SURFACE ACOUSTIC WAVE DEVICE WITH HIGH ELECTROMECHANICAL COUPLING COEFFICIENT BASED ON DOUBLE-LAYER ELECTRODES AND PREPARATION METHOD THEREOF

Abstract

A surface acoustic wave (SAW) device having a high electromechanical coupling coefficient based on double-layer electrodes and a preparation method thereof. A structure of the SAW device includes a Cu electrode, a piezoelectric film and an Al electrode on a substrate in sequence. A signal terminal of the Cu electrode is opposite to a ground terminal of the Al electrode. A ground terminal of the Cu electrode is opposite to a signal terminal of the Al electrode. Since Sezawa wave mode that is adopted is formed by coupling film thickness vibration and transverse vibration, a longitudinal electric field (in a direction of thickness of a film) and a transverse electric field (in a propagation direction of SAW) are excited through the double-layer electrodes so that the electromechanical coupling coefficient of the SAW device is improved by changing a coupling pattern between the electric fields and the piezoelectric film.

Claims

1. A SAW device, characterized in that, a Cu electrode, a piezoelectric film and an Al electrode are arranged on a substrate in sequence; and a signal terminal of the Cu electrode is opposite to a ground terminal of the Al electrode, and a ground terminal of the Cu electrode is opposite to a signal terminal of the Al electrode.

2. The SAW device according to claim 1, wherein, a thickness of the Cu electrode is 50-100 nm; and a thickness of the Al electrode is 50-100 nm.

3. The SAW device according to claim 1, wherein, the piezoelectric film is at least one of a ZnO film, an AlN film, a doped ZnO film, and a doped AlN film.

4. The SAW device according to claim 1, wherein, a thickness of the piezoelectric film is 100-1500 nm.

5. The SAW device according to claim 1, wherein, the substrate is a c-plane sapphire substrate, SiC or diamond.

6. The SAW device according to claim 1, wherein, a gap provided between the substrate and the piezoelectric film is filled with a silicon oxide film.

7. A preparation method of the SAW device, comprising steps in following 1) or 2): 1) depositing the Cu electrode, the piezoelectric film and the Al electrode on the substrate in sequence to obtain the SAW device according to claim 1; 2) depositing the Cu electrode and the silicon oxide film on the substrate in sequence, then depositing successively, after a surface of the silicon oxide film has been modified by polishing, the piezoelectric film and the Al electrode to obtain the SAW device.

8. The preparation method according to claim 7, wherein, the Cu electrode and the Al electrode are prepared through electron beam evaporation coating.

9. The preparation method according to claim 8, wherein, conditions of the electron beam evaporation coating include that: a temperature is 10˜100° C.; and a distance between a target and the substrate is 50-100 cm.

10. The preparation method according to claim 7, wherein, the surface of the silicon oxide film is modified through chemically mechanical polishing.

11. The preparation method according to claim 7, wherein, the silicon oxide film is prepared through radio frequency magnetron sputtering.

12. The preparation method according to claim 11, wherein, conditions of the radio frequency magnetron sputtering include that: a magnetron sputtering source is a plane target magnetron sputtering source; a power is 1000 W; a temperature is 20˜400° C.; a pressure of system is 0.5˜1.2 Pa; and a distance between a target and the substrate is 60-80 mm.

13. The preparation method according to claim 7, wherein, the piezoelectric film is prepared through radio frequency magnetron sputtering.

14. The preparation method according to claim 13, wherein, conditions of the radio frequency magnetron sputtering include that: a magnetron sputtering source is a plane target magnetron sputtering source; a power is 140 W; a temperature is 20˜400° C.; a pressure of system is 0.5˜1.2 Pa; and a distance between a target and the substrate is 60-80 mm.

15. (canceled)

16. The preparation method according to claim 7, characterized in that, a thickness of the Cu electrode is 50-100 nm; and a thickness of the Al electrode is 50-100 nm.

17. The preparation method according to claim 7, wherein, the piezoelectric film is at least one of a ZnO film, an AlN film, a doped ZnO film, and a doped AlN film.

18. The preparation method according to claim 7, wherein, a thickness of the piezoelectric film is 100-1500 nm.

19. The preparation method according to claim 7, wherein, the substrate is a c-plane sapphire substrate, SiC or diamond.

20. A method of preparation of a SAW filter having a high acoustic velocity and a high electromechanical coupling coefficient, comprising a step of using the SAW device according to claim 1 to prepare the said SAW filter.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0042] FIG. 1 is a schematic cross-sectional view of a SAW device of double-layer electrodes according to an embodiment of the present disclosure, in which 1—c-plane sapphire; 2—SiO.sub.2; 3—Cu; 4—ZnO; 5—Al.

[0043] FIG. 2 is a schematic diagram of acoustic velocity varying as a normalized thickness of piezoelectric film that is obtained by finite element method simulation.

[0044] FIG. 3 is a schematic diagram of an electromechanical coupling coefficient varying as a function of a normalized thickness of piezoelectric film that is obtained by finite element method simulation.

DETAILED DESCRIPTION OF THE EMBODIMENTS

[0045] Experimental methods used in the following embodiments are those routine methods in the art, unless otherwise specified herein.

[0046] Materials and reagents used in the following embodiments are available commercially, unless otherwise specified herein.

Embodiment 1

[0047] 1) A c-plane sapphire substrate having a 2 microns periodic interdigital electrode pattern is prepared by photolithography. After photolithography is applied, the substrate is placed in an electron beam evaporation coater, in which a vacuum system is enabled to evacuate to 9×10.sup.−6 Pa, a power of an electron gun is adjusted to 20%, and a target (purity: 99.999%) is cleaned for 5 min.

[0048] 2) After the power indicator is stable, a target baffle is opened, and an evaporation rate of Cu electrode material is 0.4 Å/s, and it is deposited 75 nm.

[0049] 3) After the evaporation is complete, the power supply is turned off. Then, fill the vacuum chamber of the electron beam evaporation coating machine with nitrogen until the pressure in the vacuum chamber reaches atmospheric pressure Then, the chamber is opened to take out the sapphire substrate, on which a Cu electrode has been prepared by the evaporation process.

[0050] 4) The substrate after lift-off process is placed into a magnetron sputtering chamber for growth of a silicon dioxide film. A radio frequency sputtering mode is selected, in which a distance between the target and the substrate is set to 70 mm, a power is set to 1000 W, an argon flow rate is set to 18 ml/min, an oxygen flow rate is set to 12 ml/min, and a gas pressure is stabilized at 0.5 Pa. Before the baffle is opened, pre-sputtering is performed for about 180 s, a sputtering time is controlled at 6 s, and it is deposited 75 nm.

[0051] 5) After the sputtering is completed, the power supply is turn off. Then, the magnetron sputtering vacuum chamber is filled with nitrogen until a pressure in the vacuum chamber becomes the atmospheric pressure, and then it is opened to take out the substrate. The surface of the silicon dioxide film is trimmed by chemically mechanical polishing to ensure flatness of the substrate during growth of ZnO

[0052] 6) A ZnO film is sputtered on the polished substrate surface. A radio frequency sputtering mode is selected, in which a distance between a target and the substrate is set to 70 mm, a power is set to 140 W, an argon flow rate is set to 18 ml/min, an oxygen flow rate is set to 10 ml/min, a gas pressure is stabilized at 0.8 Pa, and a temperature is stabilized at 350° C. Before the baffle is opened, pre-sputtering is performed for about 180 s, a sputtering time is controlled at 2250 s, and it is deposited 300 nm.

[0053] 7) An upper electrode pattern is prepared through photoetching nesting process so that a ground terminal of the upper electrode is opposite to a signal terminal of the lower electrode. Next, an Al upper electrode is prepared by electron beam evaporation coating, a specific process of which is similar to the above step 1), where an evaporation rate of Al was 0.5 Å/s and it is deposited 75 nm.

[0054] 8) The film prepared in the step 7) is peeled off in acetone to obtain a desired SAW device, a structural schematic diagram of which is shown in FIG. 1.

[0055] A SAW device of single-layer electrode (Al electrode, a thickness of which is the same as a thickness of the Al electrode of the double-layer electrode structure) is prepared according to the steps 1), 6) and 7) in Embodiment 1.

[0056] The performance of the above-prepared SAW devices of double-layer electrodes and of single-layer electrode are predicted through a COMSOL finite element simulation, respectively. A resulted schematic diagram of acoustic velocity varying as a function of a normalized thickness of a piezoelectric film is shown in FIG. 2. A resulted schematic diagram of an electromechanical coupling coefficient varying as a function of the normalized thickness of the piezoelectric film is shown in FIG. 3. It can be seen that, in the case that the normalized thickness ratio is 0.175, a maximum of the electromechanical coupling coefficient of the SAW device of double-layer electrodes of the present disclosure is about 7.5%. Although the SAW of single-layer electrode has a higher acoustic velocity, a maximum of the electromechanical coupling coefficient is only half of that of the double-layer electrode device. Therefore, the double-layer electrode structure provided by the present disclosure can, under the premise of ensuring high acoustic velocity, significantly improve the electromechanical coupling coefficient of the SAW device, which provides a practical solution for the future large-bandwidth SAW filter.

INDUSTRIAL APPLICATION

[0057] The present disclosure has the following beneficial effects.

[0058] Since the adopted Sezawa wave mode is formed by coupling film thickness vibration and transverse vibration, the present disclosure is characterized in that a longitudinal electric field (in a direction of thickness of a film) and a transverse electric field (in a propagation direction of SAW) are excited through the double-layer electrodes so that the electromechanical coupling coefficient of the SAW device can be improved by changing a coupling pattern between the electric fields and the piezoelectric film.