Method and System For Directly Heating A Protein-Enriched Milk Product By Introducing Steam Into Said Milk Product
20220378057 · 2022-12-01
Inventors
- Dennis Glinke (Hannover, DE)
- Ulrich Rolle (Everswinkel, DE)
- Jurgen Gehling (Stadtlohn, DE)
- Ludger Tacke (Velen, DE)
- Hubert Assing (Ahaus, DE)
Cpc classification
A23C3/0337
HUMAN NECESSITIES
A23C3/037
HUMAN NECESSITIES
A23C3/005
HUMAN NECESSITIES
International classification
Abstract
Directly heating a protein-enriched milk product occurs by introducing steam, the direct heating taking the form of an infusion or injection method. The described technique significantly extends service time, ensuring a content of non-denatured whey proteins in the treated protein-enriched milk product greater than that obtained in the prior art. The milk product, which is preheated and kept at temperature is indirectly cooled before direct heating by a recuperative cooling step from the preheating temperature to a cool-down temperature with a temperature difference ranging from 5 K to 10 K. The direct heating from the cool-down temperature to the high pasteurization temperature is controlled by direct heating setting parameters which are known per se. Finally, the milk product is cooled by flash cooling from the high pasteurization temperature to a necessarily required exit temperature.
Claims
1. A method for directly heating protein-enriched milk product by introducing steam into said milk product, wherein: (a) during direct heating, the steam heats the milk product to produce a germ-free state by means of direct high-temperature pasteurization to a high pasteurization temperature, (b) prior to the direct heating, the milk product is indirectly preheated to a preheating temperature and, following on from the preheating when viewed in the direction of flow of the milk product, a first instance of keeping the preheated milk product at temperature is carried out for a defined and controlled first dwell time, (c) following on from the direct heating to the high pasteurization temperature when viewed in the direction of flow of the milk product, a second instance of keeping the milk product at temperature is carried out for a defined and controlled second dwell time, (d) water in an amount corresponding to that of previously supplied steam is removed from the high-temperature pasteurized milk product that has been kept at temperature by flash cooling by means of decompression to a lower pressure, the milk product which is preheated and kept at temperature is indirectly cooled prior to direct heating by means of a recuperative cooling step from the preheating temperature to a cool-down temperature with a temperature difference in a range from 5 K to 10 K, the direct heating from the cool-down temperature to the high pasteurization temperature is controlled by means of direct heating setting parameters which are known per se and in accordance with feature (d), the milk product is cooled by flash cooling from the high pasteurization temperature to a necessarily required exit temperature.
2. (canceled)
3. The method according to claim 1, wherein: the temperature difference is 10 K.
4. The method according to claim 1, wherein: the direct heating setting parameters are pressure, temperature, and a duration of action of the steam.
5. The method according to claim 1, wherein: the direct heating is achieved by means of a per se known infusion method.
6. The method according to claim 1, wherein: the direct heating is achieved by means of a per se known injection method.
7. A system for directly heating a protein-enriched milk product by introducing steam into said milk product, comprising: a direct heating apparatus for the milk product for direct high-temperature pasteurization by means of steam to a high pasteurization temperature. a preheater that is arranged upstream of the direct heating apparatus when viewed in the direction of flow of the milk product and that serves to indirectly preheat the milk product to a preheating temperature, a first holding tube for a first instance of keeping the preheated milk product at temperature and arranged between the direct heating apparatus and the preheater, a first conveying apparatus arranged downstream of the direct heating apparatus for conveying the high-temperature pasteurized milk product, a second holding tube arranged downstream of the first conveying apparatus for a second instance of keeping the high-temperature pasteurized milk product at temperature, a vacuum apparatus arranged downstream of the second holding tube and in which water in an amount corresponding to that of previously supplied steam is subsequently removed from the high-temperature pasteurized milk product that has been kept at temperature by flash cooling by means of decompression to a lower pressure, and a cooler designed as a recuperator is arranged between the direct heating apparatus and the first holding tube, which cooler cools the preheated milk product down from a preheating temperature to a cool-down temperature by means of indirect cooling.
8. The system according to claim 7, wherein: the direct heating apparatus is designed in the form of a per se known infusion apparatus.
9. The system according to claim 7, wherein: the direct heating apparatus is designed in the form of a per se known injection apparatus.
10. The method according to claim 3, wherein: the direct heating setting parameters are pressure, temperature, and a duration of action of the steam.
11. The method according to claim 10, wherein: the direct heating is achieved by means of a per se known infusion method.
12. The method according to claim 3, wherein: the direct heating is achieved by means of a per se known injection method.
13. The method according to claim 4, wherein: the direct heating is achieved by means of a per se known infusion method.
14. The method according to claim 4, wherein: the direct heating is achieved by means of a per se known injection method.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0049] The invention is represented in more detail by the following description and the appended figures of the drawing and the claims. While the invention is realized in a wide variety of embodiments of a method of the generic type and in a wide variety of embodiments of a system of the generic type for carrying out the method, a preferred exemplary embodiment of the method according to the invention and of the system according to the invention are described in the following based on the drawing.
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DETAILED DESCRIPTION
[0060] A system 100 known from the cited prior art according to
[0061] An outlet opening on the lower end of the infusion apparatus 80 is connected via an outlet pipe 30 to a first conveying apparatus 10, for example a rotating positive displacement pump or a centrifugal pump, which is connected via a third product line portion 32 to a second holding tube 12 for a second instance HH2 of keeping the product at temperature for the purpose of maintaining the high pasteurization temperature T5=THE for a second dwell time Δt2. The second holding tube 12 leads via a fourth product line portion 34 to a vacuum chamber 14. The second conveying apparatus 10 conveys the high-temperature pasteurized milk product P that has been kept at the high pasteurization temperature THE from the infusion apparatus 80 to the vacuum chamber 14. The vacuum chamber 14 is designed to remove, by means of so-called flash cooling FK, from the milk product P being cooled by means of a pressure drop, the amount of water W that is supplied to the infusion apparatus 80 as steam D in the form of exhaust vapors, and to discharge said vapors via a vapor outlet 38 preferably arranged in the upper region. A milk product P treated in this manner exits the vacuum chamber 14 at an exit temperature T6=TA via a discharge line 36, which is arranged in the lower region of said chamber on a tapering base and which leads through a second conveying apparatus 16.
[0062] The milk product P to be heat-treated enters the system 100 via a milk product inlet 18 at a preheater 2 for preheating VE the product to the preheating temperature T1=TVE. The preheater 2 leads via a first product line portion 20 to a first holding tube 4 for the first instance HH1 of keeping the product at temperature for the purpose of maintaining the preheating temperature T2=TVE for a first dwell time Ad. The first holding tube 4 opens out into the headspace of the infusion apparatus 80 via a second product line portion 22 and the product inlet 28 downstream thereof. The preheater 2 is fed with a preferably regenerative heat transfer medium M via a heat transfer medium inlet 2a and a heat transfer medium outlet 2b.
[0063] As an alternative to the above-described infusion apparatus 80, the direct heating apparatus 8 of the system 100 (
[0064] A system 1000 according to the invention (
[0065] A cooler 6 designed as a recuperator is arranged between the direct heating apparatus 8, 80, 800 and the first holding tube 4, the product side of which cooler is guided via the second product line portion 22. The cooler 6 is supplied with a second coolant K2, preferably cold water, via a second coolant inlet 6a and a second coolant outlet 6b and it has the function of cooling down the milk product P that has been preheated and kept at temperature by a temperature difference ATK from the preheating temperature T2=TVE to a cool-down temperature T3=TK by means of indirect cooling K.
[0066] Experiments that serve to prove that the goals formulated with the object according to the invention have been achieved were carried out using the system 1000 according to the invention. Three of these experiments, which were carried out on consecutive days and which are denoted as Experiment I, II, and III, are referred to below with regard to a selection of relevant results and measured values.
[0067] Experiments I, II and III—Overview
[0068] The first experiment (without cooling K) used the process sequence according to
[0069] In Experiment I, the milk product P that has been preheated to the preheating temperature T2=TVE and kept at temperature is guided through the “inactive” cooler 6 via the second product line portion 22 without cooling K and supplied to the direct heating apparatus 8 designed as an infusion apparatus 80 at the preheating temperature T2=TVE.
[0070] In Experiments II and III, the milk product P that has been preheated to the preheating temperature T2=TVE and kept at temperature is in each case guided via the second product line portion 22 through the “active” cooler 6, where it is indirectly cooled K by the temperature difference ATK to the cool-down temperature T3=TK. The temperature difference ATK in Experiment II differs from that in Experiment III. The milk product P enters the direct heating apparatus 8 designed as an infusion apparatus 80 at the relevant cool-down temperature T3=TK.
[0071] All relevant temperatures and dwell times in Experiments I to III for the heat treatment of the protein-enriched milk product P, from the preheating VE in the preheater 2 at the preheating temperature T1=TVE to the treated milk product P in the discharge line 36 at an exit temperature T6=TA (
TABLE-US-00001 TABLE 1 TVE in TK in Experiment ° C. Δt1 in s ° C. THE in ° C. Δt2 in s TA in ° C. I 85 30 — 137.5 1 83 II 85 30 80 137.5 1 78.5 III 85 30 75 137.5 1 73
[0072] Experiment results
[0073] A selection of the measured values obtained in Experiments I to III is given in Table 2 below. The relevant heating indicators, namely non-denatured β-lactoglobulin and furosine, for estimating and monitoring the actual thermal load on milk products and their significance for the nutritional and sensorial quality of said milk products have already been addressed above. The associated measured values obtained in Experiments I to III are highlighted in gray in Table 2.
[0074] In
TABLE-US-00002 TABLE 2 Experiment I II III Without cooling With cooling With cooling TVE = 85° C./ TVE = 85° C./ TVE = 85° C./ Δt1 = 30s/without Δt1 = 30s/TK = 80° C./ Δt1 = 30s/TK = 75° C./ Raw K/THE = 137.5° C./ Raw THE = 137.5° C./ Raw THE = 137.5° C./ Constituents milk Δt2 = 1s/TA = 83° C. milk Δt2 = 1s/TA = 78.5° C. milk Δt2 = 1s/TA = 73° C. pH 6.75 6.77 6.75 6.78 6.76 6.80 (12° C.) (9° C.) (10° C.) (02° C.) (11° C.) (11 ° C.) Dry matter DM in % 12.15 11.47 11.67 11.01 11.49 10.33 Fat in % 0.08 0.161 0.08 0.13 0.09 0.11 Ash in % 0.96 0.90 0.93 0.86 0.91 0.81 Protein in % 6.38 5.98 6.11 5.72 6.02 5.38 β-LG in g/kg milk (*) 8.35 1.92 6.90 2.20 6.85 2.55 β-LG in g/kg protein (*) 130.9 32.1 112.9 38.5 113.8 47.4 Furosine in mg/kg milk Furosine in mg/100 g protein 2.66 9.44 2.78 9.39 2.66 8.36 Lactulose in mg/kg milk 9 53 8 44 6 50 (*): P-lactoglobulin (acid-soluble)
[0075] Result
[0076] The experiment results (Table 2) show that the indirect cooling K according to the invention in Experiment II (ΔTK=5 K.fwdarw.L/Lo=0.34) and in Experiment III (ΔTK=10 K.fwdarw.L/Lo=0.42) results in a desirable, unexpected, and surprising increase in the content of non-denatured β-lactoglobulin compared with Experiment I (without cooling K; ΔTK=0 K.fwdarw.L/Lo=0.25), wherein, under the other given process conditions in the system 1000, the cooling by ΔTK=10 K in Experiment III produces an optimal result (
[0077] In
[0078] Result
[0079] The experiment results (Table 2) show that the indirect cooling K according to the invention in Experiment II (ΔTK=5 K.fwdarw.F/Fo=3.38) and in Experiment III (ΔTK=10 K.fwdarw.F/Fo=3.14) results in a desirable, unexpected, and surprising decrease in the content of furosine compared with Experiment I (without cooling K; ΔTK=0 K 4 F/Fo=3.55), wherein, under the other given process conditions in the system 1000, the cooling by ATK=10 K in Experiment III produces an optimal result.
[0080] It cannot be established with certainty based on Experiments I to III whether the increase in the content of β-lactoglobulin and the decrease in the content of furosine are solely attributable to the indirect cooling K according to the invention prior to the direct heating DE. It cannot be excluded that the observed differences, which are desirable, unexpected, and surprising, are predominantly attributable to the indirect cooling K according to the invention and, if anything, to a rather small extent on the required stronger cooling of the protein-enriched milk product P during the flash cooling FK (different exit temperatures 78.5° C. and 73° C. for Experiments II and III, respectively, compared with TA=83° C. for Experiment I).
[0081] However, this uncertainty does not appear to be essential to the invention, especially because Experiments II and III must necessarily end at different exit temperatures TA with respect to each other and in each case with respect to Experiment I. Said exit temperatures necessarily result from the condition set wherein water in an amount corresponding to that of previously supplied steam is removed from the high-temperature pasteurized milk product that has been kept at temperature by flash cooling by means of decompression to a lower pressure. Ultimately, the indirect cooling according to the invention is also the cause of this situation and is responsible for its possible effects.
[0082] Water in an amount corresponding to that of previously supplied steam is removed from the high-temperature pasteurized milk product that has been kept at temperature by flash cooling by means of decompression to a lower pressure can only be fulfilled depending on the amount of steam (preferably saturated steam) supplied in each case during the direct heating DE in Experiments I to III and thus necessarily with accordingly assigned, different exit temperatures TA. The flash cooling FK also includes the removal of the amount of water that is necessarily required as compensation by the relevant indirect cooling K process from the preheating temperature TVE to the cool-down temperature TK (enthalpy decrease), again in the form of an adequate amount of steam D during the direct heating DE from the cool-down temperature TK to the high pasteurization temperature THE (enthalpy increase).
[0083] The exit temperatures TA assigned to Experiments I to III (see Table 1) must necessarily be different to fulfill the condition set wherein water in an amount corresponding to that of previously supplied steam is removed from the high-temperature pasteurized milk product that has been kept at temperature by flash cooling by means of decompression to a lower pressure.
[0084] Experiment I (without Cooling)
[0085] In order to remove the amount of water W that corresponds to the amount of previously supplied steam D for the heating, from the preheating temperature TVE=85° C. to the high pasteurization temperature THE=137.5° C., from the high-temperature pasteurized milk product P during flash cooling FK, a saturation pressure ps or corresponding absolute pressure (low pressure with respect to atmospheric pressure) that allows the milk product P to boil at a saturation temperature Ts(ps)=83° C., which also corresponds to the exit temperature TA, must be set in the vacuum apparatus 14 (see
[0086] Experiment II (with Cooling; Cooling from TVE=85° C. to TK=80° C.; ΔTK=5 K)
[0087] The cooling of the milk product P by a temperature difference ΔTK=5 K requires a corresponding dissipation of heat or enthalpy decrease from or in the milk product P. This enthalpy decrease in Experiment II must be compensated during the direct heating DE by an additional supply of steam, preferably saturated steam, compared with Experiment I in order to arrive at the same high pasteurization temperature THE as in Experiment I (THE=137.5° C.).
[0088] To prevent the milk product P from being “watered down” by the additional supply of steam in Experiment II, an amount of water corresponding to the additional amount of steam must be removed from the milk product P in the vacuum chamber 14 by means of the so-called flash cooling FK in the form of vapors. This process takes place when the milk product P is in a state of saturation.
[0089] Experiment III (with Cooling; Cooling from TVE=85° C. to TK=75° C.; ΔTK=10 K)
[0090] The cooling of the milk product P by a temperature difference ΔTK=10 K requires a corresponding dissipation of heat or enthalpy decrease from or in the milk product P. This enthalpy decrease in Experiment III must be compensated during the direct heating DE by an additional supply of steam, preferably saturated steam, in an even higher amount compared with Experiment I and thus in a higher amount than in Experiment II to arrive at the same high pasteurization temperature THE as in Experiment I and Experiment II (THE=137.5° C.).
[0091] To prevent the milk product P from being “watered down” by the additional supply of steam in Experiment III to an even greater extent than in Experiment II, an amount of water corresponding to the additional amount of steam must be removed from the milk product P in the vacuum chamber 14 by means of the so-called flash cooling FK in the form of vapors. This process takes place when the milk product P is in a state of saturation.
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[0096] The discernible darker areas on the end face of the suction nozzle in the black-and-white image in
[0097] The facts and results presented above in relation to the direct heating apparatus 8 designed as an infusion apparatus 80 can be applied analogously to a direct heating apparatus 8 designed as an injection apparatus 800 (
[0098] The following is a list of reference numbers used in the drawings and this description, which reference to the figures in which they first appear.
FIG. 1 (Prior Art)
[0099] 100 System according to the prior art [0100] 8 Direct heating apparatus [0101] 80 Infusion apparatus [0102] 800 Injection apparatus [0103] 2 Preheater [0104] 2a Heat transfer medium inlet [0105] 2b Heat transfer medium outlet [0106] 4 First holding tube [0107] 10 First conveying apparatus [0108] 12 Second holding tube [0109] 14 Vacuum apparatus [0110] 16 Second conveying apparatus [0111] 18 Milk product inlet (for milk product P to be treated) [0112] 20 First product line portion [0113] 22 Second product line portion [0114] 26 Steam inlet [0115] 28 Product inlet [0116] 30 Outlet pipe [0117] 32 Third product line portion [0118] 34 Fourth product line portion [0119] 36 Discharge line (for treated milk product P) [0120] 38 Vapor outlet [0121] 40 First coolant inlet [0122] 42 First coolant outlet [0123] D Steam [0124] DE Direct heating [0125] FK Flash cooling [0126] HE High-temperature pasteurization [0127] HH1 First instance of keeping at temperature [0128] HH2 Second instance of keeping at temperature [0129] IFV Infusion method [0130] IJV Injection method [0131] K1 First coolant [0132] M Heat transfer medium [0133] P Milk product (protein-enriched) [0134] TA Exit temperature (=T6) [0135] TVE Preheating temperature (=T1, T2) [0136] THE High pasteurization temperature (=T4, T5) [0137] VE Preheating [0138] W Water [0139] Δt1 First dwell time [0140] Δt2 Second dwell time
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FIGS. 6 to 10B
[0152] I First experiment (without cooling K) [0153] II Second experiment (with cooling K) [0154] III Third experiment (with cooling K)
TABLE-US-00003
indicates data missing or illegible when filed [0155] F Furosine (measured value in mg/100 g protein) [0156] Fo Furosine (measured value, reference value for normalization) [0157] F/Fo Furosine
[0158] (Normalized measured values in [mg/100 g protein]/[mg/100 g protein]=[1])
[0159] L Non-denatured β-lactoglobulin (measured value in g/kg protein)
[0160] Lo becomes
[0161] (Measured value, reference value for normalization) L/Lo Non-denatured β-lactoglobulin
[0162] (Normalized measured values in [g/kg protein]/[g/kg protein]=[1])
[0163] MR Maillard reaction (browning)
[0164] PF Fouling layer (product fouling; formation of deposits)