Aqueous oxidizing composition for hair

Abstract

Present invention relates to an aqueous oxidizing composition for hair which makes possible achieving homogeneous coloration of multiple damaged hair and especially provides excellent grey coverage with oxidative hair dyes. The object of the invention is an aqueous oxidizing composition for hair comprising one or more oxidizing agent, one or more polyol, one or more oil, one or more solid fatty alcohol and one or more surfactant wherein fatty alcohol to oil weight ratio is less than 1, weight ratio of surfactant to sum of fatty alcohol and oil is less than 0.25 and polyol concentration is less than or equal to 2% by weight calculated to the total of the composition.

Claims

1. An aqueous oxidizing composition for hair comprising: (a) one or more oxidizing agent, (b) one or more polyol selected from the group consisting of glycerin, 1,2-propylene glycol, polyglycerins with 2 to 10 glycerin units, panthenol, glycol, butyleneglycol, 1,2-butanediol, 1,4-butanediol, 2,3-butanediol, pentylene glycol and 1,5-pentanediol, (c) one or more oil selected from the group consisting of synthetic oils and natural oils, (d) one or more fatty alcohol which is solid at room temperature (20 C.), and (e) one or more surfactant selected from the group consisting of anionic, amphoteric and cationic surfactants, wherein (i) fatty alcohol to oil weight ratio is less than 1, (ii) weight ratio of surfactant to sum of fatty alcohol and oil is less than 0.25, (iii) oil concentration is 0.5 to 10% by weight calculated to the total of the composition, and (iv) polyol concentration is less than or equal to 2% by weight, calculated to the total of the composition.

2. The composition according to claim 1, wherein the one or more oxidizing agent is hydrogen peroxide.

3. The composition according to claim 2, wherein the hydrogen peroxide is present at a concentration of 1 to 20% by weight calculated to the total of the compositions.

4. The composition according to claim 2, having a pH between 2 and 5.

5. The composition according to claim 1, comprising glycerine as the sole polyol.

6. The composition according to claim 1, wherein the one or more oil is liquid at room temperature.

7. The composition according to claim 1, comprising mineral oil as the sole oil component.

8. The composition according to claim 1, wherein the one or more fatty alcohol is selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and mixtures thereof.

9. The composition according to claim 8, wherein the one or more fatty alcohol is present at a concentration of 0.4 to 9.9% by weight calculated to the total of the composition.

10. The composition according to claim 1, wherein the one or more surfactant is anionic surfactant.

11. The composition according to claim 10, wherein the one or more surfactant is sodium lauryl sulfate.

12. The composition according to claim 1, wherein the one or more surfactant is selected from quaternary ammonium compounds of the general structure ##STR00005## where R.sub.5 is a saturated or unsaturated, branched or non-branched alkyl chain with 8-22 C atoms, or
R.sub.9CONH(CH2).sub.n where R.sub.9 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 1- 4, or
R.sub.10COO(CH2).sub.n where R10 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 1-4, and and R.sub.6, R.sub.7 and R.sub.8 are independent from each other H or lower alkyl chain with 1 to 4 carbon atoms, and X is an anion.

13. The composition according to claim 1, wherein the one or more surfactant is present at a concentration of 0.05 to 4.9% by weight calculated to the total of the composition.

14. An aqueous oxidizing composition for hair comprising: (a) one or more oxidizing agent, (b) one or more polyol selected from the group consisting of glycerin, 1,2-propylene glycol, polyglycerins with 2 to 10 glycerin units, panthenol, glycol, butyleneglycol, 1,2-butanediol, 1,4-butanediol, 2,3-butanediol, pentylene glycol and 1,5-pentanediol, (c) one or more oil selected from the group consisting of synthetic oils and natural oils, (d) one or more fatty alcohol which is solid at room temperature (20 C.), and (e) one or more surfactant selected from the group consisting of anionic, amphoteric and cationic surfactants, wherein (i) fatty alcohol to oil weight ratio is less than 1, (ii) weight ratio of surfactant to sum of fatty alcohol and oil is less than 0.25, (iii) oil concentration is 0.5 to 10% by weight calculated to the total of the composition, and (iv) polyol concentration is less than 1% by weight, calculated to the total of the composition.

15. A process for coloring hair comprising: a) mixing the oxidizing composition according to claim 1 with a composition comprising one or more hair dye, b) applying onto hair a mixture obtained from step a), c) leaving the mixture obtained from step a) on hair for 1 to 45 min, d) rinsing off from hair the mixture obtained from step a).

16. The process according to claim 15, wherein the one or more hair dye is a direct dye.

17. A process for coloring hair comprising: a) mixing the oxidizing composition according to claim 1 with a composition comprising one or more oxidative dye precursors having an alkaline pH, b) applying onto hair a mixture obtained from step a), c) leaving the mixture obtained from step a) on hair for 1 to 45 min, c) rinsing off from hair the mixture obtained from step a).

18. A kit for dyeing hair comprising two or more products, wherein one of the two or more products is the aqueous oxidizing composition according to claim 1.

Description

EXAMPLE 1

(1) TABLE-US-00001 % by weight Oxidizing composition Cetearyl alcohol 2.0 Mineral oil 2.5 Sodium lauryl sulphate 0.2 Glycerin 0.9 Hydrogen peroxide 6.0 Salicylic acid 0.05 Phosphoric acid/sodium phosphate q.s. to pH 2.1 Water to 100 Dyeing composition Decyl glucoside 0.1 Sodium laureth sulphate 0.1 Polyquaternium - 7 0.5 Sodium sulphite 0.5 Ascorbic acid 0.5 Monoethanol amine 4.0 Ammonium hydroxide 4.0 EDTA di sodium salt 0.5 Ethanol 10.0 4-amino-m-cresol 0.35 4-amino-2-hydroxytoluene 0.2 2-Hydroxyethyl-p-phenylenediamine sulfate 0.15 m-aminophenol 0.1 Resorcinol 0.2 2,5,6-triamino-4-pyrimidinol sulphate 0.05 2-amino-6-chloro-4-nitrophenol 0.11 Fragrance 0.5 Water q.s. to 100 pH of the above composition was 9.8.

(2) The above oxidizing and dyeing compositions were mixed at a weight ratio of 1:1 and the mixture had a pH of 9.8.

(3) Partial grey and damaged hair was dyed with the above compositions. It was observed that the hair was dyed homogeneously and grey coverage was 100%.

EXAMPLE 2

(4) TABLE-US-00002 % by weight Oxidizing composition Behenyl alcohol 2.0 Isopropyl myristate 2.5 Behentrimonium chloride 0.2 Panthenol 0.9 Hydrogen peroxide 6.0 Salicylic acid 0.05 Phosphoric acid/sodium phosphate q.s. to pH 3.1 Water to 100 Dyeing composition 4-amino-m-cresol 0.4 4-amino-2-hydroxytoluene 0.2 2-Hydroxyethyl-p-phenylenediamine sulfate 0.15 m-aminophenol 0.1 Resorcinol 0.2 Basic red 51 0.5 Basic orange 31 0.5 Basic yellow 87 0.2 HC red 3 0.5 Ammonium hydroxide 8.0 Ceteareth-30 0.2 Water to 100 pH of the above composition was 9.8.

(5) The above oxidizing and dyeing compositions were mixed at a weight ratio of 1:1 and the mixture had a pH of 9.5.

(6) Partial grey and damaged hair was dyed with the above compositions. It was observed that the hair was dyed homogeneously and grey coverage was 100%.