LIQUEFIED HYDROGEN STORAGE TANK, AND METHOD FOR CONTROLLING TEMPERATURE OF LIQUEFIED HYDROGEN STORAGE TANK

Abstract

Disclosed are a liquefied hydrogen storage tank which is applicable to a storage facility storing a large amount of hydrogen in a liquefied state or a vehicle transporting liquefied hydrogen and a liquefied hydrogen storage tank, and a method for controlling the temperature of the liquefied hydrogen storage tank which can control the generation rate of boil-off gas from liquefied hydrogen and can maintain the liquefied hydrogen storage tank at a low pressure. The liquefied hydrogen storage tank is a storage container storing liquefied hydrogen, has an inner space including a lower space in which liquefied hydrogen is stored and an upper space in which a gas is stored, and includes a heat inflow prevention unit disposed in the upper space or at an interface between the upper space and the lower space and preventing inflow of thermal energy into the lower space through the upper space.

Claims

1. A liquefied hydrogen storage tank acting as a storage container storing liquefied hydrogen, the liquefied hydrogen storage tank having an inner space comprising a lower space in which liquefied hydrogen is stored and an upper space in which a gas is stored, wherein the liquefied hydrogen storage tank comprises a heat inflow prevention unit disposed in the upper space or at an interface between the upper space and the lower space and preventing inflow of thermal energy into the lower space through the upper space.

2. The liquefied hydrogen storage tank according to claim 1, wherein the heat inflow prevention unit is disposed at a fixed location corresponding to a maximum allowable level of the liquefied hydrogen in the liquefied hydrogen storage tank.

3. The liquefied hydrogen storage tank according to claim 1, wherein the heat inflow prevention unit adjoins a surface of the liquefied hydrogen stored in the liquefied hydrogen storage tank or is at least partially immersed in the liquefied hydrogen, the heat inflow prevention being variable in location depending on the level of the liquefied hydrogen.

4. The liquefied hydrogen storage tank according to claim 1, wherein the heat inflow prevention unit comprises a gas layer between the heat inflow prevention unit and the surface of the liquefied hydrogen stored in the liquefied hydrogen storage tank to be disposed at a location spaced apart from the surface of the liquefied hydrogen.

5. The liquefied hydrogen storage tank according to claim 1, wherein the heat inflow prevention unit comprises: a floating plate floating in the liquefied hydrogen stored in the liquefied hydrogen storage tank or adjoining the surface of the liquefied hydrogen; or an upper heat exchanger cooling the upper space or the surface of the liquefied hydrogen in the lower space.

6. The liquefied hydrogen storage tank according to claim 5, wherein the floating plate is formed of a heat insulating material having a lower density than the liquefied hydrogen and having buoyancy.

7. The liquefied hydrogen storage tank according to claim 5, wherein the floating plate comprises: a body; and a powdered heat insulating material packed in the body.

8. The liquefied hydrogen storage tank according to claim 5, wherein the floating plate comprises one or more floating plates.

9. A method for controlling a temperature of the liquefied hydrogen storage tank according to claim 1, comprising: suppressing evaporation of liquefied hydrogen stored in the liquefied hydrogen storage tank by solidifying a surface layer of the liquefied hydrogen through cooling of the upper space.

Description

DESCRIPTION OF DRAWINGS

[0030] FIGURE is a schematic view of a liquefied hydrogen storage tank according to one embodiment of the present invention.

EMBODIMENTS

[0031] The above and other aspects, features, and advantages of the present invention will become apparent from the detailed description of the following embodiments in conjunction with the accompanying drawings.

[0032] Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. It should be noted that like components will be denoted by like reference numerals throughout the specification and the accompanying drawings. In addition, it should be understood that the present invention may be embodied in different ways and is not limited to the following embodiments.

[0033] A liquefied hydrogen storage tank, a system and method for controlling boil-off gas from liquefied hydrogen, and a system and method for supplying liquefied hydrogen according to embodiments of the present invention described below may be applied to both onshore and offshore storage facilities and vehicles.

[0034] In the following description, it is assumed that embodiments of the present invention are used in offshore applications and a vehicle provided with a liquefied hydrogen storage tank is a ship.

[0035] In addition, a demand site supplied with liquefied hydrogen is an onshore liquefied hydrogen storage station.

[0036] The ship to which embodiments of the present invention are applied is a ship provided with a liquefied hydrogen storage facility, and may include self-propelled vessels, such as a liquefied hydrogen carrier, and non-self-propelled floating offshore structures, such as a floating production storage offloading (FPSO) and a floating storage regasification unit (FSRU). However, in embodiments described below, it is assumed that the ship is a liquefied hydrogen carrier.

[0037] Hereinafter, a liquefied hydrogen storage tank, a system and method for controlling boil-off gas from liquefied hydrogen according to embodiments of the present invention will be described with reference to FIG. 1.

[0038] Referring to FIG. 1, a liquefied hydrogen storage tank 100 according to one embodiment of the present invention is a storage container capable of storing liquefied hydrogen therein, and has an inner space including a lower space (liquid space) in which liquefied hydrogen is stored and an upper space (vapor space) in which a low-density gas is stored.

[0039] In addition, the liquefied hydrogen storage tank 100 according to this embodiment includes a heat inflow prevention unit disposed in the upper space or at an interface between the upper space and the lower space to control the temperature of a surface layer of liquefied hydrogen stored in the lower space or the temperature of the upper space.

[0040] Here, the lower space and the upper space are not physically separated from each other and the volumes of the upper space and the lower space depend on the level of liquefied hydrogen in the liquefied hydrogen storage tank. In addition, the volumes of the upper space and the lower space also depend on the period of time between loading and unloading of liquefied hydrogen to and from the storage tank 100 and the temperature change in the storage tank 100. In addition, the volumes of the upper space and the lower space are inversely related to each other. That is, the volume of the lower space decreases with increasing volume of the upper space and vice versa.

[0041] The heat inflow prevention unit according to this embodiment may be disposed at a fixed location corresponding to a maximum allowable level of liquefied hydrogen in the storage tank 100, or may be variable in location depending on the level of liquefied hydrogen in the storage tank 100.

[0042] In addition, the heat inflow prevention unit may adjoin the surface of liquefied hydrogen stored in the storage tank 100, or may be immersed only at a lower end thereof in liquefied hydrogen stored in the storage tank 100.

[0043] Alternatively, the heat inflow prevention unit may include a gas layer between the heat inflow prevention unit and the surface of liquefied hydrogen stored in the storage tank 100 to be disposed in the upper space at a location spaced apart from the surface of the stored liquefied hydrogen.

[0044] The heat inflow prevention unit according to this embodiment may include at least one selected from among a floating plate 110 that floats on the surface of the stored liquefied hydrogen or adjoins the surface of the stored liquefied hydrogen and an upper heat exchanger 120 disposed at a location lower than the floating plate 110 and controlling the temperature of the upper space, which has a relatively low density and a relatively high temperature.

[0045] The floating plate 110 according to this embodiment is formed of a material that can float on the surface of liquefied hydrogen stored in the storage tank 100 while having heat insulation properties, and serves to prevent external heat introduced into an upper portion of the inner space from the outside of the storage tank from flowing into the surface layer of liquefied hydrogen.

[0046] In this embodiment, the heat insulating material forming the floating plate 110 may include at least one selected from the group consisting of polyurethane foam (PUF) and hollow glass bubbles.

[0047] The floating plate 110 may include a material that has a lower density than liquefied hydrogen and has buoyancy in liquefied hydrogen. Alternatively, the floating plate 110 may include a body and a powdered heat insulating material packed in the body so as to have buoyancy.

[0048] In this embodiment, the heat inflow prevention unit may include multiple floating plates 110. When the heat inflow prevention unit includes multiple floating plates 110, it is possible to prevent shrinkage of the floating plate 110 due to cryogenic temperatures of liquefied hydrogen or damage to the floating plate 110 due to sloshing of liquefied hydrogen during transport of the storage tank 100.

[0049] The upper heat exchanger 120 according to this embodiment cools the upper space to prevent intrusion of external heat (such as solar heat) through the upper portion of the storage tank 100 to a certain degree and to inhibit external air introduced into the storage tank 100 from exchanging heat with the surface layer of liquefied hydrogen stored in the storage tank.

[0050] The upper heat exchanger 120 may be disposed under the floating plate 110, and may be connected to the floating plate 110. By cooling the upper space of the storage tank 100 or the surface layer of liquefied hydrogen using the upper heat exchanger 120, it is possible to effectively control generation of boil-off gas and to achieve improved cooling efficiency.

[0051] The upper heat exchanger 120 may be a tube type or plate type heat exchanger.

[0052] According to this embodiment, the upper heat exchanger 120 may be connected to a refrigerator (not shown) that supplies a refrigerant for cooling liquefied hydrogen.

[0053] In this embodiment, the refrigerant may be helium and the refrigerator may supply helium at a temperature of about 4.5 K to about 21 K to the upper heat exchanger 120.

[0054] Next, a method for controlling the internal temperature of the liquefied hydrogen storage tank 100 according to this embodiment and generation boil-off gas from liquefied hydrogen in the liquefied hydrogen storage tank 100 will be described.

[0055] The liquefied hydrogen storage tank 100 according to this embodiment is a large-capacity storage tank having a volume of 100 m.sup.3 or more, and may include at least two liquefied hydrogen storage tanks.

[0056] In addition, the storage tank 100 according to this embodiment may be operated at a pressure of 0.1 bar to 6 bar, preferably a pressure of 3 bar or less, more preferably a pressure of 1 bar or less or atmospheric pressure.

[0057] The upper space of the storage tank 100 according to this embodiment may be maintained in a temperature range in which liquefied hydrogen is present in a solid-liquid mixed state, for example, at a temperature in the range of about 13 K to 21 K, 20 K or less, or 13 K to 14 K, by the heat inflow prevention unit.

[0058] Within this temperature range, at least a portion of liquefied hydrogen is present in a solid state denser than a liquid state and thus the liquefied hydrogen is present in a solid-liquid mixed state, preferably in the form of a slurry.

[0059] Density of liquefied hydrogen changes by about 1 kg/m.sup.3 in response to a temperature change of 1 K. For example, the liquefied hydrogen has a density of about 77 kg/m.sup.3 at a temperature of 14 K and a density of 77 kg/m.sup.3 at a temperature of 21 K.

[0060] In addition, the upper space of the storage tank 100 according to this embodiment may be maintained at the triple-point temperature of liquefied hydrogen by the heat inflow prevention unit.

[0061] When a portion of liquefied hydrogen stored in the storage tank 100, particularly the surface of the liquefied hydrogen, is allowed to be present in the form of a slurry, it is possible to suppress the tendency of liquefied hydrogen to evaporate, thereby allowing storage of hydrogen in a stable liquid state.

[0062] As a portion of the liquefied hydrogen begins to solidify, ortho-para conversion of the liquefied hydrogen is suppressed, thereby preventing liquid-to-gas phase change and further evaporation of the liquefied hydrogen and thus maintaining the liquefied hydrogen in a stable state. A portion of liquefied hydrogen stored in the storage tank 100, particularly, the surface layer of the liquefied hydrogen, may be allowed to be present in the form of a slurry by the upper heat exchanger 120.

[0063] The upper heat exchanger 120 solidifies a portion of liquefied hydrogen stored in the storage tank 100, specifically, liquefied hydrogen around the location of the upper heat exchanger 120. The upper heat exchanger 120 accordingly to this embodiment may be selectively activated when reactivity of the liquefied hydrogen stored in the storage tank 100 increases above a reference value or at a temperature lower than or equal to a specific temperature.

[0064] According to this embodiment, stable storage of hydrogen can be achieved by solidifying a portion of liquefied hydrogen stored in the large capacity storage tank 100, rather than the entirety of the liquefied hydrogen, using the upper heat exchanger 120 disposed in the upper space of the storage tank 100 as a solidification device inducing liquid-to-solid phase change of liquefied hydrogen, such that a portion of hydrogen in the storage tank is present in a solid state retaining a larger amount of cold heat, thereby maximizing retention of latent heat in the hydrogen.

[0065] Although some embodiments have been described herein, it should be understood by those skilled in the art that these embodiments are given by way of illustration only and the present invention is not limited thereto. In addition, it should be understood that various modifications, variations, and alterations can be made by those skilled in the art without departing from the spirit and scope of the present invention.

LIST OF REFERENCE NUMERALS

[0066] 100: Liquefied hydrogen storage tank [0067] 110: Floating plate [0068] 120: Upper heat exchange