Coaxial material-stirring lance and method of use
10240218 ยท 2019-03-26
Inventors
Cpc classification
C21C7/0075
CHEMISTRY; METALLURGY
F27D2003/169
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D3/0033
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
C21C7/00
CHEMISTRY; METALLURGY
F27D3/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D3/16
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A coaxial material-stirring lance (40) and method used to treat molten metal in a ladle, the lance having a stirring gas chamber (48), and a plurality of gas permeable ports (50 52) arranged as upper and lower port arrays along a length of the gas chamber, and at least one material chamber (43) positioned inside and coaxial with the gas chamber and terminating in at least one material ports (60). In another embodiment, a second material chamber is included inside the gas chamber, parallel to and immediately adjacent the material chamber. In use, the coaxial material-stirring lance is lowered into the ladle of molten metal, and gas and material are both introduced into a respective chamber. Gas mixes material through the molten metal, causing impurities to be removed from the metal.
Claims
1. A coaxial material-stirring lance (40) for use in a hot metal desulfurization process performed in a mill having a motorized lance drive with a lance weight support capacity, a ladle holding a predetermined quantity of hot metal, and a gas manifold supplying a gas supply, where the coaxial material-stirring lance is supported by the motorized lance drive in the predetermined quantity of hot metal in the ladle, the coaxial material-stirring lance comprising: a gas chamber (48) having a first end and a terminal end, and a length between the first end and the terminal end defining a chamber wall, the chamber wall further defining an interior space having an interior wall side facing the interior space and an opposed outer wall side; a refractory coat (46) encasing an exterior of the coaxial material-stirring lance; a gas connection pipe (44) at the first end coupled to the gas manifold and to the gas supply; at least one material chamber (43) defined by a material chamber wall having at a first end a material connection pipe (42) and at a second end terminating in at least one material discharge port (60); a port disposed as a gas permeable structure having a body formed with an inlet at one end and an opposed outlet, the inlet positioned against the opposed outer wall side and secured to a through-hole formed into the chamber wall, and the outlet positioned relative to the refractory coat so as to allow fluid communication between the interior space of the gas chamber and an exterior area beyond the refractory coat through the port; and a weight of the coaxial material-stirring lance (40); wherein the weight of the coaxial material-stirring lance is a same weight as the lance weight capable of support by the motorized lance drive; wherein the refractory coat encases both the outer wall side and an exterior of the body of the port; wherein the outlet has an outlet diameter measurement between about 0.5 cm to about 13 cm; wherein the port is further comprised of a bottom port (51) and at least one of an upper port (50) and a lower port (52) in vertical spaced-apart relationship with the bottom port; wherein the bottom port and the at least one of the upper port and the lower port is at least one of a pipe, a porous plug, a directional plug, and a nozzle; and wherein the material chamber (43) is positioned inside the gas chamber (48) so as to create a pair of coaxial chambers.
2. The coaxial material-stirring lance (40) in claim 1, wherein the material chamber (43) terminates in a pipe having a pair of opposed material discharge ports (60), forming a T-configuration.
3. The coaxial material-stirring lance (40) in claim 1, wherein the upper port (50) is an upper array having a plurality of ports arranged in a cross-shaped orientation (54) having two pairs of opposed ports leading from the gas chamber (48).
4. The coaxial material-stirring lance (40) in claim 3, wherein the lower port (52) is a lower array having a plurality of ports arranged in an cross-shaped orientation (54) having two pairs of opposed ports leading from the gas chamber (48) and in relation to the upper array, the lower array is turned approximately 45 degrees such that the upper array has a cross-shaped orientation and the lower array has an X-shaped orientation, the upper array and the lower array arranged in alternating cross and X-shaped orientations.
5. The coaxial material-stirring lance (40) in claim 1, wherein the upper port is an upper array comprised of a pair of opposed ports (56).
6. The coaxial material-stirring lance (40) in claim 5, wherein the lower port is a lower array comprised of a pair of opposed ports (56) oriented in relation to the upper array such that the lower array is turned 90 degrees relative to the upper array and wherein the upper array and lower array are arranged in an alternating pattern.
7. The coaxial material-stirring lance (40) of claim 1, wherein the at least one of the upper port (50) and the lower port (52) is a spiral array (58) of ports about the chamber wall having at least two ports in vertical spaced-apart relationship about the chamber wall separated by no more than 45 degrees about the chamber wall such that the at least two ports are vertically unaligned.
8. The coaxial material-stirring lance (40) of claim 7, wherein at least one of the upper port, middle port, and lower port of the spiral array (58) of the upper port (50) has a smaller outlet diameter measurement relative to another outlet diameter measurement of at least one of the upper port, middle port, and lower port of the spiral array (58) of the lower port (52).
9. The coaxial material-stirring lance (40) of claim 1, further comprising a second material chamber (43) adjacent to and parallel to the material chamber (43); wherein the second material chamber (43) has a material connection pipe (42) at a first end and terminates in at least one material discharge port (60) at a second end; and wherein the second material chamber (43) is positioned inside the gas chamber (48).
10. A method of using the coaxial material-stirring lance (40) of claim 1, during a hot metal desulfurization purification process using an existing motorized lance drive with a maximum lance weight support capacity to support the coaxial material-stirring lance, a quantity of hot metal in a ladle having a predetermined volume and size, a gas manifold with a gas supply, and a desulfurizing material, the method comprising the steps of: Positioning the coaxial material-stirring lance vertically into the ladle of hot metal; Introducing a quantity of desulfurizing material into the material chamber; Introducing a volume of stirring gas into the gas chamber; Discharging the quantity of desulfurizing material from the material chamber through a material port and into the hot metal; and Discharging the volume of stirring gas through at least the bottom port into the hot metal.
11. The method of claim 10, wherein the steps of discharging the quantity of material and discharging the volume of stirring gas is performed simultaneously.
12. The coaxial material-stirring lance of claim 1, wherein the bottom port (51) has a first outlet diameter measurement and the at least one of the upper port (50) and the lower port (52) has a second outlet diameter measurement.
13. A method of using the coaxial material-stirring lance (40) of claim 9, during a hot metal desulfurization purification process using an existing motorized lance drive with a maximum lance weight support capacity to support the coaxial material-stirring lance, a quantity of hot metal in a ladle having a predetermined volume and size, a gas manifold with a gas supply, and a desulfurizing material, the method comprising the steps of: Positioning the coaxial material-stirring lance vertically into the ladle of hot metal; Introducing a quantity of desulfurizing material into the material chamber; Introducing a volume of stirring gas into the gas chamber; Discharging the quantity of desulfurizing material from the material chamber through a material port and into the hot metal; and Discharging the volume of stirring gas through at least the bottom port into the hot metal.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The features and advantages of the invention will become apparent from a consideration of the subsequent detailed description presented in connection with accompanying drawings, in which:
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DRAWINGS LIST OF REFERENCE NUMERALS
(19) The following is a list of reference labels used in the drawings to label components of different embodiments of the invention, and the names of the indicated components. 2 ladle 4 slag pot 5 desulfurization reagent or material 6 hot metal 6a surface of hot metal 8 ladle spout 10 gas bubbles 24 slag 40 coaxial material-stirring lance 42 material connection pipe 43 material chamber 44 gas connection pipe 46 refractory coating 48 stirring gas chamber or gas chamber 50 upper stirring port or upper port 51 bottom stirring port or bottom port 52 lower stirring port or lower port 54 first port array embodiment or cross-shaped port array 56 second port array embodiment or opposed port array 58 third port array embodiment or spiral port array 60 material discharge port
GLOSSARY OF IMPORTANT TERMS
(20) Hot metal or molten metal: metal heated to a temperature such that the metal is in a liquid state, and includes metals commonly purified by heating in a ladle such as steel and iron
(21) Material: desulfurization reagent or reagents
(22) Port: a structure capable of passing gas, including but not limited to porous plugs, pipes, and nozzles
DETAILED DESCRIPTION
(23) A coaxial material-stirring lance 40 and method of use is shown in
(24) Turning now to
(25) Turning now to
(26) Turning now to
(27) For both the first port array and second port array, turning to
(28) Turning now to
(29) In
(30) In
(31) Turning to
(32) In
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(34) Turing now to
(35) When the coaxial material-stirring lance 40 is in use, the material 5 is dispersed from the material ports 60 and stirring gas bubbles 11 are emitted from any combination of upper, lower, and bottom gas ports 50 52 51 creating turbulence in the hot metal 6. The inventor notes that the ports 50 51 52 of the coaxial material-stirring lance can be configured, when desired, to have only functioning lower and bottom ports, for instance, or only functioning lower ports, or any other combination, including a single port, typically a bottom port 51, at or near the lowermost end of the gas chamber as desired. The port arrays 54 56 58 create different stirring gas patterns in the hot metal, and result in greater dispersion of the material 5 in the hot metal, and thus in greater efficiency, plus reduces the quantity of material 5 needed during desulfurization and the final result is a more consistent end product. The slag 24 on the surface 6a can then be removed using conventional methods, typically with a paddle or other skimming apparatus.
(36) The inventor is recently aware of a recent coaxial lance described in U.S. Pat. No. 9,206,487 B2 (Hicks), disposed as an inner tube and an outer tube (or gap as termed by Hicks), into which stirring gas is introduced either into the inner tube, which then moves into the outer tube via channels formed into the inner tube, or pumped directly into the outer tube, before being expelled out the end of the lance and into the hot metal. Material and gas in some embodiments are also mixed inside the lance in a mixing chamber (Hicks'
(37) The inventor notes that his coaxial material-stirring lance 40 as described herein is different from the lance in Hicks in many important ways: (1) material and gas are housed in separate, coaxial but independently operating chambers and material and gas never mix inside the lance 40; (2) material is expelled from the material chamber through specific material ports 60 and gas is expelled from the gas chamber through specific gas ports 50 51 52, and never does material and gas exit the lance 40 via a same port; (3) the gas chamber is always the outermost chamber, and has at least one port formed along the length of the gas chamber through the refractory coating through which gas is directly expelled into the hot metal, and in the embodiments described herein, several describe multiple gas ports and multiple port patterns and zones of ports formed into the length of the gas chamber allowing gas to be introduced into the hot metal not just near a bottom of the lance but along the entire length of the lance; and (4) the ability to control the volume of gas introduced to the hot metal and by varying port size and array, create areas inside the ladle in which lower volumes of gas are emitted but in other areas where higher gas volumes are desired, the ability to increase the volume of gas in those areas using a single lance and a single gas chamber and source of gas.
(38) In contrast, gas in Hicks moves between communicating inner and outer tubes prior to expulsion out the bottom of the lance and into the hot metal. Under no circumstances does the gas ever leave the outer tube directly through channels formed into the outer tube through the refractory coating and directly into the hot metal as is the case with the present invention. Gas in Hicks moves between the inner and outer tubes, or between a series of interconnected tubes stacked end on end, so contents of the inner and outer tubes can mix inside the inner tube. The inventor notes that the Hicks lance shows gas only exiting the lance at or near the bottom of the lance, due to the presence of the various internal seals creating a series of stacked end-on-end, interconnected internal pressure chambers for gas and/or internal mixing chambers for gas and material. For these chambers to work as designed, they must be large enough to create the desired internal pressure and/or hold enough material and gas for mixing, and having gas and/or material exit the lance anywhere other than at or near the bottom of the lance would be impractical and render the internal interconnected chambers meaningless, as each interconnected chamber relies on the happenings inside the internal chamber above it. Further, Hicks cannot vary the volume of gas flowing out of any port into the hot metal; gas exits the lance at the same rate, and only inside the Hicks lance can the pressure of the gas stored be varied, via the series of internal chambers and seals.
(39) In short, the inventor believes his invention is superior to the Hicks lance due to the gas port locations, the plurality of ports used along the length of the gas chamber, and the gas port arrays, particularly the spiral array, which allow greater gas and material dispersion inside the ladle. Hicks believes that mixing gas and material inside the lance prior to introduction into the hot metal increases dispersion of the material into the hot metal when a single exit port is used, but the inventor believes his gas port locations, gas port arrays, and the ability to have different volumes of gas emitted in spatially different parts of the ladle results in superior mixing of the material with the hot metal overall and thus superior efficiency in removing impurities as compared to Hicks or any of the prior art.
(40) The inventor notes that while
(41) The inventor notes the stirring gas can be introduced into the hot metal with or without material also being introduced, providing the mill operator flexibility of use of the coaxial material-stirring lance 40. The inventor stresses that his use of the term port, in the singular or plural, includes any gas permeable structure such as porous plugs, nozzles, and pipes, and the Figures that show porous plugs, for instance,
(42) The inventor notes the coaxial material-stirring lance 40 provides many benefits to the mill operator. The weight of the lance 40 for instance, is essentially the same as that of a standard prior art lance. Thus the coaxial material-stirring lance 40 can be installed onto an existing lance drive system with no structural modifications required. The only modifications to the lance drive system consist of an additional gas manifold and an additional hose to a top of the lance 40 to deliver gas to the lance 40, relatively simple and inexpensive modifications.
(43) The inventor notes the coaxial material-stirring lance allows for significant cost reductions and efficiency/quality increases to the mill operator. Steelmaking efficiency is improved without incurring the additional capital equipment cost as required by the prior art systems, and as the coaxial material-stirring lance 40 is a combined material and gas stirring lance, only a single lance must be replaced. The mill operator may use gas only, material only, or have gas and material introduced into the hot metal simultaneously, or at different times or different frequencies, as desired, allowing the mill operator the most flexibility and functionality with a single lance. The dual material chamber embodiment represents significant cost savings for the mill operator, as a single lance (and its requisite equipment) can achieve a same or better results as the dual material lance systems previously patented, and without substantive capital investment by the mill operator.
(44) It is to be understood the above-described arrangements are only illustrative of the application of the principles of the present invention. Numerous modifications and alternative arrangements may be devised by those skilled in the art without departing from the scope of the present invention. For instance, the invention is shown as being generally cylindrical in shape, with a circular cross section, however other shapes, such as triangular and hexagonal prisms, with triangular and hexagonal cross sections, cubes and cuboid, with square and rectangular cross sections, or other three dimensional shapes, even spherical or irregular can also be used. The coaxial combination of gas and material chambers in a single lance, the port arrays which maximize mixing of material within the hot metal, and the ability to control the volume and/or rate of flow of stirring gas via port size, type, and location are key features of the coaxial material-stirring lance. Whether the coaxial chambers have square or other shaped cross sections, or flat walls versus curved, are variations that are inconsequential to the functioning of the invention, and the circular cross sections shown in the Figures are not meant to exclude these other possible shapes for the coaxial chambers but are just an example of one possible useful shape.