITQ-13, ZSM-22, MCM-22, NU-87, and ZSM-23, the mass fraction of the amorphous porous material contained in the carrier is 10 to 90 wt %, and the mass faction of the molecular sieve having a 10-member ring structure contained therein is 5 to 80 wt %; step 2: preparing a noble metal impregnation solution from one or more of compounds of noble metals Pt, Pd, Ru, Rh, Re, and Ir and deionized water or an acid solution, wherein the concentration of the noble metal impregnation solution is in a concentration gradient ranging from 0.05 to 5.0 wt %; and step 3: preparing a hydrogenation catalyst having a noble metal mass fraction of 0.05 to 2.0 wt % by incipient impregnation: sequentially impregnating the carrier with the impregnation solutions from low to high concentrations during the carrier impregnation process, or impregnating the carrier with the noble metal impregnation solution at a low concentration ranging from 0.05 to 0.5 wt % and gradually increasing the concentration of the noble metal impregnation solution to 2.0 to 5.0 wt % in the impregnation process, followed by homogenization for 10 minutes to 3 hours, drying at 90 to 140 C. for 3 to 10 h, and calcination at 450 to 600 C. for 3 to 10 h; characterized in that, in step 3, the step of gradually increasing the concentration of the noble metal impregnation solution is dropping a noble metal impregnation solution having a concentration higher than that of the noble metal impregnation solution at a low concentration into the noble metal impregnation solution at a low concentration at a constant speed during the impregnation process.

2. The method according to claim 1, characterized in that the amorphous porous material is selected from one or more of Al.sub.2O.sub.3, SiO.sub.2, Al.sub.2O.sub.3SiO.sub.2, TiO.sub.2, Al.sub.2O.sub.3TiO.sub.2, ZrO.sub.2, and Al.sub.2O.sub.3ZrO.sub.2.

3. The method according to claim 1, characterized in that the noble metal is selected from one or two of Pt, Pd, Ru, and Re compounds, and the mass fraction of the noble metal contained in the catalyst is 0.1 to 1.0 wt %.

4. The method according to claim 3, characterized in that, in step 3, the mass fraction of the noble metal in the prepared hydrogenation catalyst is 0.2 to 0.6 wt %.

5. The method according to claim 1, characterized in that, in step 3, the concentration of the noble metal component in the prepared catalyst particle increases from the center of the particle to the outer surface thereof, the ratio of the metal content at the circumcenter of the particle to the metal content on the circumcircle surface of the particle is 0.1 to 0.6, and the ratio of the metal content at 0.5 R to the metal content on the outer surface is 0.4 to 0.8, where the circumradius is R with the circumcenter of the cross section of the catalyst particle taken as the starting point.

6. A noble metal hydrogenation catalyst prepared by the method for preparing a noble metal hydrogenation catalyst according to claim 1, characterized in that the concentration of the noble metal component in the noble metal hydrogenation catalyst increases from the center of the particle to the outer surface thereof, the ratio of the metal content at the circumcenter of the particle to the metal content on the circumcircle surface of the particle is 0.1 to 0.6, and the ratio of the metal content at 0.5 R to the metal content on the outer surface is 0.4 to 0.8, where the circumradius is R with the circumcenter of the cross section of the catalyst particle taken as the starting point.

7. The noble metal hydrogenation catalyst according to claim 6, characterized in that the noble metal is selected from one or two of Pt, Pd, Ru, and Re compounds, and the mass fraction of the noble metal contained in the catalyst is 0.05 to 2.0 wt %.

8. The noble metal hydrogenation catalyst according to claim 7, characterized in that the mass fraction of the noble metal contained in the catalyst is 0.1 to 1.0 wt %.

9. The noble metal hydrogenation catalyst according to claim 8, characterized in that the mass fraction of the noble metal contained in the catalyst is 0.2 to 0.6 wt %.

10. A method for preparing lubricant base oil by using the noble metal hydrogenation catalyst prepared by the method according to claim 1 as a catalyst, characterized in that a waxy hydrocarbon raw material is contacted with the noble metal hydrogenation catalyst on a catalyst bed under a hydrogen atmosphere and a product flows outward to obtain a lubricant base oil.

11. The method for preparing lubricant base oil according to claim 10, characterized in that the waxy hydrocarbon raw material is selected from hydrocracked tail oil having a boiling point higher than 350 C., or hydrogenated vacuum gas oil, or slack wax, or ointment.

12. The method for preparing lubricant base oil according to claim 11, characterized in that the waxy hydrocarbon raw material has a sulfur content of no more than 100 g/g and a nitrogen content of no more than 100 g/g.

13. The method for preparing lubricant base oil according to claim 12, characterized in that the waxy hydrocarbon raw material has a sulfur content of no more than 50 g/g and a nitrogen content of no more than 50 g/g.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a plot of noble metal distribution from the center to the surface of the catalyst particle according to the present invention; and

(2) FIG. 2 is a plot of noble metal distribution from the center to the surface of the catalyst particle according to the present invention.

DETAILED DESCRIPTION OF EMBODIMENTS

(3) The present invention provides a method for preparing a noble metal hydrogenation catalyst comprising:

(4) step 1: preparing a carrier from a molecular sieve having a 10-member ring structure and/or an amorphous porous material, wherein the molecular sieve having a 10-member ring structure is selected from one or more of ZSM-5, SAPO-11, EU-1, ITQ-13, ZSM-22, MCM-22, NU-87, and ZSM-23, the mass fraction of the inorganic porous material contained in the carrier is 10 to 90 wt %, and the mass faction of the molecular sieve contained therein is 5 to 80 wt %;

(5) step 2: preparing a noble metal impregnation solution from one or more of compounds of noble metals Pt, Pd, Ru, Rh, Re, and Ir and deionized water or an acid solution, wherein the concentration of the noble metal impregnation solution is 0.1 to 5.0 wt %, and preparing a hydrogenation catalyst having a noble metal mass fraction of 0.05 to 2.0 wt % by incipient impregnation; and

(6) step 3: preparing noble metal impregnation solutions in a concentration gradient ranging from 0.05 to 5.0 wt % with deionized water, and sequentially impregnating the carrier with the impregnation solutions from low to high concentrations during the carrier impregnation process, or preparing a noble metal impregnation solution at a low concentration ranging from 0.05 to 0.5 wt % and impregnating the carrier by gradually increasing the concentration of the noble metal impregnation solution to 2.0 to 5.0 wt % in the impregnation process, followed by homogenization for 10 minutes to 3 hours, drying at 90 to 140 C. for 3 to 10 h, and calcination at 450 to 600 C. for 3 to 10 h.

(7) Herein, the inorganic porous material is selected from one or more of Al.sub.2O.sub.3, SiO.sub.2, Al.sub.2O.sub.3SiO.sub.2, TiO.sub.2, Al.sub.2O.sub.3TiO.sub.2, ZrO.sub.2, or Al.sub.2O.sub.3ZrO.sub.2.

(8) Herein, the noble metal is selected from one or two of Pt, Pd, Ru, and Re compounds, and the mass fraction of the noble metal contained in the catalyst is preferably 0.1 to 1.0 wt %.

(9) Herein, in step 2, the mass fraction of the noble metal in the prepared hydrogenation catalyst is preferably 0.2 to 0.6 wt %.

(10) Herein, in step 3, the concentration of the noble metal component in the prepared catalyst particle increases gradually from the center of the particle to the outer surface thereof, the ratio of the metal content at the circumcenter of the particle to the metal content on the circumcircle surface of the particle is 0.1 to 0.6, and the ratio of the metal content at 0.5 R to the metal content on the outer surface is 0.4 to 0.8, where the circumradius is R with the circumcenter of the cross section of the catalyst particle taken as the starting point.

(11) Herein, in step 3, the step of gradually increasing the concentration of the noble metal impregnation solution is dropping a noble metal impregnation solution having a concentration higher than that of the noble metal impregnation solution at a low concentration into the noble metal impregnation solution at a low concentration at a constant speed during the impregnation process.

(12) Herein, the concentration of the noble metal component in the noble metal hydrogenation catalyst increases gradually from the center of the particle to the outer surface thereof, the ratio of the metal content at the circumcenter of the particle to the metal content on the circumcircle surface of the particle is 0.1 to 0.6, and the ratio of the metal content at 0.5 R to the metal content on the outer surface is 0.4 to 0.8, where the circumradius is R with the circumcenter of the cross section of the catalyst particle taken as the starting point.

(13) Herein, the noble metal is selected from one or two of Pt, Pd, Ru, and Re compounds, and the mass fraction of the noble metal contained in the catalyst is preferably 0.05 to 2.0 wt %.

(14) Herein, the mass fraction of the noble metal contained in the catalyst is 0.1 to 1.0 wt %, preferably 0.2 to 0.6wt %.

(15) Further, the present invention provides a method for preparing lubricant base oil by using the noble metal hydrogenation catalyst prepared by the method described above as a catalyst.

(16) In the method for preparing lubricant base oil, a waxy hydrocarbon raw material is contacted with the noble metal hydrogenation catalyst on a catalyst bed under a hydrogen atmosphere and the product flows outward to obtain a lubricant base oil having a low pour point, high viscosity index and high yield.

(17) In the method for preparing lubricant base oil, the waxy hydrocarbon raw material is selected from hydrocracked tail oil having a boiling point higher than 350 C., or hydrogenated vacuum gas oil, or slack wax, or an ointment.

(18) In the method for preparing lubricant base oil, the waxy hydrocarbon raw material has a sulfur content of no more than 100 g/g and a nitrogen content of no more than 100 g/g.

(19) In the method for preparing lubricant base oil, the waxy hydrocarbon raw material has a sulfur content of no more than 50 g/g and a nitrogen content of no more than 50 g/g.

(20) Further, the present invention provides use of the noble metal hydrogenation catalyst prepared by the above method for preparing a noble metal hydrogenation catalyst in preparation of lubricant base oil.

(21) Specifically, the process of preparation of the noble metal hydrogenation catalyst according to the present invention includes:

(22) step 1: preparing a carrier from a molecular sieve having a 10-member ring structure and/or an amorphous porous material, wherein the molecular sieve having a 10-member ring structure is selected from one or more of ZSM-5, SAPO-11, EU-1, ITQ-13, ZSM-22, MCM-22, NU-87, and ZSM-23, the mass fraction of the inorganic porous material contained in the carrier is 10 to 90 wt %, and the mass faction of the molecular sieve contained therein is 5 to 80 wt %;

(23) step 2: preparing a noble metal impregnation solution from one or more of compounds of noble metals Pt, Pd, Ru, Rh, Re, and Ir and deionized water or an acid solution, wherein the concentration of the noble metal impregnation solution is 0.1 to 5.0 wt %, and preparing a hydrogenation catalyst having a noble metal mass fraction of 0.05 to 2.0 wt % by incipient impregnation; and

(24) step 3: preparing noble metal impregnation solutions in a concentration gradient ranging from 0.05 to 5.0 wt % with deionized water, and sequentially impregnating the carrier with the impregnation solutions from low to high concentrations during the carrier impregnation process, or preparing a noble metal impregnation solution at a low concentration ranging from 0.05 to 0.5 wt % and impregnating the carrier by gradually increasing the concentration of the noble metal impregnation solution to 2.0 to 5.0 wt % in the impregnation process, followed by homogenization for 10 minutes to 3 hours, drying at 90 to 140 C. for 3 to 10 h, and calcination at 450 to 600 C. for 3 to 10 h; wherein the step of gradually increasing the concentration of the noble metal impregnation solution is dropping a noble metal impregnation solution having a concentration higher than that of the noble metal impregnation solution at a low concentration into the noble metal impregnation solution at a low concentration at a constant speed during the impregnation process.

(25) During the preparation of the catalyst, the amorphous porous material is selected from one or more of Al.sub.2O.sub.3, SiO.sub.2, Al.sub.2O.sub.3SiO.sub.2, TiO.sub.2, Al.sub.2O.sub.3TiO.sub.2, ZrO.sub.2, or Al.sub.2O.sub.3ZrO.sub.2.

(26) The concentration of the noble metal component in the prepared noble metal hydrogenation catalyst increases gradually from the center of the particle to the outer surface thereof, the ratio of the metal content at the circumcenter of the particle to the metal content on the circumcircle surface of the particle is 0.1 to 0.6, and the ratio of the metal content at 0.5 R to the metal content on the outer surface is 0.4 to 0.8, where the circumradius is R with the circumcenter of the cross section of the catalyst particle taken as the starting point.

(27) During the preparation of the noble metal hydrogenation catalyst, the noble metal selected in the present invention is one or more noble metal compounds of Pt, Pd, Ru, Rh, Re, and Ir, preferably one or two of Pt, Pd, Ru, and Re compounds, and the mass fraction of the noble metal contained in the catalyst is preferably 0.1 to 1.0 wt %, more preferably 0.2 to 0.6wt %.

(28) For the noble metal hydrogenation catalyst prepared according to the present invention, the forming method may be extruding, tableting, or dripping, preferably extruding. The appearance of the catalyst may be a spherical shape, a bar shape (cylindrical, three-leaf clover, or four-leaf clover), a Rasching ring, and preferably a bar shape.

(29) The noble metal hydrogenation catalyst prepared according to the present invention is primarily used in the manufacture of high quality lubricant base oil. The method for preparing lubricant base oil is to contact a waxy hydrocarbon raw material contact with the noble metal hydrogenation catalyst on a catalyst bed under a hydrogen atmosphere, and allow the product to flow outward to give a lubricant base oil having a low pour point, high viscosity index and high yield. Herein, the waxy hydrocarbon raw material is selected from hydrocracked tail oil having a boiling point higher than 350 C., or hydrogenated vacuum gas oil, or slack wax, or an ointment. Moreover, the waxy hydrocarbon raw material has a sulfur content of no more than 100 g/g, preferably no more than 50 g/g, and a nitrogen content of no more than 100 g/g, preferably no more than 50 g/g.

EXAMPLE 1

(30) A catalyst was prepared by incipient impregnation. Inorganic porous materials comprising 45 wt % of Al.sub.2O.sub.3, 20 wt % of Al.sub.2O.sub.3SiO.sub.2, 10 wt % of SiO.sub.2, and 20 wt % TiO.sub.2 in a carrier were mechanically kneaded with 5 wt % of EU-1 molecular sieve into a carrier with a water absorption of 0.60 ml/g.

(31) 200 g of the carrier was weighed and sprayed and impregnated with 50 ml of an impregnation solution containing PtCl.sub.2 at a concentration of 0.05 wt %. During the spray impregnation, 70 ml of an impregnation solution containing 0.16 wt % PtCl.sub.2in diluted hydrochloric acid was dropped into the previous impregnation solution at a constant speed over 30 minutes. The catalyst was homogenized in the spray impregnation apparatus for 10 minutes, dried at 90 C. for 10 hours, and then calcinated at 600 C. for 3 hours to afford catalyst A-1 , wherein the mass fraction of Pt contained in the prepared catalyst A-1 was 0.05% (on catalyst mass basis).

EXAMPLE 2

(32) A catalyst was prepared by incipient impregnation. Inorganic porous materials comprising 20 wt % of Al.sub.2O.sub.3, 20 wt % of Al.sub.2O.sub.3ZrO.sub.2, 10 wt % of TiO.sub.2, and 10 wt % Al.sub.2O.sub.3TiO.sub.2 in a carrier were mechanically kneaded with 40 wt % of ITQ-13 and ZSM-23 molecular sieves into a carrier with a water absorption of 0.7 ml/g.

(33) 200 g of the carrier was weighed and sprayed and impregnated with 50 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 0.2 wt %. During the spray impregnation, 90 ml of an impregnation solution containing 0.7 wt % PtCl.sub.2 and PdCl.sub.2 in diluted hydrochloric acid was dropped into the previous impregnation solution at a constant speed over 30 minutes. The catalyst was homogenized in the spray impregnation apparatus for 3 hours, dried at 140 C. for 3 hours, and then calcinated at 450 C. for 10 hours to afford catalyst A-2, wherein the mass fraction of Pt and Pd contained in the prepared catalyst A-2 was 0.2% (on catalyst mass basis).

EXAMPLE 3

(34) A catalyst was prepared by incipient impregnation. Inorganic porous materials comprising 10 wt % of Al.sub.2O.sub.3SiO.sub.2 and 10 wt % ZrO.sub.2 in a carrier were mechanically kneaded with 40 wt % of MCM-22 and 40 wt % of ZSM-23 molecular sieves into a carrier with a water absorption of 0.75 ml/g.

(35) 200 g of the carrier was weighed and sprayed and impregnated with 50 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 0.4 wt %. During the spray impregnation, 100 ml of an impregnation solution containing 1.6 wt % PtCl.sub.2 and PdCl.sub.2 in diluted hydrochloric acid was dropped into the previous impregnation solution at a constant speed over 30 minutes. The catalyst was homogenized in the spray impregnation apparatus for 2 hours, dried at 100 C. for 6 hours, and then calcinated at 550 C. for 6 hours to afford catalyst A-3, wherein the mass fraction of Pt and Pd contained in the prepared catalyst A-3 was 0.6% (on catalyst mass basis).

EXAMPLE 4

(36) A catalyst was prepared by incipient impregnation. Inorganic porous materials comprising 10 wt % of Al.sub.2O.sub.3, 10 wt % of Al.sub.2O.sub.3SiO.sub.2, and 10 wt % Al.sub.2O.sub.3ZrO.sub.2 in a carrier were mechanically kneaded with 30 wt % of ZSM-22 and 40 wt% of NU-87 molecular sieves into a carrier with a water absorption of 0.65 ml/g.

(37) 200 g of the carrier was weighed and sprayed and impregnated with 30 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 0.3 wt %. During the spray impregnation, 100 ml of an impregnation solution containing 1.7 wt % PtCl.sub.2 and PdCl.sub.2 in diluted hydrochloric acid was dropped into the previous impregnation solution at a constant speed over 30 minutes. The catalyst was homogenized in the spray impregnation apparatus for 1 hour, dried at 100 C. for 6 hours, and then calcinated at 550 C. for 6 hours to afford catalyst A-4, wherein the mass fraction of Pt and Pd contained in the prepared catalyst A-4 was 0.6% (on catalyst mass basis).

EXAMPLE 5

(38) Catalyst A-5 was prepared with the same steps as in Example 4 except that impregnation solutions at different concentrations were used during the spray impregnation where 40 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 1.0 wt % was firstly sprayed and impregnated, and 90 ml of an impregnation solution containing 3.0 wt % PtCl.sub.2 and PdC1.sub.2 in diluted hydrochloric acid was dropped into the previous impregnation solution at a constant speed. In the prepared catalyst A-5, the mass fraction of Pt and Pd was 1.0% (on catalyst mass basis).

EXAMPLE 6

(39) Catalyst A-6 was prepared with the same steps as in Example 5 except that impregnation solutions at different concentrations were used during the spray impregnation where 20 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 1.5 wt % was firstly sprayed and impregnated, and 110 ml of an impregnation solution containing 5.0 wt % PtCl.sub.2 and PdCl.sub.2 in diluted hydrochloric acid was dropped into the previous impregnation solution at a constant speed. In the prepared catalyst A-6, the mass fraction of Pt and Pd was 2.0% (on catalyst mass basis).

COMPARATIVE EXAMPLE 1

(40) Catalyst B-1 was prepared with the same steps as in Example 2 except that 200 g Al.sub.2O.sub.3 inorganic material was kneaded into a carrier having a water absorption of 0.80 ml/g, and the carrier was sprayed and impregnated with 160 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 1.1 wt %. In the prepared catalyst B-1, the mass fraction of Pt and Pd was 0.6% (on catalyst mass basis).

COMPARATIVE EXAMPLE 2

(41) Catalyst B-2 was prepared with the same steps as in Example 2 except that 200 g of the carrier was weighed and sprayed and impregnated once with 140 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 0.4 wt %. In the prepared catalyst B-2, the mass fraction of Pt and Pd was 0.2% (on catalyst mass basis).

COMPARATIVE EXAMPLE 3

(42) Catalyst B-3 was prepared with the same steps as in Example 4 except that 200 g of the carrier was sprayed and impregnated once with 130 ml of an impregnation solution containing PtCl.sub.2 and PdCl.sub.2 at a concentration of 1.4 wt %. In the prepared catalyst B-3, the mass fraction of Pt and Pd was 0.6% (on catalyst mass basis).

EXAMPLE 7

(43) Nobel metal contents and noble metal relative distribution in catalysts A-1, A-2, A-3, A-4, A-5, A-6, B-1, B-2, and B-3 were characterized by ICP and EDS characterization means.

(44) TABLE-US-00001 TABLE 1 Results of physical properties of the catalysts Noble metal relative distribution (molar ratio) Catalyst Total content of m(center*)/m(outer m(0.5 R*)/m(outer No. Pt and Pd, g/g surface*) surface*) A-1 485 0.11 0.48 A-2 2009 0.31 0.54 A-3 5991 0.17 0.42 A-4 6011 0.38 0.67 A-5 10032 0.41 0.74 A-6 19988 0.59 0.80 B-1 6017 0.94 0.97 B-2 2003 0.92 0.98 B-3 6007 0.93 0.97 Note: center* is the circumcenter of the cross section of a catalyst particle; R is the cicumradius of the cross section of a catalyst particle, with the circumcenter of the cross section of the catalyst particle as the starting point; outer surface* is the circumcircle surface of the cross section of a catalyst particle.

(45) As seen in Table 1, although catalysts A-1, A-2, A-3, A-4, A-5, and A-6 comprised a low content of noble metal active components, the noble metals showed a trend of their relative distribution in the catalyst increasing in a gradient from inside of the catalyst particle to the outer surface thereof, that is, the ratio of the metal relative content at the circumcenter of the particle to the metal relative content on the circumcircle surface of the particle is 0.1 to 0.6, and the ratio of the metal content at 0.5 R to the metal content on the outer surface is 0.4 to 0.8; whereas, for catalysts B-1, B-2 and B-3 in the Comparative Examples, the noble metals showed a uniform distribution from inside to outside of the catalyst particle.

EXAMPLE 8

(46) Actual assessment of raw material hydrogenation was conducted using A-2, A-4, B-2, and B-3 as exemplary catalysts.

(47) Hydrogenation assessment reaction was carried out on a 100 ml hydrogenation stationary bed, and the raw material oil for assessment was hydrogenated vacuum gas oil. The properties of raw material were shown in Table 2.

(48) TABLE-US-00002 TABLE 2 Properties of raw material oil Density (20 C.), g/ml 0.8669 Distillation range HK, C. 404 50%, C. 513 KK, C. 557 Sulfur, g/g 37 Nitrogen, g/g 29 Viscosity (100 C.), mm.sup.2/s 11.6 Viscosity index 52 Aromatics content, wt % 30.8 Condensation point, C. 51 Pour point, C. 27

(49) Operating conditions for the assessment were shown in Table 3.

(50) TABLE-US-00003 TABLE 3 Operating conditions for the assessment Temperature, C. 375 Pressure, MPa 12 Liquid hourly mass space velocity, h.sup.1 0.85 Hydrogen/oil volume ratio 600

(51) Assessment results after the catalysts had operated for 200 hours were shown in Table 4.

(52) TABLE-US-00004 TABLE 4 Assessment results Analysis results Analyzed items A-2 A-4 B-2 B-3 Sulfur, g/g 0.7 <0.1 4.9 1.4 Nitrogen, g/g 0.3 <0.1 2.4 0.7 Viscosity, mm.sup.2/s 10.4 10.2 9.6 9.3 Viscosity index 121 132 104 115 Condensation point, C. 18 24 12 15 Pour point, C. 15 21 9 12 Aromatics content, wt % 1.2 <1 4.5 3.1 Total yield of base oil, 90.6 89.1 87.3 86.2 wt %

(53) As seen from the assessment results in Table 4, the hydrogenation catalyst having noble metal components distributed in an increasing gradient prepared according to the method of the present invention exhibited superior refining performance, aromatics saturation performance, hydroisomerization performance, performance in decreasing pour point of base oil, as well as total yield of base oil over the hydrogenation catalyst having a uniform distribution of active components prepared by a conventional method, and showed great promise in application in the production of high quality lubricant base oil.

(54) The noble metal catalyst prepared in the present invention is primarily used in the production of high quality lubricant base oil. The method according to the present invention is advantageous in that a distribution of noble metals in an increasing gradient in the catalyst (i.e., metal content increasing in a gradient from the inside to the outside of the catalyst particle) is achieved by impregnating the catalyst with noble metal compounds in a low concentration content, and thus an ideal distribution of noble metal compounds in a low content in the catalyst is realized and active centers in the noble metals are efficiently utilized. The catalyst prepared according to the present invention has high activity and good stability, and particularly, the catalyst prepared in the present invention shows a significant effect in the field of heavy oil processing and premium lubricant base oil production, having advantages of superior hydroisomerization performance, excellent aromatics saturation performance, as well as producing lubricant base oil with high viscosity index, low pour point and high yield of base oil. The utilization of noble metals in the noble metal hydrogenation catalyst prepared according to the present invention is improved, and thereby the loading of noble metals in the catalyst may be effectively decreased, and the manufacturing cost is greatly lowered. The catalyst is remarkably effective in heavy oil processing and production of premium lubricant base oil and thus promising in application.

(55) The noble metal hydrogenation catalyst of the present invention and the preparation method thereof are applicable in the manufacture of aromatics saturation catalysts, reforming hydrogenation catalysts, PAO hydrogenation catalysts, diesel hydrogenation catalysts, and hydroisomerization catalysts, and are particularly applicable in the manufacture of noble metal hydrogenation catalysts for heavy oil processing and production of premium lubricant base oil. The present invention achieves prominent effects in practice and shows great promise in application.

(56) It is obvious that there are numerous other embodiments for the present invention, and various alteration and modification can be made by persons skilled in the art according to the present invention without departing from the spirit and scope of the present invention, but the alteration and modification should fall within the scope of the present invention defined in the claims.