LIQUID CRYSTAL MEDIUM

Abstract

A liquid crystal medium comprising one or more compounds of formula PT and one or more compounds of formula GF and/or UI

##STR00001## in which the occurring groups and parameters have the meanings defined in claim 1. Also, high-frequency components comprising these media, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, tunable filters, tunable metamaterial structures, and electronic beam steering antennas, e.g. phased array antennas.

Claims

1. A liquid-crystal medium comprising one or more compounds of formula PT ##STR00446## in which R.sup.P denotes H or straight-chain alkyl having 1 to 12 C atoms branched alkyl having 3 to 12 C atoms, straight-chain alkenyl having 2 to 12 C atoms, or branched alkenyl having 3 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00447## and where one or more non-adjacent CH.sub.2-groups may be replaced by O, ##STR00448## denotes ##STR00449## in which L.sup.1, L.sup.2 and L.sup.3, identically or differently, denote H, F, Cl or alkyl having 1 to 6 C atoms, t.sub.1 is 0 and t.sub.2 is 1, or t.sub.1 is 1 and t.sub.2 is 0; the medium further comprising one or more compounds selected from the group of compounds of the formulae GF and UI ##STR00450## in which R.sup.G and R.sup.U have the meanings given for R.

2. The medium according to claim 1, wherein the group ##STR00451## in formula PT denotes ##STR00452##

3. The medium according to claim 1, wherein the one or more compounds of the formula PT are selected from the group of compounds of the formulae PT-1 to PT-4: ##STR00453## in which R.sup.P denotes straight chain alkyl having 1 to 7 C atoms or branched alkyl having 3 to 9 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00454##

4. The medium according to claim 1, wherein the medium additionally comprises one or more compounds selected from the group of compounds of the formulae I, II and III: ##STR00455## in which R.sup.1 denotes H, non-fluorinated alkyl having 1 to 12 C atoms, or non-fluorinated alkenyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00456## where one or more non-adjacent CH.sub.2-groups may be replaced by O, n is 0, 1 or 2, ##STR00457## on each occurrence, independently of one another, denote ##STR00458## In which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denote ##STR00459## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, ##STR00460## denotes ##STR00461## and wherein ##STR00462## alternatively denotes ##STR00463## in which R.sup.L has the meanings defined above for ##STR00464## R.sup.2 denotes H, non-fluorinated alkyl having 1 to 12 C atoms, or non-fluorinated alkenyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00465## where one or more non-adjacent CH.sub.2-groups may be replaced by O, Z.sup.21 denotes trans-CH?CH, trans-CF?CF or C?C, and ##STR00466## denotes ##STR00467## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denotes ##STR00468## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, ##STR00469## denotes ##STR00470## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denotes ##STR00471## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, and wherein the compounds of the formulae GF and UI are excluded from the compounds of the formula II; R.sup.3 denotes H, non-fluorinated alkyl or non-fluorinated alkoxy having 1 to 17 C atoms, or non-fluorinated alkenyl, non-fluorinated alkenyloxy or non-fluorinated alkoxyalkyl having 2 to 15 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00472## one of Z.sup.31 and Z.sup.32 denotes trans-CH?CH, trans-CF?CF or C?C, and the other one, independently thereof, denotes C?C, trans-CH?CH, trans-CF?CF or a single bond, and ##STR00473## Independently of one another, denote ##STR00474## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denotes ##STR00475## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, and wherein ##STR00476## alternatively denotes ##STR00477## in which R.sup.L has the meanings defied above for ##STR00478## denotes ##STR00479## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denotes ##STR00480## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, and wherein the compounds of the formula PT are excluded from the compounds of the formula III.

5. The liquid crystal medium according claim 1, wherein the medium comprises one or more compounds selected from the group of compounds of the formulae I-1 to I-5 ##STR00481## in which L.sup.1, L.sup.2 and L.sup.3, on each occurrence, identically or differently, denote H or F, and R.sup.1 denotes H, non-fluorinated alkyl having 1 to 12 C atoms, or non-fluorinated alkenyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00482## where one or more non-adjacent CH.sub.2-groups may be replaced by O, ##STR00483## denotes ##STR00484## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denote ##STR00485## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, and ##STR00486## denotes ##STR00487##

6. The liquid crystal medium according to claim 1, wherein the medium comprises one or more compounds selected from the group of compounds of the formulae II-1 to II-3 ##STR00488## in which R.sup.2 denotes H, non-fluorinated alkyl having 1 to 12 C atoms, or non-fluorinated alkenyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00489## where one or more non-adjacent CH.sub.2-groups may be replaced by O, ##STR00490## denotes ##STR00491## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denotes ##STR00492## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, and ##STR00493## denotes ##STR00494## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denotes ##STR00495## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F.

7. The medium according to claim 1, wherein the medium comprises one or more compounds of formula III selected from the group consisting of the compounds of the formulae III-1 to III-6 ##STR00496## in which Z.sup.31 and Z.sup.32, independently of one another, denote trans-CH?CH or trans-CF?CF, and in formula III-6 alternatively one of Z.sup.31 and Z.sup.32 may denote C?C and the other groups have the meaning given in claim 1 under formula III, R.sup.3 denotes non-fluorinated alkyl or alkoxy having 1 to 7 C atoms or non-fluorinated alkenyl having 2 to 7 C atoms, and one of ##STR00497## denotes ##STR00498## and the others, independently of one another, denote ##STR00499## where ##STR00500## alternatively denotes ##STR00501##

8. The medium according to claim 1, wherein the medium comprises one or more compounds of formula XII ##STR00502## in which R.sup.12 denotes H, alkyl or alkoxy having 1 to 12 C atoms, or alkenyl, alkenyloxy or alkoxyalkyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00503## or denotes a group R.sup.P, R.sup.P denotes halogen, CN, NCS, R.sup.F, R.sup.FO or R.sup.FS, wherein R.sup.F denotes fluorinated alkyl or fluorinated alkenyl having up to 9 C atoms, Z.sup.121, Z.sup.122 identically or differently, denote CH?CH, CF?CF, CH?CF, CF?CH, C?C or a single bond, X.sup.1, X.sup.2, X.sup.3 and X.sup.4, identically or differently, denote Cl or F, t is 0 or 1, and ##STR00504## denote a radical selected from the following groups: a) the group consisting of 1,4-phenylene, 1,4-naphthylene, and 2,6-naphthylene, in which one or two CH groups may be replaced by N and in which one or more H atoms may be replaced by L, wherein tetrafluoro-1,4-phenylene is excluded, b) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene, bicyclo[1.1.1]pentane-1,3-diyl, 4,4-bicyclohexylene, bicyclo[2.2.2]octane-1,4-diyl, spiro[3.3]-heptane-2,6-diyl, in which one or more non-adjacent CH.sub.2 groups may be replaced by O and/or S and in which one or more H atoms may be replaced by F, c) the group consisting of thiophene-2,5-diyl, thieno[3,2-b]thiophene-2,5-diyl, selenophene-2,5-diyl, each of which may also be mono- or polysubstituted by L, L on each occurrence, identically or differently, denotes F, Cl, CN, SCN, SF.sub.5 or straight-chain or branched, in each case optionally fluorinated, alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12 C atoms.

9. The medium according to claim 1, wherein the medium comprises one or more compounds selected from the group consisting of the compounds of the formulae XII-1 to XII-11 ##STR00505## in which L.sup.1, L.sup.2 and L.sup.3, identically or differently, denote H, F, Cl, methyl, ethyl, n-propyl, isopropyl, cyclopropyl, cyclobutyl, cyclopentyl or cyclopentenyl, and R.sup.12 denotes H, alkyl or alkoxy having 1 to 12 C atoms, or alkenyl, alkenyloxy or alkoxyalkyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00506## or denotes a group R.sup.P R.sup.P denotes halogen, CN, NCS, R.sup.F, R.sup.FO or R.sup.FS, wherein R.sup.F denotes fluorinated alkyl or fluorinated alkenyl having up to 9 C atoms, and X.sup.1, X.sup.2, X.sup.3 and X.sup.4, identically or differently, denote Cl or F.

10. The medium according to claim 1, wherein the medium comprises one or more compounds of the formula I-3 ##STR00507## in which R.sup.1 denotes H, non-fluorinated alkyl having 1 to 12 C atoms, or non-fluorinated alkenyl having 2 to 12 C atoms, in which one or more CH.sub.2-groups may be replaced by ##STR00508## where one or more non-adjacent CH.sub.2-groups may be replaced by O, ##STR00509## denotes ##STR00510## in which R.sup.L, on each occurrence, identically or differently, denotes H or alkyl having 1 to 6 C atoms, or denote ##STR00511## in which one or more H atoms may be replaced by alkyl having 1 to 6 C atoms or F, and ##STR00512## denotes ##STR00513##

11. An electronic component comprising a first substrate and a second substrate facing each other, a liquid crystal layer sandwiched between said substrates, an electrode provided on each substrate or two electrodes provided on only one of the substrates for supplying an electric potential across said liquid crystal layer to drive liquid crystals in a predetermined configuration, wherein the liquid crystal layer comprises the liquid crystal medium according to claim 1.

12. The component according to claim 11, wherein the component is configured for use in high-frequency technology.

13. The component according to claim 11, wherein the component is a liquid-crystal based antenna element, a phase shifter, a tunable filter, a tunable metamaterial structure, a matching circuit or a varactor.

14. A microwave antenna array, wherein it comprises one or more components according to claim 11.

15. The component according to claim 11, wherein the component is a transmissive or a reflective spatial light modulator.

Description

EXAMPLES

[0771] The following examples illustrate the present invention without limiting it in any way. It is clear to the person skilled in the art from the physical properties what properties can be achieved and in what ranges they can be modified. In particular, the combination of the various properties which can preferably be achieved is thus well defined for the person skilled in the art.

Synthesis Examples

Abbreviations

[0772] dist. distilled [0773] DABCO 1,4-Diazabicyclo[2.2.2]octane [0774] THF Tetrahydrofuran [0775] MTB ether Methyl-tert-butyl ether [0776] dist. distilled [0777] XPhos 2-Dicyclohexylphosphino-2,4,6-triisopropylbiphenyl [0778] XPhos Pd G2 Chloro(2-dicyclohexylphosphino-2,4,6-triisopropyl-1,1-biphenyl)[2-(2-amino-1,1-biphenyl)palladium (II) [0779] Pd(amphos)Cl.sub.2 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)-dichloropalladium(II)

Synthesis Example 1: 1-[2-(4-Butylphenyl)ethynyl]-2,5-difluoro-4-isothiocyanato-benzene

Step 1.1: 4-[2-(4-Butylphenyl)ethynyl]-2,5-difluoro-aniline

[0780] ##STR00442##

[0781] XPhos Pd G2 (40 mg, 0.05 mmol), XPhos (24 mg, 0.05 mmol) and copper(I) iodide (4.8 mg, 0.03 mmol) are added to a mixture of 1-butyl-4-ethynylbenzene (4.0 g, 25 mmol), 4-bromo-2,5-difluoro-aniline (5.0 g, 24 mmol) and diisopropylamine (60 ml) in THF (60 ml) under argon atmosphere slightly below the boiling point. The reaction mixture is heated at reflux temperature for 4 h. Then it is allowed to cool to room temperature, and the precipitate is filtered, washed with THF, and the filtrate is concentrated in vacuo. The residue is purified by silica gel chromatography (solvent heptane/MTB ether) to give 4-[2-(4-butylphenyl)ethynyl]-2,5-difluoro-aniline as a brown oil.

Step 1.2: 1-[2-(4-Butylphenyl)ethynyl]-2,5-difluoro-4-isothiocyanato-benzene

[0782] ##STR00443##

[0783] Thiophosgene (2.2 ml, 28 mmol) is slowly added to a solution of 4-[2-(4-butylphenyl)ethynyl]-2,5-difluoro-aniline (7.2 g, 25 mmol) and DABCO (7.1 g, 63 mmol) in dichloromethane (120 ml) at 0? ? C. under argon atmosphere. The reaction mixture is stirred at room temperature for 1 h. Then it is quenched with dist. water and brine. The aqueous phase is separated and extracted with dichloromethane. The combined organic phases are washed with brine, dried (sodium sulfate), filtered and concentrated in vacuo. The residue is purified by silica gel chromatography (solvent heptane/MTB ether) and crystallization (heptane) to give white crystals of 1-[2-(4-butylphenyl) ethynyl]-2,5-difluoro-4-isothiocyanato-benzene.

[0784] Phase sequence K 48 N (23) I.

[0785] ??=8.92

[0786] ?n=0.3776

[0787] ?.sub.1=74 mPas

Synthesis Example 2: 2-[2-(4-Butylphenyl)ethynyl]-1,3-difluoro-5-isothiocyanato-benzene

Step 2.1: 4-[2-(4-Butylphenyl)ethynyl]-3,5-difluoro-aniline

[0788] ##STR00444##

[0789] XPhos Pd G2 (40 mg, 0.05 mmol), XPhos (25 mg, 0.05 mmol) and copper(I) iodide (5 mg, 0.03 mmol) are added to a mixture of 1-butyl-4-ethynylbenzene (4.0 g, 25 mmol) and 3,5-difluoro-4-iodo-aniline (6.3 g, 25 mmol) in diisopropylamine (60 ml) and THF (60 ml) under argon atmosphere slightly below the boiling point. The reaction mixture is heated at reflux temperature overnight. Then it is allowed to cool to room temperature, and the precipitate is filtered off and washed with THF. The filtrate is concentrated in vacuo. The residue is purified by silica gel chromatography (eluent 1-chlorobutane) to give 4-[2-(4-butylphenyl)ethynyl]-3,5-difluoro-aniline (3) as a brown oil.

Step 2.2: 2-[2-(4-Butylphenyl)ethynyl]-1,3-difluoro-5-isothiocyanato-benzene

[0790] ##STR00445##

[0791] Thiophosgene (1.9 ml, 24 mmol) is slowly added to a solution of 4-[2-(4-butylphenyl)ethynyl]-3,5-difluoro-aniline (6.1 g, 20 mmol) and DABCO (6.0 g, 53 mmol) in dichloromethane (100 ml) at 0? C. under argon atmosphere, and the reaction mixture is stirred at room temperature for 1 h. Then it is quenched with dist. water and brine. The aqueous phase is separated and extracted with dichloromethane. The combined organic phases are washed with brine, dried (sodium sulfate), filtered and concentrated in vacuo. The residue is purified by silica gel chromatography (eluent heptane) and crystallization (heptane) to give colorless crystals of 2-[2-(4-butylphenyl)ethynyl]-1,3-difluoro-5-isothiocyanato-benzene.

[0792] Phase sequence: K 44 N (29) I.

[0793] ??=3.70

[0794] ?n=0.3690

[0795] ?.sub.1=53 mPas

Mixture Examples

[0796] Comparative examples C1 and Mixture Examples M1 to M12 are prepared and investigated as described below.

Comparative Example C1

[0797]

TABLE-US-00007 PTU-3-S 13.0 Clp. [? C.]: 157 PTU-5-S 10.0 ?.sub.? [1 kHz, 20? C.]: 4.2 PPTU-4-S 6.0 ?.sub.1 [mPa s, 20? C.]: 452 PPTU-5-S 15.0 K.sub.1 [pN, 20? C.]: 19.9 PGTU-4-S 8.0 K.sub.3 [pN, 20? C.]: 23.7 PGU-3-S 18.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.19 CPTU-5-S 30.0 V.sub.0 [V, 20? C.]: 0.96 ? 100.0 E.sub.r,? [20? C., 19 GHz]: 3.81 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0054 ?.sub.r,? [20? C., 19 GHz]: 2.54 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0110 ? [20? C., 19 GHz]: 0.334 ? [20? C., 19 GHz]: 30.4

Mixture Example M1

[0798]

TABLE-US-00008 PPTU-4-S 5.0 Clp. [? C.]: 156 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 19.7 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 23.5 PGU-3-S 15.0 ?.sub.? [1 kHz, 20? C.]: 3.8 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 487 PTUI-2-S 12.0 K.sub.1 [pN, 20? C.]: 19.9 PTUI-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.0 PTUP-4-S 16.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.16 ? 100.0 V.sub.0 [V, 20? C.]: 1.06 E.sub.r,? [20? C., 19 GHz]: 3.71 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0055 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0088 ? [20? C., 19 GHz]: 0.342 ? [20? C., 19 GHz]: 39.0

[0799] Unexpectedly, the replacement of the compounds PTU-3-S and PTU-5-S in mixture C1 with the isomeric compounds PTUI-2-S and PTUI-4-S of the formula UI, and addition of the compound PTUP-4-S of formula PT results in a significant increase of the figure of merit from 30.4 to 39.0.

Mixture Example M2

[0800]

TABLE-US-00009 PPTU-4-S 5.0 Clp. [? C.]: 157 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 21.2 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 25.1 PGU-3-S 15.0 ?.sub.? [1 kHz, 20? C.]: 3.9 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 524 PTG(F)-3-S 12.0 K.sub.1 [pN, 20? C.]: 20.8 PTG(F)-4-S 10.0 K.sub.3 [pN, 20? C.]: 24.3 PTUP-4-S 16.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.17 ? 100.0 V.sub.0 [V, 20? C.]: 1.04 LTS bulk [h, ?30? C.]: 480 E.sub.r,? [20? C., 19 GHz]: 3.77 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0053 ?.sub.r,? [20? C., 19 GHz]: 2.45 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0090 ? [20? C., 19 GHz]: 0.348 ? [20? C., 19 GHz]: 38.9

Mixture Example M3

[0801]

TABLE-US-00010 PPTU-4-S 5.0 Clp. [? C.]: 158 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 16.1 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 19.7 PGU-3-S 15.0 ?.sub.? [1 kHz, 20? C.]: 3.6 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 404 PTUI-2-S 12.0 K.sub.1 [pN, 20? C.]: 19.5 PTUI-4-S 10.0 K.sub.3 [pN, 20? C.]: 22.8 PUITP-4-S 16.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.17 ? 100.0 V.sub.0 [V, 20? C.]: 1.16 LTS bulk [h, ?30? C.]: 120 E.sub.r,? [20? C., 19 GHz]: 3.87 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0055 ?.sub.r,? [20? C., 19 GHz]: 2.52 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0084 ? [20? C., 19 GHz]: 0.349 ? [20? C., 19 GHz]: 41.4

Mixture Example M4

[0802]

TABLE-US-00011 PPTU-4-S 5.0 Clp. [? C.]: 158.5 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 17.5 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 21.2 PGU-3-S 15.0 ?.sub.? [1 kHz, 20? C.]: 3.7 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 437 PTG(F)-3-S 12.0 K.sub.1 [pN, 20? C.]: 20.0 PTG(F)-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.0 PUITP-4-S 16.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.15 ? 100.0 V.sub.0 [V, 20? C.]: 1.13 LTS bulk [h, ?30? C.]: 72 E.sub.r,? [20? C., 19 GHz]: 3.83 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0052 ?.sub.r,? [20? C., 19 GHz]: 2.49 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0083 ? [20? C., 19 GHz]: 0.350 ? [20? C., 19 GHz]: 42.1

Mixture Example M5

[0803]

TABLE-US-00012 PPTU-4-S 5.0 Clp. [? C.]: 155.5 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 18.0 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 21.7 PGU-3-S 5.0 ?.sub.? [1 kHz, 20? C.]: 3.7 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 514 CPU(F.F)-3-S 10.0 K.sub.1 [pN, 20? C.]: 19.4 PTUP-4-S 15.0 K.sub.3 [pN, 20? C.]: 24.0 PTG(F)-3-S 13.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.24 PTG(F)-4-S 10.0 V.sub.0 [V, 20? C.]: 1.10 ? 100.0 E.sub.r,? [20? C., 19 GHz]: 3.66 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0050 ?.sub.r,? [20? C., 19 GHz]: 2.42 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0078 ? [20? C., 19 GHz]: 0.339 ? [20? C., 19 GHz]: 43.5

Mixture Example M6

[0804]

TABLE-US-00013 PPTU-4-S 5.0 Clp. [? C.]: 154 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 16.6 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 20.2 PGU-3-S 5.0 ?.sub.? [1 kHz, 20? C.]: 3.6 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 479 CPU(F.F)-3-S 10.0 K.sub.1 [pN, 20? C.]: 18.5 PTUP-4-S 15.0 K.sub.3 [pN, 20? C.]: 22.7 PTUI-2-S 13.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.23 PTUI-4-S 10.0 V.sub.0 [V, 20? C.]: 1.12 ? 100.0 E.sub.r,? [20? C., 19 GHz]: 3.67 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0052 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0077 ? [20? C., 19 GHz]: 0.337 ? [20? C., 19 GHz]: 44.0

Mixture Example M7

[0805]

TABLE-US-00014 PPTU-4-S 5.0 Clp. [? C.]: 157 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 15.0 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 18.5 PGU-3-S 5.0 ?.sub.? [1 kHz, 20? C.]: 3.5 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 513 CPU(F.F)-3-S 10.0 K.sub.1 [pN, 20? C.]: 19.0 PUITP-4-S 15.0 K.sub.3 [pN, 20? C.]: 22.6 PTG(F)-3-S 13.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.19 PTG(F)-4-S 10.0 V.sub.0 [V, 20? C.]: 1.19 ? 100.0 LTS bulk [h, ?30? C.]: 264 E.sub.r,? [20? C., 19 GHz]: 3.67 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0048 ?.sub.r,? [20? C., 19 GHz]: 2.42 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0073 ? [20? C., 19 GHz]: 0.342 ? [20? C., 19 GHz]: 46.9

Mixture Example M8

[0806]

TABLE-US-00015 PPTU-4-S 5.0 Clp. [? C.]: 155.5 PPTU-5-S 12.0 ?? [1 kHz, 20? C.]: 13.6 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 17.0 PGU-3-S 5.0 ?.sub.? [1 kHz, 20? C.]: 3.4 CPTU-5-S 24.0 ?.sub.1 [mPa s, 20? C.]: 396 CPU(F.F)-3-S 10.0 K.sub.1 [pN, 20? C.]: 18.3 PUITP-4-S 15.0 K.sub.3 [pN, 20? C.]: 22.1 PTUI-2-S 13.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.21 PTUI-4-S 10.0 V.sub.0 [V, 20? C.]: 1.22 ? 100.0 E.sub.r,? [20? C., 19 GHz]: 3.67 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0050 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0071 ? [20? C., 19 GHz]: 0.338 ? [20? C., 19 GHz]: 47.6

Mixture Example M9

[0807]

TABLE-US-00016 PPTU-4-S 6.0 Clp. [? C.]: 155.5 PPTU-5-S 15.0 ?? [1 kHz, 20? C.]: 14.6 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 18.0 CPU(F.F)-3-S 18.0 ?.sub.? [1 kHz, 20? C.]: 3.4 PTUI-2-S 12.0 ?.sub.1 [mPa s, 20? C.]: 494 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.3 PTUP-4-S 15.0 K.sub.3 [pN, 20? C.]: 22.9 ? 100.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.25 V.sub.0 [V, 20? C.]: 1.18 E.sub.r,? [20? C., 19 GHz]: 3.65 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0048 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0066 ? [20? C., 19 GHz]: 0.333 ? [20? C., 19 GHz]: 50.9

Mixture Example M10

[0808]

TABLE-US-00017 PPTU-4-S 6.0 Clp. [? C.]: 156 PPTU-5-S 15.0 ?? [1 kHz, 20? C.]: 15.9 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 19.4 CPU(F.F)-3-S 18.0 ?.sub.? [1 kHz, 20? C.]: 3.5 PTG(F)-3-S 12.0 ?.sub.1 [mPa s, 20? C.]: 530 PTG(F)-4-S 10.0 K.sub.1 [pN, 20? C.]: 19.5 PTUP-4-S 15.0 K.sub.3 [pN, 20? C.]: 23.2 ? 100.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.19 V.sub.0 [V, 20? C.]: 1.17 LTS bulk [h, ?30? C.]: 288 E.sub.r,? [20? C., 19 GHz]: 3.66 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0046 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0066 ? [20? C., 19 GHz]: 0.338 ? [20? C., 19 GHz]: 51.0

Mixture Example M11

[0809]

TABLE-US-00018 PPTU-4-S 6.0 Clp. [? C.]: 156.5 PPTU-5-S 15.0 ?? [1 kHz, 20? C.]: 11.9 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 15.2 CPU(F.F)-3-S 18.0 ?.sub.? [1 kHz, 20? C.]: 3.3 PTUI-2-S 12.0 ?.sub.1 [mPa s, 20? C.]: 435 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 17.9 PUITP-4-S 15.0 K.sub.3 [pN, 20? C.]: 22.8 ? 100.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.27 V.sub.0 [V, 20? C.]: 1.29 LTS bulk [h, ?30? C.]: 264 E.sub.r,? [20? C., 19 GHz]: 3.74 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0046 ?.sub.r,? [20? C., 19 GHz]: 2.48 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0060 ? [20? C., 19 GHz]: 0.337 ? [20? C., 19 GHz]: 56.5

Mixture Example M12

[0810]

TABLE-US-00019 PPTU-4-S 6.0 Clp. [? C.]: 158 PPTU-5-S 15.0 ?? [1 kHz, 20? C.]: 13.1 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 16.5 CPU(F.F)-3-S 18.0 ?.sub.? [1 kHz, 20? C.]: 3.4 PTG(F)-3-S 12.0 ?.sub.1 [mPa s, 20? C.]: 476 PTG(F)-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.8 PUITP-4-S 15.0 K.sub.3 [pN, 20? C.]: 23.0 ? 100.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.23 V.sub.0 [V, 20? C.]: 1.26 LTS bulk [h, ?30? C.]: 264 E.sub.r,? [20? C., 19 GHz]: 3.73 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0045 ?.sub.r,? [20? C., 19 GHz]: 2.48 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0061 ? [20? C., 19 GHz]: 0.334 ? [20? C., 19 GHz]: 54.7

Mixture Example M13

[0811]

TABLE-US-00020 PPTU-4-S 6.0 PPTU-5-S 15.0 CPTU-5-S 24.0 CPU(F.F)-3-S 18.0 PTG(F)-3-S 12.0 PTG(F)-4-S 5.0 PTUI-4(1.sup.[2])-S 5.0 PUITP-4-S 15.0 ? 100.0 Mixture Example M14 PPTU-4-S 6.0 PPTU-5-S 15.0 CPTU-5-S 24.0 CPU(F.F)-3-S 18.0 PTG(F)-3-S 12.0 PTG(F)-4-S 5.0 PTG(F)-4(1.sup.[2])-S 5.0 PUITP-4-S 15.0 ? 100.0

Mixture Example M15

[0812]

TABLE-US-00021 PPTU-4-S 6.0 Clp. [? C.]: 157.5 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 18.4 PGU-3-S 14.0 ?.sub.? [1 kHz, 20? C.]: 3.5 CPTU-5-S 25.0 ?? [1 kHz, 20? C.]: 14.9 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 400 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 19.9 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.8 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.20 ? 100.0 V.sub.0 [V, 20? C.]: 1.22 LTS bulk [h, ?30? C.]: 360 ? [20? C., 19 GHz]: 0.346 ?.sub.r,? [20? C., 19 GHz]: 3.73 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0052 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0075 ? [20? C., 19 GHz]: 46.1

Mixture Example M16

[0813]

TABLE-US-00022 PPTU-4-S 6.0 Clp. [? C.]: 156 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 22.7 PGU-3-S 14.0 ?.sub.? [1 kHz, 20? C.]: 3.7 CPTU-5-S 25.0 ?? [1 kHz, 20? C.]: 19.0 PTUI-2-S 11.0 K.sub.1 [pN, 20? C.]: 19.7 PTUI-4-S 11.0 K.sub.3 [pN, 20? C.]: 23.5 PTUP-4-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.20 PTUP-5-S 10.0 V.sub.0 [V, 20? C.]: 1.07 ? 100.0 LTS bulk [h, ?30? C.]: 1000 ? [20? C., 19 GHz]: 0.347 ?.sub.r,? [20? C., 19 GHz]: 3.73 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0052 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0080 ? [20? C., 19 GHz]: 43.1

Mixture Example M17

[0814]

TABLE-US-00023 PPTU-4-S 6.0 Clp. [? C.]: 154.5 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 14.5 CPTU-5-S 21.0 ?.sub.? [1 kHz, 20? C.]: 3.2 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 11.3 PTUI-4-S 11.0 ?.sub.1 [mPa s, 20? C.]: 515 PUITP-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.3 PUITP-5-S 10.0 K.sub.3 [pN, 20? C.]: 23.1 CPU(F.F)-3-S 18.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.26 ? 100.0 V.sub.0 [V, 20? C.]: 1.35 ? [20? C., 19 GHz]: 0.337 ?.sub.r,? [20? C., 19 GHz]: 3.64 ?.sub.r,? [20? C., 19 GHz]: 2.41 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0047 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0059 ? [20? C., 19 GHz]: 57.5

Mixture Example M18

[0815]

TABLE-US-00024 PPTU-4-S 6.0 Clp. [? C.]: 155.5 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 14.3 CPTU-5-S 25.0 ?.sub.? [1 kHz, 20? C.]: 3.2 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 11.1 PTUI-4-S 11.0 ?.sub.1 [mPa s, 20? C.]: 504 PUITP-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.0 PUITP-5-S 10.0 K.sub.3 [pN, 20? C.]: 23.2 CPUI-4-S 14.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.28 ? 100.0 V.sub.0 [V, 20? C.]: 1.34 ? [20? C., 19 GHz]: 0.338 ?.sub.r,? [20? C., 19 GHz]: 3.64 ?.sub.r,? [20? C., 19 GHz]: 2.41 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0048 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0056 ? [20? C., 19 GHz]: 60.3

Mixture Example M19

[0816]

TABLE-US-00025 PPTU-4-S 6.0 Clp. [? C.]: 154.5 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 14.7 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 3.2 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 11.5 PTUI-4-S 12.0 ?.sub.1 [mPa s, 20? C.]: 507 PUITP-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.3 PUITP-5-S 10.0 K.sub.3 [pN, 20? C.]: 23.2 CPU(F.F)-3-S 14.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.27 ? 100.0 V.sub.0 [V, 20? C.]: 1.33 ? [20? C., 19 GHz]: 0.338 ?.sub.r,? [20? C., 19 GHz]: 3.67 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0048 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0060 ? [20? C., 19 GHz]: 56.7

Mixture Example M20

[0817]

TABLE-US-00026 PPTU-4-S 6.0 Clp. [? C.]: 155.5 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 15.2 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 3.3 CPTU-5-S 21.0 ?? [1 kHz, 20? C.]: 11.9 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 499 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 18.3 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 22.8 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.24 CPUI-4-S 12.0 V.sub.0 [V, 20? C.]: 1.31 ? 100.0 ? [20? C., 19 GHz]: 0.338 ?.sub.r,? [20? C., 19 GHz]: 3.70 ?.sub.r,? [20? C., 19 GHz]: 2.45 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0050 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0064 ? [20? C., 19 GHz]: 53.2

Mixture Example M21

[0818]

TABLE-US-00027 PPTU-4-S 6.0 Clp. [? C.]: 154.5 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 16.8 PGU-3-S 8.0 ?.sub.? [1 kHz, 20? C.]: 3.4 CPTU-5-S 25.0 ?? [1 kHz, 20? C.]: 13.4 PTUI-2-S 12.0 ?.sub.1 [mPa s, 20? C.]: 509 PTUI-4-S 12.0 K.sub.1 [pN, 20? C.]: 19.3 PUITP-4-S 12.0 K.sub.3 [pN, 20? C.]: 23.9 PUITP-5-S 12.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.24 ? 100.0 V.sub.0 [V, 20? C.]: 1.27 ? [20? C., 19 GHz]: 0.347 ?.sub.r,? [20? C., 19 GHz]: 3.75 ?.sub.r,? [20? C., 19 GHz]: 2.45 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0051 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0069 ? [20? C., 19 GHz]: 50.3

Mixture Example M22

[0819]

TABLE-US-00028 PPTU-4-S 6.0 Clp. [? C.]: 157.5 PPTU-5-S 15.0 ?.sub.? [1 kHz, 20? C.]: 16.3 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 3.3 CPTU-5-S 25.0 ?? [1 kHz, 20? C.]: 13.0 PTUI-2-S 12.0 ?.sub.1 [mPa s, 20? C.]: 502 PTUI-4-S 12.0 K.sub.1 [pN, 20? C.]: 19.6 PUITP-4-S 12.0 K.sub.3 [pN, 20? C.]: 24.0 PUITP-5-S 12.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.22 ? 100.0 V.sub.0 [V, 20? C.]: 1.30 LTS bulk [h, ?30? C.]: 0.347 ? [20? C., 19 GHz]: 3.77 ?.sub.r,? [20? C., 19 GHz]: 2.46 ?.sub.r,? [20? C., 19 GHz]: tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0050 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0067 ? [20? C., 19 GHz]: 52.2

Mixture Example M23

[0820]

TABLE-US-00029 PPTU-4-S 6.0 Clp. [? C.]: 153 PPTU-5-S 13.0 ?.sub.? [1 kHz, 20? C.]: 21.6 PGU-3-S 8.0 ?.sub.? [1 kHz, 20? C.]: 3.6 CPTU-5-S 25.0 ?? [1 kHz, 20? C.]: 18.0 PTUI-2-S 12.0 K.sub.1 [pN, 20? C.]: 19.0 PTUI-4-S 12.0 K.sub.3 [pN, 20? C.]: 23.5 PTUP-4-S 12.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.23 PTUP-5-S 12.0 V.sub.0 [V, 20? C.]: 1.09 ? 100.0 LTS bulk [h, ?30? C.]: 336 ? [20? C., 19 GHz]: 0.351 ?.sub.r,? [20? C., 19 GHz]: 3.68 ?.sub.r,? [20? C., 19 GHz]: 2.39 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0052 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0076 ? [20? C., 19 GHz]: 46.5

Mixture Example M24

[0821]

TABLE-US-00030 PPTU-4-S 6.0 Clp. [? C.]: 155.5 PPTU-5-S 15.0 ?.sub.? [1 kHz, 20? C.]: 21.2 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 3.6 CPTU-5-S 25.0 ?? [1 kHz, 20? C.]: 17.6 PTUI-2-S 12.0 K.sub.1 [pN, 20? C.]: 19.3 PTUI-4-S 12.0 K.sub.3 [pN, 20? C.]: 23.8 PTUP-4-S 12.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.23 PTUP-5-S 12.0 V.sub.0 [V, 20? C.]: 1.10 ? 100.0 LTS bulk [h, ?30? C.]: 336 ? [20? C., 19 GHz]: 0.353 ?.sub.r,? [20? C., 19 GHz]: 3.75 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0052 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0075 ? [20? C., 19 GHz]: 47.0

Mixture Example M25

[0822]

TABLE-US-00031 PPTU-4-S 6.0 Clp. [? C.]: 158 PPTU-5-S 14.0 ?.sub.? [1 kHz, 20? C.]: 17.7 CPTU-5-S 20.0 ?.sub.? [1 kHz, 20? C.]: 3.3 PTUI-2-S 10.0 ?? [1 kHz, 20? C.]: 14.4 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 19.4 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 25.2 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.30 PTUP-4-S 10.0 V.sub.0 [V, 20? C.]: 1.23 PTUP-5-S 10.0 ? [20? C., 19 GHz]: 0.353 ? 100.0 ?.sub.r,? [20? C., 19 GHz]: 3.76 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0049 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0062 ? [20? C., 19 GHz]: 57.4

Mixture Example M26

[0823]

TABLE-US-00032 PPTU-4-S 6.0 Clp. [? C.]: 152 PPTU-5-S 14.0 ?.sub.? [1 kHz, 20? C.]: 15.9 CPTU-5-S 4.0 ?.sub.? [1 kHz, 20? C.]: 3.3 PTUI-2-S 9.0 ?? [1 kHz, 20? C.]: 12.6 PTUI-4-S 9.0 K.sub.1 [pN, 20? C.]: 18.3 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.5 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.29 PTUP-4-S 10.0 V.sub.0 [V, 20? C.]: 1.27 PTUP-5-S 10.0 ? [20? C., 19 GHz]: 0.343 CPU(F.F)-3-S 18.0 ?.sub.r,? [20? C., 19 GHz]: 3.71 ? 100.0 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0046 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0058 ? [20? C., 19 GHz]: 59.2

Mixture Example M27

[0824]

TABLE-US-00033 PPTU-4-S 6.0 Clp. [? C.]: 153.5 PPTU-5-S 14.0 ?.sub.? [1 kHz, 20? C.]: 16.4 CPTU-5-S 9.0 ?.sub.? [1 kHz, 20? C.]: 3.3 PTUI-2-S 9.0 ?? [1 kHz, 20? C.]: 13.1 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.5 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 24.0 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.30 PTUP-4-S 10.0 V.sub.0 [V, 20? C.]: 1.25 PTUP-5-S 10.0 ? [20? C., 19 GHz]: 0.347 CPU(F.F)-3-S 12.0 ?.sub.r,? [20? C., 19 GHz]: 3.73 ? 100.0 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0047 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0059 ? [20? C., 19 GHz]: 58.8

Mixture Example M28

[0825]

TABLE-US-00034 PPTU-4-S 6.0 Clp. [? C.]: 157.5 PPTU-5-S 18.0 ?.sub.? [1 kHz, 20? C.]: 17.9 CPTU-5-S 16.0 ?.sub.? [1 kHz, 20? C.]: 3.3 PTUI-2-S 10.0 ?? [1 kHz, 20? C.]: 14.5 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 20.0 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 24.7 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.24 PTUP-4-S 10.0 V.sub.0 [V, 20? C.]: 1.24 PTUP-5-S 10.0 ? [20? C., 19 GHz]: 0.354 ? 100.0 ?.sub.r,? [20? C., 19 GHz]: 3.74 ?.sub.r,? [20? C., 19 GHz]: 2.42 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0049 tan ?.sub.? .sub.r,? [20? C., 19 GHz]: 0.0062 ? [20? C., 19 GHz]: 57.4

Mixture Example M29

[0826]

TABLE-US-00035 PPTU-4-S 6.0 Clp. [? C.]: 153 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 18.0 CPTU-5-S 21.0 ?.sub.? [1 kHz, 20? C.]: 3.4 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 14.6 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 17.8 PTUP-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.0 PTUP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.30 CPU(F.F)-3-S 18.0 V.sub.0 [V, 20? C.]: 1.16 ? 100.0 LTS bulk [h, ?20? C.]: 1000 ? [20? C., 19 GHz]: 0.338 ?.sub.r,|| [20? C., 19 GHz]: 3.65 ?.sub.r,? [20? C., 19 GHz]: 2.42 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0065 ? [20? C., 19 GHz]: 52.0

Mixture Example M30

[0827]

TABLE-US-00036 PPTU-4-S 6.0 Clp. [? C.]: 153.5 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 18.4 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 3.4 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 15.0 PTUI-4-S 12.0 K.sub.1 [pN, 20? C.]: 17.9 PTUP-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.3 PTUP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.30 CPU(F.F)-3-S 14.0 V.sub.0 [V, 20? C.]: 1.16 ? 100.0 LTS bulk [h, ?20? C.]: 1000 ? [20? C., 19 GHz]: 0.342 ?.sub.r,|| [20? C., 19 GHz]: 3.63 ?.sub.r,? [20? C., 19 GHz]: 2.39 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0065 ? [20? C., 19 GHz]: 52.6

Mixture Example M31

[0828]

TABLE-US-00037 PPTU-4-S 6.0 Clp. [? C.]: 157 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 19.2 CPTU-5-S 24.0 ?.sub.? [1 kHz, 20? C.]: 3.5 PTUI-2-S 10.0 ?? [1 kHz, 20? C.]: 15.7 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 18.6 PTUP-4-S 13.0 K.sub.3 [pN, 20? C.]: 27.1 PTUP-5-S 13.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.46 CPU(F.F)-3-S 10.0 V.sub.0 [V, 20? C.]: 1.15 ? 100.0 ? [20? C., 19 GHz]: 0.347 ?.sub.r,|| [20? C., 19 GHz]: 3.64 ?.sub.r,? [20? C., 19 GHz]: 2.38 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0065 ? [20? C., 19 GHz]: 53.8

Mixture Example M32

[0829]

TABLE-US-00038 PPTU-4-S 6.0 Clp. [? C.]: 155 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 19.5 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 3.5 CPTU-5-S 15.0 ?? [1 kHz, 20? C.]: 16.0 PTUI-2-S 10.0 K.sub.1 [pN, 20? C.]: 18.6 PTUI-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.0 PTUP-4-S 12.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.24 PTUP-5-S 12.0 V.sub.0 [V, 20? C.]: 1.14 CPU(F.F)-3-S 16.0 ? [20? C., 19 GHz]: 0.345 ? 100.0 ?.sub.r,|| [20? C., 19 GHz]: 3.66 ?.sub.r,? [20? C., 19 GHz]: 2.40 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0049 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0069 ? [20? C., 19 GHz]: 50.0

Mixture Example M33

[0830]

TABLE-US-00039 PPTU-4-S 6.0 Clp. [? C.]: 161.5 PPTU-5-S 14.0 ?.sub.|| [1 kHz, 20? C.]: 16.5 CPTU-5-S 10.0 ?.sub.? [1 kHz, 20? C.]: 3.3 PTUI-2-S 7.0 ?? [1 kHz, 20? C.]: 13.2 PTUI-4-S 7.0 K.sub.1 [pN, 20? C.]: 19.3 PUITP-4-S 9.0 K.sub.3 [pN, 20? C.]: 24.4 PUITP-5-S 9.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.27 PTUP-4-S 10.0 V.sub.0 [V, 20? C.]: 1.27 PTUP-5-S 10.0 ? [20? C., 19 GHz]: 0.344 CPU(F.F)-3-S 18.0 ?.sub.r,|| [20? C., 19 GHz]: 3.68 ? 100.0 ?.sub.r,? [20? C., 19 GHz]: 2.42 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0045 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0058 ? [20? C., 19 GHz]: 59.8

Mixture Example M34

[0831]

TABLE-US-00040 PPTU-4-S 6.0 Clp. [? C.]: 161 PPTU-5-S 14.0 ?.sub.|| [1 kHz, 20? C.]: 14.7 PTUI-2-S 5.0 ?.sub.? [1 kHz, 20? C.]: 3.1 PTUI-4-S 5.0 ?? [1 kHz, 20? C.]: 11.5 PUITP-4-S 10.0 K.sub.1 [pN, 20? C.]: 18.3 PUITP-5-S 10.0 K.sub.3 [pN, 20? C.]: 23.7 PTUP-4-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.30 PTUP-5-S 10.0 V.sub.0 [V, 20? C.]: 1.33 CPU(F.F)-3-S 16.0 ? [20? C., 19 GHz]: 0.340 CPUI-4-S 14.0 ?.sub.r,|| [20? C., 19 GHz]: 3.64 ? 100.0 ?.sub.r,? [20? C., 19 GHz]: 2.40 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0043 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0050 ? [20? C., 19 GHz]: 68.1

Mixture Example M35

[0832]

TABLE-US-00041 PPTU-4-S 6.0 Clp. [? C.]: 158 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 18.8 PGU-3-S 15.0 ?.sub.? [1 kHz, 20? C.]: 3.5 CPTU-5-S 26.0 ?? [1 kHz, 20? C.]: 15.3 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 494 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 20.0 PUITP-4-S 9.0 K.sub.3 [pN, 20? C.]: 23.9 PUITP-5-S 9.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.20 ? 100.0 V.sub.0 [V, 20? C.]: 1.21 ? [20? C., 19 GHz]: 0.347 ?.sub.r,|| [20? C., 19 GHz]: 3.73 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0052 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0078 ? [20? C., 19 GHz]: 44.5

Mixture Example M36

[0833]

TABLE-US-00042 PPTU-4-S 6.0 Clp. [? C.]: 155.5 PPTU-5-S 14.0 ?.sub.|| [1 kHz, 20? C.]: 15.0 CPTU-5-S 25.0 ?.sub.? [1 kHz, 20? C.]: 3.2 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 11.8 PTUI-4-S 12.0 ?.sub.1 [mPa s, 20? C.]: 491 PUITP-4-S 9.0 K.sub.1 [pN, 20? C.]: 18.5 PUITP-5-S 9.0 K.sub.3 [pN, 20? C.]: 23.5 CPU(F.F)-3-S 14.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.27 ? 100.0 V.sub.0 [V, 20? C.]: 1.32 ? [20? C., 19 GHz]: 0.336 ?.sub.r,|| [20? C., 19 GHz]: 3.63 ?.sub.r,? [20? C., 19 GHz]: 2.41 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0060 ? [20? C., 19 GHz]: 56.0

Mixture Example M37

[0834]

TABLE-US-00043 PPTU-4-S 6.0 Clp. [? C.]: 156 PPTU-5-S 15.0 ?.sub.|| [1 kHz, 20? C.]: 15.1 CPTU-5-S 25.0 ?.sub.? [1 kHz, 20? C.]: 3.2 PTUI-2-S 11.0 ?? [1 kHz, 20? C.]: 11.9 PTUI-4-S 12.0 ?.sub.1 [mPa s, 20? C.]: 490 PUITP-4-S 9.0 K.sub.1 [pN, 20? C.]: 18.6 PUITP-5-S 9.0 K.sub.3 [pN, 20? C.]: 23.0 CPU(F.F)-3-S 13.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.23 ? 100.0 V.sub.0 [V, 20? C.]: 1.32 ? [20? C., 19 GHz]: 0.335 ?.sub.r,|| [20? C., 19 GHz]: 3.66 ?.sub.r,? [20? C., 19 GHz]: 2.43 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0062 ? [20? C., 19 GHz]: 54.5

Mixture Example M38

[0835]

TABLE-US-00044 PPTU-4-S 6.0 Clp. [? C.]: 155 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 15.4 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 3.3 CPTU-5-S 19.0 ?? [1 kHz, 20? C.]: 12.1 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 492 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 18.5 PUITP-4-S 9.0 K.sub.3 [pN, 20? C.]: 22.5 PUITP-5-S 9.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.22 CPU(F.F)-3-S 16.0 V.sub.0 [V, 20? C.]: 1.30 ? 100.0 ? [20? C., 19 GHz]: 0.342 ?.sub.r,|| [20? C., 19 GHz]: 3.66 ?.sub.r,? [20? C., 19 GHz]: 2.41 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0064 ? [20? C., 19 GHz]: 53.5

Mixture Example M39

[0836]

TABLE-US-00045 PPTU-4-S 6.0 Clp. [? C.]: 156 PPTU-5-S 15.0 ?.sub.|| [1 kHz, 20? C.]: 15.7 PGTU-4-S 6.0 ?.sub.? [1 kHz, 20? C.]: 3.3 CPTU-5-S 19.0 ?? [1 kHz, 20? C.]: 12.4 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 488 PTUI-4-S 11.0 K.sub.1 [pN, 20? C.]: 19.0 PUITP-4-S 9.0 K.sub.3 [pN, 20? C.]: 22.5 PUITP-5-S 9.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.19 CPU(F.F)-3-S 14.0 V.sub.0 [V, 20? C.]: 1.30 ? 100.0 ? [20? C., 19 GHz]: 0.340 ?.sub.r,|| [20? C., 19 GHz]: 3.65 ?.sub.r,? [20? C., 19 GHz]: 2.41 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0048 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0065 ? [20? C., 19 GHz]: 52.3

Mixture Example M40

[0837]

TABLE-US-00046 PPTU-4-S 6.0 Clp. [? C.]: 156 PPTU-5-S 13.0 ?.sub.|| [1 kHz, 20? C.]: 17.5 PGU-3-S 14.0 ?.sub.? [1 kHz, 20? C.]: 3.4 CPTU-5-S 20.0 ?? [1 kHz, 20? C.]: 14.1 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 502 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 19.5 PUITP-4-S 10.0 K.sub.3 [pN, 20? C.]: 23.0 PUITP-5-S 10.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.18 CPUI-4-S 6.0 V.sub.0 [V, 20? C.]: 1.25 ? 100.0 ? [20? C., 19 GHz]: 0.343 ?.sub.r,|| [20? C., 19 GHz]: 3.71 ?.sub.r,? [20? C., 19 GHz]: 2.44 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0052 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0073 ? [20? C., 19 GHz]: 47.0

Mixture Example M41

[0838]

TABLE-US-00047 PPTU-4-S 6.0 Clp. [? C.]: 156.5 PPTU-5-S 15.0 ?.sub.|| [1 kHz, 20? C.]: 17.9 PGU-3-S 14.0 ?.sub.? [1 kHz, 20? C.]: 3.5 CPTU-5-S 20.0 ?? [1 kHz, 20? C.]: 14.4 PTUI-2-S 11.0 ?.sub.1 [mPa s, 20? C.]: 493 PTUI-4-S 10.0 K.sub.1 [pN, 20? C.]: 19.8 PUITP-4-S 9.0 K.sub.3 [pN, 20? C.]: 23.6 PUITP-5-S 9.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.19 CPUI-4-S 6.0 V.sub.0 [V, 20? C.]: 1.24 ? 100.0 ? [20? C., 19 GHz]: 0.343 ?.sub.r,|| [20? C., 19 GHz]: 3.74 ?.sub.r,? [20? C., 19 GHz]: 2.46 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0052 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0075 ? [20? C., 19 GHz]: 46.0

Mixture Example M42

[0839]

TABLE-US-00048 PPTU-4-S 6.0 Clp. [? C.]: 161.5 PPTU-5-S 12.0 ?.sub.|| [1 kHz, 20? C.]: 19.4 PGU-3-S 14.0 ?.sub.? [1 kHz, 20? C.]: 3.6 PGTU-4-S 5.0 ?? [1 kHz, 20? C.]: 15.9 CPTU-5-S 25.0 ?.sub.1 [mPa s, 20? C.]: 512 PTUI-2-S 10.0 K.sub.1 [pN, 20? C.]: 20.7 PTUI-4-S 10.0 K.sub.3 [pN, 20? C.]: 24.0 PUITP-4-S 9.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.16 PUITP-5-S 9.0 V.sub.0 [V, 20? C.]: 1.21 ? 100.0 ? [20? C., 19 GHz]: 0.350 ?.sub.r,|| [20? C., 19 GHz]: 3.72 ?.sub.r,? [20? C., 19 GHz]: 2.42 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0052 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0080 ? [20? C., 19 GHz]: 44.0

Mixture Example M43

[0840]

TABLE-US-00049 PPTU-4-S 6.0 Clp. [? C.]: 166 PPTU-5-S 12.0 ?.sub.|| [1 kHz, 20? C.]: 17.3 PGU-3-S 14.0 ?.sub.? [1 kHz, 20? C.]: 3.4 CPTU-5-S 20.0 ?? [1 kHz, 20? C.]: 13.8 PTUI-2-S 8.0 ?.sub.1 [mPa s, 20? C.]: 542 PTUI-4-S 8.0 K.sub.1 [pN, 20? C.]: 20.4 PUITP-4-S 8.0 K.sub.3 [pN, 20? C.]: 24.8 PUITP-5-S 8.0 K.sub.3/K.sub.1 [pN, 20? C.]: 1.22 PPU-TO-S 16.0 V.sub.0 [V, 20? C.]: 1.28 ? 100.0 ? [20? C., 19 GHz]: 0.344 ?.sub.r,|| [20? C., 19 GHz]: 3.74 ?.sub.r,? [20? C., 19 GHz]: 2.46 tan ?.sub.? r,|| [20? C., 19 GHz]: 0.0055 tan ?.sub.? r,? [20? C., 19 GHz]: 0.0084 ? [20? C., 19 GHz]: 41.2