METHODS AND APPARATUS FOR GENERATING A MIXED REFRIGERANT FOR USE IN NATURAL GAS PROCESSING AND PRODUCTION OF HIGH PURITY LIQUEFIED NATURAL GAS
20190086147 ยท 2019-03-21
Inventors
Cpc classification
F25J2235/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/025
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0219
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0238
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0035
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2260/20
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2290/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2240/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0045
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/004
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2220/66
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0233
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/70
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0055
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0209
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2290/80
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2230/32
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0022
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2215/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2230/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2220/68
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J1/0231
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2270/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A novel method and system for liquefying and distilling raw natural gas into NGL and liquid methane (LNG) product streams, with at least one novel feature including the use of a mixed refrigerant comprising naturally occurring natural gas liquids that were recovered from the inlet gas stream being processed. Heat exchangers and distillation towers are configured to produce high purity liquefied natural gas (LNG) and NGL product streams, utilizing liquid NGL as the process refrigerant for both systems.
Claims
1. A method of operating a gas processing plant by using an NGL product from the gas processing plant as a mixed refrigerant for liquefying an inlet hydrocarbon gas being introduced to said gas processing plant, wherein said liquefied inlet hydrocarbon gas is further processed into the NGL product and a methane rich residue gas the method comprising: introducing the inlet hydrocarbon gas to a first heat exchange unit utilizing a mixed refrigerant to produce a cooled hydrocarbon gas having a liquid portion and a vapor portion; flowing the liquid and vapor portions to a first pressurized distillation tower; flowing a vapor product of hydrocarbons comprising methane rich residue gas from the first pressurized distillation tower; flowing NGL product from the first pressurized distillation tower; flowing said NGL product to at least the first heat exchange unit said NGL product to be used as the mixed refrigerant to aid in cooling of the hydrocarbon gas.
2. The method of claim 1, further comprising vaporizing at least a portion of the mixed refrigerant forming a mixed refrigerant vapor portion and a mixed refrigerant liquid portion, separating the mixed refrigerant vapor portion from the mixed refrigerant liquid portion, recompressing and condensing that vapor portion and recombining with the liquid portion to form a final NGL product.
3. The method of claim 1, wherein the NGL product contains a percentage of ethane and methane, the method further comprising: flowing the methane rich residue gas to an LNG liquefaction unit utilizing a mixed refrigerant; providing the NGL product to the LNG liquefaction unit for use as the mixed refrigerant; and, liquefying the methane rich natural gas in the LNG liquefaction unit using the NGL product as the mixed refrigerant to liquefy the methane rich natural gas into Liquid Natural Gas (LNG).
4. The method of claim 3, further comprising vaporizing at least a portion of the mixed refrigerant forming a mixed refrigerant vapor portion and a mixed refrigerant liquid portion and separating the mixed refrigerant vapor portion from the mixed refrigerant liquid portion.
5. The method of claim 4, wherein the mixed refrigerant vapor portion is utilized as the mixed refrigerant in the process used to liquefy methane rich natural gas (LNG) while the mixed refrigerant liquid portion is delivered as a final NGL product.
6. The method of claim 5, wherein the mixed refrigerant generated for use in the LNG process may be used in an open loop process or as make-up into a closed loop process.
7-16. (canceled)
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20. A method of operating a liquefaction unit to liquefy methane rich natural gas into liquid natural gas (LNG), the method comprising: introducing methane rich natural gas from a gas processing plant to a liquefaction unit utilizing a mixed refrigerant; providing NGL product to the liquefaction unit for use as the mixed refrigerant, wherein the NGL product contains methane and ethane, and wherein the NGL product is from said gas processing plant, or another gas processing plant; and, liquefying the methane rich natural gas in the liquefaction unit using the NGL product as the mixed refrigerant to liquefy the methane rich natural gas into Liquid Natural Gas (LNG).
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0019] The following drawings are provided merely to illustrate a few non-limiting embodiments of the present invention, and are not meant to limit the scope of the claims of the invention.
[0020] For simplicity and clarity of illustration, the drawing figures illustrate the general manner of construction, and description and details of well-known features and techniques may be omitted to avoid unnecessarily obscuring the invention. Additionally, elements in the drawing figures are not necessarily drawn to scale, some areas or elements may be expanded to help improve understanding of embodiments of the invention.
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DETAILED DESCRIPTION OF THE INVENTION
[0031] The innovative teachings of the present invention will be described with particular reference to few non-limiting embodiments (by way of example, and not of limitation). The present invention describes several embodiments, and none of the statements below should be taken as limiting the claims generally.
[0032] The present invention discloses new approaches, both methods and apparatus, to take advantage of the produced Natural Gas Liquids (NGL) from gas processing plants and use these liquids as a refrigerant for both the Gas Processing Plant and a natural gas liquefaction plant (LNG Plant). The present invention takes advantage of the naturally occurring elements contained in the raw natural gas stream entering the Gas Processing Plant facility, without need of importing or storing components that are outside of the naturally occurring components, such as ethylene, propylene, nitrogen, butylene, etc. The new invention method also demonstrates ways in which to improve the overall efficiency and performance of the LNG Plant mixed refrigeration system.
[0033] The methodology for the non-limiting system described herein is based upon processing of raw natural gas streams and utilizing the recovered hydrocarbon liquids (NGL Product) from the Gas Processing Plant as the refrigerant for both the Gas Processing Plant and, if present, the LNG Plant. This methodology may be utilized with any of the common Gas Processing technologies in use today. Simply stated, rather than operating the Gas Processing Plant in the conventional manner, to deliver a NGL Product from the plant fractionation tower to pipeline for sale, a portion of the NGL Product may be recycled, in an open loop, back through the plant heat exchange loop providing refrigeration duty for the process. A portion of the exiting refrigerant from the heat exchange loop may be vapor; if the refrigerant is comprised of two phases, the vapor and liquid portions are separated, with the liquid being pumped to required sales pressure and the vapor portion being compressed and condensed for comingling with the liquid portion for product sales. The system allows for fully integrated heat exchange using Process Heat Exchangers and a minimal number of other pieces of process equipment, thus maintaining a minimal Plot Area. And since the refrigerant (NGL Product) is already a liquid when it exits the fractionation tower, there is no need for a closed loop Refrigerant Compressor System to be installed in the Gas Processing Plant.
[0034] The NGL Product from the Gas Processing Plant may also be utilized to generate the mixed refrigerant to be used in the LNG Plant refrigeration process and is much more robust and flexible than other mixed refrigerant systems which commonly use components that are not naturally occurring in gas feed streams and must be stored on site.
[0035] The system does not require use of any turbo expander machinery, though these items may be used to improve overall system efficiency. The Gas Processing Plant and LNG Liquefaction Plants utilize any commonly used technology; however, the refrigeration requirement is provided via the mixed refrigerant which is the NGL Product. As the refrigerant is generated as liquid from the fractionation tower within the Gas Processing Plant, there is no need for a closed loop refrigerant compression within the Gas Processing Plant design. Vaporized refrigerant from the Gas Processing Plant may be captured for further fractionation, used as make-up to the LNG Plant mixed refrigerant, used as fuel gas or condensed and routed to pipeline. The open loop mixed refrigerant system is significantly more efficient than a single component, closed loop refrigerant system, thus minimizing energy input and reducing overall atmospheric emissions by eliminating equipment and storage requirements. This invention may be a standalone system as a mixed refrigerant for natural gas processing and recovery of Natural Gas Liquids (NGL) as well as being used as a mixed refrigerant in the process of recovering methane (LNG) as a liquid.
[0036] As will be recognized by those skilled in the art, the innovative concepts described in the present invention may be modified and varied over a tremendous range of applications, and accordingly the scope of patented subject matter is not limited by any of the specific exemplary teachings given. It is intended to embrace all such alternatives, modifications and variations that fall within the spirit and broad scope of the appended claims.
[0037] This method and system will meet all of the necessary refrigeration functions required of a typical Gas Processing Plant and LNG facility, of any size or Inlet Gas composition, but in a much more efficient and cost effective manner. This method and system allows for combining Gas Processing for NGL recovery and LNG liquefaction into one plant location while it eliminates the need for separate refrigeration systems, reduces compression requirements, eliminates use of special refrigerants and the storage required for them, and thereby requires less equipment, thus minimizing the overall plant footprint, reducing emissions and lowering capital and operating costs.
[0038] In one embodiment, a system for liquefying and distilling raw natural gas in a NGL processing facility to recover natural gas components as liquid products (NGL) that meets all Y-Grade product specifications and then using the NGL Product as a mixed refrigerant.
[0039] In one embodiment, a system for liquefying and distilling high quality methane gas in a LNG Liquefaction Plant using a system generated mixed refrigerant from the NGL Product.
[0040] Because the NGL is a finished product coming out of the Gas Processing Plant, the system may operate under an open loop design, and the need for a closed loop refrigerant system within the Gas Processing Plant design may therefore be eliminated. Additionally, the Gas Processing Plant may be operated in a slightly different mode to generate a mixed refrigerant that may not only provide the refrigerant service for the Gas Processing Plant, but also be used as the feedstock for the mixed refrigerant system used in a LNG Liquefaction Plant.
[0041] The present system may provide the necessary refrigeration duty for essentially any Gas Processing Plant technology currently used within the Oil & Gas Industry, as well as be used to generate and provide the mixed refrigerant necessary for LNG liquefaction, while minimizing capital and operating costs, reducing energy input and reducing overall atmospheric emissions.
[0042] The terms first, second, third, fourth, and the like in the description and the claims, if any, may be used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the terms so used are interchangeable. Furthermore, the terms comprise, include, have, and any variations thereof, are intended to cover non-exclusive inclusions, such that a process, method, article, apparatus, or composition that comprises a list of elements is not necessarily limited to those elements, but may include other elements not expressly listed or inherent to such process, method, article, apparatus, or composition.
[0043] The necessary materials and facilities for gas feeding and gas pipes, heat exchange material, controlling valves are known arts in the field. Other enabling descriptions may be found in the US Patent Application Publication US 2011/0259044 A1 the entirety of which is hereby incorporated by reference.
[0044] Referring now to
[0045] The pretreatment and molecular sieve system 102 is well known in gas processing and is designed to remove water and carbon dioxide (CO2) from the inlet gas in order to prevent freezing in the gas processing plant and is a typical system for essentially all cryogenic gas processing plants. It is believed that any suitable commercially available pretreatment and molecular sieve system may be utilized in the practice of the present invention.
[0046] The inlet stream 1 is separated in vessel VSSL-100 into liquid stream 16 and inlet gas stream 1 which is feed to molecular sieve system 102, exiting as treated inlet gas 2 that then flows to the cryogenic gas processing plant for recovery of the ethane and heavier hydrocarbon components from the treated gas stream.
[0047] The treated inlet gas 2 from pretreatment is chilled and partially condensed in the first process heat exchanger system 103A, exchanging heat with several product and process streams (6D, 7 and 9), exiting as chilled and partially condensed stream 13, passing through valve VLVE-100 as stream 13A before being fed to the cold separator 105. The vapor portion stream 4 off the cold separator 105 is split with a portion 4A flowing to the second process heat exchanger 103B where the stream is condensed and sub-cooled, exiting as stream 4L which is then fed to the top of the fractionation tower 109 and the remaining portion 4B is fed to the expander 107A where the gas is work expanded exiting as stream 4M and fed to the fractionation tower 109. Please note, that while tower 109 is illustrated as having 10 stages, any suitable number of stages could be utilized, and streams 4L, 4M, 3M, Q5, and 18 may enter tower 109 at any suitable stage as desired not just at the stages as shown. Cold liquids stream 3 from the cold separator is flashed, via level control, through valve VLVE-101 and are routed as stream 3M to an intermediate point of fractionation tower 109.
[0048] Fractionation tower 109 is a distillation tower with multiple sections that may operate over a wide range of conditions as necessary to generate the desired Natural Gas Liquid (NGL) product from the bottom of the tower stream 5. The vapor overhead from the fractionation tower 109 stream 6 is that remaining portion of the treated inlet gas stream 2 not recovered as liquid stream 5 from the bottom of the fractionation tower 109. This residue gas stream 6 is then typically used to provide a portion of the gas processing plant 100 heat exchange cooling duty in process heat exchangers 103B (as stream 6C) and 103A (as stream 6D) before exiting as stream 6H and being compressed in compressor 107B. Please note that VLVE-103 may or may not be present in each embodiment. Exiting as stream 24, it is then passed through heat exchanger XCHG-100 exiting as stream 6S and routed to sales or fed to a LNG liquefaction plant 130.
[0049] The above described gas processing system is one example of many different processing technologies currently in use. No matter the technology used, there has been and still remains a long standing need in many cases to include additional refrigeration within the system to attain the desired recovery levels of heavy hydrocarbons into a liquid NGL product or to provide a specific quality of residue gas for feed to a pipeline or LNG liquefaction plant. Additionally, if a LNG liquefaction plant is present, a refrigerant capable of supplying the necessary level of cryogenic refrigeration must be provided the entirety of which is hereby incorporated within the embodiments of the invention.
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[0059] To improve the efficiency and performance of the LNG liquefaction Plant 130 and the mixed refrigerant system 132 the present invention utilizes several unique features including partial condensation of the mixed refrigerant stream 50 in the first heat exchange unit 133; separation of stream 50 into its liquid stream 52 and its vapor stream 54 in separator 135 and using each stream as separate refrigerant supply streams to the LNG process heat exchanger 140; use of flashed LNG vapor streams 150 and 154 and a portion of LNG liquid stream 152 as refrigerant streams in the LNG process heat exchanger 140.
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[0061] Some non-limiting embodiments of the present invention may utilize the finished NGL Product from a Gas Processing Plant as an open loop, single mixed refrigerant, to provide required refrigeration duty to the Gas Processing Plant.
[0062] Some prior art designs use an internal heat pump to provide system refrigeration and reboiler heat that is subject to the internal operation of the plant process and results in difficult and inefficient operation. These are also not open-loop designs. Use of the finished NGL Product, in an open loop manner, allows for much more efficient control and easier operation.
[0063] It should be noted that the amount of NGL generated should always be sufficient to provide the required refrigeration needs for the Gas Processing Plant.
[0064] In the practice of the present invention, the leaner the Inlet Gas stream is in C2+, the less process refrigeration that is required; thus, even though there is less NGL produced, less is required for Plant refrigeration needs. Conversely, the richer the inlet gas, the more refrigeration is required to condense and recover the NGL products; but, the increased NGL production provides the additional refrigeration duty requirements.
[0065] In some non-limiting embodiments, only a portion of the NGL Product stream may be used as refrigerant within the Plant, thus minimizing the amount of vaporized refrigerant that must be recompressed and condensed for remixing with rest of NGL Product to sales.
[0066] Simulations show that this type of open-loop, mixed refrigerant system will require 15% to 20% less overall refrigerant compression horsepower than a typical closed-loop propane refrigerant system.
[0067] Some non-limiting embodiments of the present invention provide a means to generate and utilize a single mixed refrigerant stream for use in both Natural Gas Processing, for the recovery of a NGL Product, and for the liquefying of the methane-rich Residue Gas stream into Liquefied Natural Gas (LNG).
[0068] Various non-limiting embodiments of the present invention provide a single mixed refrigerant system to provide cooling duty for both Gas Processing and LNG liquefaction processes.
[0069] Various non-limiting embodiments of the present invention provide that the NGL Product from the Gas Processing Plant is utilized to make-up refrigerant into the LNG Plant mixed refrigerant system.
[0070] In various non-limiting embodiments of the present invention, and depending on the amount of LNG to be produced, the NGL Product may be used in an open-loop configuration, or made up into a closed-loop system on a batch basis.
[0071] In various non-limiting embodiments of the present invention, when making up into a closed-loop, mixed refrigerant system for the LNG Liquefaction Plant, the composition of the NGL Product, from the Gas Processing Plant, may be easily modified to include additional methane and other light-end components into the mixed refrigerant stream.
[0072] For some non-limiting embodiments of the present invention, maintaining a specific and constant refrigerant composition is not a requirement for proper operation of this new invention.
[0073] For some non-limiting embodiments of the present invention, the refrigerant consists of only those components that are naturally occurring within the natural gas feed stream into the Gas Processing Plant.
[0074] For some non-limiting embodiments of the present invention, some changes in the refrigerant composition are acceptable, without effect on the overall system operation.
[0075] Some non-limiting embodiments of the present invention have an advantage over prior art design, in that those designs require addition of components that do not naturally occur in natural gas feed streams, such as Propylene, Ethylene and Butylene.
[0076] For some non-limiting embodiments of the present invention, due to specific compositional requirements, on-site storage of these components is oftentimes required.
[0077] For some non-limiting embodiments of the present invention, if a change in composition is required for process operation, this may be done manually and with a shutdown of the system.
[0078] Some non-limiting embodiments of the present invention encourage the combination of Gas Processing and Natural Gas Liquefaction into one facility, whereas this is almost never done currently. By doing both operations at the same time, at the same facility, the following benefits may be realized.
[0079] For some non-limiting embodiments of the present invention the Inlet Gas only has to be treated for CO2, H2S and water removal one time, at the inlet to the Gas Processing Plant.
[0080] For some non-limiting embodiments of the present invention, the C2+ hydrocarbons from the Inlet Gas may be recovered within the Gas Processing Plant, making the feed gas to the LNG Liquefaction Plant suitable for liquefaction without freezing concerns.
[0081] It should be noted that not all gas fed into Sales Gas Pipelines are free of the above contaminants, and that most LNG Liquefaction take their feedstock directly off of pipelines, meaning LNG Feed Gas has to again be treated for removal of CO2, H2S and water; and, LNG Feed Gas may need to be processed for removal of heavy-end hydrocarbons.
[0082] For some non-limiting embodiments of the present invention Using a single mixed refrigerant to act in providing cooling duty to both the Gas Processing Plant and LNG Liquefaction Plant reduces the amount of equipment and storage facilities required to perform refrigeration duties for both plants.
[0083] None of the description in the present invention should be read as implying that any particular element, step, or function is an essential element which must be included in the claim scope: THE SCOPE OF PATENTED SUBJECT MATTER IS DEFINED ONLY BY THE ALLOWED CLAIMS. Moreover, none of these claims are intended to invoke paragraph six of 35 USC section 112 unless the exact words means for are followed by a participle.
[0084] The claims as filed are intended to be as comprehensive as possible, and NO subject matter is intentionally relinquished, dedicated, or abandoned.