Semiconductor device and method for driving semiconductor device
10249347 ยท 2019-04-02
Assignee
Inventors
Cpc classification
G11C5/147
PHYSICS
G11C11/404
PHYSICS
International classification
G11C14/00
PHYSICS
G11C11/404
PHYSICS
G11C11/4074
PHYSICS
Abstract
A normally-off state of an OS transistor is maintained or an on-state current thereof is increased without additionally generating a positive potential or a negative potential. When data is written to a node connecting an OS transistor and a capacitor, a potential supplied to the other side of the capacitor is set to an L level, and when the data is retained, the potential is switched from the L level to an H level. In addition, a power switch for a volatile memory circuit is provided on a low power supply potential side so that the supply of a power supply voltage can be stopped. Accordingly, at the time of data retention, a source and a drain of the OS transistor can be set at a high potential, whereby the normally-off state can be maintained and the on-state current can be increased.
Claims
1. A semiconductor device comprising: a first memory cell; and a second memory cell, wherein each of the first memory cell and the second memory cell comprises: a transistor comprising a gate, a first terminal, and a second terminal; a volatile memory circuit electrically connected to the first terminal and a bit line; and a capacitor comprising a first electrode electrically connected to the second terminal and a second electrode electrically connected to a potential control line, wherein the volatile memory circuits of the first and second memory cells are directly connected to a same word line, wherein the volatile memory circuit of the first memory cell is configured to store a datum in a first period, wherein a node between the transistor and the capacitor of the first memory cell is configured to store the datum in a second period, wherein the potential control line is set at a low power supply potential when the transistor of the first memory cell is in an on state in the first period, and wherein the potential control line is set at a high power supply potential when the transistor of the first memory cell is in an off state in the second period.
2. The semiconductor device according to claim 1, wherein the high power supply potential and the low power supply potential are supplied to the volatile memory circuit of the first memory cell in the first period, and wherein the high power supply potential is supplied to the volatile memory circuit of the first memory cell and a supply of the low power supply potential to the first memory cell is stopped in the second period.
3. The semiconductor device according to claim 1, wherein the transistor comprises a semiconductor layer containing an oxide semiconductor.
4. The semiconductor device according to claim 1, wherein the transistor is a first transistor, and wherein each of the volatile memory circuits of the first and second memory cells comprises a second transistor including a semiconductor layer containing silicon.
5. The semiconductor device according to claim 4, wherein the first transistor is stacked over the second transistor.
6. The semiconductor device according to claim 1, wherein each of the volatile memory circuits of the first and second memory cells is a static random access memory.
7. The semiconductor device according to claim 1, wherein each of the volatile memory circuits of the first and second memory cells is a flip-flop.
8. A semiconductor device comprising: a first memory cell; and a second memory cell, wherein each of the first memory cell and the second memory cell comprises: a first transistor comprising a gate, a first terminal, and a second terminal; a second transistor comprising a gate, a first terminal, and a second terminal; a volatile memory circuit electrically connected to the first terminal of the first transistor and a bit line; and a capacitor comprising a first electrode electrically connected to the second terminal of the first transistor and a second electrode electrically connected to a potential control line, a high power supply line electrically connected to the volatile memory circuit of the first memory cell; and a low power supply line electrically connected to the volatile memory circuit of the first memory cell through the second transistor of the first memory cell, wherein the volatile memory circuits of the first and second memory cells are directly connected to a same word line, wherein the volatile memory circuit of the first memory cell is configured to store a datum in a first period, wherein a node between the first transistor and the capacitor of the first memory cell is configured to store the datum in a second period, wherein the potential control line is set at a low power supply potential when the first and second transistors of the first memory cell are in an on state in the first period, and wherein the potential control line is set at a high power supply potential when the first and second transistors of the first memory cell are in an off state in the second period.
9. The semiconductor device according to claim 8, wherein the first transistor comprises a semiconductor layer containing an oxide semiconductor.
10. The semiconductor device according to claim 8, wherein each of the volatile memory circuits of the first and second memory cells comprises a third transistor including a semiconductor layer containing silicon.
11. The semiconductor device according to claim 10, wherein the first transistor is stacked over the third transistor.
12. The semiconductor device according to claim 8, wherein each of the volatile memory circuits of the first and second memory cells is a static random access memory.
13. The semiconductor device according to claim 8, wherein each of the volatile memory circuits of the first and second memory cells is a flip-flop.
14. A method for driving a semiconductor device comprising a first memory cell and a second memory cell, each of the first memory cell and the second memory cell comprising: a transistor comprising a gate, a first terminal, and a second terminal; a volatile memory circuit electrically connected to the first terminal and a bit line; and a capacitor comprising a first electrode electrically connected to the second terminal and a second electrode electrically connected to a potential control line, wherein the volatile memory circuits of the first and second memory cells are directly connected to a same word line, the method comprising the steps of: setting the potential control line at a low power supply potential and supplying a potential of the first terminal to the second terminal through the transistor of the first memory cell in an on state; retaining the potential of the first terminal at the second terminal of the first memory cell by turning off the transistor; raising a potential of the second terminal of the first memory cell by switching the potential control line from the low power supply potential to a high power supply potential when the transistor of the first memory cell is in an off state; and stopping a supply of the low power supply potential to the volatile memory circuit of the first memory cell.
15. The method for driving a semiconductor device according to claim 14, wherein the supply of the low power supply potential is stopped by bringing a wiring to which the low power supply potential is supplied into an electrically floating state.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(20) Embodiments will be hereinafter described with reference to drawings. However, the embodiments can be implemented with various modes. It will be readily appreciated by those skilled in the art that modes and details can be changed in various ways without departing from the spirit and scope of the present invention. Therefore, the present invention should not be construed as being limited to the description in the following embodiments. In the modes of the present invention described below, the same components in different diagrams are commonly denoted by the same reference numerals.
(21) In drawings, the size, the layer thickness, or the region is exaggerated for clarity in some cases. Therefore, embodiments of the present invention are not limited to such a scale. Note that drawings are schematic views showing ideal examples, and embodiments of the present invention are not limited to shapes or values shown in the drawings. For example, the following can be included: variation in signal, voltage, or current due to noise or difference in timing.
(22) In this specification and the like, a transistor is an element having at least three terminals of a gate, a drain, and a source. In addition, the transistor has a channel region between a drain (a drain terminal, a drain region, or a drain electrode) and a source (a source terminal, a source region, or a source electrode), and current can flow through the drain, the channel region, and the source.
(23) Here, since the source and the drain of the transistor change depending on the structure, the operating condition, and the like of the transistor, it is difficult to define which is a source or a drain. Thus, in some cases, a portion which functions as the source and a portion which functions as the drain are not called a source and a drain, and one of the source and the drain is referred to as a first terminal and the other thereof is referred to as a second terminal.
(24) Note that ordinal numbers such as first, second, and third in this specification are used in order to avoid confusion among components, and the terms do not limit the components numerically.
(25) Note that in this specification, the phrase A and B are connected or A is connected to B means the case where A and B are electrically connected to each other as well as the case where A and B are directly connected to each other. Here, the phrase A and B are electrically connected or A is electrically connected to B means the following case: when an object having any electrical function exists between A and B, an electric signal can be transmitted and received between A and B.
(26) Note that in this specification, terms for describing arrangement, such as over and under, are used for convenience for describing the positional relationship between components with reference to drawings. Further, the positional relationship between components is changed as appropriate in accordance with a direction in which each component is described. Thus, the positional relationship is not limited to that described with a term used in this specification and can be explained with another term as appropriate depending on the situation.
(27) Note that the positional relationships of circuit blocks in diagrams are specified for description, and even in the case where different circuit blocks have different functions in the diagrams, the different circuit blocks might be provided in an actual circuit or region so that different functions are achieved in the same circuit block. The functions of circuit blocks in diagrams are specified for description, and even in the case where one circuit block is illustrated, blocks might be provided in an actual circuit or region so that processing performed by one circuit block is performed by a plurality of circuit blocks.
(28) Note that a voltage refers to a potential difference between a given potential and a reference potential (e.g., a ground potential) in many cases. Therefore, a voltage, a potential, and a potential difference can also be referred to as a potential, a voltage, and a voltage difference, respectively. Note that a voltage refers to the difference between potentials of two points, and a potential refers to electrostatic energy (electric potential energy) of a unit charge at a given point in an electrostatic field.
(29) Note that in general, potential and voltage are relative values. Therefore, ground potential is not always 0 V.
(30) In this specification and the like, the term parallel indicates that the angle formed between two straight lines is greater than or equal to 10 and less than or equal to 10, and accordingly also includes the case where the angle is greater than or equal to 5 and less than or equal to 5. In addition, the term perpendicular indicates that the angle formed between two straight lines is greater than or equal to 80 and less than or equal to 100, and accordingly also includes the case where the angle is greater than or equal to 85 and less than or equal to 95.
(31) In this specification and the like, trigonal and rhombohedral crystal systems are included in a hexagonal crystal system.
Embodiment 1
(32) In this embodiment, a circuit configuration and operation of a semiconductor device according to one embodiment of the disclosed invention will be described with reference to
(33) Note that a semiconductor device is a device including a semiconductor element. The semiconductor device includes a driver circuit or the like for driving a circuit including a semiconductor element. Note that a semiconductor device may include a driver circuit, a power supply circuit, or the like as well as a circuit having a configuration described as one embodiment of the present invention.
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(35) The circuit diagram in
(36) The first terminal Tr_D supplies an H level potential (hereinafter referred to as H or H level) corresponding to data 1 or an L level potential (hereinafter referred to as L or L level) corresponding to data 0 to be retained in a volatile memory circuit. For example, the first terminal Tr_D is electrically connected to a node in a static random access memory (SRAM) or a flip-flop.
(37) In a period during which the data 1 or 0 is stored in the volatile memory circuit, a power supply voltage is supplied to the volatile memory circuit through a power supply line including a wiring that supplies a high power supply potential and a wiring that supplies a low power supply potential.
(38) In the semiconductor device described in this embodiment, a transistor having a small off-state current is used as the transistor Tr.
(39) Unless otherwise specified, the off-state current in this specification refers to a drain current of a transistor in the off state (also referred to as non-conduction state and cutoff state). Unless otherwise specified, the off state of an n-channel transistor means that the voltage between its gate and source (Vgs: gate-source voltage) is lower than the threshold voltage Vth, and the off state of a p-channel transistor means that the gate-source voltage Vgs is higher than the threshold voltage Vth. For example, the off-state current of an n-channel transistor sometimes refers to a drain current that flows when the gate-source voltage Vgs is lower than the threshold voltage Vth.
(40) The off-state current of a transistor depends on Vgs in some cases. For this reason, when there is Vgs at which the off-state current of a transistor is lower than or equal to I, it may be said that the off-state current of the transistor is lower than or equal to I. The off-state current of a transistor may refer to off-state current at given Vgs, off-state current at Vgs in a given range, or off-state current at Vgs at which sufficiently low off-state current is obtained.
(41) As an example, the assumption is made of an n-channel transistor where the threshold voltage Vth is 0.5 V and the drain current is 110.sup.9 A at Vgs of 0.5 V, 110.sup.13 A at Vgs of 0.1 V, 110.sup.19 A at Vgs of 0.5 V, and 110.sup.22 A at Vgs of 0.8 V. The drain current of the transistor is 110.sup.19 A or lower at Vgs of 0.5 V or at Vgs in the range of 0.8 V to 0.5 V; therefore, it can be said that the off-state current of the transistor is 110.sup.19 A or lower. Since there is Vgs at which the drain current of the transistor is 110.sup.22 A or lower, it may be said that the off-state current of the transistor is 110.sup.22 A or lower.
(42) In this specification, the off-state current of a transistor with a channel width W is sometimes represented by a current value in relation to the channel width W or by a current value per given channel width (e.g., 1 m). In the latter case, the unit of off-state current may be represented by current per length (e.g., A/m).
(43) The off-state current of a transistor depends on temperature in some cases. Unless otherwise specified, the off-state current in this specification may be an off-state current at room temperature, 60 C., 85 C., 95 C., or 125 C. Alternatively, the off-state current may be an off-state current at a temperature at which the reliability of a semiconductor device or the like including the transistor is ensured or a temperature at which the semiconductor device or the like is used (e.g., temperature in the range of 5 C. to 35 C.). When there is Vgs at which the off-state current of a transistor at room temperature, 60 C., 85 C., 95 C., 125 C., a temperature at which the reliability of a semiconductor device or the like including the transistor is ensured, or a temperature at which the semiconductor device or the like is used (e.g., temperature in the range of 5 C. to 35 C.) is lower than or equal to I, it may be said that the off-state current of the transistor is lower than or equal to I.
(44) The off-state current of a transistor depends on voltage Vds between its drain and source in some cases. Unless otherwise specified, the off-state current in this specification may be an off-state current at Vds with an absolute value of 0.1 V, 0.8 V, 1 V, 1.2 V, 1.8 V, 2.5 V, 3 V, 3.3 V, 10 V, 12 V, 16 V, or 20 V. Alternatively, the off-state current may be an off-state current at Vds at which the reliability of a semiconductor device or the like including the transistor is ensured or Vds used in the semiconductor device or the like. When there is Vgs at which the off-state current of a transistor is lower than or equal to I at given Vds, it may be said that the off-state current of the transistor is lower than or equal to I. Here, given Vds is, for example, 0.1 V, 0.8 V, 1 V, 1.2 V, 1.8 V, 2.5 V, 3 V, 3.3 V, 10 V, 12 V, 16 V, 20 V, Vds at which the reliability of a semiconductor device or the like including the transistor is ensured, or Vds used in the semiconductor device or the like.
(45) In the above description of off-state current, a drain may be replaced with a source. That is, the off-state current sometimes refers to a current that flows through a source of a transistor in the off state.
(46) In this specification, the term leakage current sometimes expresses the same meaning as off-state current.
(47) In this specification, the off-state current sometimes refers to a current that flows between a source and a drain when a transistor is off, for example.
(48) In this embodiment, the high power supply potential is VDD as an example, and the low power supply potential is 0 V (e.g., GND).
(49) In this embodiment, as an example of the transistor Tr having a small off-state current, an OS transistor, which is an n-channel transistor, is used. The n-channel transistor Tr is turned on when the potential supplied to the gate terminal Tr_G is the H level and turned off when the potential is the L level.
(50) When the transistor Tr is turned on, a potential which corresponds to data 1 or 0 and is supplied to the first terminal Tr_D is supplied to the second terminal Tr_S through the transistor Tr. Note that the period during which data at the first terminal Tr_D is supplied to the second terminal Tr_S is referred to as a backup period or a write period.
(51) When the transistor Tr is kept off, the H level or L level potential supplied to the second terminal Tr_S during the backup period can be retained, so that charge accumulated in the capacitor Cp can be retained for a long time. In the period during which the H level or L level potential at the second terminal Tr_S is retained, the supply of the power supply voltage is stopped; thus, the period is referred to as a power-off period or a retention period.
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(53) In the backup period shown in
(54) In the power-off period shown in
(55) The stop of the supply of the power supply voltage means the stop of the supply of at least one of the high power supply potential and the low power supply potential to the volatile memory circuit. For example, in the case where only the high power supply potential is supplied and the supply of the low power supply potential is stopped, the supply of the power supply voltage is stopped.
(56) The supply of the power supply potential can be stopped by turning off a switch provided between a wiring that supplies the power supply potential and a node to which the power supply potential is to be supplied in the volatile memory circuit. Alternatively, the supply may be stopped by making the output of a power supply circuit high impedance.
(57) To stop the supply of the power supply voltage in the power-off period in
(58) In the power-off period, the potentials of both the wirings that supply the power supply potentials are set to the high power supply potential, whereby each node of the volatile memory circuit is set at the H level potential; consequently, the first terminal Tr_D can be fixed at the H level.
(59) The H level potential and the L level potential of the gate terminal Tr_G in
(60) Note that the H level potential and the L level potential of each of the first terminal Tr_D, the second terminal Tr_S, and the potential control line PL in
(61) According to
(62) In that case, in the power-off period, Vgs can be a negative voltage even when the L level potential of the gate terminal Tr_G is GND. Thus, even when the transistor Tr is not a normally-off transistor, its off-state current can be kept small for a long time, whereby data can be retained at the second terminal Tr_S for a long time.
(63) Furthermore, according to
(64) According to
(65) According to
(66) According to
(67) In the power-off period, when the potential of the potential control line PL is switched from the L level to the H level, the H level potential and the L level potential of the second terminal Tr_S are increased to the potential H+V and the potential L+V, respectively. In order to increase V, for example, it is preferable to increase the capacitance of the capacitor Cp, to reduce parasitic capacitance of the transistor Tr (parasitic capacitance between the gate and the source), and to reduce the channel length L, the channel width W, or the like of the transistor Tr. Thus, as an example, the capacitance of the capacitor Cp is preferably larger than that of a gate capacitance in the channel region of the transistor Tr (capacitance formed by a gate electrode, a gate insulating film, and a semiconductor layer (a channel region)). As a more preferable example, the capacitance of the capacitor Cp is larger than or equal to twice the gate capacitance in the channel region of the transistor Tr. As another example, the area of the electrodes included in the capacitor Cp is preferably larger than the area of the channel region of the transistor Tr. As a more preferable example, the area of the electrodes included in the capacitor Cp is preferably larger than or equal to twice the area of the channel region of the transistor Tr.
(68) Next, specific examples of the circuit configuration of the semiconductor device are described with reference to
(69)
(70) A semiconductor device 100a in
(71) The semiconductor device 100a in
(72) The volatile memory circuit 101a is a circuit that can input, output, and retain data in a period during which the power supply voltage is supplied; for example, an SRAM can be used.
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(74) In the case where data at two nodes, a node VN1 and a node VN2, included in the volatile memory circuit 101 are retained in
(75) In the semiconductor device 100a, the H level or L level potential corresponding to data 1 or 0 retained in the volatile memory circuit 101 is written to and retained at the node NVN. In the semiconductor device 100a, when the transistor Tr is turned on, the H level or L level potential of the node VN is written to the node NVN, and when the transistor Tr is turned off, the H level or L level potential is retained. The potential of each terminal of the transistor at the time the potential is written to and retained at the node NVN can be the same as that in
(76) Note that in
(77) In the case of the semiconductor device 100a according to
(78) In the case of the semiconductor device 100a according to
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(80) In the semiconductor device 100b in
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(82) In the circuit configuration in
(83) In the semiconductor device 100c in
(84)
(85) A semiconductor device 100d in
(86) The semiconductor device 100d in
(87) The volatile memory circuit 102 is a circuit that can input, output, and retain data in accordance with a control signal such as a clock signal supplied from the outside in a period during which the power supply voltage is supplied; for example, a flip-flop or the like can be used.
(88)
(89) In the semiconductor device 100FF in
(90) Note that in
(91) In the semiconductor device 100d, the H level or L level potential corresponding to data 1 or 0 retained in the volatile memory circuit 102 is written to and retained at the node NVN. In the semiconductor device 100d, when the transistor Tr is turned on, the H level or L level potential of the node VN is written to the node NVN, and when the transistor Tr is turned off, the H level or L level potential is retained. The potential of each terminal of the transistor at the time the potential is written to and retained at the node NVN can be the same as that in
(92) In the case of the semiconductor device 100d according to
(93) In the case of the semiconductor device 100d according to
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(95) In the semiconductor device 100e in
(96)
(97) In the circuit configuration in
(98) In the semiconductor device 100f in
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(100) In
(101)
(102) In
(103) In
(104) In the timing chart in
(105) Next, in the backup period, the power supply voltage is supplied, and the potential V_k1 of the node NVN is rewritten with the potential V_k of the node VN at the timing of switching of the potential of the data control line OSG from the L level to an H level. After the potential of the node NVN is rewritten with the potential V_k, the potential of the data control line OSG is changed from the H level to the L level. In addition, the potential of the potential control line PL is switched from the L level to an H level. Then, the potential V_k of the node NVN is increased to the potential V_k+V.
(106) Next, in the retention period, the supply of the power supply voltage is stopped, and the data control line OSG is set at the L level. At that time, when a switch provided for a wiring for the low power supply potential is turned off and the potential of the wiring to which the low power supply potential has been supplied is increased to VDD because of leakage current flowing in the volatile memory circuit 101, the potential of wirings of the power supply line can be made equal to VDD and thus the supply of the power supply voltage is stopped. Accordingly, the node VN is set at the H level potential that is the potential of the power supply line. As the potential of the node NVN, the potential V_k+V set in the backup period is retained when the potential control line PL is held at the H level and the data control line OSG is held at the L level.
(107) In one embodiment of the present invention, the potential of a node corresponding to a source or a drain of the transistor Tr is increased in the retention period. Accordingly, Vgs can be a negative voltage even when the L level potential of the data control line OSG is GND. Thus, even when the transistor Tr is not a normally-off transistor, its off-state current can be kept small for a long time, whereby data at the node VN can be retained at the node NVN for a long time.
(108) Next, in the recovery period, the supply of the power supply voltage is stopped; the potential of the potential control line PL is switched from the H level to the L level; and the potential V_k+V of the node NVN is returned to the potential V_k. In addition, the potential of the data control line OSG is switched from the L level to the H level, and charge is shared by the node VN and the node NVN. Then, the potential of the node NVN changes in accordance with the potential V_k. In this state, the supply of the power supply voltage is restarted, and the potential of the node NVN is returned to the potential V_k. In addition, the potential of the data control line OSG is changed from the H level to the L level. Then, the operation returns to the active period.
(109) In one embodiment of the present invention, Vgs of the transistor Tr in an off state can be a negative voltage; therefore, it is not necessary to use a normally-off transistor whose threshold voltage is adjusted in advance using a back gate voltage or the like. Thus, a normally-off transistor does not need to be used as the transistor Tr, and a normally-on transistor can be used. With the use of a normally-on transistor as the transistor Tr, the on-state current of the transistor can be increased. This can shorten the data backup period.
(110)
(111) The semiconductor device 100 in
(112) In the semiconductor device 100 in
(113) Note that when the power switch PSW is turned off, the potential of the node GL can be increased from GND to VDD eventually. This is because of leakage current of the volatile memory circuit 101. More precisely, there is a small leakage current of the power switch PSW, and therefore, the node GL does not become exactly VDD but becomes a potential around VDD.
(114) When the power switch PSW is turned on, the potential of the node GL becomes GND. More precisely, owing to the on-state resistance of the power switch PSW and the leakage current of the volatile memory circuit 101, the node GL does not become exactly GND but becomes a potential around GND.
(115) In the semiconductor device 100 in
(116)
(117) In the backup period in
(118) Note that in the backup period in
(119) Note that the frequency of switching of the potential of the potential control line PL from the L level to the H level and the frequency of switching of the potential of the data control line OSG from the H level to the L level are preferably low such that data is not affected by release of charge accumulated in the capacitor Cp through the transistor Tr. In this regard, the switching of the potential of the potential control line PL from the L level to the H level and the switching of the potential of the data control line OSG from the H level to the L level may be performed at the same time.
(120) Next, in the retention period in
(121) Next, in the recovery period in
(122)
(123) The semiconductor device 100GL in
(124) The configuration in
(125) In the semiconductor device 100GL in
(126) In the semiconductor device 100GL in
(127)
(128) In the backup period in
(129) Next, in the retention period in
(130) Next, in the recovery period in
(131) In the above-described embodiment of the present invention, the potential of a node corresponding to a source or a drain of the transistor Tr is increased in the retention period. Accordingly, Vgs can be a negative voltage even when the L level potential of the data control line OSG is GND. Thus, even when the transistor Tr is not a normally-off transistor, off-state current can be kept small for a long time, whereby data at the node VN can be retained at the node NVN for a long time.
(132) In addition, in one embodiment of the present invention, Vgs of the transistor Tr in an off state can be a negative voltage; therefore, it is not necessary to use a normally-off transistor whose threshold voltage is adjusted in advance using a back gate voltage or the like. A normally-off transistor does not need to be used as the transistor Tr, and a normally-on transistor can be used. With the use of a normally-on transistor as the transistor Tr, the on-state current of the transistor can be increased. This can shorten the data backup and recovery periods.
(133) The structure described above in this embodiment can be combined with any of the structures described in the other embodiments as appropriate.
Embodiment 2
(134) This embodiment will explain an oxide semiconductor layer that can be used as a semiconductor layer of the transistor with low off-state current described in the foregoing embodiment.
(135) An oxide semiconductor used for a channel formation region in the semiconductor layer of the transistor preferably contains at least indium (In) or zinc (Zn). In particular, the oxide semiconductor preferably contains both In and Zn. The oxide semiconductor preferably contains a stabilizer for strongly bonding oxygen, in addition to In and Zn. The oxide semiconductor preferably contains at least one of gallium (Ga), tin (Sn), zirconium (Zr), hafnium (Hf), and aluminum (Al) as the stabilizer.
(136) As another stabilizer, the oxide semiconductor may contain one or more kinds of lanthanoid such as lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).
(137) As the oxide semiconductor used for the semiconductor layer of the transistor, any of the following can be used, for example: indium oxide, tin oxide, zinc oxide, InZn-based oxide, SnZn-based oxide, AlZn-based oxide, ZnMg-based oxide, SnMg-based oxide, InMg-based oxide, InGa-based oxide, InGaZn-based oxide (also referred to as IGZO), InAlZn-based oxide, InSnZn-based oxide, SnGaZn-based oxide, AlGaZn-based oxide, SnAlZn-based oxide, InHfZn-based oxide, InZrZn-based oxide, InTiZn-based oxide, InScZn-based oxide, InYZn-based oxide, InLaZn-based oxide, InCeZn-based oxide, InPrZn-based oxide, InNdZn-based oxide, InSmZn-based oxide, InEuZn-based oxide, InGdZn-based oxide, InTbZn-based oxide, InDyZn-based oxide, InHoZn-based oxide, InErZn-based oxide, InTmZn-based oxide, InYbZn-based oxide, InLuZn-based oxide, InSnGaZn-based oxide, InHfGaZn-based oxide, InAlGaZn-based oxide, InSnAlZn-based oxide, InSnHfZn-based oxide, and InHfAlZn-based oxide.
(138) For example, an InGaZn-based oxide with an atomic ratio of In:Ga:Zn=1:1:1, 3:1:2, or 2:1:3 or an oxide with an atomic ratio close to the above atomic ratios can be used.
(139) If an oxide semiconductor film forming the semiconductor layer contains a large amount of hydrogen, the hydrogen and the oxide semiconductor are bonded to each other, so that part of the hydrogen serves as a donor and causes generation of an electron which is a carrier. As a result, the threshold voltage of the transistor shifts in the negative direction. It is therefore preferable that after formation of the oxide semiconductor film, dehydration treatment (dehydrogenation treatment) be performed to remove hydrogen or moisture from the oxide semiconductor film so that the oxide semiconductor film is highly purified to contain impurities as little as possible.
(140) Note that oxygen in the oxide semiconductor film is sometimes reduced by the dehydration treatment (dehydrogenation treatment). For that reason, it is preferable that oxygen be added to the oxide semiconductor film to fill oxygen vacancies increased by the dehydration treatment (dehydrogenation treatment). In this specification and the like, supplying oxygen to an oxide semiconductor film may be expressed as oxygen adding treatment, or treatment for making the oxygen content of an oxide semiconductor film be in excess of that of the stoichiometric composition may be expressed as treatment for making an oxygen-excess state.
(141) In this manner, hydrogen or moisture is removed from the oxide semiconductor film by the dehydration treatment (dehydrogenation treatment) and oxygen vacancies therein are filled by the oxygen adding treatment, whereby the oxide semiconductor film can be turned into an i-type (intrinsic) oxide semiconductor film or a substantially i-type (intrinsic) oxide semiconductor film that is extremely close to an i-type oxide semiconductor film. Note that substantially intrinsic means that the oxide semiconductor film contains extremely few (close to zero) carriers derived from a donor and has a carrier density which is 110.sup.17/cm.sup.3 or lower, 110.sup.16/cm.sup.3 or lower, 110.sup.15/cm.sup.3 or lower, 110.sup.14/cm.sup.3 or lower, or 110.sup.13/cm.sup.3 or lower, particularly preferably lower than 810.sup.11/cm.sup.3, still further preferably lower than 110.sup.11/cm.sup.3, yet further preferably lower than 110.sup.10/cm.sup.3, and is 110.sup.9/cm.sup.3 or higher.
(142) The transistor including an i-type or substantially i-type oxide semiconductor film can have extremely favorable off-state current characteristics. For example, the off-state drain current of the transistor including the oxide semiconductor film can be 110.sup.18 A or less, preferably 110.sup.21 A or less, more preferably 110.sup.24 A or less at room temperature (approximately 25 C.), or 110.sup.15 A or less, preferably 110.sup.18 A or less, more preferably 110.sup.21 A or less at 85 C. Note that the off state of an n-channel transistor refers to a state where a gate voltage is sufficiently lower than the threshold voltage. Specifically, the transistor is off when the gate voltage is lower than the threshold voltage by 1 V or more, 2 V or more, or 3 V or more.
(143) The oxide semiconductor film may include one or more of the following: an oxide semiconductor having a single crystal structure (hereinafter referred to as a single crystal oxide semiconductor); an oxide semiconductor having a polycrystalline structure (hereinafter referred to as a polycrystalline oxide semiconductor); an oxide semiconductor having a microcrystalline structure (hereinafter referred to as a microcrystalline oxide semiconductor), and an oxide semiconductor having an amorphous structure (hereinafter referred to as an amorphous oxide semiconductor). Furthermore, the oxide semiconductor film may be formed using a CAAC-OS film. Furthermore, the oxide semiconductor film may include an amorphous oxide semiconductor and an oxide semiconductor having a crystal grain. Described below are the CAAC-OS and the microcrystalline oxide semiconductor.
(144) First, a CAAC-OS film will be described.
(145) The CAAC-OS film is one of oxide semiconductor films having a plurality of c-axis aligned crystal parts.
(146) In a transmission electron microscope (TEM) image of the CAAC-OS film, a boundary between crystal parts, that is, a grain boundary is not clearly observed. Thus, in the CAAC-OS film, a reduction in electron mobility due to the grain boundary is less likely to occur.
(147) According to the TEM image of the CAAC-OS film observed in a direction substantially parallel to a sample surface (cross-sectional TEM image), metal atoms are arranged in a layered manner in the crystal parts. Each layer of metal atoms has a morphology reflecting a surface over which the CAAC-OS film is formed (hereinafter, a surface over which the CAAC-OS film is formed is referred to as a formation surface) or a top surface of the CAAC-OS film, and is arranged parallel to the formation surface or the top surface of the CAAC-OS film.
(148) On the other hand, according to the TEM image of the CAAC-OS film observed in a direction substantially perpendicular to the sample surface (plan-view TEM image), metal atoms are arranged in a triangular or hexagonal configuration in the crystal parts. However, there is no regularity of arrangement of metal atoms between different crystal parts.
(149)
(150)
(151) Note that in an electron diffraction pattern of the CAAC-OS film, spots (bright spots) indicating alignment are shown. For example, when electron diffraction with an electron beam having a diameter of 1 nm or more and 30 nm or less (such electron diffraction is also referred to as nanobeam electron diffraction) is performed on the top surface of the CAAC-OS film, spots are observed (see
(152) From the results of the cross-sectional TEM image and the plan-view TEM image, alignment is found in the crystal parts in the CAAC-OS film.
(153) Most of the crystal parts included in the CAAC-OS film each fit inside a cube whose one side is less than 100 nm. Thus, there is a case where a crystal part included in the CAAC-OS film fits inside a cube whose one side is less than 10 nm, less than 5 nm, or less than 3 nm. Note that when a plurality of crystal parts included in the CAAC-OS film are connected to each other, one large crystal region is formed in some cases. For example, a crystal region with an area of 2500 nm.sup.2 or more, 5 m.sup.2 or more, or 1000 m.sup.2 or more is observed in some cases in the plan-view TEM image.
(154) A CAAC-OS film is subjected to structural analysis with an X-ray diffraction (XRD) apparatus. For example, when the CAAC-OS film including an InGaZnO.sub.4 crystal is analyzed by an out-of-plane method, a peak appears frequently when the diffraction angle (2) is around 31. This peak is derived from the (009) plane of the InGaZnO.sub.4 crystal, which indicates that crystals in the CAAC-OS film have c-axis alignment, and that the c-axes are aligned in a direction substantially perpendicular to the formation surface or the top surface of the CAAC-OS film.
(155) On the other hand, when the CAAC-OS film is analyzed by an in-plane method in which an X-ray is incident on a sample in a direction substantially perpendicular to the c-axis, a peak appears frequently when 2 is around 56. This peak is derived from the (110) plane of the InGaZnO.sub.4 crystal. Here, analysis ( scan) is performed under conditions where the sample is rotated around a normal vector of a sample surface as an axis ( axis) with 2 fixed at around 56. In the case where the sample is a single crystal oxide semiconductor film of InGaZnO.sub.4, six peaks appear. The six peaks are derived from crystal planes equivalent to the (110) plane. On the other hand, in the case of a CAAC-OS film, a peak is not clearly observed even when scan is performed with 2 fixed at around 56.
(156) According to the above results, in the CAAC-OS film having c-axis alignment, while the directions of a-axes and b-axes are different between crystal parts, the c-axes are aligned in a direction parallel to a normal vector of a formation surface or a normal vector of a top surface. Thus, each metal atom layer arranged in a layered manner observed in the cross-sectional TEM image corresponds to a plane parallel to the a-b plane of the crystal.
(157) Note that the crystal part is formed concurrently with deposition of the CAAC-OS film or is formed through crystallization treatment such as heat treatment. As described above, the c-axis of the crystal is aligned in a direction parallel to a normal vector of a formation surface or a normal vector of a top surface. Thus, for example, in the case where the shape of the CAAC-OS film is changed by etching or the like, the c-axis might not be necessarily parallel to a normal vector of a formation surface or a normal vector of a top surface of the CAAC-OS film.
(158) Distribution of c-axis aligned crystal parts in the CAAC-OS film is not necessarily uniform. For example, in the case where crystal growth leading to the crystal parts of the CAAC-OS film occurs from the vicinity of the top surface of the film, the proportion of the c-axis aligned crystal parts in the vicinity of the top surface is higher than that in the vicinity of the formation surface in some cases. Further, when an impurity is added to the CAAC-OS film, a region to which the impurity is added may be altered and the proportion of the c-axis aligned crystal parts in the CAAC-OS film might vary depending on regions.
(159) Note that when the CAAC-OS film with an InGaZnO.sub.4 crystal is analyzed by an out-of-plane method, a peak may also be observed when 2 is around 36, in addition to the peak at 2 of around 31. The peak at 2 of around 36 indicates that a crystal having no c-axis alignment is included in part of the CAAC-OS film. It is preferable that in the CAAC-OS film, a peak appear when 2 is around 31 and that a peak not appear when 2 is around 36.
(160) The CAAC-OS film is an oxide semiconductor film having low impurity concentration. The impurity is an element other than the main components of the oxide semiconductor film, such as hydrogen, carbon, silicon, or a transition metal element. In particular, an element that has higher bonding strength to oxygen than a metal element included in the oxide semiconductor film, such as silicon, disturbs the atomic arrangement of the oxide semiconductor film by depriving the oxide semiconductor film of oxygen and causes a decrease in crystallinity. Further, a heavy metal such as iron or nickel, argon, carbon dioxide, or the like has a large atomic radius (molecular radius), and thus disturbs the atomic arrangement of the oxide semiconductor film and causes a decrease in crystallinity when it is contained in the oxide semiconductor film. Note that the impurity contained in the oxide semiconductor film might serve as a carrier trap or a carrier generation source.
(161) The CAAC-OS film is an oxide semiconductor film having a low density of defect states. In some cases, oxygen vacancies in the oxide semiconductor film serve as carrier traps or serve as carrier generation sources when hydrogen is captured therein.
(162) The state in which impurity concentration is low and density of defect states is low (the number of oxygen vacancies is small) is referred to as a highly purified intrinsic or substantially highly purified intrinsic state. A highly purified intrinsic or substantially highly purified intrinsic oxide semiconductor film has few carrier generation sources, and thus can have a low carrier density. Therefore, a transistor including the oxide semiconductor film rarely has negative threshold voltage (is rarely normally on). The highly purified intrinsic or substantially highly purified intrinsic oxide semiconductor film has a low density of defect states, and thus has few carrier traps. Accordingly, the transistor including the oxide semiconductor film has little variation in electrical characteristics and high reliability. Electric charge trapped by the carrier traps in the oxide semiconductor film takes a long time to be released and might behave like fixed electric charge. Thus, the transistor including the oxide semiconductor film having high impurity concentration and a high density of defect states has unstable electrical characteristics in some cases.
(163) With the use of the CAAC-OS film in a transistor, variation in the electrical characteristics of the transistor due to irradiation with visible light or ultraviolet light is small.
(164) Next, a microcrystalline oxide semiconductor film will be described.
(165) In an image obtained with the TEM, crystal parts cannot be found clearly in the microcrystalline oxide semiconductor film in some cases. In most cases, the size of a crystal part included in the microcrystalline oxide semiconductor film is greater than or equal to 1 nm and less than or equal to 100 nm, or greater than or equal to 1 nm and less than or equal to 10 nm. A microcrystal with a size greater than or equal to 1 nm and less than or equal to 10 nm, or a size greater than or equal to 1 nm and less than or equal to 3 nm, is specifically referred to as nanocrystal (nc). An oxide semiconductor film including nanocrystal is referred to as an nc-OS (nanocrystalline oxide semiconductor) film. In an image of the nc-OS film which is obtained with the TEM, for example, a grain boundary is not clearly detected in some cases.
(166) In the nc-OS film, a microscopic region (for example, a region with a size greater than or equal to 1 nm and less than or equal to 10 nm, in particular, a region with a size greater than or equal to 1 nm and less than or equal to 3 nm) has a periodic atomic arrangement. There is no regularity of crystal orientation between different crystal parts in the nc-OS film. Thus, the orientation of the whole film is not observed. Accordingly, in some cases, the nc-OS film cannot be distinguished from an amorphous oxide semiconductor film depending on an analysis method. For example, when the nc-OS film is subjected to structural analysis by an out-of-plane method with an XRD apparatus using an X-ray having a diameter larger than the size of a crystal part, a peak indicating a crystal plane does not appear. Further, a halo pattern is shown in a selected-area electron diffraction pattern of the nc-OS film obtained by using an electron beam having a probe diameter (e.g., 50 nm or larger) larger than the size of a crystal part. Meanwhile, spots are shown in a nanobeam electron diffraction pattern of the nc-OS film obtained by using an electron beam having a probe diameter close to or smaller than the size of a crystal part. Furthermore, in a nanobeam electron diffraction pattern of the nc-OS film, regions with high luminance in a circular (ring) pattern are shown in some cases. Moreover, in a nanobeam electron diffraction pattern of the nc-OS film, a plurality of spots are shown in a ring-like region in some cases (see
(167) The nc-OS film is an oxide semiconductor film that has high regularity as compared with an amorphous oxide semiconductor film. Therefore, the nc-OS film has a lower density of defect states than an amorphous oxide semiconductor film. Note that there is no regularity of crystal orientation between different crystal parts in the nc-OS film. Therefore, the nc-OS film has a higher density of defect states than the CAAC-OS film.
(168) Note that an oxide semiconductor film may be a stacked film including two or more films of an amorphous oxide semiconductor film, a microcrystalline oxide semiconductor film, and a CAAC-OS film, for example.
(169) In the case where an oxide semiconductor film has a plurality of structures, the structures can be analyzed using nanobeam electron diffraction in some cases.
(170)
(171)
(172) The camera 78 is installed so as to face the fluorescent plate 92 and can take an image of a pattern appearing on the fluorescent plate 92. An angle formed by a straight line which passes through the center of a lens of the camera 78 and the center of the fluorescent plate 92 and an upper surface of the fluorescent plate 92 is, for example, 15 or more and 80 or less, 30 or more and 75 or less, or 45 or more and 70 or less. As the angle is reduced, distortion of the transmission electron diffraction pattern taken by the camera 78 becomes larger. Note that if the angle is obtained in advance, the distortion of an obtained transmission electron diffraction pattern can be corrected. Note that the film chamber 82 may be provided with the camera 78. For example, the camera 78 may be set in the film chamber 82 so as to be opposite to the incident direction of electrons 84. In this case, a transmission electron diffraction pattern with less distortion can be taken from the rear surface of the fluorescent plate 92.
(173) A holder for fixing the substance 88 that is a sample is provided in the sample chamber 74. The holder transmits electrons passing through the substance 88. The holder may have, for example, a function of moving the substance 88 in the direction of the X, Y, and Z axes. The movement function of the holder may have an accuracy of moving the substance in the range of, for example, 1 nm to 10 nm, 5 nm to 50 nm, 10 nm to 100 nm, 50 nm to 500 nm, and 100 nm to 1 m. The range is preferably determined to be an optimal range for the structure of the substance 88.
(174) Then, a method for measuring a transmission electron diffraction pattern of a substance by the transmission electron diffraction measurement apparatus described above will be described.
(175) For example, changes in the structure of a substance can be observed by changing (scanning) the irradiation position of the electrons 84 that are a nanobeam on the substance, as illustrated in
(176) Even when the substance 88 is a CAAC-OS film, a diffraction pattern similar to that of an nc-OS film or the like is partly observed in some cases. Therefore, whether a CAAC-OS film is favorable can be determined by the proportion of a region where a diffraction pattern of a CAAC-OS film is observed in a predetermined area (also referred to as proportion of CAAC). In the case of a high-quality CAAC-OS film, for example, the proportion of CAAC is higher than or equal to 50%, preferably higher than or equal to 80%, further preferably higher than or equal to 90%, still further preferably higher than or equal to 95%. Note that the proportion of a region where a diffraction pattern different from that of a CAAC-OS film is observed is referred to as the proportion of non-CAAC.
(177) For example, transmission electron diffraction patterns were obtained by scanning a top surface of a sample including a CAAC-OS film obtained just after deposition (represented as as-sputtered) and a top surface of a sample including a CAAC-OS film subjected to heat treatment at 450 C. in an atmosphere containing oxygen. Here, the proportion of CAAC was obtained in such a manner that diffraction patterns were observed by scanning for 60 seconds at a rate of 5 nm/second and the obtained diffraction patterns were converted into still images every 0.5 seconds. Note that as an electron beam, a nanobeam with a probe diameter of 1 nm was used. The above measurement was performed on six samples. The proportion of CAAC was calculated using the average value of the six samples.
(178)
(179) Here, most of diffraction patterns different from that of a CAAC-OS film are diffraction patterns similar to that of an nc-OS film. Furthermore, an amorphous oxide semiconductor film was not able to be observed in the measurement region. Therefore, the above results suggest that the region having a structure similar to that of an nc-OS film is rearranged by the heat treatment owing to the influence of the structure of the adjacent region, whereby the region becomes CAAC.
(180)
(181) With such a measurement method, the structure of an oxide semiconductor film having a plurality of structures can be analyzed in some cases.
(182) Note that the structures, methods, and the like described in this embodiment can be used as appropriate in combination with any of the structures, methods, and the like described in other embodiments.
Embodiment 3
(183) In this embodiment, an example of a cross-sectional structure of a transistor used in a semiconductor device of one embodiment of the disclosed invention will be described with reference to drawings.
(184)
(185) The channel length direction refers to a direction in which a carrier moves between a pair of impurity regions functioning as a source region and a drain region by the most direct way, and the channel width direction refers to a direction perpendicular to the channel length direction.
(186) In
(187) The transistor PG1 may include the channel formation region in a semiconductor film or a semiconductor substrate of silicon, germanium, or the like in an amorphous, microcrystalline, polycrystalline, or single crystal state. Alternatively, the transistor PG1 may include the channel formation region in an oxide semiconductor film or an oxide semiconductor substrate. In the case where channel formation regions of all the transistors are included in an oxide semiconductor film or an oxide semiconductor substrate, the transistor Tr is not necessarily stacked over the transistor PG1, and the transistors Tr and PG1 may be formed in the same layer.
(188) In the case where the transistor PG1 is formed using a thin silicon film, any of the following can be used in the thin film: amorphous silicon formed by a sputtering method or a vapor phase growth method such as a plasma-enhanced CVD method; polycrystalline silicon obtained by crystallization of amorphous silicon by treatment such as laser annealing; single crystal silicon obtained by separation of a surface portion of a single crystal silicon wafer by implantation of hydrogen ions or the like into the silicon wafer; and the like.
(189) A substrate 400 where the transistor PG1 is formed can be, for example, a silicon substrate, a germanium substrate, or a silicon germanium substrate. In
(190) The transistor PG1 is electrically isolated by an element isolation method. As the element isolation method, a trench isolation method (a shallow trench isolation (STI) method) or the like can be used.
(191) In a projection of the substrate 400 that exists in a region other than the trench, an impurity region 402 and an impurity region 403 of the transistor PG1 and a channel formation region 404 placed between the impurity regions 402 and 403 are provided. Further, the transistor PG1 includes an insulating film 405 covering the channel formation region 404 and a gate electrode 406 that overlaps with the channel formation region 404 with the insulating film 405 provided therebetween.
(192) In the transistor PG1, a side portion and an upper portion of the projection in the channel formation region 404 overlap with the gate electrode 406 with the insulating film 405 positioned therebetween, so that carriers flow in a wide area including the side portion and the upper portion of the channel formation region 404. Therefore, an area over the substrate occupied by the transistor PG1 can be reduced, and the number of transferred carriers in the transistor PG1 can be increased. As a result, the on-state current and field-effect mobility of the transistor PG1 are increased. Suppose the length in the channel width direction (channel width) of the projection in the channel formation region 404 is W, and the thickness of the projection in the channel formation region 404 is T. When the aspect ratio of the thickness T to the channel width W is high, a region where carriers flow becomes larger. Thus, the on-state current of the transistor PG1 can be further increased and the field-effect mobility of the transistor PG1 can be further increased.
(193) Note that when the transistor PG1 is formed using a bulk semiconductor substrate, the aspect ratio is preferably 0.5 or more, further preferably 1 or more.
(194) An insulating film 411 is provided over the transistor PG1. Openings are formed in the insulating film 411. Conductive films 412 and 413 that are electrically connected to the impurity regions 402 and 403, respectively, and a conductive film 414 that is electrically connected to the gate electrode 406 are formed in the openings.
(195) The conductive film 412 is electrically connected to a conductive film 416 formed over the insulating film 411. The conductive film 413 is electrically connected to a conductive film 417 formed over the insulating film 411. The conductive film 414 is electrically connected to a conductive film 418 formed over the insulating film 411.
(196) An insulating film 420 is provided over the conductive films 416 to 418. An insulating film 421 having a blocking effect of preventing diffusion of oxygen, hydrogen, and water is provided over the insulating film 420. As the insulating film 421 has higher density and becomes denser or has a fewer dangling bonds and becomes more chemically stable, the insulating film 421 has a higher blocking effect. The insulating film 421 that has the effect of blocking diffusion of oxygen, hydrogen, and water can be formed using, for example, aluminum oxide, aluminum oxynitride, gallium oxide, gallium oxynitride, yttrium oxide, yttrium oxynitride, hafnium oxide, or hafnium oxynitride. The insulating film 421 having an effect of blocking diffusion of hydrogen and water can be formed using, for example, silicon nitride or silicon nitride oxide.
(197) An insulating film 422 is provided over the insulating film 421, and the transistor Tr is provided over the insulating film 422.
(198) The transistor Tr includes, over the insulating film 422, a semiconductor film 430 including an oxide semiconductor, conductive films 432 and 433 functioning as a source and drain electrodes and electrically connected to the semiconductor film 430, a gate insulating film 431 covering the semiconductor film 430, and a gate electrode 434 overlapping with the semiconductor film 430 with the gate insulating film 431 positioned therebetween. Note that an opening is formed in the insulating films 420 to 422. The conductive film 433 is connected to the conductive film 418 in the opening.
(199) Note that in
(200) In the case where the transistor Tr has a pair of gate electrodes, one of the gate electrodes may be supplied with a signal for controlling the on/off state, and the other of the gate electrodes may be supplied with a potential from another element. In this case, potentials with the same level may be supplied to the pair of gate electrodes, or a fixed potential such as the ground potential may be supplied only to the other of the gate electrodes. By controlling the level of a potential supplied to the other of the gate electrodes, the threshold voltage of the transistor can be controlled.
(201) In
(202)
(203) The insulating film 422 preferably has a function of supplying part of oxygen to the oxide semiconductor films 430a to 430c by heating. It is preferable that the number of defects in the insulating film 422 be small, and typically the spin density at g=2.001 due to a dangling bond of silicon be lower than or equal to 110.sup.18 spins/cm.sup.3. The spin density is measured by electron spin resonance (ESR) spectroscopy.
(204) The insulating film 422, which has a function of supplying part of the oxygen to the oxide semiconductor films 430a to 430c by heating, is preferably an oxide. Examples of the oxide include aluminum oxide, magnesium oxide, silicon oxide, silicon oxynitride, silicon nitride oxide, gallium oxide, germanium oxide, yttrium oxide, zirconium oxide, lanthanum oxide, neodymium oxide, hafnium oxide, and tantalum oxide. The insulating film 422 can be formed by a plasma CVD (chemical vapor deposition) method, a sputtering method, or the like.
(205) Note that in this specification, oxynitride contains more oxygen than nitrogen, and nitride oxide contains more nitrogen than oxygen.
(206) Note that in the transistor Tr illustrated in
(207) With the s-channel structure, specifically, when a potential at which the transistor Tr is turned off is supplied to the gate electrode 434, the amount of off-state current that flows between the conductive films 432 and 433 through the end portions can be reduced. For this reason, in the transistor Tr, even when the distance between the conductive films 432 and 433 at the end portions of the oxide semiconductor film 430b is reduced as a result of reducing the channel length to obtain high on-state current, the transistor Tr can have low off-state current. Consequently, with the short channel length, the transistor Tr can have high on-state current when in an on state and low off-state current when in an off state.
(208) With the s-channel structure, specifically, when a potential at which the transistor Tr is turned on is supplied to the gate electrode 434, the amount of current that flows between the conductive films 432 and 433 through the end portions of the oxide semiconductor film 430b can be increased. The current contributes to an increase in the field-effect mobility and the on-state current of the transistor Tr. When the end portions of the oxide semiconductor film 430b overlap with the gate electrode 434, carriers flow in a wide region of the oxide semiconductor film 430b without being limited to a region in the vicinity of the interface between the oxide semiconductor film 430b and the gate insulating film 431, which results in an increase in the amount of carrier movement in the transistor Tr. As a result, the on-state current of the transistor Tr is increased, and the field-effect mobility is increased to greater than or equal to 10 cm.sup.2/V.Math.s or to greater than or equal to 20 cm.sup.2/V.Math.s, for example. Note that here, the field-effect mobility is not an approximate value of the mobility as the physical property of the oxide semiconductor film but is the apparent field-effect mobility in a saturation region of the transistor, which is an index of current drive capability.
(209) Although this embodiment is described with reference to
(210) Note that the structures, methods, and the like described in this embodiment can be used as appropriate in combination with any of the structures, methods, and the like described in other embodiments.
Embodiment 4
(211) Although the conductive films and the semiconductor films which are described in any of the above embodiments can be formed by a sputtering method, such films may be formed by another method, e.g., a thermal CVD method. A metal organic chemical vapor deposition (MOCVD) method or an atomic layer deposition (ALD) method may be employed as an example of a thermal CVD method.
(212) A thermal CVD method has an advantage that no defect due to plasma damage is generated since it does not utilize plasma for forming a film.
(213) Deposition by a thermal CVD method may be performed in such a manner that a source gas and an oxidizer are supplied to a chamber at a time, the pressure in the chamber is set to an atmospheric pressure or a reduced pressure, and reaction is caused in the vicinity of the substrate or over the substrate.
(214) Deposition by an ALD method may be performed in such a manner that the pressure in a chamber is set to an atmospheric pressure or a reduced pressure, source gases for reaction are sequentially introduced into the chamber, and then the sequence of the gas introduction is repeated. For example, two or more kinds of source gases are sequentially supplied to the chamber by switching respective switching valves (also referred to as high-speed valves). For example, a first source gas is introduced, an inert gas (e.g., argon or nitrogen) or the like is introduced at the same time as or after the introduction of the first source gas so that the source gases are not mixed, and then a second source gas is introduced. Note that in the case where the first source gas and the inert gas are introduced at a time, the inert gas serves as a carrier gas, and the inert gas may also be introduced at the same time as the introduction of the second source gas. Alternatively, the first source gas may be exhausted by vacuum evacuation instead of the introduction of the inert gas, and then the second source gas may be introduced. The first source gas is adsorbed on the surface of the substrate to form a first layer; then the second source gas is introduced to react with the first layer; as a result, a second layer is stacked over the first layer, so that a thin film is formed. The sequence of the gas introduction is repeated a plurality of times until a desired thickness is obtained, whereby a thin film with excellent step coverage can be formed. The thickness of the thin film can be adjusted by the number of repetition times of the sequence of the gas introduction; therefore, an ALD method makes it possible to accurately adjust a thickness and thus is suitable for manufacturing a minute FET.
(215) The conductive films and the semiconductor films which are described in the above embodiments can be formed by a thermal CVD method such as a MOCVD method or an ALD method. For example, in the case where an InGaZnO film is formed, trimethylindium, trimethylgallium, and dimethylzinc are used. Note that the chemical formula of trimethylindium is In(CH.sub.3).sub.3. The chemical formula of trimethylgallum is Ga(CH.sub.3).sub.3. The chemical formula of dimethylzinc is Zn(CH.sub.3).sub.2. Without limitation to the above combination, triethylgallium (chemical formula: Ga(C.sub.2H.sub.5).sub.3) can be used instead of trimethylgallium and diethylzinc (chemical formula: Zn(C.sub.2H.sub.5).sub.2) can be used instead of dimethylzinc.
(216) For example, in the case where a tungsten film is formed using a deposition apparatus employing ALD, a WF.sub.6 gas and a B.sub.2H.sub.6 gas are sequentially introduced a plurality of times to form an initial tungsten film, and then a WF.sub.6 gas and an H.sub.2 gas are introduced at a time, so that a tungsten film is formed. Note that an SiH.sub.4 gas may be used instead of a B.sub.2H.sub.6 gas.
(217) For example, in the case where an oxide semiconductor film, e.g., an InGaZnO film is formed using a deposition apparatus employing ALD, an In(CH.sub.3).sub.3 gas and an O.sub.3 gas are sequentially introduced a plurality of times to form an InO layer, a Ga(CH.sub.3).sub.3 gas and an O.sub.3 gas are introduced at a time to form a GaO layer, and then a Zn(CH.sub.3).sub.2 gas and an O.sub.3 gas are introduced at a time to form a ZnO layer. Note that the order of these layers is not limited to this example. A mixed compound layer such as an InGaO layer, an InZnO layer, or a GaZnO layer may be formed by mixing of these gases. Note that although an H.sub.2O gas which is obtained by bubbling with an inert gas such as Ar may be used instead of an O.sub.3 gas, it is preferable to use an O.sub.3 gas, which does not contain H. Instead of an In(CH.sub.3).sub.3 gas, an In(C.sub.2H.sub.5).sub.3 gas may be used. Instead of a Ga(CH.sub.3).sub.3 gas, a Ga(C.sub.2H.sub.5).sub.3 gas may be used. Furthermore, a Zn(CH.sub.3).sub.2 gas may be used.
(218) The structure described above in this embodiment can be combined with any of the structures described in the other embodiments as appropriate.
Embodiment 5
(219) In this embodiment, application examples of the semiconductor device described in the foregoing embodiment to an electronic component and to an electronic device including the electronic component will be described with reference to
(220)
(221) A semiconductor device including the transistors illustrated in
(222) The post-process can be completed through steps shown in
(223) A dicing step of grinding the back surface of the substrate and separating the substrate into a plurality of chips is performed. Then, a die bonding step of individually picking up separate chips to be mounted on and bonded to a lead frame is performed (Step S3). In this die bonding step, the chip is bonded to the lead frame by an appropriate method depending on a product, for example, bonding with a resin or a tape. Note that in the die bonding step, a chip may be mounted on and bonded to an interposer.
(224) Next, wire bonding for electrically connecting a lead of the lead frame and an electrode on a chip through a metal wire is performed (Step S4). As a metal wire, a silver wire or a gold wire can be used. For wire bonding, ball bonding or wedge bonding can be employed.
(225) A wire-bonded chip is subjected to a molding step of sealing the chip with an epoxy resin or the like (Step S5). With the molding step, the inside of the electronic component is filled with a resin, so that the mounted circuit portion and wire can be protected from external mechanical force and deterioration of characteristics due to moisture or dust can be reduced.
(226) Subsequently, the lead of the lead frame is plated. Then, the lead is cut and processed into a predetermined shape (Step S6). With the plating process, corrosion of the lead can be prevented, and soldering for mounting the electronic component on a printed circuit board in a later step can be performed with higher reliability.
(227) Next, printing process (marking) is performed on a surface of the package (Step S7). Then, through a final test step (Step S8), the electronic component is completed (Step S9).
(228) Since the electronic component described above includes the semiconductor device of the foregoing embodiment, it is possible to reduce the off-state current without use of an additionally generated negative potential and to increase the on-state current without application of a separately generated positive potential to a gate of an OS transistor. Therefore, the size and power consumption of the electronic component are reduced.
(229)
(230) Next, the description is made on applications of the above electronic component to electronic devices such as a computer, a portable information appliance (including a mobile phone, a portable game machine, and an audio reproducing device), electronic paper, a television device (also referred to as television or television receiver), and a digital video camera.
(231)
(232) Note that the first display portion 903a is a panel having a touch input function, and for example, as illustrated in the left of
(233) One of the first display portion 903a and the second display portion 903b can be detached from the portable information appliance as shown in the right of
(234) The portable information appliance in
(235) The portable information appliance illustrated in
(236) In addition, the housing 902 illustrated in
(237)
(238)
(239)
(240)
(241) As described above, the electronic devices shown in this embodiment incorporate the circuit board including the semiconductor device of the foregoing embodiment. Consequently, it is possible to obtain the electronic devices which include the electronic component with reduced size and reduced power consumption.
(242) This application is based on Japanese Patent Application serial No. 2013-234761 filed with Japan Patent Office on Nov. 13, 2013, the entire contents of which are hereby incorporated by reference.