TEMPERATURE BARRIER COATING FOR RIM-ROTOR
20220381149 · 2022-12-01
Inventors
Cpc classification
C04B2235/3222
CHEMISTRY; METALLURGY
C08L79/08
CHEMISTRY; METALLURGY
C04B2235/3246
CHEMISTRY; METALLURGY
C04B2235/3225
CHEMISTRY; METALLURGY
F01D5/288
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/28
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D25/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02T50/60
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C04B2235/9607
CHEMISTRY; METALLURGY
F05D2300/20
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2230/90
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/3007
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C08L79/08
CHEMISTRY; METALLURGY
F01D5/284
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/18
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F01D5/28
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C04B35/48
CHEMISTRY; METALLURGY
F01D25/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D5/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A rim-rotor assembly has an annular structure including a composite rim and a hub. Blades project from the hub, tips of the blades contacting the annular structure, the blades configured to be loaded in compression against the annular structure. A thermal barrier is in the annular structure, the thermal barrier defining at least part of a radially inward surface of the annular structure. The tips of the blades contact the thermal barrier, the thermal barrier being a thermal barrier coating.
Claims
1. A rim-rotor assembly comprising: an annular structure including a composite rim; a hub; blades projecting from the hub, tips of the blades contacting the annular structure, the blades configured to be loaded in compression against the annular structure; and a thermal barrier in the annular structure, the thermal barrier defining at least part of a radially inward surface of the annular structure, the tips of the blades contacting the thermal barrier, the thermal barrier being a thermal barrier coating.
2. The rim-rotor assembly according to claim 1, wherein the annular structure includes a cooling ring between the composite rim and the thermal barrier.
3. The rim-rotor assembly according to claim 2, wherein the cooling ring defines cooling channels.
4.-6. (canceled)
7. The rim-rotor assembly according to claim 1, wherein the blades are connected to the hub by sliding joints, and are biased into compression against the annular structure.
8. The rim-rotor assembly according to claim 1, wherein the blades have a bottom segment connected to the hub, and a top segment against the annular structure, the bottom segment and the top segment interconnected by a translational joint.
9. The rim-rotor assembly according to claim 1, wherein the composite rim includes carbon fibers in a matrix.
10. (canceled)
11. The rim-rotor assembly according to claim 1, wherein the thermal barrier coating includes a layer of yttrium-stabilized-zirconia or of yttrium aluminum garnet.
12.-13. (canceled)
14. The rim-rotor assembly according to claim 11, wherein the layer is of yttrium-stabilized-zirconia, and has a density between 4.2 and 5.5 g/cc inclusively.
15. The rim-rotor assembly according to claim 1, wherein the layer is of yttrium aluminum garnet, and has a density between 3.2 and 4.2 g/cc inclusively.
16. (canceled)
17. The rim-rotor assembly according to claim 16, wherein the bond layer has a thickness ranging between 75 to 150 μm, inclusively.
18. The rim-rotor assembly according to claim 16, wherein the bond layer is MCrAlY or NiAl.
19. The rim-rotor assembly according to claim 16, wherein the bond layer has a porosity ranging between 5 to 15% inclusively.
20. The rim-rotor assembly according to claim 11, wherein the thermal barrier includes an anti-friction layer radially inward of the layer.
21. The rim-rotor assembly according to claim 20, wherein the anti-friction layer has a thickness ranging between 25 to 100 μm, inclusively.
22. The rim-rotor assembly according to claim 20, wherein the anti-friction layer is boron nitride.
23. The rim-rotor assembly according to claim 20, wherein the anti-friction layer is at discrete separate zones opposite the tips of the blades.
24. The rim-rotor assembly according to claim 11, wherein the tips of the blades include an anti-friction layer.
25. The rim-rotor assembly according to claim 1, wherein the thermal barrier is annular.
26. The rim-rotor assembly according to claim 25, wherein the thermal barrier has a uniform thickness.
27. The rim-rotor assembly according to claim 25, wherein the thermal barrier has a non-uniform thickness.
28.-29. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0047] Referring to the drawings and more particularly to
[0048] The annular surrounding structure may include a rim 101, also referred to as outer rim, or also as rim-rotor, though rim-rotor may include other annular components as expressed above and below. In a rim-rotor turbomachine, the rim 101 may generally have a diameter ranging from 7.5 cm and 80.0 cm. The rim 101 may be made of different materials. In an embodiment, the rim 101 is made of a composite material, the composite material being fibers in a polymer matrix. To maximize operational speed, minimize weight and provide structural rigidity, the fibers may be carbon fibers. For example, the carbon fibers may be a high modulus and/or high strength grade. A portion of the fibers (e.g. a substantial portion) may be oriented mostly tangentially (length of fibers along the circumference) to maximize the tangential properties of the composite rim 101. A lightweight matrix with proper compatibility with carbon fibers may be used to provide the properties required for high speed operation (e.g. RPM of 130,000, for a 400-500 m/s of tangential speed). A polymer matrix with high temperature resistance is preferred, from polymer families such as cyanate-ester, polyimide or phtalonitrile, but other polymers may be used depending on use conditions. As other possibilities, the rim 101 may be made of a ceramic matrix composite (CMC), a metal matrix composite (MMC), among possibilities.
[0049] As further part of the surrounding annular structure of the rim-rotor turbomachine 100, a cooling ring 102 may be integrally connected to the rim 101. The cooling ring 102 is positioned radially inward of the composite rim 101. The cooling ring 102 may include an air-cooled fin array and/or a conductive material, as detailed below. A low-conductivity layer or coating layer, referred to as a thermal barrier 103, may be integrally connected to the cooling ring 102 (if present) or to the composite rim 101. The thermal barrier 103 may be annular, and is radially inward of the composite rim 101 and of the cooling ring 102. In an embodiment, the surrounding annular structure of the rim-rotor turbomachine 100 includes the rim 101, the cooling ring 102 and the thermal barrier 103, from radially outward to radially inward. The thermal barrier 103 may define part or all of the radially inward surface of the surrounding annular structure. For example, the thermal barrier 103 may be discontinuous, such as where blades contact the surrounding annular structure (though the thermal barrier 103 may also be thicker at such locations).
[0050] In the rim-rotor turbomachine 100, the cooling ring 102 and the thermal barrier 103 define a structural insulation layer between a plurality of turbine blades 104 and the composite rim 101. This architecture may allow the use of ceramic material rated for high temperature use, for the blades 104. The blades 104 are mainly loaded in compression as retained by the composite rim 101 that takes the centrifugal loads in tensile stresses. The structural insulation between the blades 104 and the composite rim 101 must resist high compressive stresses while providing a high thermal gradient. The inner side, or hot side, of the thermal barrier 103 is in contact with the blades 104 at an elevated temperature, and the outer side, or cold side, must be below or near the composite maximum operating temperature, if the cooling ring 102 is present to contribute to cooling. To provide the high thermal gradient, the structural insulation layer may have the cooling ring 102 in the form of an air-cooled fins array that generates a radial heat flux, and the thermal barrier 103 being a low-conductivity layer or coating applied between the blades 104 and the cooling ring 102. The thermal barrier 103 must be strong in compression to transmit the centrifugal loads from the blades 104 to the cooling ring 102, and sufficiently compliant to follow the structural and thermal expansion of the cooling ring 102.
[0051] Referring concurrently to
[0052] To maintain the blade root 104B in contact with the sliding plane SP, an axial force may be applied on the blade 104, such as on a blade root backface. This axial force is created by the spring-mass retainer 106 in contact with the blade root 104 and with a retainer part 107, such as for instance a nut, or like abutment surface connected to the hub 105. The spring-mass retainer 106 imparts a spring effect resulting in an axial force on the blade roots 104B. To allow an axial relative position and motion of the blades 104 while maintaining contacts, the spring-mass retainer 106 may include radial cuts creating individual beam springs per blade, the beam springs projecting from a common spring-mass center ring. As the rim-rotor turbomachine 100 starts rotating, the blades 104 start moving axially, thereby reducing the spring preload. To ensure sufficient force is maintained on the blade roots 104B during high rotational speed, offset masses 106A may be added at the end of the spring beams, creating an angle between the spring head center of mass and the radial axis (in the Y-Z plane), and resulting in an increase of axial force on the blade root 104B when rotational speed increases. To ensure sufficient force is applied by the spring-mass during rotation, the mass head may be for example between 10 and 50% of the blade 104 with which it makes contact. The angle between the spring head center of mass and the radial axis may be between 3 degrees and 30 degrees. An angle of 15 degrees is well suited as it limits the radial forces being transferred while creating sufficient axial forces to maintain suitable assembly rigidity.
[0053] In an embodiment, the rim-rotor turbomachine 100 uses oxidation-resistant materials at gas temperature above 900 degrees C., such as ceramics for the blades 104 with compressive loading where maximal tensile stresses are at 40% or less than the maximal compressive stresses. The blades 104 will conduct a large heat flux to the components in thermal communication. Due to the low centrifugal forces experienced by the hub 105, the hub 105 can be made of an oxidation-resistant material at gas temperature above 900 degrees C., with a tensile strength above 100 MPa at temperature above 900 degrees C. (e.g., ceramics and/or ceramic-metal matrix composites and/or ceramic-matric composites, as compared to metallic alloys). In cases where small axial displacements are made possible (for example when a high-angle sliding plane angle is used), the low flexibility requirement of the spring-mass may allow the spring-mass retainer 107 to be made of high temperature materials like ceramic. In the depicted case, where higher flexibility of the spring component may be required due to the lower sliding plane angle, a metallic material, such as a nickel or titanium super-alloy providing sufficient strength and oxidation and creep resistance, can be used. An insulation piece or layer may be provided between the spring-mass retainer 107 and the blade roots 104B, such as a ceramic coating, or a low conductivity ceramic pad or ball, thereby reducing the spring-mass air cooling requirement. The insulation has a secondary benefit of increasing the resistance to lateral friction at the contact point between the spring-mass retainer 107 and the blades 104 by increasing the hardness by at least 50%.
[0054] In a specific embodiment, the thermal barrier 103 may include a coating referred as Thermal Barrier Coating (TBC). The TBC is applied on the inner face of the cooling ring 102, effectively reducing both the conduction between the blades 104 and the cooling ring 102 and the heat transfer by convection between the hot gases flowing through the blades 104 and the cooling ring 102. The thermal barrier 103 may include various layers (the layers being for instance annular), such as a bond coat 108, a top coat 109 and a low-friction coat 110. The thickness of the thermal barrier 103 is selected to provide sufficient thermal insulation while limiting the added weight that would add to the supporting annular structure of the rim-rotor turbomachine 100. The density, the thermal conductivity and the compressive strength of the thermal barrier are therefore important characteristics to provide adequate rim-rotor turbomachine performance. The top coat 109 may be a ceramic top coat with different base materials and mixtures. In a variant, the top coat 109 is yttrium-stabilized-zirconia (YSZ). In another variant, the top coat 109 may be yttrium aluminum garnet (YAG). In an embodiment, the top coat 109 has thickness of 300 μm up to 1500 μm, inclusively, though the thickness of the top coat 109 may be outside this range as well. The top coat 109 may have a porosity level between 10 and 30%, inclusively. If the top coat 109 is a YSZ coat, a density may range between 4.2 and 5.5 g/cc inclusively, while the range of density for a top coat of YAG is 25% lower than that of the YSZ coat, between 3.2 and 4.2 g/cc inclusively. Properties suitable are a thermal conductivity of around 1 W/Km, a mechanical compressive strength of at least 500 MPa and a minimum strain of 0.5% before cracking/spalling to limit heat conduction and resist mechanical stresses. To improve adhesion of the top coat 109 to the base material of the cooling ring 102 and/or to increase corrosion resistance, the bond coat 108 may be applied, as for example a bond coat of MCrAlY (Nickel/Cobalt-Chrome-Aluminium-Yttria), NiAl (Nickel-Aluminium) or other mixtures. A thickness of the bond coat 108 may range from 75 to 150 μm, inclusively. The bond coat 108 applied may have a 5 to 15% porosity, inclusively, to provide strain resistance, to better match thermal elongation of the top coat 109 relative to the cooling ring 102, and to increase the adhesion of the top coat. The coatings used for the bond coat 108 and/or top coat 109 can be applied by different methods, for example air plasma spray (APS), high velocity oxygen fuel (HVOF) or physical vapor deposition (PVD), providing a layer of porous material. The structure of the layer of bond coats 108 and/or top coat 109 are arranged in order to provide sufficient compression resistance for the compressive loads associated with operation of the rim-rotor turbomachine 100.
[0055] In a specific embodiment, an additional layer is part of the thermal barrier 103, radially inward of the top coat 109. The additional layer is of low-friction dry lubricant 110 applied to reduce the friction coefficient between the tip of the blade 104 and the surrounding annular structure. Indeed, due to mismatch in thermal expansion between the blades 104 and the supporting annular structure, sliding may be required to reduce the tensile stresses in the blades 104 imposed by thermal conditions. Reducing the coefficient of friction at the blade tip with a dry lubricant coating layer 110, such as boron nitride or other dry lubricants, may reduce blade stresses and hence increase a durability of the blades 104. The dry lubricant coating layer 110 may be applied by aerosol, painting, air plasma spray or by other methods. A thickness of the layer 110 may range from 25 to 100 μm, inclusively, though the thickness of the layer 110 may be outside of this range. As this coat 110 is at the interface between the blades 104 and the surrounding annular structure, application of the anti-friction coat may be localized at the blade contact, or even directly applied on the blade tip, discrete separate zones. Therefore, the layer 110, if present, may not be continuously annular.
[0056] In another embodiment, the cooling ring 102 and the thermal barrier 103 may both be made with a TBC, where if required, fins would be made within the TBC itself. Hence, the cooling ring 102 and the thermal barrier 103 could also form a single part made from TBC. The expression “fins” pertains to surfaces separated by void enabling air impingement for cooling. Other expressions that could be used to define such features include channels, heat-exchange surfaces, concavities, walls, etc. The geometries of the fins are designed to create an increased heat exchange surface area with the cooling air while being large enough to support the compressive loading. The fins may be continuous or cut along the flow path, possibly resulting in an array of pins in specific arrangement. The passage area created between adjacent fins (channel width) may vary along the channel line to control pressure losses and heat transfer. A width of a channel or space between fins may be 200 to 800 μm, inclusively, as an example. Fins of 500 to 2000 μm may be used, inclusively, and as an example. The channels may go from axial face to axial face of the cooling ring 102, whether in a straight path or a helical path. The channels define the fins, the fins separating the channels.
[0057] In another variant, the cooling ring 102 may be made of high strength composite material, possibly joined within the outer composite rim 101, with the thermal barrier 103 applied at the inner circumference. Stated differently, the cooling ring 102 could be part of the composite rim 101, for instance by having the same material. Suitable materials include carbon-fiber-polymer composite such as high modules and/or high strength carbon fiber and high temperature polymer (e.g., cyanate ester, polyimide, phtalonitrile).
[0058] In another variant, the cooling ring 102 may be made from a metallic annular part where the array of fins, such as for example defined on the outer surface of the cooling ring 102, are made in insulating material such as a TBC (YSZ, YAG, etc), effectively creating low conductivity fins. A possible manufacturing method would be to apply a TBC on both surfaces of the metallic annular part and machine channels in the outer TBC layer to create the fins or like heat-exchange surfaces. Another metallic layer could be introduced between those TBC fins and the composite rim 101 for structural integrity.
[0059] Ceramic material for the blades 104 is selected to operate at high temperature, supporting stresses at temperatures higher than metallic blades. In case the blade temperature exceeded the oxidative or corrosion limits of the ceramic, environmental barrier coatings (EBC) could be applied on the blade surfaces in contact with the hot gases.
[0060] The thermal heat flux reaching the cooling ring 102 are from two main sources, by the conduction from the blades 104, and by the hot gas convection with the exposed surface of the supporting annular structure between the blades 104. The thickness of the thermal barrier 103 may be uniform as shown in
[0061] Referring to
[0062] Referring to
[0063] Referring to
[0064] For simplicity, a two-segment blade will be described and may be composed of a superior blade segment 202, i.e., radially outward, and an inferior blade segment 203, i.e., radially inward. The superior blade segment 202 may be made of ceramics, high temperature metallic alloy, or the like. The superior blade segment 202 may be supported by the peripheral annular structure defined by a high-strength composite rim-rotor 205, that may have the same construction as for the embodiments of
[0065] Referring to
[0066]
[0067]
[0068] Referring now to
[0069] The superior and inferior blade segments 202 and 203, respectively, may be made from different materials, such as metallic super-alloys, monolithic ceramics, ceramic matrix composites (CMCs) or any other appropriate material. For an application in a gas turbine where the gas temperature is above the operating temperature of the blades 201, blade cooling may be necessary. In-blade convective cooling with cooling air flowing through the blades 201 can be used, i.e., with the blades being hollow for air to circulate therein. A thermal barrier coating may be applied on the outer surfaces of the blades to further increase the cooling effectiveness, and therefore the inlet temperature capability of the rim-rotor turbomachine 200. For the superior blade segment 202, cooling air may be routed from the air-cooled fins of the cooling ring 209 to the blade internal cooling passages. Air may exit the blades 201 with small holes to create film-cooling around the blade surface and further extend the cooling system effectiveness.
[0070] In a first aspect, the present disclosure provides a gas turbine that uses a rim-rotor configuration to allow the use of ceramics under compression. The rim-rotor turbine comprises a high-strength composite rim-rotor, an insulating layer made of ceramic or metallic alloy or composite material, ceramic or high temperature alloy aerodynamic blades, and a hub. A thermal barrier coating (TBC) is used at the interface of the blades and the outer supporting structure to reduce the heat flux going towards the composite rim-rotor.
[0071] In a second aspect, the present disclosure provides a gas turbine configuration that uses a rim-rotor configuration to allow the use of ceramics under compression. The rim-rotor turbine comprises a high-strength composite rim-rotor, ceramic or high temperature insulating layer, ceramic or high temperature alloy aerodynamic blades, and a hub allowing sliding and/or relative movement of the blades and/or deformation of the hub. A TBC is used to reduce the cooling mass flow in the insulation layer. The TBC may have an over thickness at the interface with blade tips, for further insulation from the heat conducted from the ceramic blades.
[0072] In a third aspect, the present disclosure provides a gas turbine configuration that uses a rim-rotor configuration to allow the use of extended turbine blade. The rim-rotor turbine comprises a high-strength composite rim-rotor, ceramic or high temperature insulating layer, ceramic or high temperature alloy aerodynamic blades, and a hub, where the blades are supported by both the base and the tip. The superior portion of the blade is supported by the outer rim-rotor through compressive loading, and the hub supports the inferior section of the blade by tensile loading. This configuration allows an increase in both the blade length and tip speed compared to state-of-the-art turbines.
[0073] The variants described herein for the rim-rotor turbomachine 100 and rim-rotor turbomachine 200 may enable the increase of the working fluid temperature in Brayton cycles and variants, to achieve high efficiency and high power density.