Alkylation system and a process for cooling a vent stream

Abstract

One exemplary embodiment can be a process for cooling a vent stream from a receiver. Generally, the process may include providing a refrigerant including at least one compound contained in the receiver so the refrigerant leaking into the receiver can be compatible with the process.

Claims

1. A process for cooling a vent stream from a receiver of a depropanizer column in an acid alkylation zone, comprising providing a refrigerant comprising propane to one or more cooling coils contained in a vent condenser of the receiver wherein the propane in the one or more cooling coils is at a pressure greater than the receiver, pumping the refrigerant with a pump and chilling the refrigerant in an exchanger before entering the one or more cooling coils.

2. The process according to claim 1, wherein the refrigerant in the one or more cooling coils is at a temperature of no more than about 30 C.

3. The process according to claim 1, wherein the receiver is at a pressure of no more than about 1,720 kPa.

4. The process according to claim 1, further comprising sending the refrigerant contained in the one or more cooling coils to a pump.

Description

BRIEF DESCRIPTION OF THE DRAWING

(1) The FIGURE is a schematic depiction of an exemplary alkylation system or unit.

DETAILED DESCRIPTION

(2) Referring to the FIGURE, an acid alkylation system or unit 100 can include an acid alkylation zone 140 and a fractionation zone 200. Typically, the acid alkylation zone 140 can be any suitable alkylation zone, typically utilizing an acid alkylation catalyst. Usually, the acid alkylation catalyst can include a hydrogen fluoride. Exemplary alkylation zones are disclosed in, e.g., U.S. Pat. No. 5,098,668.

(3) The fractionation zone 200 can include one or more distillation columns, such as a depropanizer column 240. Exemplary distillation columns of the fractionation zone 200 are disclosed in, e.g., U.S. Pat. No. 4,348,544. The depropanizer column 240 can provide an overhead stream 260, a side-stream 270, and a bottom stream 280. Usually, the side-stream 270 can include or be rich in one or more hydrocarbons, such as C.sub.3-C.sub.5 hydrocarbons, more typically, C.sub.4 hydrocarbons. The bottom stream 280 can include or be rich in C.sub.4.sup.+ hydrocarbons, typically an alkylate product. The overhead stream 260 can include or be rich in one or more C.sub.4.sup. hydrocarbons and an alkylation catalyst, typically an acid such as hydrogen fluoride. The overhead stream 260 can be received within a receiver 300 forming a boot 304. The boot 304 can collect an alkylation catalyst and provide an alkylation catalyst stream 308 that can be recycled to the acid alkylation zone 140.

(4) The receiver 300 can also provide a hydrocarbon product in a stream 262 that can be split into a reflux stream 264 sent back to the depropanizer column 240 and an overhead product stream 266, typically including propane. In addition, the receiver 300 can form a vent condenser or a stack 310 that can provide a vent stream 314 including C.sub.2.sup. hydrocarbons with a reduced level of an acid alkylation catalyst. The vent stream 314 can be provided to a scrubber 380 to provide a scrubber effluent stream 384 that can be sent to any suitable destination, such as fuel gas or the flare. Typically, the receiver 300 can be at a pressure of no more than about 1,720 kPa.

(5) In the vent condenser 310, one or more cooling coils 320 can be provided to cool the vent stream 314 prior to exiting the vent condenser 310 to partially recover propane and the acid alkylation catalyst. Typically, the one or more cooling coils 320 can contain at least a portion of the refrigerant, and the refrigerant can be at a pressure greater than the pressure in the receiver 300. The vent stream 314 can be at a temperature of no more than about 20 C. and a pressure of no more than about 1,720 kPa. The refrigerant can enter the one or more cooling coils 320 and then exit in a line 322.

(6) Typically, the one or more cooling coils 320 can include any suitable refrigerant, such as an olefin or a paraffin, in a liquid phase. Usually, a suitable olefin can include a C.sub.2-C.sub.4 olefin, and a suitable paraffin can include propane. Preferably, the refrigerant can be a dry propane obtained from, e.g., a propane stripper or a product dryer, chilled, and pumped to about 60 to about 140 kPa above the pressure in the receiver 300. In the event of a coil leak, the high-pressure cold propane as the working fluid in the vent condenser 310 can leak into the depropanizer column 240, rather than the alkylation catalyst leaking into the one or more cooling coils 320. Hence, the alkylation catalyst, typically hydrogen fluoride, cannot contaminate the wet gas or fuel systems. Moreover, a leak can be detected quickly and fixed by monitoring the refrigerant level in the one or more cooling coils 320 or a surge drum 330.

(7) The line 322 can communicate with the surge drum 330. The refrigerant can pass through a line 324 to a pump 340, which can pump the refrigerant up to a pressure of about 1,900 kPa.

(8) Afterwards, the refrigerant can pass through a line 326 to the exchanger 360. Chilling can be provided by vaporizing the same or different refrigerant. Typically, a liquefied petroleum gas stream 364 at a pressure of about 300 to about 500 kPa and a temperature of about 5 to about 5 C. can be provided to cool the vaporized refrigerant. After exiting the exchanger 360, the refrigerant can be at a temperature of no more than about 20 C., preferably below about 0 C. The refrigerant may return to the vent condenser 310 via a line 328.

(9) Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The preceding preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.

(10) In the foregoing, all temperatures are set forth in degrees Celsius and, all parts and percentages are by weight, unless otherwise indicated.

(11) From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.