Method for manufacturing Direct Reduced Iron and DRI manufacturing equipment

Abstract

A method for manufacturing Direct Reduced Iron wherein iron ore is reduced in a DRI shaft by a reducing gas including hydrogen obtained by thermal cracking of methane inside a plasma torch, the reducing gas further including top gas coming from the DRI shaft and a DRI manufacturing equipment including a DRI shaft (1) and a plasma torch (40), wherein the plasma torch is connected on one side to a methane supply (41) and, on the other side, to the DRI shaft (1), the DRI shaft being provided with a recycling loop allowing to inject its top gas back in the DRI shaft.

Claims

1-13. (canceled)

14. A method for manufacturing Direct Reduced Iron, the method comprising: reducing iron ore in a DRI shaft by a reducing gas including hydrogen obtained by thermal cracking of methane inside a plasma torch, the reducing gas further including top gas coming from the DRI shaft.

15. The method as recited in claim 14 wherein the hydrogen is mixed with the top gas before being injected in the DRI shaft.

16. The method as recited in claim 15 wherein the reducing gas is heated after mixing of the top gas with the hydrogen.

17. The method as recited in claim 16 wherein the heating of the reducing gas is performed using CO.sub.2 neutral electricity.

18. The method as recited in claim 14 wherein the reducing gas is injected in the DRI shaft in a reduction section.

19. The method as recited in claim 14 wherein the top gas coming from the DRI shaft is scrubbed to remove water before being added to the reducing gas.

20. The method as recited in claim 14 wherein a ratio of top gas to hydrogen is set from 5:1 to 1:5.

21. The method as recited in claim 20 wherein a carbon content of the Direct Reduced Iron is set from 0.5 to 5 wt. %.

22. DRI manufacturing equipment comprising: a DRI shaft; and a plasma torch connected on one side to a methane supply and, on an other side, to the DRI shaft, the DRI shaft being provided with a recycling loop allowing injection of a top gas back into the DRI shaft.

23. The DRI equipment as recited in claim 22 further comprising a mixer connected on one mixer side to an outlet of the plasma torch and to a top of the DRI shaft and, on an other mixer side, to the DRI shaft.

24. The DRI equipment as recited in claim 23 further comprising a heater for the mixer, the heater being powered by CO.sub.2 neutral electricity.

25. The DRI equipment as recited in claim 23 wherein the mixer is connected to a reduction section of the DRI shaft.

26. The DRI equipment as recited in claim 22 further comprising a scrubber connected to the top gas outlet of the DRI shaft.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0028] Other characteristics and advantages of the invention will emerge clearly from the description of it that is given below by way of an indication and which is in no way restrictive, with reference to the appended figures in which:

[0029] FIG. 1 illustrates a DRI manufacturing equipment according to the invention,

[0030] FIG. 2 illustrates a preferred embodiment of a DRI manufacturing equipment according to the invention.

DETAILED DESCRIPTION

[0031] Elements in the figures are illustration and may not have been drawn to scale.

[0032] FIG. 1 is a schematic view of a DRI manufacturing equipment according to the invention. The DRI manufacturing equipment includes a DRI shaft 1 comprising from top to bottom an inlet for iron ore 10 that travels through the shaft by gravity, a reduction section located in the mid-part of the shaft, a cooling section located at the bottom and an outlet 12 from which the direct reduced iron is finally extracted.

[0033] On top of the shaft, the top gas exiting the DRI shaft is collected in a pipe 20 which is connected to the DRI shaft 1, creating thereby a recycling loop for such top gases to be reinjected back in the DRI shaft. The gases are travelling up to the bottom, in counter-current towards the flow of iron ore.

[0034] In a preferred embodiment, the top gas can be reinjected in the reduction section of the DRI shaft through a pipe 11.

[0035] The DRI manufacturing equipment further comprises a plasma torch 40 which is connected on one side to a methane supply 41 and, on the other side, to the DRI shaft 1 by a connecting pipe 42.

[0036] A plasma torch is a device for generating a directed flow of plasma. Thermal plasmas can be generated in plasma torches by applying electric energy to a gas. The electric energy can be direct current, alternating current, radio-frequency or other types of discharges. In a direct current torch, an electric arc is formed between the electrodes, which can be made for example of copper, tungsten, graphite or silver. The thermal plasma is formed from the input of gas, projecting outward as a plasma jet.

[0037] The most commonly used plasma types are dielectric barrier discharges, microwave and gliding arc plasmas. Dielectric barrier discharges are created by applying an electric potential difference between two electrodes, of which at least one is covered by a dielectric barrier. They typically operate at room temperature and are called cold plasmas.

[0038] Microwave and gliding arc plasmas operate at higher temperatures (typically 1000-3000 K) and are therefore called warm plasmas.

[0039] In the frame of the invention, the plasma can be created by using methane as the plasmagenic gas, allowing the non-oxidative conversion of CH.sub.4 into hydrogen and solid carbon. Methane is transformed into an ionized gas, consisting of various chemically active species, like radicals, ions, excited atoms and molecules, and electrons. The electrons in the plasma absorb the applied electric energy and activate the molecules by excitation, ionization, and dissociation, creating the above-mentioned reactive species, which can further react to form new molecules. This allows chemical conversions to occur.

[0040] It is also possible to initiate a plasma with the use of another gas and to introduce methane in a second step in such plasma to get it transformed as described above.

[0041] The man skilled in the art knows how to control the quality of the plasma as a function of the gas pressure and the torch input power. In a preferred embodiment, the specific energy input (SEI, i.e., ratio of plasma power over gas flow rate) is ranging from 0.1 to 500 KJ l.sup.?1, preferably from 100 to 400 KJ l.sup.?1, allowing to reach a conversion rate of methane to hydrogen of 50 to vol 99%, preferably of 70 to vol 99%.

[0042] Plasma is very flexible and can easily be switched on/off, so it can use intermittently produced CO.sub.2 neutral electricity from renewable sources, which cannot be stored on the grid.

[0043] CO.sub.2 neutral electricity from renewable source is defined as energy that is collected from renewable resources, which are naturally replenished on a human timescale, including sources like sunlight, wind, rain, tides, waves, and geothermal heat.

[0044] In an embodiment, whenever hydrogen coming from the cracking of methane is not produced in a sufficient amount, due for example to the partial unavailability of electricity from renewable sources, an additional supply of hydrogen can be injected in the reduction section of the DRI shaft.

[0045] The DRI manufacturing equipment may further comprise a scrubber 2 located on the top gas outlet of the DRI shaft, before the reinjection into the shaft 1. The top gas exiting from the DRI shaft usually comprises H.sub.2, CO, CH.sub.4, H.sub.2O, CO.sub.2 and N.sub.2 in various proportions. The top gas scrubbing operation allows removing water vapor from the rest of the stream to improve its reduction potential.

[0046] In a preferred embodiment, after scrubbing, the top gas comprises from 40 to 75 vol % of H.sub.2, from 0 to 30 vol % of carbon monoxide CO, from 0 to 10 vol % of methane CH.sub.4, from 0 to 25 vol % of carbon dioxide CO.sub.2, up to 5 vol % of H.sub.2O, the remainder being nitrogen N.sub.2. It is preferred to have, after scrubbing, a ratio of H.sub.2/N.sub.2 from 1.5 to 3 in such top gas.

[0047] Once the top gas exits the scrubber 2, it can optionally be compressed and/or reheated before its reinjection in the DRI shaft through the connecting pipe 11. In a preferred embodiment, its temperature is set to a range from 700? C. to 1000? C., preferably from 800 to 1000? C.

[0048] To increase the carbon content of the Direct reduced Iron, an additional source of carbon can be injected in the transition section 50 and/or in the cooling section of the shaft 1. Such additional source of carbon can be in a gaseous form and/or in a solid form and can, for example, consists of biogas and/or of bio-coal. It is also possible to use the solid carbon formed as a by-product of the plasma conversion of methane as such additional source of carbon or even as the sole source of carbon to set the carbon content of the Direct reduced Iron.

[0049] A biogas is a renewable energy source that can be obtained by the breakdown of organic matter in the absence of oxygen inside a closed system called bioreactor. Biogas can be produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste, food waste or any biodegradable materials.

[0050] A bio-coal is a carbon-neutral fuel that can replace fossil coal in industrial processes. It is produced by pyrolysis and carbonization of biomass performed within controlled temperature and residence time conditions. Thermal conversion of biomass, which is done under oxygen-free conditions process, allows to remove volatile organic compounds and cellulose components from the feedstock and create a solid biofuel with characteristics like the ones in fossil coal.

[0051] In a preferred embodiment, the carbon content of the Direct Reduced Iron is set from 0.5 to 5 wt. %, preferably from 1 to 3 wt. % or from 2 to 3 wt. %, which allows getting a Direct Reduced Iron that can be easily handled and that keeps a good combustion potential and a good level of passivation for its future use.

[0052] The DRI manufacturing equipment may further comprise a recycling loop in the cooling section that allows extracting part of the gas present at that level to send it in a scrubber 30 and then in a compression unit 31 before reinjecting it in the shaft 1.

[0053] FIG. 2 is showing a schematic DRI manufacturing equipment according to another embodiment of the invention. On top of the shaft, the top gas exiting the DRI shaft is collected in a pipe 20 which is connected to a scrubber 2, to remove water vapor from the rest of the stream, in a similar way as the equipment of FIG. 1.

[0054] In a preferred embodiment, after scrubbing, the top gas comprises from 40 to 75 vol % of H.sub.2, from 0 to 30 vol % of carbon monoxide CO, from 0 to 10 vol % of methane CH.sub.4, from 0 to 25 vol % of carbon dioxide CO.sub.2, up to 5 vol % of H.sub.2O, the remainder being nitrogen N.sub.2. It is preferred to have, after scrubbing, a ratio of H.sub.2/N.sub.2 from 1.5 to 3 in such top gas.

[0055] The scrubbed gas can then be sent to one of the inlet of a mixer 4 through a connecting pipe 21.

[0056] The other inlet of said mixer 4 is connected to the outlet of a plasma torch 40 to incorporate the hydrogen produced by cracking of the methane coming from the methane supply 41.

[0057] After being mixed, the reduction gas can optionally be heated through heating means provided to the mixer, such heating means being powered by CO.sub.2 neutral electricity. In a preferred embodiment, the temperature of the reduction gas is set to a range from 700? ? C. to 1000? C., preferably from 800 to 1000? C.

[0058] The reduction gas made of top gas and hydrogen is then sent back to the DRI shaft, preferably in its reduction section through a pipe 11.

[0059] In a preferred embodiment, the ratio of top gas to hydrogen is set from 5:1 to 1:5, preferably from 2:1 to 1:2. Such ratio is notably defined to control the respective amounts of H.sub.2 and CO in the reduction stream. When the proportion of CO must be increased, the proportion of top gas in the reduction gas will be increased. When the proportion of H.sub.2 must be increased, the proportion of top gas in the reduction gas will be decreased.

[0060] To increase the carbon content of the Direct reduced Iron, an additional source of carbon can be injected in the transition section 50 and/or in the cooling section. Such additional source of carbon can be in a gaseous form and/or in a solid form and can, for example, consists of biogas and/or of bio-coal. It is also possible to use the solid carbon formed as a by-product of the plasma conversion of methane as such additional source of carbon or even as the sole source of carbon to set the carbon content of the Direct reduced Iron.

[0061] In a preferred embodiment, the carbon content of the Direct Reduced Iron is set from 0.5 to 5 wt. %, preferably from 1 to 3 wt. % or from 2 to 3 wt. %, which allows getting a Direct Reduced Iron that can be easily handled and that keeps a good combustion potential for its future use.

[0062] By using the method according to the invention, Direct reduced Iron can be manufactured with the appropriate quality and yield, while remaining CO.sub.2 neutral and taking optimal advantage of green resources like intermittent CO.sub.2 neutral electricity from renewable sources.